Modified lithium battery diaphragm and preparation method thereof

By applying a ceramic coating containing potassium sodium tartrate on the lithium battery separator, failure and short-circuit problems caused by metal impurities in the battery are solved, the stability and safety of the battery are improved, and its service life is extended.

CN119725994APending Publication Date: 2025-03-28TIANJIN DG MEMBRANE
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Patent Information

Application Number
CN202411433018.0
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2024-10-15
Publication Date
2025-03-28

AI Technical Summary

Technical Problem

Existing lithium batteries may introduce metal impurities in the electrolyte during the manufacturing process, resulting in reduced battery life and circulation efficiency, and there is a risk of failure and short circuit.

Method used

A modified lithium battery separator with ceramic coating containing potassium sodium tartrate on the PE or PP base film is used to form a soluble complex with metal ions such as copper and iron in the electrolyte to reduce free metal impurities.

Benefits of technology

It significantly reduces the content of metal impurities inside the battery, improves the stability and safety of the battery, extends the cycle life, reduces the risk of short circuits, and improves the mechanical strength and durability of the diaphragm.

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Abstract

The invention relates to the field of batteries, and discloses a modified lithium battery diaphragm which comprises a ceramic coating containing sodium potassium tartrate tetrahydrate and coated on a PE (polyethylene) or PP (polypropylene) base membrane, the ceramic coating is prepared from the following components in parts by mass: 40 to 60 parts of ultrapure water, 30 to 45 parts of a ceramic material, 0.1 to 0.8 part of a dispersing agent, 1.2 to 3.6 parts of sodium potassium tartrate tetrahydrate, 6 to 12 parts of nano cellulose, 1.4 to 3.2 parts of an adhesive and 0.1 to 0.2 part of a wetting agent. Soluble complexes are formed by the potassium sodium tartrate and metal ions such as copper and iron in the electrolyte, so that the content of metal impurities in the battery is remarkably reduced. Compared with the technical scheme that the metal impurities in the electrolyte cannot be effectively controlled in the prior art, the problems of battery failure and short circuit risk caused by the metal impurities are successfully solved, the reliability of the battery is improved, and the service life of the battery is prolonged.
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