Additives for build materials and related printed 3D articles

By adding cyclopolymerizable functional group additives to polymerizable liquids for 3D printing, the mechanical integrity and durability of UV curable acrylate formulations are enhanced, addressing the issues of fracture and degradation in existing 3D printed articles.

JP7763265B2Active Publication Date: 2025-10-313D SYSTEMS INC
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Patent Information

Application Number
JP2023563977
Authority / Receiving Office
JP · JP
Patent Type
Patents
Current Assignee / Owner
Priority Date
2021-05-07
Filing Date
2022-05-05
Publication Date
2025-10-31
Estimated Expiration
2042-05-05

AI Technical Summary

Technical Problem

3D printed articles made from UV curable acrylate formulations often lack desirable mechanical properties and are prone to fracture or degradation, leading to premature failure.

Method used

Incorporating additives with cyclopolymerizable functional groups separated by aliphatic or alkylene oxide linkers into polymerizable liquids, which can include oligomeric or monomeric curable materials, and using photoinitiators for polymerization via free radical mechanisms to enhance structural reinforcement.

Benefits of technology

The resulting 3D articles exhibit improved mechanical properties, including tensile modulus, tensile strength, and resistance to hydrolysis, with enhanced durability and resistance to degradation.

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Abstract

Described herein are additives for three-dimensional printing materials or inks that, in some embodiments, can impart one or more structural improvements to articles printed from the printing materials. In one aspect, a polymerizable liquid includes at least one additive that includes a plurality of cyclopolymerizable functional groups separated by an aliphatic linker or an alkylene oxide linker.
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