7365 results about "Methanol" patented technology

Provided is a laminate capable of electrolyzing an oxygen compound gas represented by CO2 with high conversion efficiency and suppressing deterioration in electrolytic performance. In this laminate having a structure in which an electrolyte layer is sandwiched between an anode catalyst layer and a cathode catalyst layer, a perovskite oxide and CuFe2O4 are contained in the cathode catalyst layer, and the content of CuFe2O4 in the cathode catalyst layer is at least 10 mass%.

The invention discloses a method for catalytically oxidizing lignin to depolymerize into an aviation oil intermediate by using a cellulose carbon aerogel supported copper nano-catalyst. Comprising the following steps: (1) dissolving cellulose powder into a mixed alkali solution of NaOH and urea, and stirring at low temperature to obtain a clear and transparent cellulose solution; and washing to be neutral to obtain well dispersed cellulose suspension. And (2) carrying out suction filtration molding, and freeze-drying for a period of time to obtain the cellulose aerogel. And (3) immersing in an ethanol solution of copper nitrate for ultrasonic treatment, and drying in a vacuum drying oven. And (4) carrying out high-temperature calcination in an N2 atmosphere to obtain a catalyst which is marked as Cu / CA. And (5) the catalyst can efficiently catalyze a Fenton-like reaction to oxidize a dimer model compound of lignin in acidic, neutral and alkaline environments to obtain products including benzoic acid, acetophenone, benzyl alcohol, phenol and the like, the required hydrogen peroxide concentration is low, and the catalyst has the advantages of simple process, high catalytic activity, low cost and the like, can be used for effectively degrading lignin to prepare aviation oil intermediates, and has wide application prospects. And repeated cyclic utilization is realized.

The invention relates to the technical field of methanol production, and discloses an efficient gas-liquid distribution device for a methanol synthesis reaction tower. The liquid distribution assembly is used for distributing a catalyst; the filler assembly is used for promoting gas-liquid contact; when the liquid distribution assembly runs, the liquid distribution assembly drives the atomization assembly to atomize the catalyst flowing on the inner wall of the tank body; the liquid distribution assembly comprises a rotating shaft, the rotating shaft is rotationally installed in the tank body, a wind wheel is fixedly connected to the rotating shaft, a liquid disc is fixedly connected to the top end of the rotating shaft, a plurality of first spray heads are hinged to the liquid disc, and hoses are arranged between the first spray heads and the liquid disc. Through the arrangement of the liquid distribution assembly, the multiple first spray heads can swing in a reciprocating mode in the rotating process, so that the spraying range of the first spray heads is expanded, the situation that spraying blind areas occur in the tank body is avoided, catalysts in the tank body are distributed more evenly, and the gas-liquid contact efficiency is improved.

The invention discloses a control method for improving the cold starting performance of a methanol extended-range hybrid power system, relates to the field of engine control, and solves the technical problem that the existing methanol engine starting mode has limited effects on the thermal atmosphere of methanol atomization, premixing and methanol injection ignition success under the low-temperature condition. The method comprises the steps that an engine starting success condition is set, the real-time environment temperature is obtained, when the real-time environment temperature is larger than the preset first starting temperature, a first starting strategy is adopted to start an engine, and whether the engine is started successfully or not is judged according to the engine starting success condition. The invention further discloses a system for improving the cold start performance of the methanol extended-range hybrid power system. Methanol atomization is promoted, methanol is fully premixed, and the successful thermal atmosphere effect and success rate of a methanol injection point are improved.

The invention relates to the technical field of preparation of catalysts, in particular to a catalyst for in-situ capture of carbon dioxide, a preparation method of the catalyst and application of the catalyst to preparation of methanol from methane, and the preparation method comprises the following steps: S1, mixing and stirring Bi (NO3) 3.5 H2O, dilute nitric acid and an adsorption modifier; s2, filtering to obtain a white precipitate, drying, slowly heating to 450 DEG C in a muffle furnace, and keeping the temperature for 20-30 minutes to obtain a faint yellow solid; s3, dispersing in a modified dissolving solution, sealing the reactor, and purging with argon for 10-15 minutes; and S4, injecting CH4, reacting for 2 hours under the irradiation of a xenon lamp, washing a solid obtained by suction filtration with deionized water, and drying at 60 DEG C for 10-12 hours to obtain the high-performance catalyst. The invention aims at the field of preparation of high-value chemicals from photocatalytic methane, solves the problem of generation of carbon dioxide by peroxidation of methane, and captures the peroxidation product carbon dioxide through the cooperation of the adsorption modifier and the modified dissolving solution to inhibit peroxidation of methane.

The invention relates to a preparation method and application of a porous material for preparing methanol through carbon dioxide adsorption and conversion. When the material is prepared, firstly, 4, 4 '4' '-(1, 3, 5-triazine-2, 4, 6-trimethylene) triphenylamine and 1, 2-acenaphthequinone are treated in a mixed solvent containing dioxane / acetonitrile / 6M acetic acid, and AT-COF is obtained; further synthesizing by adopting an impregnation method to obtain IrRu-COF; and finally, uniformly mixing the active gamma-aluminum oxide and the IrRu-COF material to form a carrier dispersion liquid, and then carrying out PEI loading, vacuum impregnation, washing and drying to obtain the PEI functionalized gamma-Al2O3 / COF composite catalyst. The technical closed loop from low-concentration CO2 capture to solar driven conversion is realized, the process flow is simple, and the energy consumption is low.

The invention discloses a low-temperature methanol washing RTO tail gas treatment device adopting a self-circulation air cooling double-valve-plate butterfly valve, and relates to the technical field of waste gas treatment. By arranging the condensation impurity removal mechanism, when coal waste gas passes through one condensation assembly, low-temperature tail gas cleaned by the low-temperature methanol washing mechanism can flow through a plurality of heat exchange pipes in the condensation assembly at the same time, so that the temperature of the outer walls of the heat exchange pipes is rapidly reduced to be below zero DEG C; coal tar gas and water vapor flowing through the low-temperature heat exchange pipe can be quickly cooled and solidified after being in contact with the outer wall of the low-temperature heat exchange pipe, so that the effect of separating the coal tar gas and the water vapor from the tail gas is achieved; a cold source which cannot be utilized and can influence subsequent RTO furnace treatment in the part of tail gas is ingeniously used for separating energy of coal tar and water vapor in the waste gas, a refrigerating device does not need to be independently arranged in the cooling and condensing process of the coal tar and the water vapor, and the purposes of energy conservation and emission reduction are achieved.

The invention discloses a preparation method of a crown ether functionalized anti-pollution nanofiltration membrane, which comprises the following steps: soaking a membrane of a commercial nanofiltration membrane in pure water, and coating the surface with a double-end epoxy compound ethanol solution; uniformly coating the surface of the membrane with an aza 12-crown-4 methanol solution; and drying the membrane in an atmosphere of 40-90 DEG C to obtain the crown ether functionalized anti-pollution nanofiltration membrane. The nano-filtration membrane is realized by chemically grafting aza 12-crown-4 on the membrane surface of a commercial nano-filtration membrane by utilizing a double-end epoxy compound; compared with a traditional nanofiltration membrane, the crown ether functionalized nanofiltration membrane provided by the invention has the advantages that the electronegativity of the surface is reduced, and the surface is similar to an aquatic plant molecular brush structure, so that the deposition of pollutants on the surface of the membrane can be effectively improved, and the anti-pollution performance of the membrane is enhanced; meanwhile, due to the complexing effect of 12-crown-4 molecules on lithium ions, the lithium ions can be effectively captured, concentration polarization of the lithium ions on the surface of the diaphragm is improved, and then the magnesium-lithium separation efficiency of the diaphragm is improved.

An example of a multi-fluid kit for three-dimensional (3D) printing includes a fusing agent and a surface treating agent. The fusing agent includes an electromagnetic radiation absorber and a first aqueous vehicle. The surface treating agent includes a second aqueous vehicle, a surfactant, and benzyl alcohol dissolved in the second aqueous vehicle.

This invention discloses a method for preparing a CuZnAlGa-based layered double hydroxide (TLH)-derived catalyst for methanol production from carbon dioxide-rich syngas. Using Cu, Zn, Al, and Ga metal salts as precursors, Na₂CO₃ and NaOH as precipitants, and a mixed alcohol-water solution as an auxiliary solvent, co-precipitation is performed under controlled temperature and pH to obtain a LDH-like catalyst precursor. After high-temperature calcination and in-situ reduction in a hydrogen atmosphere, a layered framework structure of Cu nanoparticles immobilized by oxides is obtained. The LDH-like structure provides lattice confinement, preventing Cu particle aggregation, and the interaction between Cu and the oxides enhances the catalyst surface's adsorption capacity for CO and CO₂, thereby improving the activity and stability of methanol production from carbon dioxide-rich syngas.

The invention provides a technical application method for strengthening oxidation performance of Fenton reaction by a defect-rich carbon-based cocatalyst, and relates to the technical field of advanced oxidation catalysts for sewage treatment. Zinc nitrate and 2-methylimidazole are assembled in a methanol solution through a template method, a ZIF-8 material is obtained after centrifugal cleaning, the ZIF-8 is further carbonized through pyrolysis, Zn element is evaporated in the pyrolysis process, a porous and defect-rich carbon-based cocatalyst is obtained, the porous and defect-rich carbon-based cocatalyst is introduced into a Fenton oxidation system, circulation of Fe < 3 + > / Fe < 2 + > in the Fenton reaction can be efficiently promoted, and the catalytic activity of the catalyst is improved. Fe < 2 + > regeneration is enhanced, and the generation capability of active species of a Fenton reaction system is enhanced, so that the removal efficiency of pollutants in water is improved.

The invention provides a high-molecular adsorption material with high selectivity on platinum group metals as well as a preparation method and application of the high-molecular adsorption material, and belongs to the technical field of material science. Comprising the following steps: (1) preparing a methanol solution containing platinum group metal ions, and adding a functional monomer mixture and modified graphene oxide to form a pre-assembled compound; (2) adding a cross-linking agent and an initiator, removing oxygen, and polymerizing to obtain a polymer; and (3) grinding the polymer, eluting metal ions, washing to be neutral, and drying. The high-molecular adsorption material provided by the invention takes modified graphene oxide as a support body, template molecules and specific functional monomers (4-vinylpyridine and 2-mercaptobenzimidazole) are combined to form a pre-assembled compound, then a cross-linking agent and an initiator are added, recognition sites are fixed through cross-linking polymerization, and finally, the high-molecular adsorption material is obtained after the template molecules are eluted. The adsorbent is high in adsorption rate, capable of specifically adsorbing platinum group metal, good in stability and reproducibility and capable of being repeatedly used.

The invention discloses a preparation method of a mesoporous Zn-ZSM-5 molecular sieve for preparing aromatic hydrocarbon from methanol, and belongs to the technical field of synthesis of inorganic materials. Aiming at the problems that a conventional mesoporous Zn / ZSM-5 molecular sieve catalyst Zn blocks orifices, the mesoporous structure is disordered, the molecular sieve solid yield is low, a molecular sieve framework is seriously damaged and the like, the preparation method comprises the following steps: uniformly mixing zinc gluconate with an aluminum source, a silicon source and a template agent, putting the mixture into a closed reaction container, carrying out hydrothermal crystallization, and sequentially washing, drying and roasting to obtain the mesoporous Zn / ZSM-5 molecular sieve catalyst. The sodium type molecular sieve is obtained; the preparation method comprises the following steps: carrying out multiple ion exchange on a sodium type molecular sieve by using an ammonium chloride solution, and sequentially carrying out suction filtration, washing, drying and roasting to obtain the mesoporous Zn-ZSM-5 molecular sieve. According to the preparation method of the methanol-to-aromatic hydrocarbon Zn / ZSM-5 molecular sieve provided by the invention, the obtained molecular sieve is used in the methanol-to-aromatic hydrocarbon process, and has the characteristics of high carbon deposition resistance, high aromatic hydrocarbon selectivity, low Zn wastage rate and the like.

The invention provides a Pt-Sn bimetallic catalyst and a preparation method and application thereof.The preparation method comprises the steps that 1, a Y molecular sieve is placed in a mixed solution of KOH and methyl alcohol, centrifugation and washing are conducted till the Y molecular sieve is neutral after stirring, drying and roasting are conducted, and a non-acid KY molecular sieve is obtained; the silica-alumina ratio of the Y molecular sieve is 3-100; 2) taking the non-acidic KY molecular sieve as a carrier, and loading Sn by adopting an atomic layer deposition technology to obtain a Sn-modified non-acidic KY molecular sieve; and 3) loading Pt by using the Sn-modified non-acidic KY molecular sieve as a carrier and adopting an atomic layer deposition technology to obtain the Pt-Sn bimetallic catalyst. According to the preparation method provided by the invention, spatial distribution of Pt and Sn is accurately regulated and controlled by combining an atomic layer deposition technology, so that the electronic state of Pt species is adjusted, alkane is promoted to be dehydrogenated into an olefin intermediate, and the aromatization catalytic activity and the aromatic hydrocarbon selectivity of alkane are improved.

The invention belongs to the field of detection and analysis, and relates to a method for separating and detecting enantiomers in (S)-2-amino-3-[2-(tert-butoxy)-2-oxoacetamido] tert-butyl propionate hydrochloride. According to the method, HPLC is adopted for separation and detection, a polysaccharide derivative chiral chromatographic column is selected as a chromatographic column, a mobile phase A is a weak base aqueous solution, and a mobile phase B is acetonitrile and / or methanol. The method is strong in specificity, high in separation degree, high in accuracy, stable, reliable and high in sensitivity, and a simple, accurate, rapid and reliable detection method is provided for control of impurities in a starting material of (S)-2-amino-3-[2-(tert-butoxy)-2-oxoacetamido] tert-butyl propionate hydrochloride.

The invention discloses a Pt-ZnO / In2O3 catalyst for preparing methanol through hydrogenation of carbon dioxide and a preparation method of the Pt-ZnO / In2O3 catalyst, and relates to the technical field of catalyst preparation, and the preparation method comprises the following steps: preparing a ZnO / In2O3 catalyst by using a coprecipitation method; and loading platinum on the surface of the ZnO / In2O3 catalyst by an impregnation method to obtain the Pt-ZnO / In2O3 catalyst. The Pt-ZnO / In2O3 catalyst does not generate a sintering phenomenon in the use process, has long-term stability, realizes modification of the In2O3-based catalyst by adding zinc oxide, and can significantly improve the conversion rate of carbon dioxide and product selectivity.

The invention discloses a preparation method of EVOH, and relates to the technical field of EVOH. According to the method, a low-temperature (0-5 DEG C) methanol-n-hexane mixed solvent system is creatively adopted and matched with a penetration enhancer to realize synergistic extraction, so that synchronous and deep removal of polar and non-polar small molecular impurities in the EVA is finally realized, the content of impurities in the EVA is remarkably reduced, and the self-polymerization reaction of residual monomers is effectively inhibited; therefore, a key guarantee is provided for subsequent preparation of high-quality EVOH products. The film processed by the EVOH prepared by the invention has the characteristics of few crystal points and high product quality, and can be applied to the field of high-barrier packaging film materials.

The invention belongs to the technical field of traditional Chinese medicine detection, and discloses a detection method for a characteristic spectrum of Uighur medicine Kspecific heat extracting tablets and application of the detection method. The detection method provided by the invention comprises the following steps: preparing a test sample solution by taking a 75% methanol solution as a solvent, and determining the test sample solutions prepared from different batches of test samples by adopting ultra-high performance liquid chromatography to obtain a characteristic spectrum; the chromatographic conditions of the ultra-high performance liquid chromatography are as follows: a chromatographic column is a C18 chromatographic column, a mobile phase A is acetonitrile, a mobile phase B is a 0.1 vol% phosphoric acid solution, and the flow velocity is 0.25-0.35 mL / min; the detection wavelength is 0 to 18 minutes, and the wavelength is 327 nm; the time is 18 to 28.5 min, and the wavelength is 254 nm; when the time is 28.5 to 37.6 minutes, the wavelength is 242 nm; after 37.6 to 70 minutes, the wavelength is 210 nm; the sample size is 1 microliter, the column temperature is 20-40 DEG C, and gradient elution is carried out. The invention provides a more scientific identification and quality control method for the Kespecific heat tablets.

The utility model discloses a heat source optimizing device for a reboiler of a methanol pre-rectifying tower, which comprises the pre-rectifying tower and the reboiler, and is characterized in that a branch pipeline is separated from the crude methanol discharge of a tower kettle and is connected with a negative pressure flash tank, and the crude methanol in the negative pressure flash tank is subjected to gas-liquid separation through flash evaporation; the bottom of the negative-pressure flash tank is connected with a methanol circulating pump, and a liquid-phase material is conveyed to a first heat exchanger at the top of the tower and returns to the negative-pressure flash tank after exchanging heat with steam at the top of the tower; a gas-phase material in the negative-pressure flash tank enters a compressor, is compressed and heated and then returns to the tower kettle of the pre-rectifying tower; according to the utility model, the process is improved by combining flash evaporation of a tower kettle discharge part with heat pump rectification, and meanwhile, the flash evaporation liquid is recycled to recycle steam heat at the top of the tower, so that the steam consumption of a reboiler of the methanol pre-rectifying tower and the use amount of circulating water at the top of the tower are effectively reduced, meanwhile, the reboiler does not need to be added, and the compression ratio of a heat pump compressor can be reduced.

The invention discloses preparation of a phenanthroline-based covalent organic framework photocatalyst and application of the phenanthroline-based covalent organic framework photocatalyst in photocatalytic production of hydrogen peroxide. According to the method, a hydrogen peroxide production experiment is carried out in a water-oxygen system or a benzyl alcohol-water-oxygen system by taking phenanthroline-based COF as a photocatalyst. According to the invention, through regulation and control of molecular flatness engineering, an electron-rich phenanthroline unit (Phen) anchored by a pyridine expansion plane and electron-deficient triazine (TTA) are integrated into a COF skeleton, and a novel electron donor-acceptor (D-A) type COF is synthesized. The COF has the advantages of proper energy band structure, excellent photo-induced electron and hole separation efficiency, strong D-A interaction, good hydrophilicity and the like, and the efficiency of photocatalytic hydrogen peroxide production reaction within a short time is greatly improved. The invention provides a use method of the COF photocatalyst which is cheap, convenient, rapid, efficient and environment-friendly, and has a potential application prospect.

The invention discloses a large-current-carrying-capacity flexible power cable, which belongs to the technical field of cable preparation, is used for solving the technical problem that the flame retardant property and the mechanical property of the power cable need to be further improved in the prior art, and specifically comprises a cable core, a wrapping layer, an insulating layer and a sheath layer which are sequentially arranged from inside to outside. The preparation method comprises the following steps: preparing alkoxy silane containing a benzocyclobutene group, preparing flame-retardant particles by using a sol-gel method, preparing modified polyurethane by using modified polysiloxane and 2, 5-furandimethanol as soft segments, naphthalene diisocyanate as a hard segment and trimethylolpropane as a chain extender, and preparing the flame-retardant flame-retardant polyurethane. The linear low-density polyethylene, the MAH-g-PE, the modified polyurethane, the flame-retardant particles and the auxiliary additive are melted and extruded outside the wire core to form the insulating layer, so that the power cable is obtained, the flame-retardant property of the power cable is effectively improved, and the mechanical property and the current-carrying stability of the power cable are also improved.

The present invention discloses a method, device and application for producing aviation kerosene from methanol, and belongs to the field of petrochemical product processing technology. The method comprises: generating a methanol dehydration reaction product from a methanol raw material under the catalytic action of a first molecular sieve catalyst, separating and treating the methanol dehydration reaction product, and then mixing it with one or more of recycled fuel gas, recycled liquefied gas or recycled gasoline under the catalytic action of a second molecular sieve catalyst to generate a reaction oil gas, the reaction oil gas is fractionated to obtain a kerosene fraction, and the kerosene fraction is subjected to a hydrogenation and refining treatment to obtain aviation kerosene. The method for producing aviation kerosene using methanol as a raw material provided by the present invention has opened up a new way to produce aviation kerosene; the process flow is short and compact, and can effectively achieve energy conservation and emission reduction.

The invention provides application of a silver-bismuth tungstate catalyst in preparation of methanol from light-driven CO2, and belongs to the technical field of CO2 conversion and reduction. Bismuth tungstate nanosheets, silver salt and water are mixed, the size of silver particles is controlled by adjusting the pH value, the silver-bismuth tungstate catalyst is obtained, and the size of the silver particles is 20-50 nm; silver is evenly distributed on the surface of bismuth tungstate, the obtained silver-bismuth tungstate catalyst is large in specific surface area and high in light response capacity, the silver-bismuth tungstate catalyst can generate a large number of high-energy hot electrons during illumination, in-situ photo-thermal conversion is achieved, no external heat source is needed for heat supply, the photo-thermal effect is enhanced, CO2 conversion is promoted, and the methanol yield is increased.

The invention discloses a preparation method and application of a high-nitrogen-doped ordered mesoporous carbon supported copper catalyst, and belongs to the technical field of catalyst preparation. The preparation method comprises the following steps: by taking cane sugar and a copper-nitrogen complex as raw materials, SBA-15 as a template agent and sulfuric acid as a catalyst, carrying out equivalent-volume impregnation, low-temperature heat treatment, 800-900 DEG C high-temperature carbonization and nitric acid / hydrofluoric acid demolding to prepare pyrrole nitrogen enriched or pyridine nitrogen enriched high-nitrogen doped ordered mesoporous carbon with a large specific surface area; the preparation method comprises the following steps: loading a copper species on high-nitrogen-doped ordered mesoporous carbon by adopting an equivalent-volume impregnation method, and reducing at 350-400 DEG C to prepare the high-nitrogen-doped ordered mesoporous carbon loaded copper catalyst. The prepared catalyst is high in nitrogen content, large in specific surface area, high in pyridine nitrogen or pyrrole nitrogen enrichment degree and uniform in copper particle dispersion and shows efficient catalytic performance in methanol oxidative carbonylation reaction, and the highest methanol conversion rate is 9.3%.

The invention relates to the technical field of repair materials, and particularly discloses an extracellular matrix fiber material as well as a preparation method and application thereof. The invention discloses a preparation method of an extracellular matrix fiber material. The preparation method comprises the following steps: taking animal tissues, and carrying out virus inactivation, decellularization and antigen removal, degreasing, drying, grinding and sterilization; the decellularization and antigen removal method comprises the following specific steps: sequentially soaking a sample with a surfactant solution for h; then, soaking treatment is carried out by adopting a salt-alkali solution which contains 0.05-3 mol / L of salt and has the pH value of 8-11; then carrying out soaking treatment by adopting a 0.1-1wt% enzyme solution; and in degreasing, one or more of normal hexane, trichloromethane, dichloromethane, methanol, ethanol, acetone, diethyl ether and ethyl acetate are used for soaking the sample. According to the technical scheme, the ECM powder particle material with high growth factor content is prepared.

The invention discloses a high-solid-content MIL-101 (Fe) / PIM-1 mixed matrix membrane and a preparation method thereof, and belongs to the technical field of gas separation membranes. The preparation method comprises the following steps: firstly, dissolving an iron source in a PIM-1 polymer solution to form a homogeneous membrane casting solution; forming the obtained membrane casting solution, and removing the solvent to obtain a PIM-1 / Fe (II) composite substrate containing Fe (III); then, the substrate is alternately immersed in a terephthalic acid methanol solution and a ferric salt methanol solution, and MIL-101 (Fe) is generated in the polymer matrix through in-situ limited crystallization by layer-by-layer limited crystallization. According to the method, the problem of interfacial compatibility between the MOF filler and the polymer matrix is effectively solved, and high loading capacity (up to 52.9 wt.%) of MIL-101 (Fe) is realized without agglomeration. Meanwhile, the membrane has excellent COplasticizing resistance and long-term operation stability, and has a wide application prospect in the fields of carbon capture and the like.

The invention relates to the technical field of multi-layer copolyester films, and discloses a high-temperature-resistant antistatic multi-layer copolyester film and a preparation method and application thereof, and the multi-layer copolyester film comprises an ABA three-layer structure obtained through melt co-extrusion; the layer A is prepared from the following raw materials in percentage by mass: 5 to 30 percent of anti-blocking agent master batch and the balance of modified copolyester; the raw material of the layer B is modified copolyester; the modified copolyester is prepared from a binary acid mixture, a dihydric alcohol mixture and a catalyst through an esterification reaction and a condensation polymerization reaction; the binary acid mixture comprises furandicarboxylic acid and 2, 2 '-bifuran-5, 5'-dicarboxylic acid, and the dihydric alcohol mixture comprises ethylene glycol, 2, 2, 4, 4-tetramethyl-1, 3-cyclobutanediol and 1, 4-cyclohexanedimethanol. According to the invention, the modified copolyester is used as a main raw material, and the film is endowed with good temperature resistance in a copolymerization modification manner, and has stable and lasting antistatic performance.

The invention relates to the technical field of wastewater treatment, and provides a treatment method of glycine production wastewater. The treatment method of glycine production wastewater comprises the following steps: (1) rectifying glycine wastewater to recover methanol, adding dilute sulphuric acid to adjust the pH value to 2.5-3.0, stirring, and standing; (2) transferring the supernate into another container, adding a ZIF-8 modified material, stirring, standing, filtering, collecting filter residues and filtrate, washing the filter residues with diethyl ether, and recovering urotropine; and (3) evaporating and concentrating the filtrate under the vacuum condition of-0.08 MPa and the temperature of 50-60 DEG C, and separating out high-purity ammonium chloride crystals. According to the treatment method for the glycine production wastewater, the problem that an existing treatment method is poor in removal effect on urotropin in the glycine production wastewater is solved; and the treated glycine production wastewater reaches the discharge standard.

The invention relates to the technical field of chemical production, in particular to a method for efficiently synthesizing epichlorohydrin. The method provided by the invention comprises the following steps: adding a mixed solution of chloropropene and methanol and part of hydrogen peroxide into a reactor; then injecting residual hydrogen peroxide through a middle-section feeding hole of the reactor; constant-temperature circulating water is adopted to control a front-section temperature control area of the reactor to be at a first temperature, a middle-section temperature control area of the reactor to be at a second temperature and a rear-section temperature control area of the reactor to be at a third temperature, and the third temperature, the first temperature and the second temperature are gradually increased in sequence. The method provided by the invention can effectively solve the problems of side reaction increase, too fast catalyst deactivation and the like caused by local overheating of the fixed bed reactor, and significantly improves product selectivity and production efficiency.

The invention discloses a zero-carbon park multi-energy collaborative optimization system based on electricity-carbon-hydrogen-alcohol coupling, and the system comprises a multi-energy flow coupling architecture which constructs a closed-loop system formed by connecting a renewable energy power generation module, a green hydrogen preparation module, a methanol synthesis module and a carbon capture module; the intelligent optimization model is deployed in a system control layer and comprises a multi-target collaborative optimization algorithm execution unit; the self-adaptive regulation and control system comprises a weather prediction module, a load demand analysis module and an equipment parameter regulation module; the system comprises a digital management platform, three-dimensional visualization, an integrated server and block chain nodes. Therefore, according to the system, a multi-energy-flow closed-loop architecture is constructed, energy flow efficient cooperation is achieved through intelligent optimization and self-adaptive regulation and control, the resource configuration precision is improved in combination with digital management, the utilization rate of renewable energy sources can be effectively increased, and the system flexibility is enhanced.