2947results about "Catalysts" patented technology

A process for converting an ethanol feed stream to ethylene, comprising passing a portion of said ethanol feed stream to two reactors in parallel and then passing the combined product to a third reactor operated at a higher temperature to prevent the formation of ethers such as diethyl ether.

The invention belongs to the field of photocatalytic materials, and particularly relates to a high-entropy sulfide and a preparation method and application thereof. The high-entropy sulfide is granular, the molecular general formula is (MnaFebCocCudZe) xS, x is equal to 1, and the atomic ratio of Mn to Fe to Co to Cu to Zn is a: b: c: d: e of (1-2): (1-2): (1-2): (1-2): (1-2): (1-2): (1-2). The preparation method comprises the following steps: S1, dissolving metal salt in a mixed solvent of isopropanol and glycerol according to the atomic ratio of metal elements, and carrying out solvothermal reaction to obtain a precursor; and S2, dispersing the precursor in ethanol, adding thioacetamide as a sulfur source, and carrying out solvothermal reaction to obtain the high-entropy sulfide. The high-entropy sulfide disclosed by the invention is used as a photocatalytic material and shows excellent photocatalytic performance.

A process for producing isooctane by introducing a butane feed stream (containing n-butane, i-butane) and hydrogen into a catalytic hydrogenolysis reactor to produce a hydrogenolysis product stream; separating the hydrogenolysis product stream into a butane stream (i-butane, optionally n-butane); feeding the butane stream to a catalytic dehydrogenation reactor to produce a dehydrogenation product stream comprising saturated and unsaturated four-carbon hydrocarbons; and feeding the dehydrogenation product stream to an oligomerization unit to produce isooctene and dehydrogenating the isooctene to produce isooctane.

Provided herein are systems and methods for converting CO2 and a reduction gas, such as H2 or a hydrocarbon, using a reduction catalyst and an aromatic catalyst into mixtures of paraffins, and aromatics for use as aviation fuel. The reduction catalyst and aromatic catalyst, and systems and methods incorporating the same, provide advantages over other methods in the art related to increased yield, catalyst stability and longevity.

The invention discloses a preparation method of a perovskite type high-temperature-resistant CO2 methanation catalyst, which comprises the following steps: firstly, preparing CaZrO3, then dissolving CaZrO3 powder, a nickel source, a soluble organic fuel and a certain amount of ethylene glycol in deionized water according to a molar ratio of 1: (0.2-0.8): (0.1-0.5), stirring to obtain a dispersion liquid, then putting carrier monoclinic ZrO2 powder in the dispersion liquid, and stirring to obtain the perovskite type high-temperature-resistant CO2 methanation catalyst. The preparation method comprises the following steps: uniformly mixing the raw materials, carrying out ultrasonic treatment for 5-12 hours, heating the obtained mixture at 300-550 DEG C until spontaneous combustion, carrying out high-temperature calcination at 800-900 DEG C for 1-2 hours after flame is extinguished, collecting the calcined product, and carrying out ball milling and granulation to obtain the NiO-CaZrO3 / ZrO2 catalyst with a certain mesh number. According to the preparation method of the catalyst, a solution combustion method is introduced in the preparation process, so that active components of the prepared catalyst are fully dispersed, and further high-temperature calcination is performed on the basis, so that the active components are stably anchored on the surface of the ZrO2 carrier, and the catalytic activity and the stability of the catalyst are improved.

Process for making sustainable aviation fuel (SAF) from specific bio-ethylene oligomerization reactions producing a C4-C8 alpha-olefin and a by-product mixture of C10 olefins. This mixed decene stream is upgraded by further oligomerizing with at least one C4-C6 alpha-olefin to provide a C16− olefin stream, which is hydrogenated to C16− paraffins which is used to form a SAF. Employing bio-ethylene to produce the mixed decene stream, which is relatively low-value due in part to its non-selectivity, leverages that non-selectivity into a desirable sustainable aviation fuel product where the low selectivity is preferable. These and other embodiments and aspects are described herein.

The present invention belongs to the technical field of design and synthesis of carbon-monoxide and carbon-dioxide-based Fischer-Tropsch synthesis catalysts, and discloses a novel iron-based Fischer-Tropsch synthesis catalyst containing both iron and carbon and a synthesis method and use thereof. The present invention specifically relates to a catalyst mixture for use in hydrogenation of CO and / or CO2, which catalyst mixture comprises i) iron oxide promoted by alkali metal, alkaline earth metal or transition metal, and ii) iron carbide. The invention further relates to a method for production of iron carbide composite comprising different iron carbides, and the use of said carbide composite in combination with alkali metal, alkaline earth metal or transition metal promoted iron oxide for use in hydrogenation of CO and / or CO2.

The invention discloses a carbon dioxide hydrogenation methanation-cracking carbon preparation series method, which comprises the following steps: generating CH4 through a reaction of # imgabs0 # imgabs1 #, and realizing the production of a carbon material by adopting the technologies of condensation separation of CH4 and water vapor, CH4 cracking reaction of # imgabs2 #, cyclic utilization of hydrogen and the like. The process is composed of a carbon dioxide hydrogenation methanation reactor and a methane cracking reactor. In the methanation reactor, CO2 and H2 react under a low-temperature condition to generate CH4 and water vapor; cH4 and water vapor are separated by adopting a compressor condensation separation technology, and the separated CH4 is conveyed to a cracking reactor. In the methane cracking reactor, CH4 is cracked at a high temperature to generate H2 and a carbon nanomaterial, and then H2 is returned to the methanation reactor again. The separation of CH4 and water vapor at a relatively low temperature is realized in the tandem carbonization process through a low-temperature condensation technology; through low-temperature CO2 methanation and CH4 catalytic cracking, the content of CO2 is reduced, a high-quality carbon nanomaterial is obtained, and cyclic utilization of CO2 and H2 is realized.

The invention discloses a catalyst for synthesizing low-carbon olefin through CO2 hydrogenation reaction as well as preparation and application of the catalyst. The catalyst comprises an active component A and a core-shell structure B (at) C, wherein the active component A is a metal oxide with catalytic activity for synthesizing low-carbon olefin through a CO2 hydrogenation reaction; in the core-shell structure B (at) C, B is an SAPO molecular sieve, and C is selected from one or more of B2O3, SiO2, Al2O3, TiO2, ZrO2, kaolin and montmorillonite. The catalyst is used for synthesizing low-carbon olefin through CO2 hydrogenation, and can obviously improve the CO2 conversion efficiency and reduce the CO selectivity.

Processes are disclosed for the production of liquefied petroleum gas (LPG) hydrocarbons, utilizing both alcohol (e.g., methanol) synthesis and in situ dehydration of the alcohol to hydrocarbons, and particularly propane and / or butane. Operational adjustments and / or variations, involving activation of LPG synthesis catalyst systems at relatively high temperatures, followed by initial operation at relatively low temperatures, surprisingly lead to improvements in the stability of such catalyst systems. These improvements are often in conjunction with other benefits, for example greater selectivity and / or per-pass yield, with such improvements and benefits resulting from the ability to operate at reduced temperatures. Problems typically encountered in the art due to catalyst instability, such as the need for frequent replacement and / or regeneration, are thereby potentially reduced or even eliminated.

A Liquid Organic Hydrogen Carrier (LOHC) dehydrogenation system is described, capable of meeting time-variable hydrogen demands with short dynamics while always ensuring a high degree of dehydrogenation under all operating conditions. The system comprises one or more reactors comprising an LOHC vessel and a recirculation circuit comprising a recirculation pump, a preheater capable of supplying the reaction heat as sensible heat, and a cartridge containing the solid catalyst.

The present invention relates to a catalytically active material, the preparation thereof, and the use of the catalytically active material, e.g. in the catalytic oxidation of CO to CO2 or in the catalytic hydrogenation of alkyne. The catalytically active material comprises a support5 comprising a metal oxide, and atomically dispersed noble metal on the surface of the support, wherein the metal oxide is selected from TiO2, CeO2, ZnO, SnO2, Ga2O3, In2O3, ZrO2, and Fe2O3, the noble metal is selected from Pt, Pd, Rh, and Au, and the catalytically active material is obtainable by a method comprising a step of non-thermal plasma treatment in the presence of O2.

Transalkylation processes using catalysts comprising three dimensional 12 membered ring zeolites with a combination of small and large pores are described. These catalysts have increased conversion of alkylphenols to phenol, cresols, and alkylbenzenes from coal-derived liquid streams compared to catalysts consisting of HZSM-5 zeolite.

A method for producing propylene (C3H8) via oxidative dehydrogenation (ODH) of propane includes introducing a propane-containing feed gas stream into a reactor containing an alumina-supported Ga2O3 / La2O3 catalyst comprising Ga2O3 particles at least partially disposed on surfaces of a matrix comprising rough and irregular-sized La2O3 and alumina particles; passing the propane-containing feed gas stream through the reactor in contact with the alumina supported Ga2O3 / La2O3 catalyst at a temperature of 500 to 600° C. to convert at least a portion of the propane to propylene (C3H6) and produce a propylene-containing gas stream leaving the reactor; and separating the propylene from the propylene-containing gas stream. The method has a propane conversion of up to 95% based on an initial weight of the propane in the propane-containing feed gas stream, and a propylene yield of up to 60% based on the propane conversion.

The invention discloses an MWW type molecular sieve as well as a preparation method and application thereof. The weight ratio of framework aluminum (Al [F]) to non-framework aluminum (Al [EF]) of the molecular sieve is (5.0-16.0): 1. The invention provides a novel MWW type molecular sieve. The catalyst prepared by adopting the molecular sieve disclosed by the invention is applied to a reaction for preparing cyclohexylbenzene by transalkylation of polycyclohexylbenzene and benzene, and the conversion rate of the polycyclohexylbenzene and the selectivity of a cyclohexylbenzene product can be improved.

Captured carbon dioxide is converted into ultra-high purity hydrocarbons, particularly methane. A gas stream containing carbon dioxide is fed to a reactor containing both sorbent and catalyst, until the sorbent portions are substantially saturated with carbon dioxide; non-sorbed species are removed from the first reactor via vacuum and / or purge cycles with high-purity gas; hydrogen gas is introduced to the first reactor to a pressure above ambient; reactor temperature is raised to facilitate desorption of carbon dioxide; and the carbon dioxide is catalytically transformed with the hydrogen gas into methane by recirculating the gas through the reactor. Carbon dioxide adsorption and desorption occur within the sorbent portions, while methanation takes place on the catalytic portions assisted by the sorbent at a temperature substantially consistent with the desorption. Downstream upgrading steps may remove or reduce impurities to produce ultra-high purity methane for chemical vapor deposition or other processes.

A process for dehydrating ethanol to produce ethylene is provided. The ethanol is dehydrated to produce ethylene, which is subsequently converted to longer-chain olefins, which are then hydrogenated to produce long-chain paraffins. In some embodiments, a split feed is used to improve efficiency, eliminating the caustic wash column. Advantages of the process include lower steam requirements and a 30-40% reduction in combined reactor volume when using two reactors compared to a single reactor.

A heterogeneous catalyst composition including a metal and boron catalyst with boron dispersed in a molten matrix, where the molten matrix includes a eutectic mixture of alkali metal or alkaline earth metal salts or hydroxides. A process for preparing a heterogeneous catalyst composition, including combining a mixture of alkali metal or alkaline earth metal salts or hydroxides to form a matrix including a eutectic mixture, adding, to the matrix, a boron precursor and at least one metal catalyst precursor to form a catalyst precursor mixture, and heating the catalyst precursor mixture to a temperature of from 390° C. to 750° C. to form the heterogeneous catalyst composition. A process for catalytic oxidative dehydrogenation of hydrocarbons whereby a hydrocarbon-containing feedstock contacts the heterogeneous catalyst composition to generate olefinic compounds.

A system for preparing olefin from methanol, for use in solving the problem in the prior art that the reaction speed is affected due to methanol being directly delivered to participate in a reaction. The system comprises a feeding system (5). The feeding system (5) comprises a purified water heat exchanger (501), a condensate water heat exchanger (502), a steam vaporizer (503), a reaction gas heat exchanger A (505) and a methanol feeding pipe (121) which are connected in sequence. A pipeline between the purified water heat exchanger (501) and the condensate water heat exchanger (502) is communicated with a quench methanol delivery pipe (507) connected to the methanol feeding pipe (121). A heating furnace (506) is connected to the reaction gas heat exchanger A (505). After methanol passes through the purified water heat exchanger (501) and the condensate water heat exchanger (502) for heat exchange, the temperature of the methanol is increased; the steam vaporizer (503) vaporizes the methanol and then heat exchange is performed by the reaction gas heat exchanger A (505) to increase the temperature; the quench methanol delivery pipe (507) delivers low-temperature methanol to be mixed with high-temperature methanol to control the temperature of fed methanol; and the heating furnace (506) is used for heating methanol during operation. After heat exchange, vaporization, overheating and temperature control operation, the methanol is kept at an appropriate temperature to participate in the reaction, thereby ensuring the reaction speed.

A composite photocatalyst, comprising V2C@V2O5 / TiO2, is disclosed herein. Additionally, a process for producing this composite, particularly V2C@V2O5 / TiO2, involves the steps of preparing V2C@V2O5 / TiO2 composite; grinding the V2C@V2O5 / TiO2 composite; and calcining the ground product to obtain the composite photocatalyst V2C@V2O5 / TiO2. Furthermore, the disclosure encompasses utilizing the composite photocatalyst in a CO2 reduction process, wherein the photocatalyst is irradiated in a photoreactor system.

A method may include operating a dehydrogenation process whereby a hydrocarbon-containing feed is converted to light olefins, wherein the dehydrogenation process utilizes a fluidized process catalyst that circulates between a reactor and a combustor. The method may comprise withdrawing the process catalyst from the dehydrogenation process, modifying the process catalyst to form a modified catalyst, and adding the modified catalyst back to the dehydrogenation process. The process catalyst may include from 0.1 wt. % to 10 wt. % of one or more metals chosen from gallium, indium, thallium, or combinations thereof, from 1 ppmw to 1000 ppmw of one or more metals chosen from platinum, palladium, rhodium, iridium, ruthenium, osmium, or combinations thereof, and at least 85 wt. % support. Modifying the process catalyst may include adding one or more of manganese, iron, chromium, or vanadium.

A process for separating fillers from catalysts and gases in plastics in a fluidized bed catalytic pyrolysis process is described that converts waste plastics, polymers, and other waste materials to useful chemicals and fuel products, such as aromatics such as paraffins, olefins, and BTX.

The invention relates to the technical field of organic synthesis, in particular to a method and device for preparing 4-methyl-1-pentene, and the method comprises the following steps: (1) pretreating a raw material containing propylene and an inert substance, and carrying out heat exchange on the obtained refined raw material to obtain a heat-exchanged raw material; (2) carrying out dimerization reaction on the raw material subjected to heat exchange and a catalyst in the presence of inert gas, wherein the obtained reaction product is divided into a part of reaction product and a residual part of reaction product; (3) cooling the part of the reaction product as a heat exchange medium, and carrying out heat exchange with the refined raw material to obtain a heat-exchanged product; (4) separating a mixed material of the rest reaction product and the product after heat exchange to obtain a light component and a heavy component; and carrying out rectification on the heavy component to obtain the 4-methyl-1-pentene. According to the method, by controlling the reaction temperature rise, the stable reaction temperature and the uniform reaction process are ensured, and the raw material conversion rate and the product selectivity are further improved.

A machine learning model predicts a K value for a new iron ethylene oligomerization catalyst structure, where the K value has not yet been experimentally determined. The system utilizes a device comprising memory coupled to at least one processor, the memory having instructions that cause the at least one processor to: input a set of reaction conditions and a new iron ethylene oligomerization catalyst structure comprising a ligand to a random forest machine learning regressor model, wherein the random forest machine learning regressor model is trained on a data set comprising multi-dimensional features for tested iron ethylene oligomerization catalyst structures, wherein the multi-dimensional features comprise experimental K values, physical features, molecular features, and connective steric factors for each of the tested iron ethylene oligomerization catalyst structures

The invention discloses a method for preparing 1, 3-butadiene, and the method comprises the following steps: enabling a raw material containing gamma-valerolactone to be in contact and react with a catalyst to obtain the 1, 3-butadiene, the catalyst is a hydrogen type molecular sieve with a ten-membered ring topological structure, and the typical topological structure types of the catalyst comprise FER, TON, MTT, EUO, * MRE, MEL and MWW. In a fixed bed reactor, gamma-valerolactone is taken as a raw material and passes through the reactor from top to bottom. The target product 1, 3-butadiene can be efficiently prepared under the condition of 300-450 DEG C by using the catalyst.

A process for preparing middle distillates from an olefinic feedstock, bya) oligomerization fed with the olefinic feedstock, a first recycle and a second recycle, and operated in the presence of at least one oligomerization catalyst, to produce a reaction effluent containing dimers, trimers and oligomers;b) fractionating the reaction effluent into:a light fraction containing at least part of the unconverted olefinic feedstock;an intermediate fraction containing at least part of the dimers and trimers; anda heavy fraction containing the oligomers;c) recycling by the preparation of a first recycle containing at least part of the light fraction; and a second recycle containing at least part of the intermediate fraction; and transfer of the first recycle and the second recycle to step a);d) hydrogenating at least part of the heavy fraction.

Methods for preparing catalysts for oxidative dehydrogenation (ODH) of alkanes such as ethane are provided. An exemplary method includes forming a slurry including metal oxides; one or more of a bismuth compound, an antimony compound, and a tellurium compound; a reducing agent; and water; and heating the slurry to form the catalyst. The metal oxides include an oxide of molybdenum and an oxide of vanadium. The bismuth compound includes bismuth oxide, bismuth hydroxide, or a bismuth carbonate. The antimony compound includes an oxide of antimony, an antimony acetate, or an antimony ethoxide. The tellurium compound includes tellurium dioxide. The reducing agent includes molybdenum dioxide and may further include vanadium dioxide. The methods use all inorganic reagents, with no build up COx pressure observed during the hydrothermal synthesis.

The invention discloses an intermittent charging system of a solid catalyst and a charging method of the solid catalyst in a propylene dimerization process. The intermittent feeding system comprises a feeding barrel section, the feeding barrel section comprises an upper barrel section and a lower barrel section, a feeding device is arranged between the upper barrel section and the lower barrel section, the top of the upper barrel section and the bottom of the lower barrel section are provided with a first discharging valve and a second discharging valve respectively, and the side wall of the upper barrel section is provided with a purging gas inlet and an exhaust port; and the charging barrel section is communicated with a charging hole of the reaction kettle. The system and the method provided by the invention not only can meet strict requirements of the process on anhydrous and anaerobic conditions of the catalyst, but also can realize intermittent addition of the catalyst without influencing normal operation of the device, and are convenient to replace.

An embodiment of a method for producing a cyclic compound of the present invention includes a step of causing a decarboxylation reaction in a cyclic carboxylic acid compound by subjecting a starting material containing the cyclic carboxylic acid compound to a heat treatment of heating under a catalyst to obtain a cyclic compound, in which the catalyst includes zeolite formed of an aluminum / silicon-containing composite oxide, and in which the zeolite has an SiO2 / Al2O3 ratio of 7 to 500. In addition, another embodiment of the method for producing a cyclic compound of the present invention includes a step of causing a decarboxylation reaction in a cyclic carboxylic acid compound by subjecting a starting material containing the cyclic carboxylic acid compound to a heat treatment of heating in the presence of a non-solid acid to obtain a cyclic compound.