Zwitterionic Surfactant-Dye Complex for Hair Color Fastness

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Solution Overview

Problem

Current hair dye technologies face challenges in achieving uniform and long-lasting color, especially on pre-treated hair with varying damage levels, as direct dyes lack fastness properties and oxidation dyes can cause fiber damage and skin sensitization.

Innovation Solution

A combination of cationic anthraquinone dyes with zwitterionic surfactants in a cosmetic carrier, optimized for both application and dyeing performance, to enhance color uniformity and fastness to washing.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If direct dyes are used for hair coloring, then gentler application conditions are achieved, but fastness properties against washing and external influences are insufficient

Engineering Contradiction:
Improvefiber damageVSAvoidfastness properties
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent combines direct dyes with zwitterionic surfactants to create a composite coloring composition. The zwitterionic surfactant acts as a coupling agent that bridges the direct dye and the keratin fiber, forming a stable complex that maintains the gentle application conditions of direct dyes while significantly improving wash fastness and resistance to external influences.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The zwitterionic surfactant serves as an intermediary substance between the direct dye and the hair fiber. It has both hydrophilic and hydrophobic properties, allowing it to interact with both the water-soluble direct dye and the keratin structure, thereby anchoring the dye more securely to the fiber without requiring harsh oxidizing agents.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If oxidation dyes are used to achieve intense colors with good fastness, then fastness properties are improved, but fiber damage and skin sensitization occur

Engineering Contradiction:
Improvefastness propertiesVSAvoidfiber damage
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent extracts and eliminates the harmful oxidizing agents from the dyeing process while retaining the desired fastness properties. By using direct dyes combined with zwitterionic surfactants, the composition achieves oxidation-like fastness without the damaging effects of hydrogen peroxide and other oxidants on the hair fiber and skin.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The zwitterionic surfactant converts the typically weak binding of direct dyes into a strong, durable attachment. What would normally be a disadvantage (the gentle but weak binding of direct dyes) is transformed into a benefit through the surfactant's ability to form stable complexes that resist washing and external influences.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Ease of operation

If direct dyes are applied to pre-treated hair with varying damage levels, then application is simplified, but uneven color distribution occurs

Engineering Contradiction:
Improveapplication simplicityVSAvoidcolor uniformity
Core Design Contradiction:
Ease of operationVSManufacturing precision

Solution Approach 1:

The zwitterionic surfactant provides local adaptation to different hair conditions. It can adjust its interaction with the keratin fiber based on the local state of the hair, whether virgin, bleached, or permed. This allows the composition to achieve uniform color distribution across hair with varying damage levels while maintaining simple application procedures.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The combination provides brilliant, intensive, and uniform color results that persist after repeated washing, even on hair with different damage levels, while minimizing skin sensitivity and fiber damage.

Implementation Method 1

combinations of certain cationic anthraquinones as direct dyes with zwitterionic surfactants lead to colorations that solve the task to an outstanding degree

Methodology Applied
Scientific EffectElectrostatic interaction: Ion Repulsion/Attraction

Data Source

PatentEP2793819B1Colouring composition with direct dyes and zwitterionic surfactants
Publication Date: 2019.01.02 HENKEL KGAA
  • EP2793819B1 patent drawing
  • EP2793819B1 patent drawing
  • EP2793819B1 patent drawing

AI summary

The invention provides a composition for colouring keratin fibres that comprises (a) at least one compound of the formula (I) and (b) at least one zwitterionic surfactant.