5773 results about "Meth-" patented technology

A fully curable jettable composition having a viscosity less than 30 cps at a temperature within the range of 15-180° C., more preferably at a temperature of 15-100° C., e.g. 60-80° C. the composition comprising: (A) at least one low viscosity reactive resin selected from the group consisting of compounds containing an oxetane ring, cycloaliphatic epoxy resins, tetrahydrofurans, hexahydropyrans and mono-functional (meth)acrylates, said resin having a molecular weight of not greater than 300 Daltons, e.g. 250 Daltons or less, and a viscosity at a temperature in the said range of less than 30 cps, e.g. 5 to 15 cps; (B) at least one higher viscosity resin selected from the group consisting of epoxy resins, compounds containing an oxetane ring and acrylates, which resin acts to thicken the low viscosity resin and strengthen a jetted deposit of the composition, the higher viscosity resin having: a viscosity greater than twice that of the low viscosity resin at the said temperature in the range stated above, and a functionality of greater than or equal to 2; (C) at least one curable toughener, preferably having a functionality of at least 2, such as hydroxy, epoxy, acrylic or other reactive functionalised polymer/oligomer (e.g. derived by functionalising poly(tetrahydrofuran), polycaprolactone, polycarbonate diol, or a dendrimeric polyol; (D) at least one initiator for the polymerisation of the resins, and (E) at least one stabiliser for delaying the curing of the resins of the composition; wherein the low viscosity resin is slower to react than the higher viscosity resin and acts to solvate the higher viscosity resin prior to curing and at least partly during curing and wherein at least 30% of the components A and B are cationically curable resins. The composition can be jetted from piezo electric printing heads under the control of a computer program to form a multi-layered article, e.g. a three dimensional article, in which the adjacent droplets merge and are cured homogeneously together.

The invention provides a controlled release bioactive agent delivery device that includes a body member having a direction of extension, a longitudinal axis along the direction of extension, and a proximal end and a distal end, wherein at least a portion of the body member deviates from the direction of extension, and a polymeric coated composition in contact with the body member, the polymeric coated composition including a first polymer, a second polymer, and a bioactive agent, wherein the first polymer comprises polyalkyl(meth)acrylate, aromatic poly(meth)acrylate, or a combination of polyalkyl(meth)acrylate and aromatic poly(meth)acrylate, and wherein the second polymer comprises poly(ethylene-co-vinyl acetate). The invention also provides methods of delivering a bioactive agent to a patient in a controlled release manner, as well as methods of making a controlled release bioactive agent delivery device.

The invention provides chain extenders made from epoxy-functional (meth)acrylic monomers and styrenic and/or (meth)acrylic monomers. The invention further provides polymeric compositions made from the chain extenders and plastic articles made from the compositions. Finally, the invention provides methods of using the chain extenders to improve the properties of virgin, recycled, and reprocessed condensation polymers.

Blends of oligomeric urethane multi(meth)acrylate; optionally at least one other monomer selected from the group consisting of acrylic monomers, styrenic monomers and ethylenically unsaturated nitrogen heterocycles, preferably a polyol multi(meth)acrylate; and nanoparticles of an ethylenically unsaturated, preferably (meth)acrylic-functionalized, titanium or zirconium compound can be cured by ultraviolet radiation in contact with a photoinitiator to produce optical resinous articles having high refractive indices, haze ratings of at most 5% and other properties which may be tailored according to the desired use.

A curable composition comprises epoxy resin preparable by reaction of epichlorohydrin with at least one of bisphenol A or bisphenol F, polyfunctional (meth)acrylate, dicyandiamide and photoinitiator. The curable composition is useful for preparing treated backings and coated abrasive articles.

A liquid ink comprises (a) a carrier liquid having a Kauri-Butanol number less than 30; (b) a graft copolymer comprising a (co)polymeric steric stabilizer covalently bonded to a thermoplastic (co)polymeric core that is insoluble in the carrier liquid; and (c) a colorant, wherein the steric stabilizer comprises units derived from 3,3,5-trimethylcyclohexyl methacrylate, and the thermoplastic (co)polymeric core comprising units derived from at least a polymerizable monomer selected from the group consisting of (meth)acrylates having aliphatic amino radicals, nitrogen-containing heterocyclic vinyl monomers, N-vinyl substituted ring-like amide monomers, aromatic substituted ethylene monomers containing amino radicals, and nitrogen-containing vinylether monomers. The organosol provides improved liquid electrophotographic and electrographic ink compositions with improved dispersion stability, chargeability, and blocking resistance so that improved print quality or ink transfer performance are obtained.

There is provided a positive type resin composition comprising (A) a resin component comprising within the principal chain a structural unit derived from a (meth)acrylate ester and incorporating an acid dissociable, dissolution inhibiting group containing a polycyclic group on an ester side chain section, for which the solubility in alkali increases under the action of acid, (B) an acid generator component which generates acid on exposure, and (C) an organic solvent, wherein the component (A) comprises both a structural unit derived from a methacrylate ester and a structural unit derived from an acrylate ester. According to such a resist composition, a resist pattern can be formed which displays little surface roughness and line edge roughness on etching, and also offers excellent resolution and a wide depth of focus range.

A self-cleaning surface which has an artificial, at least partially hydrophobic, surface structure containing elevations and depressions, which comprises an at least partially hydrophobic surface formed from structure-forming particles of hydrophobic fumed silica having elevations and depressions ranging in dimensions of 1 to 1000 nm and the particles themselves having an average size of less than 50 μm adhered to the surface by way of a viscous, curable carrier material selected from the group consisting of polyurethane, polyurethane acrylates, silicone acrylates and singly and/or multiply unsaturated (meth)acrylates applied to the surface, which is sufficient to bond the structure forming particles without substantial wetting of the particles by the carrier material while retaining the fissured structure of elevations and depressions of the structure-forming particles in the nanometer range.

The invention relates to polymers with antimicrobial properties, consisting of: a) 99-40 wt % non functional vinylically polymerizable monomers and b) 1-60 wt % functional vinylically polymerizable monomers of general formula (I) wherein V=vinyl, (meth)acroyl, allyl or styryl, A=a possibly available linking unit, which can be alkyl, aryl, arylalkyl or hydroxy alkyl, which can also be interrupted by hetero atoms, e.g. by hetero atoms in urethane, carbonate, ester, amide or ether groups, wherein y=0 or is 1, Hsp=a hydrophilic spacer of general formula (i) -(O-CH2-CH2)r- and/or (ii) -(O-CH2-CH(CH3))s with r=0-40, s=0-40 and r+s=2-40, also m=1.2 or 3 and R1=CH3, ethyl or benzyl, R2=an alkyl radical with 8-20 C-atoms, wherein t=1, 2 or 3 and X-=Cl-, Br-, I- or alkyl sulphate.

A golf ball has a cover member and a core member. The cover member contains: 3 to 30 parts by weight of a thermoplastic elastomer containing polyamide; 5 to 50 parts by weight of a terpolymer ionomer containing ethylene, (meth)acrylic acid, and (meth)acrylic ester; 30 to 80 parts by weight of a copolymer ionomer containing ethylene and (meth)acrylic acid; and 1 to 20 parts by weight of an epoxidized-diene-based block copolymer. The core member is formed by vulcanizing a rubber composition containing: 100 parts by weight of a base rubber, A parts by weight of an alpha, beta-unsaturated carboxylic acid or a metal salt thereof, B parts by weight of an organic peroxide, and C parts by weight of a sulfide where A, B, and C satisfies the relationship:andA lies in the range from 25 to 45.

Disclosed is a carbon nanotube-containing composition which contains a carbon nanotube and a urethane compound obtained by a reaction between a hydroxyl group-containing (meth)acrylate and a isocyanate compound. Also disclosed is a composite having a coating film or a cured film composed of the carbon nanotube-containing composition on at least one surface of a base material. The carbon nanotube-containing composition and the composite are excellent in electrical conductivity, film-formability, moldability, and transparency without deteriorating the characteristic properties of the carbon nanotube itself.

The invention relates to an optionally foamed sealing composition for preformed seals which can swell when treated with water. The invention also relates to a method for the production thereof out of natural rubber and/or elastomers with a matrix comprised of natural rubber/elastomer components and particle-shaped water absorbing material stored therein. The water absorbing material is a combination of (A) polysaccharide(s) selected from cellulose, starch, starch derivatives removed from grafted starch, amylose, amylopectin, dextran, pectin, inulin, chitin, xanthan, alginic acid, alginates, carrageenan, pustulan, callose, laminarin, guluronic acid, pullulan, lichenin or mixtures of the same with (B) a highly water absorbent synthetic polymer selected from polymers based on (meth)acrylate, poly(meth)acrylic acid and the salts thereof, polyacrylamide, polyalcohols or copolymers of said synthetic polymers. The invention also relates to additional cross-linking and processing auxiliary agents and to property improving agents. It is possible to securely seal superstructures, substructures, tunnels and canals with the assistance of the inventive sealing compositions.

Non-tacky, base polymers are plasticized into pressure-sensitive adhesives and comprise: a) about 100 parts by weight of a base copolymer having a Tg greater than about 0° C., wherein the base copolymer is formed from and comprises: (1) about 50 to 70% by weight of a high Tg comonomer component, wherein the homopolymer formed from the high Tg comonomer component has a Tg of at least about 20° C.; (2) optionally, up to about 20% by weight based on the total weight of the base copolymer of an acidic comonomer; and (3) about 30 to 50% by weight of one or more low Tg (meth)acrylate comonomer, wherein the Tg homopolymer of the low Tg comonomer is less than about 20° C., and b) about 1 to about 100 parts based on the base copolymer of a nonreactive, non-volatile, non-acrylic-based plasticizing agent.

The invention belongs to the technical field of concrete additives in building materials. The high water reduction high collapse protection type polycarboxylate high-performance water reducer mainly comprises the following monomer components: unsaturated methyl vinyl polyoxyethylene ether (A), a chain transfer agent (B), a mixture (C) of one or more of unsaturated acid and unsaturated acid derivatives, an oxidant (D) and a reducing agent (E), wherein the molar ratio A: B: C: D: E of the monomers is 1:0.01-0.5:2-8:0.08-0.5:0.02-0.3. The high water reduction high collapse protection type polycarboxylate high-performance water reducer is prepared by regulating the polymer mass concentration to between 20 and 40 percent by using water, and polymerizing a redox initiator system at normal temperature. The water reducer has the advantages of low doping amount, high water reducing ratio, excellent slump retaining capacity, and high cement adaptability, and the technology has the advantages of no need of extra heat source, implementation at normal temperature, low equipment investment, low cost and suitability for large area popularization and application.

Polymerizable compositions are described containing urethane (meth)acrylate oligomers and certain polymerizable monomers useful in thermoforming or in-mold decoration applications.

A wet-skin adhesive includes a pressure-sensitive adhesive component that includes at least one monoethylenically unsaturated (meth)acrylic acid ester comprising an alkyl group having at least 4 carbons on average and at least one monoethylenically unsaturated reinforcing monomer; and a film-forming component that includes at least one monoethylenically unsaturated (meth)acrylic acid ester comprising an alkyl group having less than 4 carbons on average and at least one hydrophilic acidic monomer, wherein the wet-stick pressure-sensitive adhesive has an initial wet skin adhesion of at least about 0.8 N/dm. Advantageously, the wet-stick adhesive has an initial wet skin adhesion that is at least about 65% of an initial dry skin adhesion.

The invention relates to a process for producing mouldings by injection moulding, the steps in the process being A) Melting a mixture made from a) a (meth)acrylate copolymer composed of from 40 to 100% by weight of free-radical-polymerized C1-C4-alkyl esters of acrylic or methacrylic acid and from 0 to 60% by weight of (meth)acrylate monomers having an anionic group in the alkyl radical, where the copolymer comprises b) from 0.1 to 3% by weight of a release agent, and, where appropriate, the mixture may comprise c) from 0 to 50% by weight of a drier, d) from 0 to 30% by weight of a plasticizer, e) from 0 to 100% by weight of additives or auxiliaries, f) from 0 to 100% by weight of an active pharmaceutical ingredient, g) from 0 to 20% by weight of another polymer or copolymer, where the amounts given for components b) to g) are based on the (meth)acrylate copolymer a) and the mixture prior to melting has a content of more than 0.5% by weight of low-boiling constituents with vapour pressure of at least 1.9 bar at 120° C., B) Devolatilizing the mixture in the thermoplastic state at temperatures of at least 120° C., thereby lowering to not more than 0.5% by weight the content of the low-boiling constituents with vapour pressure of at least 1.9 bar at 120° C., C) Injecting the molten and devolatilized mixture into the mould cavity of an injection mould, the temperature of the mould cavity being below the glass transition temperature of the (meth)acrylate copolymer by at least 10° C., cooling the molten mixture, and removing the resultant moulding from the mould.

The invention provides a colored photosensitive resin composition for forming a colored image on a transparent substrate, the colored photosensitive resin composition comprising: an alkali-soluble binder, one of a monomer and an oligomer having at least two ethylenic unsaturated double bonds, one of a photopolymerization initiator and a photopolymerization initiating system, and a pigment, said alkali-soluble binder comprising a copolymer including a structural unit having a carboxyl group, a structural unit represented by the following general formula (1), and a structural unit comprising a (meth)acrylate having at least one of an aromatic ring and an alicyclic ring:

wherein R¹ represents one of a hydrogen atom and a methyl group; and each of R² to R⁶ independently represents one of a hydrogen atom, a substituted and unsubstituted alkyl group, a substituted and unsubstituted aryl group, a halogen atom and a cyano group.

A film suitable for use as a light-modulating unit of a suspended particle device (SPD) light valve. The film comprises a siloxane matrix polymer which has a refractive index>1.4630 and has droplets of a liquid light valve suspension distributed within the matrix. The liquid light valve suspension preferably comprises a polyalkyl (meth)acrylate and/or fluorinated (meth)acrylate suspending polymer and optionally may comprise one or more non-polymeric liquids.

The invention relates to organopolysiloxanes comprising (meth)acrylate groups, to a process for their preparation and to their use as radiation-curing coating materials.

Disclosed is an electrochemical device, which comprises: (A) a binder comprising polymer particles obtained from the polymerization of: (a) 20-70 parts by weight of a (meth)acrylic acid ester monomer; (b) 20-60 parts by weight of a vinyl monomer; and (c) 0.01-30 parts by weight of an unsaturated carboxylic acid monomer, based on 100 parts by weight of a binder polymer; and (B) electrochemical cells stacked multiply by using the binder, wherein the binder allows electrode active material particles in an electrode to be fixed and interconnected among themselves and between the electrode active material and a collector, and the electrode and a separator that is in contact with the electrode are bonded to each other by way of hot fusion. The binder is also disclosed. The binder has excellent adhesion and thermal bonding characteristics, and thus is useful for an electrochemical device comprising multiply stacked electrochemical cells, and can improve the overall quality of a battery.

Disclosed is a silyl (meth)acrylate copolymer which comprises 20 to 80% by weight of (a) silyl (meth)acrylate constituent units (I), 0.01 to 40% by weight of (b) acrylic unsaturated monomer constituent units (II) and 5 to 79.9% by weight of Ĉ unsaturated monomer constituent units other than the constituent units (a) and (b). Also disclosed is a process for preparing the silyl (meth)acrylate copolymer, an antifouling paint composition comprising the copolymer, a coating film formed from the paint composition, a hull with the coating film and an antifouling method using the paint composition.

It is an object of the present invention to provide an optical layered body which is produced at low cost and is superior in all an antistatic property, hardness and optical properties such as haze and a total light transmittance.

An optical layered body comprising a light-transmitting substrate and a hard coat layer formed on the light-transmitting substrate,

• • wherein the hard coat layer is a resin layer formed from a hard coat layer-forming composition containing a quaternary ammonium salt having a weight average molecular weight of 1000 to 50000, a tri- or morefunctional (meth)acrylate compound having a weight average molecular weight of 700 or less, and a permeable solvent; and
  • a content of the quaternary ammonium salt in the hard coat layer is 0.5 to 18% by weight.

The invention is directed to a hard-coated film, comprising: a transparent film substrate; and a hard-coating layer formed on at least one side of the transparent film substrate, wherein the hard-coating layer is made from a material containing a urethane acrylate, a polyol (meth)acrylate and a (meth)acrylic polymer having an alkyl group containing at least two hydroxyl groups. There can be provided a hard-coated film that has high hardness and good flexibility and is resistant to curling due to hardening and shrinking and a method of manufacturing a hard-coated film in which a reduction in production efficiency associated with an increase in the number of manufacturing steps is prevented.

It is intended to provide a transdermal absorption patch which is highly excellent in transdermal absorption properties and long-lasting drug effect even in the case where a drug-effect component contained in the transdermal absorption patch is a basic drug hardly soluble in a pressure-sensitive adhesive base, has a high stability of the drug contained therein with the passage of time and can achieve improvement in the compliance and simplification of the administration method. These problems can be solved by providing a transdermal absorption patch which contains a basic drug having an octanol/water partition coefficient (logarithm) in the free state of 3 or above, a pressure-sensitive adhesive base and a (meth)acrylic copolymer having carboxyl group.

A method for enhancing the performance of hair fixative resins in hair styling compositions by using selected polymers having certain compositions is disclosed. In particular, the present invention involves a method of improving the stiffness performance of hair fixative resins by using polymers containing 5-95% (C1-C10)alkyl (meth)acrylate, 0-70% hydroxyalkyl (meth)acrylate, 0-50% monocarboxylic acid monomer and 1-25% dicarboxylic acid monomer. The selected polymers are particularly useful in aqueous hair styling compositions containing low (80% or less) volatile organic compound (VOC) concentrations.

The present invention relates to a radiation-curable solvent-free coating composition for optical fiber having a radiation-curable urethane (meth)acrylate oligomer comprising an alkyd backbone,a reactive diluent, and a photoinitiator, and optionally an additive.

A wet stick pressure sensitive adhesive comprising the solventless polymerization product of: a) about 30 to about 70 parts by weight of an (meth)acrylate ester monomer wherein the (meth)acrylate ester monomer, when homopolymerized, has a Tg of less than about 10° C.; b) about 70 to about 30 parts by weight of a hydrophilic acidic comonomer; and c) about 10 to 100 parts based on 100 parts of the sum of components (a+b) of a non-reactive plasticizing agent, wherein the pressure sensitive adhesive adheres to wet substrate surfaces and a method of making.

A coating composition which comprises (A) a resin having a glass transition temperature of 50 to 120 DEG C., a number average molecular weight of 2,000 to 100,000, a hydroxyl value of 50 to 150 mgKOH/g and an acid value of 1 to 25 mgKOH/g, which is produced by copolymerizing 10 to 90 percent by weight of (a) a (meth)acrylic acid ester of a C1 to C12 alkyl alcohol, 10 to 50 weight % of (b) a first polymerizable double bond-containing and hydroxyl group-containing monomer, 0.1 to 10 weight % of (c) a polymerizable double bond-containing and carboxyl group-containing monomer, 0 to 20 weight % of (d) styrene, 0 to 20 weight % of (e) acrylonitrile and 0 to 10 weight of (f) a second polymerizable double bond-containing monomer, (B) at least one compound selected from the group consisting of a polyisocyanate compound having two or more unblocked isocyanate groups and/or blocked isocyanate groups in the molecule and an aminoplast resin, (C) a dispersing component of at least one inorganic oxide sol selected from the group consisting of an aluminum oxide sol, a silica sol, a zirconium oxide sol and an antimony oxide sol, wherein an amount of a nonvolatile matter of component (C) is 5 to 60 percent by weight based on a total amount of nonvolatile matter of resin (A), compound (B) and component (C). The coating composition provides cured films having excellent weathering resistance, light resistance, stain resistance, stain-removing property, chemical resistance, moisture resistance and appearance and is environmentally friendly and safe.

A coating composition forming a abrasion resistant coating comprising (A) an ultraviolet-curable silicone prepared by chemically modifying particulate colloidal silica with a specific silane compound, (B) a monomer mixture comprising a (meth)acrylate having a specific isocyanate skeleton and a urethane poly(meth)acrylate having an alicyclic skeleton, and (C) a photo-polymerization initiator. By using a urethane poly(meth)acrylate having an alicyclic skeleton as part of the component (B) and the component (A) having an enhanced reactivity of chemical modification, the compatibility of the component (A) with the component (B) is improved to give a cured coating with excellent wear resistance, weather resistance and durability.