PH double-response type concrete multifunctional admixture and preparation method thereof

By preparing a pH-responsive, multifunctional concrete admixture, and utilizing a composite hybrid particle and dispersion system, the stability and functional release issues of polycarboxylate superplasticizer during compounding were resolved, thereby improving the stability and performance of concrete.

CN122444449APending Publication Date: 2026-07-24SHANDONG HIGHWAY & BRIDGE CONSTR GRP TRANSPORTATION DEV CO LTD
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Patent Information

Application Number
CN202610878630.1
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2026-06-17
Publication Date
2026-07-24

AI Technical Summary

Technical Problem

Existing polycarboxylate superplasticizers have problems such as excessively high viscosity, easy deterioration, and shortened setting time when compounded with other components. They cannot coexist stably and release functional components in an orderly manner according to changes in the internal environment of concrete, which affects concrete performance and construction effect.

Method used

A pH-responsive, multifunctional concrete admixture is used. By preparing a composite hybrid particle and dispersion system, the release of functional components is controlled by pH sensitivity to ensure stability and functionality under acidic and alkaline conditions, including the formation of water retention and early strength in concrete.

Benefits of technology

It achieves stability and low viscosity in the polycarboxylate superplasticizer system, ensuring good performance of the mixture, avoiding the adverse effects of early strength requirements on construction time, solving the instability of functional components under acidic conditions, and meeting the performance requirements of concrete at different stages.

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Abstract

The invention discloses a PH double-response type concrete multifunctional admixture and a preparation method thereof. The preparation method of the multifunctional concrete admixture comprises the following steps: firstly, adding carboxymethyl chitosan, chitosan, nano silicon dioxide, cellulose acetate, N, N '-methylene bisacrylamide, an ammonium persulfate / tetramethylethylenediamine mixture and nano calcium silicate hydrate into an acetic acid solution, and performing ultrasonic continuous dispersion to obtain hybrid particles; secondly, a polycarboxylate superplasticizer, acrylamide, sodium alginate and the nano halloysite particles are magnetically stirred to be uniform, and a mixed dispersion solution is formed; and finally, adding the hybrid particles into the mixed dispersion solution to obtain the multifunctional concrete admixture. The concrete admixture can be kept stable under the storage condition of a polycarboxylic acid water reducer solution, and the viscosity of concrete is not increased after the concrete admixture is added into the concrete, so that the concrete admixture keeps good mixture performance, and good water retention and early strength effects are achieved.
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