Low-temperature rare earth-based denitration catalyst with nano synapse structure as well as preparation method and application of low-temperature rare earth-based denitration catalyst

By using nanosynaptic structure low-temperature rare earth-based denitrification catalysts in the steel sintering industry, the problem of insufficient catalytic activity and anti-toxicity ability of existing catalysts in low-temperature environments is solved, and efficient NOx denitrification and anti-hydrosulfur poisoning performance is achieved.

CN119733500AActive Publication Date: 2025-04-01NANJING TECH UNIV +2
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Patent Information

Application Number
CN202510080102.7
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2025-01-19
Publication Date
2025-04-01
Estimated Expiration
2045-01-19

AI Technical Summary

Technical Problem

The existing low-temperature denitrification catalysts are insufficient in the steel sintering industry, especially in the low-temperature environment, and are susceptible to water and ammonium bisulfate poisoning.

Method used

A low-temperature rare earth-based denitrification catalyst was used for nanosynaptic structures. It was prepared by a combination of titanium dioxide with nanosynaptic structures as the support, a composite oxide combining cerium oxide and yttrium oxide as the active component, and a composite oxide of priserodymium oxide and samarium oxide as the co-catalyst.

Benefits of technology

The catalyst exhibits efficient NOx denitrification performance at low temperatures, with a denitrification efficiency of more than 90%. It also has strong anti-water sulfur poisoning properties, extending the service life of the catalyst.

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Abstract

The invention discloses a preparation method and application of a low-temperature rare-earth-based denitration catalyst with a nano-synapse structure, and the catalyst takes titanium dioxide with the nano-synapse structure as a carrier, takes a composite oxide of cerium dioxide and yttrium oxide as an active component, and takes a composite oxide of praseodymium oxide and samarium oxide as a cocatalyst. Aluminum oxide is used as a synaptic forming agent, succinic acid is used as a morphology control agent, and a low-temperature hydrothermal-alkali liquor ablation-impregnation loading combined method is adopted for preparation. The catalyst synthesized by the method has the advantages of large specific surface area, sufficient exposure of active sites, strong water and sulfur poisoning resistance and the like, and can achieve the goal of ultralow emission of nitrogen oxides under the low-temperature flue gas working condition in the steel sintering industry.
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