Flame-retardant heat-insulating material for battery cell and preparation method of flame-retardant heat-insulating material

By preparing cellulose aerogels containing epoxy crosslinking agents and borate ester modified benzoxazine flame retardants, the problem of poor flame retardant performance of cellulose aerogels was solved, and a highly efficient flame retardant and heat insulation effect was achieved.

CN121021935AActive Publication Date: 2025-11-28JIANGXI LIWEN NEW ENERGY TECH CO LTD
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Patent Information

Application Number
CN202511369628.3
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2025-09-24
Publication Date
2025-11-28
Estimated Expiration
2045-09-24

AI Technical Summary

Technical Problem

In existing technologies, cellulose aerogels have poor flame retardant properties, which limits their application in power battery cells.

Method used

A flame-retardant and heat-insulating material was prepared by adding sodium hydroxide, urea, and water to a cellulose solvent, stirring and mixing, pre-cooling, adding an epoxy crosslinking agent, a borate-modified benzoxazine flame retardant, and sodium montmorillonite, ultrasonically dispersing, gelling, and freeze-drying.

Benefits of technology

It forms a three-dimensional network structure and a transparent glassy coating, which prevents the transfer of oxygen and heat, interrupts the combustion chain reaction, forms a dense protective layer, and improves the flame retardant properties of the material.

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Abstract

The invention relates to the technical field of thermal insulation materials, and discloses a flame-retardant thermal insulation material for a battery cell and a preparation method of the flame-retardant thermal insulation material. According to the invention, cellulose is subjected to dissolution, crosslinking and flame-retardant modification, and gel forming and drying, such that the flame-retardant thermal insulation material for the battery cell is obtained. An active intermediate released by an oxazine ring during ring-opening polymerization at a high temperature can catalyze a cross-linking reaction between molecular chains to form a three-dimensional network structure, so that the flame retardant property of the material is improved; boric acid ester is decomposed at a high temperature to generate boric oxide or boric acid, a transparent glassy coating is formed after melting, the surface of the material is tightly covered, oxygen and heat transfer are physically blocked, and the flame-retardant effect is achieved; phosphorus-containing free radicals generated by decomposition of phosphate can be combined with active free radicals in flames, so that a combustion chain reaction is interrupted, the flame temperature is reduced, and the flame retardant property of the material is further improved. And non-combustible or flame-retardant substances such as silicon dioxide generated by decomposition of silane can form a compact protective layer on the surface of the material, so that flame propagation is prevented, and a flame-retardant effect is achieved.
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