9010 results about "Methanol" patented technology

The present invention discloses a method for detecting and applying C1-C2-alkyl-substituted phenol isomers, which relates to the technical field of environmental detection and includes: selecting a corresponding sample pretreatment process to prepare a test sample according to the petroleum content range in the sample; under a mobile phase of methanol-5.0-6.5 mmol / L ammonia water, using LC-MS to detect the test sample to obtain the concentration of the first component and the standardized concentrations of co-eluted 3,5-dimethylphenol and 2,6-dimethylphenol; under a mobile phase of acetonitrile-4.0-10.0 mmol / L ammonia water, using LC-MS to detect the test sample to obtain the concentration of 3,5-dimethylphenol, or the standardized concentrations of co-eluted 3,5-methylphenol and 3-ethylphenol, or the standardized concentrations of co-eluted 2,6-dimethylphenol and 2,4-dimethylphenol; under a mobile phase of methanol-5.0-6.5 mmol / L ammonia water or acetonitrile-4.0-10.0 mmol / L ammonia water, using LC-MS to separately detect the calibration samples of the co-eluted components, and calculate the conversion factor of the co-eluted components and the concentration of the other component. The present invention realizes the accurate quantification of phenol and 12 C1-C2-alkyl-substituted phenol isomers.

The invention discloses a cobalt-loaded covalent organic framework material as well as a preparation method and application thereof, and belongs to the technical field of catalyst preparation. The cobalt-loaded covalent organic framework material is prepared by taking a carbonized covalent organic framework as a matrix and cobalt nitrate hexahydrate as a cobalt source, reducing by using a sodium borohydride methanol solution, and introducing transition metal cobalt into the framework through room-temperature impregnation and thermal reduction processes. In the material, active components comprise Co0 and Co < 2 + > which are uniformly distributed on a carrier. Moreover, the metal cobalt is stably loaded in a carbon skeleton through the bonding effect of heteroatoms such as nitrogen and carbon, so that the stability, the catalytic activity and the durability of the metal cobalt are effectively improved, the dissolution risk of the metal cobalt is reduced, the hidden danger of environmental pollution is reduced, and efficient catalytic activity is shown in the aspect of catalyzing and activating peroxymonosulfate to degrade organic pollutants; and good recycling stability is achieved.

The invention relates to the technical field of methanol safety monitoring, in particular to a methanol leakage prediction system based on artificial intelligence. According to the method, structural extraction of potential leakage paths is realized through dynamic sorting and surge correlation combination of methanol concentration change trends in continuous time periods, and weighted calculation is carried out on conduction characteristics between monitoring nodes in double dimensions of time series and spatial topology by virtue of a graph attention mechanism, so that the detection accuracy of the leakage paths is improved. The method comprises the following steps: establishing a path, forming quantitative expression of node influence factors in the path, capturing synchronous abnormal behaviors under an environment disturbance background through a multi-parameter coupling sudden change identification mode of air pressure and wind speed, further constructing a high-timeliness sudden change event set, and performing index fusion on the influence degree and sudden change frequency of monitoring nodes on the basis to obtain a high-timeliness sudden change event set. And space risk score distribution is formed, and a leakage possibility region prediction map is generated in combination with two-dimensional coordinates, so that boundary fine depiction of a high-risk region is realized.

The invention discloses a methanol generator flywheel assembling device and method, and relates to the technical field of generator flywheel assembling. The flywheel assembling device comprises a lifting seat, a clamping seat is mounted at the top of the lifting seat, a first oil tank is mounted below the outer side of the clamping seat, a clamping assembly is mounted at the top of a piston rod in the first oil tank, a first corrugated pipe and a second corrugated pipe are connected to the bottom of the first oil tank, and a hammering seat is mounted at the top of the lifting seat. A hammering block is longitudinally and slidably installed on the side edge of the top of the hammering base, a telescopic connecting rod is rotatably installed at the center position of the bottom of the hammering block, the bottom end of the telescopic connecting rod is rotatably connected with the bottom of the hammering base, a hammering assembly is installed on the side wall of the hammering base, and a moving assembly is installed on the inner wall of the bottom of the hammering base. A traditional manual hammering flywheel installation mode is replaced, the flywheel installation efficiency is improved, the labor cost is reduced, and the labor intensity of workers is relieved.

Provided is a laminate capable of electrolyzing an oxygen compound gas represented by CO2 with high conversion efficiency and suppressing deterioration in electrolytic performance. In this laminate having a structure in which an electrolyte layer is sandwiched between an anode catalyst layer and a cathode catalyst layer, a perovskite oxide and CuFe2O4 are contained in the cathode catalyst layer, and the content of CuFe2O4 in the cathode catalyst layer is at least 10 mass%.

The invention discloses a polytetrafluoroethylene film with high tensile strength and a preparation process thereof, and relates to the technical field of polytetrafluoroethylene films. The preparation method comprises the following steps: step 1, preparing a composite raw material: S1-1, sequentially putting a tetrafluoroethylene copolymer into acetone and methanol to be soaked, washed and dried; dispersing in a glycidyl methacrylate-methanol solution, and carrying out irradiation grafting in a nitrogen atmosphere; filtering, washing and drying to obtain an epoxy tetrafluoroethylene copolymer; s1-2, sequentially putting an epoxy tetrafluoroethylene copolymer and a composite filler into tetrahydrofuran, stirring for 24-48 hours at the temperature of 70-75 DEG C in a nitrogen atmosphere, filtering, washing and drying to obtain a composite raw material; 2, mixing polytetrafluoroethylene, the composite raw material and carboxylated polyphenylene sulfide to obtain a mixture; performing cold press molding and temperature-controlled sintering to obtain a basic film; 3, the basic film is subjected to turning forming and continuous rolling, and the polytetrafluoroethylene film is obtained.

The invention discloses a method for catalytically oxidizing lignin to depolymerize into an aviation oil intermediate by using a cellulose carbon aerogel supported copper nano-catalyst. Comprising the following steps: (1) dissolving cellulose powder into a mixed alkali solution of NaOH and urea, and stirring at low temperature to obtain a clear and transparent cellulose solution; and washing to be neutral to obtain well dispersed cellulose suspension. And (2) carrying out suction filtration molding, and freeze-drying for a period of time to obtain the cellulose aerogel. And (3) immersing in an ethanol solution of copper nitrate for ultrasonic treatment, and drying in a vacuum drying oven. And (4) carrying out high-temperature calcination in an N2 atmosphere to obtain a catalyst which is marked as Cu / CA. And (5) the catalyst can efficiently catalyze a Fenton-like reaction to oxidize a dimer model compound of lignin in acidic, neutral and alkaline environments to obtain products including benzoic acid, acetophenone, benzyl alcohol, phenol and the like, the required hydrogen peroxide concentration is low, and the catalyst has the advantages of simple process, high catalytic activity, low cost and the like, can be used for effectively degrading lignin to prepare aviation oil intermediates, and has wide application prospects. And repeated cyclic utilization is realized.

The invention relates to the technical field of methanol production, and discloses an efficient gas-liquid distribution device for a methanol synthesis reaction tower. The liquid distribution assembly is used for distributing a catalyst; the filler assembly is used for promoting gas-liquid contact; when the liquid distribution assembly runs, the liquid distribution assembly drives the atomization assembly to atomize the catalyst flowing on the inner wall of the tank body; the liquid distribution assembly comprises a rotating shaft, the rotating shaft is rotationally installed in the tank body, a wind wheel is fixedly connected to the rotating shaft, a liquid disc is fixedly connected to the top end of the rotating shaft, a plurality of first spray heads are hinged to the liquid disc, and hoses are arranged between the first spray heads and the liquid disc. Through the arrangement of the liquid distribution assembly, the multiple first spray heads can swing in a reciprocating mode in the rotating process, so that the spraying range of the first spray heads is expanded, the situation that spraying blind areas occur in the tank body is avoided, catalysts in the tank body are distributed more evenly, and the gas-liquid contact efficiency is improved.

The invention discloses a control method for improving the cold starting performance of a methanol extended-range hybrid power system, relates to the field of engine control, and solves the technical problem that the existing methanol engine starting mode has limited effects on the thermal atmosphere of methanol atomization, premixing and methanol injection ignition success under the low-temperature condition. The method comprises the steps that an engine starting success condition is set, the real-time environment temperature is obtained, when the real-time environment temperature is larger than the preset first starting temperature, a first starting strategy is adopted to start an engine, and whether the engine is started successfully or not is judged according to the engine starting success condition. The invention further discloses a system for improving the cold start performance of the methanol extended-range hybrid power system. Methanol atomization is promoted, methanol is fully premixed, and the successful thermal atmosphere effect and success rate of a methanol injection point are improved.

The invention relates to the technical field of preparation of catalysts, in particular to a catalyst for in-situ capture of carbon dioxide, a preparation method of the catalyst and application of the catalyst to preparation of methanol from methane, and the preparation method comprises the following steps: S1, mixing and stirring Bi (NO3) 3.5 H2O, dilute nitric acid and an adsorption modifier; s2, filtering to obtain a white precipitate, drying, slowly heating to 450 DEG C in a muffle furnace, and keeping the temperature for 20-30 minutes to obtain a faint yellow solid; s3, dispersing in a modified dissolving solution, sealing the reactor, and purging with argon for 10-15 minutes; and S4, injecting CH4, reacting for 2 hours under the irradiation of a xenon lamp, washing a solid obtained by suction filtration with deionized water, and drying at 60 DEG C for 10-12 hours to obtain the high-performance catalyst. The invention aims at the field of preparation of high-value chemicals from photocatalytic methane, solves the problem of generation of carbon dioxide by peroxidation of methane, and captures the peroxidation product carbon dioxide through the cooperation of the adsorption modifier and the modified dissolving solution to inhibit peroxidation of methane.

The invention relates to a preparation method and application of a porous material for preparing methanol through carbon dioxide adsorption and conversion. When the material is prepared, firstly, 4, 4 '4' '-(1, 3, 5-triazine-2, 4, 6-trimethylene) triphenylamine and 1, 2-acenaphthequinone are treated in a mixed solvent containing dioxane / acetonitrile / 6M acetic acid, and AT-COF is obtained; further synthesizing by adopting an impregnation method to obtain IrRu-COF; and finally, uniformly mixing the active gamma-aluminum oxide and the IrRu-COF material to form a carrier dispersion liquid, and then carrying out PEI loading, vacuum impregnation, washing and drying to obtain the PEI functionalized gamma-Al2O3 / COF composite catalyst. The technical closed loop from low-concentration CO2 capture to solar driven conversion is realized, the process flow is simple, and the energy consumption is low.

The invention discloses a low-temperature methanol washing RTO tail gas treatment device adopting a self-circulation air cooling double-valve-plate butterfly valve, and relates to the technical field of waste gas treatment. By arranging the condensation impurity removal mechanism, when coal waste gas passes through one condensation assembly, low-temperature tail gas cleaned by the low-temperature methanol washing mechanism can flow through a plurality of heat exchange pipes in the condensation assembly at the same time, so that the temperature of the outer walls of the heat exchange pipes is rapidly reduced to be below zero DEG C; coal tar gas and water vapor flowing through the low-temperature heat exchange pipe can be quickly cooled and solidified after being in contact with the outer wall of the low-temperature heat exchange pipe, so that the effect of separating the coal tar gas and the water vapor from the tail gas is achieved; a cold source which cannot be utilized and can influence subsequent RTO furnace treatment in the part of tail gas is ingeniously used for separating energy of coal tar and water vapor in the waste gas, a refrigerating device does not need to be independently arranged in the cooling and condensing process of the coal tar and the water vapor, and the purposes of energy conservation and emission reduction are achieved.

The invention discloses a rare earth boride nano material as well as a preparation method and application thereof. The phase state of the rare earth boride nano material is REB6 or REB4; the preparation method comprises the following steps: S1, respectively weighing a compound raw material containing an RE element and a compound raw material containing a B element; s2, adding an additive, and fully grinding; s3, reacting under the protection of inert gas; s4, after the reaction is finished, excessive methanol is added, centrifugal separation is performed after no bubbles emerge, and a precipitate A is reserved; s5, adding diluted hydrochloric acid for soaking, and performing centrifugal separation again to reserve a precipitate B; and S6, washing the precipitate B with deionized water, and drying to obtain the rare earth boride nano material. According to the preparation method disclosed by the invention, a normal-pressure and low-temperature preparation method is adopted, the pure-phase rare earth hexaboride nanocrystal can be obtained at normal pressure and the temperature as low as 300 DEG C, and no active metal elementary substance needs to be introduced in the preparation process.

The invention discloses a preparation method of a crown ether functionalized anti-pollution nanofiltration membrane, which comprises the following steps: soaking a membrane of a commercial nanofiltration membrane in pure water, and coating the surface with a double-end epoxy compound ethanol solution; uniformly coating the surface of the membrane with an aza 12-crown-4 methanol solution; and drying the membrane in an atmosphere of 40-90 DEG C to obtain the crown ether functionalized anti-pollution nanofiltration membrane. The nano-filtration membrane is realized by chemically grafting aza 12-crown-4 on the membrane surface of a commercial nano-filtration membrane by utilizing a double-end epoxy compound; compared with a traditional nanofiltration membrane, the crown ether functionalized nanofiltration membrane provided by the invention has the advantages that the electronegativity of the surface is reduced, and the surface is similar to an aquatic plant molecular brush structure, so that the deposition of pollutants on the surface of the membrane can be effectively improved, and the anti-pollution performance of the membrane is enhanced; meanwhile, due to the complexing effect of 12-crown-4 molecules on lithium ions, the lithium ions can be effectively captured, concentration polarization of the lithium ions on the surface of the diaphragm is improved, and then the magnesium-lithium separation efficiency of the diaphragm is improved.

An integrated energy system comprising a power plant including at least one nuclear reactor and electrical power generation system, the at least one nuclear reactor being configured to generate steam, and the electrical power generation system being configured to generate electricity, a desalination system configured to receive at least a portion of the electricity and steam to produce brine, an electrolysis process configured to process the brine into Sodium Hydroxide (NaOH), a Sodium Formate (HCOONa) production process configured to receive the Sodium Hydroxide (NaOH) to produce Sodium Formate (HCOONa), a Hydrogen (H2) extraction reactor configured to receive the Sodium Formate (HCOONa) and produce Hydrogen (H2), and a fuel cell configured to receive the Hydrogen (H2).

An example of a multi-fluid kit for three-dimensional (3D) printing includes a fusing agent and a surface treating agent. The fusing agent includes an electromagnetic radiation absorber and a first aqueous vehicle. The surface treating agent includes a second aqueous vehicle, a surfactant, and benzyl alcohol dissolved in the second aqueous vehicle.

The invention discloses a method for preparing regenerated flame-retardant high-shrinkage polyester by a methanol alcoholysis method, and belongs to the technical field of polyester. The method comprises the following steps: (a) mixing the waste polyester fabric with methanol, and carrying out catalytic depolymerization to obtain a regenerated DMT mixed solution; (b) carrying out impurity separation and methanol recovery treatment on the regenerated DMT mixed solution, and then carrying out cooling crystallization, centrifugal drying and rectification purification treatment to obtain pure DMT; (c) carrying out transesterification on pure DMT, ethylene glycol, a transesterification catalyst and a DEG inhibitor; (d) after the ester exchange reaction, adding CEPPA-EG and IPA-EG for copolymerization; adding a polymerization catalyst, a stabilizer and an antioxidant for polymerization reaction to obtain a modified polyester melt; and (e) granulating and drying to obtain the slices. The regenerated polyester prepared by the method has multiple functions of flame retardance, high boiling water shrinkage, low-temperature dyeing and the like, and is suitable for the fields of high-end clothing, automotive trim, electronic packaging materials and the like.

The invention discloses a capacity configuration optimization method for preparing methanol by coupling wind-solar hydrogen production with biomass gasification, belongs to the field of methanol preparation, and develops a comprehensive optimization framework to evaluate the technical economic feasibility of renewable methanol production. According to the framework, renewable energy power generation, an energy storage technology, hydrogen production through water electrolysis and methanol synthesis are integrated together, so that a production system with cost effectiveness is constructed. And establishing an optimization model to determine the optimal investment and operation strategy of green methanol production. According to the model, investment and operation decisions of a plurality of system components are considered, and a series of decision variables are set. Through the solution of the optimization model, the problem of insufficient economic evaluation and comparison technology of synthesizing methanol from renewable energy sources is solved, a scientific basis is provided for a project in planning, design and decision-making stages, and the development of the field of synthesizing methanol from renewable energy sources is promoted.

The invention discloses a porous tubular methanol solid oxide fuel cell with a closed end, the fuel cell is a tubular solid oxide fuel cell (SOFC) stack, and the tubular SOFC stack comprises a plurality of tubular SOFC single cells; in the moving direction of fuel in the inner tube, the bottom end of the inner tube of the tubular SOFC single cell is open, the top end of the inner tube of the tubular SOFC single cell is closed, and a plurality of sections of closed areas and a plurality of sections of perforated areas are arranged on the tube wall of the inner tube and are sequentially and alternately arranged. According to the inner tube structure of the tubular SOFC single cell, the distribution uniformity of methanol on the surface of the anode of the solid oxide fuel cell can be effectively improved, so that the problem of serious carbon deposition caused by non-uniform distribution of methanol on the surface of the anode of the solid oxide fuel cell is effectively solved.

The invention discloses a method for preparing fuel from waste polyolefin through noble-metal-free low-temperature aromatization, which comprises the following steps: in the atmosphere of synthesis gas, carrying out catalytic cracking on polyolefin serving as a raw material by adopting a binary mixed catalytic system to obtain aromatic hydrocarbon; the binary mixed catalytic system comprises Zr-ZnO and a molecular sieve; the catalytic cracking temperature is less than or equal to 300 DEG C. According to the low-temperature aromatization method disclosed by the invention, methanol is generated in situ through the synthesis gas, and the methanol and olefin generated by polyolefin cracking are subjected to Prins reaction, so that the aromatization reaction can be realized at the pyrolysis temperature far lower than that in the prior art, precious metals are not needed, the additional value and the application range of a plastic recovery product are greatly enhanced, and the method is suitable for industrial production. And the cost of the recovery process is reduced.

The invention provides a preparation method of silicon dioxide serving as a flow promoter in a powder coating. The preparation method comprises the following steps: synthesizing silicon dioxide by using a precipitation method; washing and filter-pressing to obtain a precipitate; re-dispersing and pulping the silicon dioxide by using pure water; performing drying; performing high-temperature crushing; the synthesis of silicon dioxide comprises the following steps: adding bottom water, and heating to 40-100 DEG C; adding water glass and acid into the bottom water in a parallel flow manner under the conditions of constant temperature and pH value of 5.0-10.0; adjusting the pH value to 2.0-4.0 by using an acid; the specific surface area of the silicon dioxide is 100-500m < 2 > / g; the bulk ratio of the silicon dioxide is not higher than 0.30 g / cm < 3 >; the particle size of the silicon dioxide is not higher than 5.0 microns; the methanol value of the silicon dioxide is higher than 30%; the drying weight loss of the silicon dioxide is not higher than 3.0%. The preparation method of the silicon dioxide serving as the flow promoter in the powder coating is simple in process and low in cost.

The invention relates to a method for recovering mixed salts (mainly containing calcium chloride, sodium chloride and potassium chloride) from a household garbage incineration fly ash leaching solution, and particularly provides two separation technical schemes. The traditional separation method generally needs to use a large amount of decalcifying agent, so that the cost is high, calcium chloride cannot be effectively recycled, and the problem of resource waste exists. In order to solve the problems, the invention selectively dissolves calcium chloride in the mixed salt by adopting a specific organic solvent (such as ethanol or methanol) and utilizing the characteristics that the solubility of calcium chloride in the solvent is high, the solubility of sodium chloride and potassium chloride is low, and the boiling point is relatively low. And a calcium chloride product can be recovered after solvent evaporation. Furthermore, the residual mixed salt is further washed using the specific organic solvent to remove entrained calcium chloride, thereby obtaining a mixed salt containing predominantly sodium chloride and potassium chloride. According to the technical scheme 1, the mixed salt subjected to separation and calcium removal is subjected to dissolution treatment under the high-temperature condition, potassium chloride is dissolved, the particle size of sodium chloride crystals is promoted to be increased, the sodium chloride crystals are obtained through solid-liquid separation, and then mother liquor is cooled and crystallized to recover potassium chloride. According to the technical scheme 2, the mixed salt subjected to separation and calcium removal is subjected to aging treatment so as to promote particle size increase of sodium chloride and potassium chloride crystals, then the aged mixed salt is separated by adopting a flotation method, and sodium chloride and potassium chloride products are recycled respectively.

The invention discloses a power control method for a methanol reforming fuel cell power generation system, and relates to the technical field of power generation system power control, and the method achieves the precise representation of the internal dynamic coupling relation of the system through the construction of a digital twin model covering the whole methanol reforming process and the whole electrochemical conversion process of a fuel cell. Therefore, the problem of hydrogen supply lag caused by reforming reaction delay in the traditional control is effectively eliminated, and the output power of the fuel cell can be highly synchronized with the load demand; the Smith predictor is adopted to perform online estimation and compensation on methanol reforming inherent time delay, and the MPC is predictively controlled to perform real-time optimization scheduling under the constraints of economical efficiency and equipment health state in combination with a multi-target model, so that the power generation efficiency is improved, the fuel consumption and the operation cost are remarkably reduced, and the inhibition capability of the system on load fluctuation is enhanced.

A precombustion chamber igniter with a retractable electric glow plug and a cold start control method for a methanol engine are provided. The precombustion chamber igniter includes a fuel injector, a spark plug, and an electric glow plug. The electric glow plug is retractable and has two working positions, at a first position, a heating segment is wholly located in an injection chamber to provide heat energy for the injection chamber, and at a second position, the heating segment is partially located in the injection chamber and passes through a first through hole, and the rest of the heating segment is located in a main combustion chamber of an engine, to provide heat energy for the injection chamber and the main combustion chamber. In a cold start stage of the engine, the heating segment of the electric glow plug is controlled to be located at the second position.

The invention belongs to the field of solid waste recycling, and relates to a hematite modified rice hull-based biochar material as well as a preparation method and application thereof. The preparation method comprises the following steps: carrying out ultrasonic treatment on rice husks in an ethanol solution, then soaking the treated rice husks in a mixed solution of methanol and formalin for activation, carrying out vacuum filtration and drying, and carrying out anaerobic calcination under the protection of a nitrogen atmosphere to obtain rice husk-based biochar; the method comprises the following steps: soaking rice husk-based biochar in an acid solution, and carrying out microwave digestion on the acid-modified rice husk-based biochar to obtain chemically-modified rice husk-based biochar; adding into a solution containing ferrous sulfate, fully stirring, and then carrying out hydrothermal treatment to obtain the hematite modified rice hull based biochar material. The method can significantly improve the conversion rate of organic matters in the sludge, increase the accumulated yield of biogas, effectively reduce the biotoxicity of heavy metals in the sludge, facilitate the resource utilization of the sludge, and have important significance for solving the environmental risk problem of the sludge.

The invention discloses a method for detecting antipsychotic drugs and metabolites thereof in a sample and a kit thereof, and relates to the technical field of biological detection.The kit comprises calibrators, quality control products, internal standard solutions and protein precipitators of 13 to-be-detected substances, and the protein precipitators comprise a zinc sulfate aqueous solution containing methanol, 13 analytes can be simultaneously detected, the separation degree of the to-be-detected substance is high, the detection time is short, the required sample size is small, and the method is suitable for TDM high-throughput detection of common antipsychotic drugs.

The present invention relates to a composition containing A) 60 to 93 wt. % of at least one aromatic polycarbonate, polyester carbonate or mixtures thereof, B) 2 to 20 wt. % of a polyester on the basis of an aromatic or cycloaliphatic dicarboxylic acid or mixtures thereof and cyclohexane dimethanol and optionally an additional aliphatic diol, and C) 1 to 20 wt. % of at least one phosphorus-containing flame retardant. The invention also relates to a component that contains the composition and to the use of components B and C in the indicated quantities in order to improve CTI and flame retardancy of polycarbonate compositions.

This invention discloses a method for preparing a CuZnAlGa-based layered double hydroxide (TLH)-derived catalyst for methanol production from carbon dioxide-rich syngas. Using Cu, Zn, Al, and Ga metal salts as precursors, Na₂CO₃ and NaOH as precipitants, and a mixed alcohol-water solution as an auxiliary solvent, co-precipitation is performed under controlled temperature and pH to obtain a LDH-like catalyst precursor. After high-temperature calcination and in-situ reduction in a hydrogen atmosphere, a layered framework structure of Cu nanoparticles immobilized by oxides is obtained. The LDH-like structure provides lattice confinement, preventing Cu particle aggregation, and the interaction between Cu and the oxides enhances the catalyst surface's adsorption capacity for CO and CO₂, thereby improving the activity and stability of methanol production from carbon dioxide-rich syngas.

The invention relates to a method and a system for synthesizing N-methylaniline and co-producing N, N-dimethylaniline by a gas phase method, and belongs to the technical field of chemical engineering. The system comprises a raw material gasification unit, a reaction unit, a separation and rectification unit and a hydrogen recovery unit which are connected through pipelines. The method comprises the following steps of: firstly, mainly synthesizing N-methylaniline from raw materials aniline and part of methanol in a first-methylaniline reactor, then partially or completely feeding first-methylaniline reaction gas into a second-methylaniline reactor, adding methanol steam, and further reacting to generate N, N-dimethylaniline. And after the product gas is subjected to heat exchange energy recovery, a liquid phase and a gas phase respectively enter the separation and rectification unit and the hydrogen recovery unit. The purification of N-methylaniline and N, N-dimethylaniline and the recovery of byproduct hydrogen are realized. The yield of N, N-dimethylaniline (in terms of aniline) can be adjusted in a range of 5-30% by adjusting reaction conditions and a feeding ratio.

The invention provides a technical application method for strengthening oxidation performance of Fenton reaction by a defect-rich carbon-based cocatalyst, and relates to the technical field of advanced oxidation catalysts for sewage treatment. Zinc nitrate and 2-methylimidazole are assembled in a methanol solution through a template method, a ZIF-8 material is obtained after centrifugal cleaning, the ZIF-8 is further carbonized through pyrolysis, Zn element is evaporated in the pyrolysis process, a porous and defect-rich carbon-based cocatalyst is obtained, the porous and defect-rich carbon-based cocatalyst is introduced into a Fenton oxidation system, circulation of Fe < 3 + > / Fe < 2 + > in the Fenton reaction can be efficiently promoted, and the catalytic activity of the catalyst is improved. Fe < 2 + > regeneration is enhanced, and the generation capability of active species of a Fenton reaction system is enhanced, so that the removal efficiency of pollutants in water is improved.