Conjugated polymer composition, its products and method for forming adduct of conjugated polymer and dopant

By using epoxy resin, amino or amido hardener, polyaniline and dopant compositions in the coating, the problems of limited service life of corrosion inhibitors and environmental pollution in the prior art are solved, and efficient self-repair and corrosion resistance are achieved.

CN116323760BActive Publication Date: 2025-03-21THE BOEING CO
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Patent Information

Application Number
CN202180068545.4
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Priority Date
2021-08-20
Filing Date
2021-10-04
Publication Date
2025-03-21
Estimated Expiration
2041-10-04

AI Technical Summary

Technical Problem

In the prior art, corrosion inhibitors commonly used in coatings for preventing metal corrosion, such as chromate, have environmental pollution risks and have limited service life, making it difficult to meet the needs for corrosion resistance and long-term protection.

Method used

A composition is provided, including an epoxy resin, an amino or amido hardener, a polyaniline, a dopant and a pigment, which is coupled to a dopant, capable of releasing the dopant "on demand" in a corrosive environment, providing a self-healing function.

Benefits of technology

The composition can significantly improve the corrosion resistance and barrier properties of metal substrates, extend the service life of the coating, and reduce the risk of pollution to the environment.

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Abstract

The present disclosure provides a composition, an article thereof, and a method for forming the composition. In at least one aspect, the composition comprises (1) an epoxy resin; (2) an amino or amido hardener; (3) polyaniline; (4) a dopant selected from a triazole compound, a thiazolyl compound, a quinoline compound, a salicylic acid compound, a benzoic acid compound, an glycolic acid compound, a phosphoric acid compound, a sulfonate, or a combination thereof; and (5) a pigment selected from titanium dioxide, silicon dioxide, talc, mica, aluminum stearate, or a combination thereof. The polyaniline + dopant accounts for less than 6% by weight of the total volume of the composition. The present disclosure provides a substrate having the composition disposed thereon. In at least one aspect, the method comprises introducing an acid form of polyaniline into a hydroxide to form a polyaniline hydroxide. The method comprises introducing a dopant into a polyaniline hydroxide to form a doped polyaniline.
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