388 results about "Catalyst regeneration" patented technology

A reactor system includes a reactor that treats a lipid feedstock using a metal oxide catalyst to produce a treated stream comprising a bio-oil. The reactor system includes a catalyst zone in which the metal oxide catalyst reacts with the lipid feedstock to produce the treated stream. The reactor system operates in a reaction mode, during which the lipid feedstock flows in a downward direction through the metal oxide catalyst to produce the treated stream. Alternately, the reactor also operates in a regeneration mode, during which coke is burned from the metal oxide catalyst thereby regenerating the metal oxide catalyst. In one aspect, a regeneration mode pressure is less than a reaction mode pressure within the reactor to fluidize the catalyst.

A process for upgrading plastic derived oil includes contacting the plastic derived oil with a mixed catalyst in a first reactor, where the mixed catalyst includes a decontamination catalyst and a cracking catalyst different from the decontamination catalyst. The first reactor reduces concentrations of halogen-containing compounds in the plastic derived oil. The process includes passing the first reactor effluent to a second reactor and contacting the first reactor effluent with the cracking catalyst to produce a second effluent comprising light olefins and naphtha range hydrocarbons. The process includes separating used mixed catalyst from the first reactor to produce a used decontamination catalyst and a second used cracking catalyst, and regenerating the decontamination catalyst and cracking catalyst in separate regenerators to reduce exposure of the cracking catalyst to halogen-containing compounds produced during regeneration of the used decontamination catalyst.

A process for upgrading plastic derived oil includes contacting a plastic derived oil stream with a decontamination catalyst in a first reactor, separating a first reactor effluent from a used decontamination catalyst, passing the first reactor effluent to a second reactor downstream of the first reactor, contacting the first reactor effluent with a cracking catalyst in the second reactor, and separating a second reactor effluent from a used cracking catalyst. The cracking catalyst is different from the decontamination catalyst. The process further includes regenerating the used decontamination catalyst in a decontamination catalyst regenerator to produce regenerated decontamination catalyst, and regenerating the used cracking catalyst in a cracking catalyst regenerator separate from the decontamination catalyst regenerator to produce regenerated cracking catalyst. Regenerating the used cracking catalyst separately reduces deactivation of the cracking catalyst by halogen-containing compounds produced during regeneration of the decontamination catalyst.

The invention relates to the field of biomass energy conversion, in particular to a multi-mode intelligent purification system and method for a biomass gasifier, and the system integrates five modules of self-adaptive multi-field coupling tar cracking, multi-dimensional real-time intelligent monitoring, in-situ nano catalyst regeneration, energy cascade recovery and digital twin driving. According to the system, through the synergistic effect of an electric field, ultrasonic waves, catalysis and a temperature gradient, the tar removal efficiency is remarkably improved to 99.5% or above, the content of tar at an outlet is lower than 5 mg / Nm < 3 >, an intelligent monitoring module collects technological parameters in real time, and precise control is ensured; the catalyst regeneration module performs in-situ regeneration on a catalyst based on monitoring data to maintain efficient operation of the system; the energy recovery module utilizes heat energy in a gradient mode and optimizes energy configuration, the digital twin module constructs a system digital model, optimization and predictive maintenance of real-time data driving are achieved, and the system achieves innovation breakthrough of intelligence and energy conservation while improving the biomass gasification purification efficiency.

The utility model discloses low-temperature denitration catalyst regeneration equipment, and relates to the technical field of denitration catalyst regeneration, the low-temperature denitration catalyst regeneration equipment comprises a treatment box and a soaking box, a water flow driving mechanism is arranged at the bottom of the treatment box and is used for driving water flow to separate dust particles which are stubborn in adhesion; according to the low-temperature denitration catalyst regeneration equipment, three-dimensional circulating vertical water flow is formed through the water flow driving mechanism, and the low-temperature denitration catalyst regeneration equipment is formed by combining the chemical action of a cleaning agent; according to the low-temperature denitration catalyst regeneration cleaning device, double cleaning of physical washing and chemical dissolution of stubborn dust particles on the surface and in pores of a low-temperature denitration catalyst body is achieved, the problem that dust is difficult to separate in traditional soaking cleaning is effectively solved, and the regeneration separation effect is remarkably improved; accurate movement of the low-temperature denitration catalyst body in the horizontal direction and the vertical direction is achieved, and manual intervention is reduced through automatic operation.

The invention discloses a method for efficiently preparing 1, 1, 2, 3-tetrachloropropene, which comprises the following steps: by taking 1, 1, 2, 2, 3-pentachloropropane / 1, 1, 1, 2, 3-pentachloropropane as a raw material, carrying out dehydrochlorination reaction in a tank reactor under the action of a composite catalyst to prepare the 1, 1, 2, 3-tetrachloropropene. Compared with the traditional dehydrochlorination of alkali liquor, the method has the advantages of less generation of three wastes, simple process operation and easiness in industrial implementation. The prepared composite catalyst can be suitable for pentachloropropane of different structures as a raw material, the catalyst compatibility is high, the application scene is wide, the composite catalyst is good in catalytic activity and high in selectivity, and the selectivity of tetrachloropropene is 95% or above and can reach 99% to the maximum. Meanwhile, the composite catalyst is good in regeneration performance, the inactivated catalyst is easy to regenerate, and the catalytic activity is not reduced after regeneration; the composite catalyst material is easy to obtain and low in price, the production cost can be greatly saved, and industrial production is facilitated.

The invention relates to a combustion optimization and cryogenic separation-based carbon dioxide enrichment and hydrogen production synergy process for a combined device, which is characterized in that regeneration of a spent catalyst in a catalytic cracking device is changed into pure oxygen incomplete combustion, and circulating carbon dioxide is used for stabilizing fluidization and controlling tail combustion. And after the regenerated flue gas is subjected to deep purification and cryogenic separation, the part rich in carbon monoxide is fed into a medium-temperature change reactor of the steam hydrocarbon reforming device for hydrogen production, so that resource upgrading of catalytic coke is realized. And compressing and cooling the part rich in carbon dioxide to obtain about 98% of liquid phase product for subsequent application. According to the catalytic cracking device, only the regenerator needs to be adjusted, the deep purification and compression cryogenic separation unit is additionally arranged, the hydrogen production device can improve the treatment capacity of the medium-temperature change reactor, implementation is convenient, and the catalytic cracking device is suitable for new and old devices. The invention further relates to a system for carbon dioxide enrichment and hydrogen production synergy of the integrated device based on combustion optimization and cryogenic separation.

The present invention relates to a temperature regulation device and a temperature regulation method for denitration catalyst regeneration. The device includes a first furnace unit, a second furnace unit and a temperature regulation component. The method includes: putting a catalyst into the first furnace unit, closing the first pipeline, heating the first furnace unit to a preset temperature threshold; opening the first pipeline and turning on the induced draft fan, adjusting the rotational speed of the induced draft fan to control the cooling rate in the first furnace unit within a first preset speed range. When the temperature difference between the first furnace unit and the second furnace unit is within a preset temperature difference range, close the first pipeline, and connect the first furnace unit to the atmosphere, and adjust the rotational speed of the induced draft fan to control the cooling rate in the first furnace unit within a second preset speed range. When the temperature in the first furnace unit reaches room temperature, turn off the induced draft fan and take out the catalyst. The device and method provided by the present invention not only control the first furnace unit and the second furnace unit to alternately heat up and cool down, but also can accurately adjust the heating / cooling rate, and also utilize the waste heat in the furnace to save energy.

The invention relates to the technical field of synthesis of organic compounds, and discloses a dibenzoylmethane preparation method, which comprises the following steps: preparation of a functionalized ionic liquid, preparation of a deep eutectic solvent, construction of a composite system, implementation of a condensation reaction, regeneration of catalytic active sites, pH adjustment, crystal separation and the like. According to the method, a temperature-responsive two-phase system formed by the functionalized ionic liquid and the deep eutectic solvent is combined with a catalyst regeneration process and a pH regulation crystallization separation technology, so that the greenization, high efficiency and integration of the dibenzoylmethane synthesis process are realized, the product purity and yield are remarkably improved, and the environmental pollution and the production cost are reduced.

A process for upgrading plastic derived oil includes contacting the plastic derived oil with a mixed catalyst in a first reactor, where the mixed catalyst includes a decontamination catalyst and a cracking catalyst different from the decontamination catalyst. The first reactor reduces concentrations of halogen-containing compounds in the plastic derived oil. The process includes passing the first reactor effluent to a second reactor and contacting the first reactor effluent with the cracking catalyst to produce a second effluent comprising light olefins and naphtha range hydrocarbons. The process includes separating used mixed catalyst from the first reactor to produce a used decontamination catalyst and a second used cracking catalyst, and regenerating the decontamination catalyst and cracking catalyst in separate regenerators to reduce exposure of the cracking catalyst to halogen-containing compounds produced during regeneration of the used decontamination catalyst.

The invention discloses a production system and method for preparing high-carbon aldehyde through carbonyl synthesis of high-carbon olefin. The system comprises a reaction device, a separation device, an aldehyde condensing device, a product tank, a polymer supplementing unit and a recycling unit, the polymer supplementing unit is connected with the separating device; the cyclic utilization unit comprises an extraction separation device connected with a liquid phase outlet of the separation device, a polymer recovery device connected with a water phase outlet of the extraction separation device, and a catalyst regeneration device connected with an organic phase outlet of the extraction separation device. According to the method, a carbonyl metal catalytic system is adopted to catalyze reaction of high-carbon olefin and synthesis gas, and heating separation of reaction liquid is performed by introducing an organic polymer protection catalyst; the separated catalyst liquid phase is subjected to water extraction separation and post-treatment, and the organic polymer and the catalyst are recycled. Recycling of the catalyst and efficient separation of the product are realized, and the stability of the catalyst separation section is enhanced.

The present invention relates to a production process for synthesizing hexamethylenediamine by catalytic hydrogenation of adiponitrile. The process comprises the following steps: 1) preparing a catalyst precursor; 2) calcining the catalyst precursor to obtain a catalyst; 3) catalytic hydrogenation of adiponitrile under the condition of the catalyst to synthesize crude hexamethylenediamine; 4) separating hexamethylenediamine from the discharge of a fluidized bed reactor containing crude hexamethylenediamine. The present invention uses Ni(NO3)2 and / or Mg(NO3)2 as main raw materials, doped with transition metal oxides, and then performs ultrasonic adsorption using Al2O3 as a catalyst carrier to load Ni(NO3)2 and / or Mg(NO3)2 and transition metal oxides on Al2O3, and obtains a catalyst through high-temperature calcination. The doping of transition metal oxides can improve the basicity of the catalyst, eliminating the need to add a strong basic co-catalyst in the catalytic reaction stage, reducing by-product formation. Moreover, it increases the specific surface area of the catalyst, thereby reducing the adsorption of the reaction product hexamethylenediamine on the catalyst, extending the service life of the catalyst, and saving the energy consumption for catalyst regeneration.

The invention discloses a catalytic filter material loaded with a Mn-CoOx composite metal oxide, a preparation method of the catalytic filter material and a regeneration method after sulfur poisoning, and belongs to the technical field of industrial tail gas denitration. According to the catalytic filter material prepared by the invention, through a complete technical route of surface functional modification of polydopamine, hydrothermal in-situ growth of a manganese-cobalt catalyst and activation by dipping in hydrogen peroxide, the dust removal function of the catalytic filter material used as the filter material is reserved, and the originally inert polymer fiber surface is activated, so that the catalyst is uniformly dispersed on the surface of the filter material and is firmly loaded on the surface of the filter material. The catalytic filter material which is poisoned and inactivated by sulfur dioxide is soaked in the hydrogen peroxide solution, so that the catalyst is regenerated, the method has the advantages of greenness, simplicity, convenience, low cost and the like, and the service life of the catalytic filter material is effectively prolonged. In conclusion, the catalytic filter material prepared by the invention is high in denitration rate, strong in combination firmness, good in stability, renewable after inactivation, green and low in cost, and has important application value in the technical field of dust removal and denitration.

A catalyst regeneration gas loop is operated in a heat exchanger decoking mode. A regeneration gas is diverted away from a burn zone of the catalyst regeneration gas loop and to a heat exchanger, where coke deposits are disposed on a surface of the heat exchanger. The regeneration gas is prevented from flowing to an oxychlorination / calcination zone of the catalyst regeneration gas loop. Within the heat exchanger, the coke deposits are combusted with oxygen of the regeneration gas, thereby removing the coke deposits from the surface of the heat exchanger and producing carbon dioxide. Oxygen is replenished to the regeneration gas. The regeneration gas is recycled to the heat exchanger.

The invention relates to the technical field of carbon dioxide separation, and discloses a method and a device for capturing and fixing carbon dioxide in ship tail gas. The method comprises the following steps: introducing seawater, an amine catalyst and ship tail gas into a CO2 trapping tower to complete CO2 absorption reaction, and discharging decarburized tail gas and a mixed solution I; introducing the mixed solution I into a CO2 immobilization reactor, carrying out solid-liquid separation after completing a CO2 immobilization precipitation reaction, and discharging a CO2 immobilization product and a mixed solution II; the mixed solution II is introduced into a catalyst regenerator, after a catalyst regeneration reaction is completed, solid-liquid separation is carried out, a CO2 fixed product and a mixed solution III are discharged, and the mixed solution III is concentrated and reused in S1. By adopting the method disclosed by the invention, the regeneration energy consumption of the amine catalyst can be reduced, and the CO2 is directly fixed to form a solid-phase product after being captured, so that the subsequent processes of compressing, liquefying and storing the CO2 in a storage tank can be omitted, and the occupied area of the device is reduced.

The present invention provides a catalyst regeneration apparatus and a catalyst regeneration method that can regenerate a degraded catalyst while suppressing a decrease in production efficiency during the production of a predetermined product. [Solution] A catalyst regeneration device for a reactor 3 that produces a predetermined product by catalytic action of catalysts in each reaction tube 2 using a plurality of reaction tubes 2, each filled with catalyst C, while continuing to introduce the raw material gas, the device comprises a catalyst degradation detection unit for detecting whether or not the catalyst C in each of the plurality of reaction tubes 2 has deteriorated, a regeneration gas supply unit 6 capable of supplying a predetermined regeneration gas to each reaction tube 2 for regenerating the deteriorated catalyst C, and a control unit 7 that controls the regeneration gas supply unit to supply regeneration gas to the reaction tube 2 having a catalyst C that has been detected to have deteriorated based on the detection results from the catalyst degradation detection unit.

The invention relates to the technical field of hydrogen production through methane cracking, in particular to a sea urchin-shaped composite catalyst, a preparation method thereof and application of the sea urchin-shaped composite catalyst in hydrogen production through methane cracking. The obtained sea-urchin-shaped composite catalyst has a sea-urchin-shaped appearance, can efficiently catalyze methane cracking to produce hydrogen, simultaneously captures CO2 produced by vapour gasification carbon deposition in a catalyst regeneration process to generate CaCO3, promotes the gasification hydrogen production of the carbon deposition and strengthens the removal effect of the carbon deposition, and the generated CaCO3 can also be converted into CO in situ, so that the catalyst has a good application prospect. The obtained catalyst has good anti-sintering performance and excellent recycling performance.

The utility model provides a kind of cleaning device for flue gas denitration catalyst regeneration, it is related to catalyst cleaning technical field, when using, as shown in Figure Three, multiple ventilation type high pressure gas blowing components are evenly arranged in the inside of cleaning pool main body, and multiple gas blowing ports are evenly arranged on the surface of the hollow blast pipe in the inside, after filling cleaning fluid in the inside of cleaning pool main body, as shown in Figure Two, ventilation type high pressure gas blowing component is blown by high pressure gas blowing pipe at both ends simultaneously, so that the gas blowing amount of the gas blowing port on the surface of each hollow blast pipe is consistent, so that the cleaning fluid in the inside is rapidly bubbled, so that the porous denitration catalyst placed on the upper end of support isolation component is efficiently cleaned, and the cleaning fluid is driven by ventilation type high pressure gas blowing component to rapidly clean the nitration agent in the inside of porous denitration catalyst by rapid bubbling, and the cleaning efficiency is increased.

The present application relates to the technical field of catalyst regeneration, and discloses a regeneration method of deactivated denitration catalysts. The regeneration method comprises the following steps: (1) performing at least one heat treatment on the deactivated denitration catalyst monomer; (2) placing the deactivated denitration catalyst monomer after heat treatment in an electrolyte solution for electrochemical treatment, and then performing rinsing; (3) placing the deactivated denitration catalyst monomer after rinsing in a mechanical reinforcement solution and an active component supplement solution in sequence for impregnation; and (4) performing oxidation calcination on the deactivated denitration catalyst monomer after impregnation, and then performing reduction. The method can perform overall regeneration on the deactivated denitration catalysts caused by metal elements such as Fe, Pb, Cu and As, organic matters such as COD, and hydrogen sulfate ammonium type miscellaneous salts, the regenerated denitration catalyst obtained can maintain the integrity of the structure, has higher mechanical strength and catalytic activity, and can be directly put into use.

The invention discloses a persulfate oxidation-based fixed bed catalysis high-salt organic wastewater treatment device and a persulfate oxidation-based fixed bed catalysis high-salt organic wastewater treatment process. The fixed bed catalysis high-salt organic wastewater treatment device comprises a pretreatment system, a liquid-solid catalytic reaction system, a reverse osmosis system and a catalyst regeneration and treatment system, and the liquid-solid catalytic reaction system comprises a primary filtration and adsorption unit, a primary catalytic oxidation unit, a secondary catalytic oxidation unit and a secondary adsorption and filtration unit. A baffle plate is arranged between every two units, so that the turbulence of wastewater is enhanced, and the liquid-solid mass transfer efficiency is improved. The treatment device disclosed by the invention has the advantages of continuous operation, salt interference resistance, low operation cost and the like, can realize efficient removal of the high-salt organic wastewater, and is suitable for treatment and recycling of the high-salt organic wastewater in the industries of coal chemical industry, pharmacy, printing and dyeing and the like.

A fluidized catalytic cracking unit system includes: a fluidized catalytic cracking unit assembly including a first catalyst regenerator and a cracking unit, the cracking unit configured to output spent catalyst to the first catalyst regenerator; and a reformer-electrolyzer-purifier assembly comprising a reformer-electrolyzer-purifier cell, the reformer-electrolyzer-purifier cell comprising an anode section and a cathode section.

The application discloses the technical field of waste gas purification catalyst regeneration, and discloses a regeneration process of a low-temperature SCR denitration catalyst; the process comprises the following steps: after the deactivated catalyst is cleaned through ultrasonic cleaning, the deactivated catalyst is sequentially immersed in a chemical activation liquid and an oxidation treatment liquid for activation and oxidation treatment, then the deactivated catalyst is immersed in a water dispersion liquid containing tungsten-silicon heteropoly acid-zirconium titanium composite oxide core-shell structure material and polyvinylpyrrolidone, vacuum-assisted impregnation, drying and gradient temperature heat treatment are carried out, and a regenerated catalyst is obtained. The core-shell structure material is prepared by the following steps: synthesizing a titanium zirconium composite oxide carrier through a sol-gel method, loading cerium manganese active components through a coprecipitation method, modifying silicotungstic acid through a layer-by-layer self-assembly technology and surface silanization modification. The regenerated catalyst has the advantages of significant improvement in sulfur resistance and alkali metal poisoning resistance, simple process operation, low energy consumption and suitability for industrial application.

The invention discloses an SCR (Selective Catalytic Reduction) denitration catalyst regeneration method which comprises the following steps: carrying out cleaning and arsenic removal on an arsenic-poisoned SCR denitration catalyst, and regenerating to obtain a regenerated catalyst; preparing a mixed impregnation liquid containing a water repellent agent, polypropylene carbonate and an organic solvent; adhering the mixed impregnation liquid to the surface of the regenerated catalyst and immersing the mixed impregnation liquid into channels of the regenerated catalyst by using a vacuum pressure impregnation process; drying to remove the organic solvent, and curing the poly (propylene carbonate) on the surface and in pores of the regenerated catalyst; a heat treatment is performed to remove the poly (propylene carbonate) and induce chemical grafting of the hydrophobing agent to the catalyst to form a hydrophobic network. The hydrophobic agent is introduced into the surface and pore channels of the arsenic-removed catalyst to construct a hydrophobic network, so that the hydrophobicity of the regenerated catalyst is improved.

The invention relates to the technical field of denitration catalyst regeneration, in particular to a preparation method of a regenerated denitration catalyst based on a reconstructed bulk phase carrier. The preparation method comprises the following steps: carrying out ultrasonic treatment on the waste catalyst by using an ethylenediamine tetraacetic acid-hydrofluoric acid mixed solution to realize targeted detoxification; carrying out hydrothermal reaction on the detoxified carrier, titanium sol, cerous nitrate and zirconium nitrate, and roasting with nitrogen to complete bulk phase reconstruction; carrying out microwave-assisted gradient loading on ammonium paratungstate and an ammonium metavanadate-oxalic acid solution on the reconstructed carrier to obtain a precursor; and roasting and activating the precursor in a gradient atmosphere to obtain the regenerated catalyst. The catalyst prepared by the invention has high denitration efficiency, excellent sulfur poisoning resistance stability, good circulation performance and long service life, can realize efficient regeneration of the waste vanadium-titanium-based denitration catalyst, is suitable for the field of industrial flue gas denitration, and has significant application value.

The invention discloses an on-line regeneration method of a copper-based methanol reforming hydrogen production catalyst, which belongs to the technical field of catalyst regeneration, and is characterized by comprising the following steps: directly adding a certain proportion of oxygen-containing gas into feed gas of a reactor in a methanol reforming hydrogen production reaction process under the conditions of not changing the operation temperature and not stopping raw material supply; oxygen-containing gas is mixed with methanol and water vapor and then enters a catalyst bed layer, and after online treatment is carried out for a period of time, supply of oxygen is stopped, so that online regeneration of catalyst activity can be completed; according to the method, the regeneration can be completed by directly introducing oxygen in the reaction process without shutdown, cooling or reaction atmosphere switching, so that the operation process is greatly simplified, and the production efficiency is improved.

This invention belongs to the field of catalytic reaction technology, specifically disclosing a Fischer-Tropsch synthesis catalyst regeneration and carbon dioxide co-production reactor and its co-production process. The reactor includes a Fischer-Tropsch synthesis fixed-bed reactor, a carbon monoxide conversion reaction unit, and a tail gas discharge unit. The Fischer-Tropsch synthesis fixed-bed reactor is filled with a Fischer-Tropsch synthesis catalyst for the Fischer-Tropsch synthesis reaction and catalyst carbon deposition and char regeneration. The carbon monoxide conversion reaction unit is located downstream of the Fischer-Tropsch synthesis fixed-bed reactor and converts the carbon monoxide generated during char regeneration into carbon dioxide. The tail gas discharge unit outputs carbon dioxide-rich gas and removes residual oxygen from the tail gas. By performing in-situ conversion of carbon monoxide during regeneration, this invention can significantly increase the volume fraction of carbon dioxide in the regenerated tail gas and provide a stable feedstock for the downstream carbon dioxide hydrogenation to methanol reaction, thereby achieving synergy between catalyst regeneration and efficient utilization of carbon resources.

The invention provides a method and system for continuously preparing trifluoroiodomethane, and the method comprises the following steps in the same reactor: S1, inputting trifluoromethane, iodine vapor and air into the reactor, and reacting under the action of a catalyst to prepare trifluoroiodomethane; s2, when the reduction amplitude of the reaction yield relative to the initial reaction yield reaches a set threshold value, stopping inputting trifluoromethane and iodine vapor into the reactor, and continuously introducing air to regenerate the catalyst; and S3, after the regeneration of the catalyst is completed, repeatedly executing the steps S1 to S2. The preparation process of the mesoporous carrier used by the catalyst comprises the following steps: dispersing nano SiO2 spheres in a magnesium acetate or aluminum acetate solution, then adding an NH4F solution, and reacting under a stirring condition to obtain a mesoporous carrier precursor; and treating the mesoporous carrier precursor by adopting a solution etching method. According to the method for continuously preparing trifluoroiodomethane, the service life of the catalyst is long, the technological process is simple and efficient, and the regeneration difficulty of the catalyst is reduced.

The invention provides a catalyst regeneration energy recovery power device, and belongs to the technical field of thermodynamics and thermodynamic. An air channel outside is communicated with the charring-regeneration system through a heat source regenerator, the charring-regeneration system is communicated with the outside through a smoke channel via a heat source heat exchanger and the heat source regenerator, a cooler is communicated with a compressor through a circulating working medium channel, and the compressor is communicated with the compressor through a circulating working medium channel through a regenerator. The compressor further communicates with an expansion machine through a circulating working medium channel via a second heat regenerator and a heat source heat exchanger, the expansion machine further communicates with the expansion machine through the circulating working medium channel via the second heat regenerator, the expansion machine further communicates with a cooler through the circulating working medium channel via the heat regenerator, and the cooler further communicates with the outside through a cooling medium channel. And the expansion machine is connected with the compressor and transmits power to form the catalyst regeneration energy recovery power device.

The utility model relates to the technical field of ash removal machines, in particular to an ash removal machine for regeneration of a denitration catalyst, which comprises a box body, four corners of the inner surface of the box body are connected with supporting springs, the top ends of the supporting springs are connected with a placing table, two sides of the placing table are connected with vibrators, two sides of the inner surface of the box body are provided with blowers, and the blowers are connected with the supporting springs. And an exhaust fan is arranged on one side of the inner surface of the box body. A denitration catalyst is placed on the surface of the top end of the placing table through a forklift, the placing table is elastically supported through the supporting springs, when dust removal is conducted on the denitration catalyst, the vibrator drives the placing table to vibrate, the dust adsorbed by the denitration catalyst is shaken off, the air blower is started, and the denitration catalyst is placed on the surface of the top end of the placing table. The air blower blows away dust accumulated on the denitration catalyst, then the exhaust fan is started to suck away the dust, the dust is conveyed into the collecting box to be collected in a centralized mode, and the problems that the dust cleaning efficiency is low, and the dust floats and is adsorbed again are solved.

The invention belongs to the field of polishing solutions, and particularly relates to a green polishing solution based on an enzymatic Fenton system. The 4H-SiC substrate polishing solution comprises a component A and a component B, the effective component of the component A is an enzyme-catalyst co-immobilized abrasive material, and the enzyme-catalyst co-immobilized abrasive material comprises an abrasive material matrix, laccase and an iron-based catalyst, and the laccase and the iron-based catalyst are loaded on the abrasive material matrix; the active ingredient of the component A is a phenol substrate, the active ingredient of the component B is a phenol substrate, after the component A and the component B are mixed, laccase catalyzes oxidation of the phenol substrate to generate H2O2 in situ, the H2O2 and an iron-based catalyst are subjected to a Fenton reaction, and hydroxyl free radicals are generated at a polishing interface in situ. According to the invention, continuous, efficient and stable supply of hydroxyl radicals is ensured through enzymatic endogenous hydrogen peroxide circulation and catalyst regeneration circulation, so that the polishing solution can realize long-time stable polishing under a nearly neutral condition, and has the advantages of environmental protection, high polishing efficiency, good surface quality and the like.