Fluororesin and preparation method thereof, holographic recording medium and holographic optical element

By using hydroxyl-terminated fluororesin in photopolymers and introducing fluorine elements through RAFT polymerization technology, the problem of insufficient refractive index difference between the existing photopolymer film-forming resin and the writing monomer is solved, and the holographic recording performance and material resistance are significantly improved.

CN119735726APending Publication Date: 2025-04-01ZHUHAI MOJIE TECH CO LTD
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Patent Information

Application Number
CN202411711853.6
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2024-11-26
Publication Date
2025-04-01

AI Technical Summary

Technical Problem

The difference in refractive index between the existing photopolymer film-forming resin and the writing monomer is insufficient, resulting in poor holographic recording performance of photopolymers, and the high temperature, low temperature, oil and chemical media resistance of the material also needs to be improved.

Method used

A hydroxyl-terminated fluororesin is used as a component of the film forming resin and is prepared by fragmentation and addition radical polymerization (RAFT) technology. The fluorine element is introduced to reduce the refractive index of the film forming resin and increase the refractive index difference with the writing monomer.

Benefits of technology

It significantly improves the holographic recording performance of photopolymers, enhances the photosensitive sensitivity and diffraction efficiency, and improves the material's high temperature resistance, low temperature resistance, oil resistance and chemical media resistance.

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Abstract

The present application discloses a hydroxyl-terminated fluororesin and a preparation method thereof, a photopolymer-type holographic recording medium and a holographic optical element. The hydroxyl-terminated fluororesin has a structural formula such as G1-G3; the photopolymer-type holographic recording medium comprises a film-forming resin, and the film-forming resin comprises at least one of the hydroxyl-terminated fluororesins G1-G3 and a polyisocyanate-based compound. In this way, the refractive index difference between the film-forming resin and the writing monomer can be increased, and the holographic recording performance of the photopolymer can be effectively improved.
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