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361results about How to "Good choice" patented technology

Synthetic method of water soluble ultraviolet light absorber BP-9

The invention discloses a synthetic method of a water soluble ultraviolet light absorber BP-9. The method mainly comprises the following process steps: (1) carrying out methylation on the main raw materials of 2, 2', 4, 4'-tetrahydroxyl benzophenone, a transition metal salt catalyst and a mixed solvent which is prepared from dichloroethane and anhydrous ethanol in equal parts by weight to obtain 2, 2'-dihydroxyl-4, 4'-dimethoxyl benzophenone; (2) carrying out sulfonation reaction on the main raw materials of methylate, sulfamic acid and C1-C3 halohydrocarbon to obtain 2, 2'-dihydroxyl-4, 4'-dimethoxyl benzophenone-5, 5'-disulfonic acid; and (3) carrying out neutral reaction on the main raw materials of sulfonated product, inorganic base and ethanol water to finally obtain the BP-9 product. The synthetic method disclosed by the invention is few in reaction step, low in cost, high in product purity and stable in quality, and raw materials are easily available.
Owner:HUANGGANG MEIFENG CHEM TECH +1

Video content retrieval method, device and terminal based on voice interaction of television system

The invention discloses a video content retrieval method and device based on television system voice interaction and a terminal, and relates to the technical field of video processing, and the method comprises the steps: when a video is played for the first time, extracting a picture frame from the video at a preset frequency, converting the picture frame into a multi-dimensional image feature vector and a corresponding video timestamp, and carrying out hierarchical storage in a database, constructing vectorized data containing visual semantic information; obtaining a voice retrieval instruction, performing intention recognition and semantic understanding, extracting a detection keyword, and generating a multi-dimensional retrieval feature vector; calculating a matching degree between the multi-dimensional retrieval feature vector and a multi-dimensional image feature vector of a video picture frame stored in a database, and screening out picture frames of which the similarity is higher than a preset similarity threshold to form a retrieval candidate matching set; and determining matched picture playing. The video content retrieval method is efficient, accurate and high in interactivity, and retrieval experience and operation efficiency of the user in the video watching process are remarkably improved.
Owner:SHENZHEN COOCAA NETWORK TECH CO LTD

Load-bearing type hot-rolled metal steel beam structure

PendingCN121992874Aavoid concentrationEliminate hidden dangers of stress concentrationBuilding constructionsStress concentrationScrew thread
The invention relates to the technical field of steel structures, in particular to a bearing type hot-rolled metal steel beam structure which comprises a vertical beam, cross beams are connected to the two parallel side faces of the vertical beam through fasteners formed by a plurality of sets of screws and first nuts, a plurality of penetrating openings are formed in one side face of each cross beam at equal intervals, and a plurality of column rods are arranged on the two sides of each cross beam. Threaded blind holes are machined in the two ends of each column rod, studs are in threaded connection with the interiors of the opposite threaded blind holes of every two adjacent column rods, rooting plates are inserted into the penetrating openings, the studs penetrate through the rooting plates, second nuts are arranged on the two sides, in the length direction of the studs, of the rooting plates, and the second nuts are in threaded connection with the studs. The invention has the following beneficial effects: the load is uniformly distributed on the whole cross beam and the connecting structure, the acting force is prevented from being concentrated on the connecting part of the cross beam and the vertical beam, and the hidden danger of stress concentration is fundamentally eliminated.
Owner:ZHENJIANG QIAO METAL PROD CO LTD

Placing device for storing high-frequency endoscopic surgery electrodes

The utility model discloses a placing device for high-frequency endoscopic surgery electrode storage, which comprises an endoscope electrode, the surface of the endoscope electrode is sleeved with an outer frame, the front side of the outer frame is open, the inside of the outer frame is movably connected with a shaft rod through a bearing, and the shaft rod is movably connected with a bearing. The top and the bottom of the surface of the shaft rod are fixedly connected with bearing discs, the endoscope electrodes are evenly inserted in the surfaces of the bearing discs in a surrounding mode, and the endoscope electrodes at different positions can be located at the open position of the outer frame in the process that the shaft rod carries the bearing discs to rotate. The endoscope electrodes are sleeved with the outer frame, the open front face is arranged to facilitate storing and taking, the shaft rod and the bearing disc are combined so that the multiple endoscope electrodes can be evenly connected in a surrounding and inserted mode, the electrodes at different positions can be located at the open position through rotation of the shaft rod, and a user can conveniently select and use the electrodes. And the storage efficiency and the use convenience of the electrode are improved.
Owner:BEIJING KESTREL CO LTD

Synthetic method of 3-olefine acid ester compound

The invention relates to a synthesis method of a 3-olefine acid ester compound. The method comprises the following steps: carrying out contact reaction on an organic phosphine ligand, a palladium compound, conjugated olefin, an alcohol compound and carbon monoxide; wherein the structural formula of the organic phosphine ligand is shown in the specification, and in the structural formula, R0 and R1 are respectively selected from hydrogen, alkyl, alkoxy, halogen or halogenated alkyl; and R2 and R3 are respectively selected from hydrogen or alkyl. The method provided by the invention has the advantages of mild conditions, no need of an acid auxiliary agent, high yield and selectivity of the generated 3-olefine acid ester compound, reduction of corrosion to a reactor, and good application prospect, and the speculation is that the electrical property of phosphorus atoms can be regulated and controlled by using the organic phosphine ligand provided by the invention, so that the reaction activity of the palladium-organic phosphine ligand catalyst is regulated and controlled, and the yield and selectivity of the 3-olefine acid ester compound are improved. Therefore, the palladium-organic phosphine ligand catalyst generated by the ligand and a palladium compound in situ can efficiently catalyze the reaction of conjugated olefin, carbon monoxide and alcohol compounds.
Owner:CHINA PETROLEUM & CHEMICAL CORP +2

A method for preparing a supported copper nitride catalyst

The application relates to the technical field of carbon dioxide electro-reduction catalysts, and discloses a preparation method of a supported copper nitride catalyst, which comprises the following steps: mixing copper cyanamide and conductive carbon material and performing ball milling; the rotating speed of the ball milling is 500 r / min-5000 r / min, and the ball milling time is 1h-24h; the mass ratio of the copper cyanamide and the conductive carbon material is 1-10:1-10. The catalyst obtained by the method has better stability, selectivity and activity in a carbon dioxide electro-catalytic reduction reaction, and the addition of the conductive carbon improves the conductivity of the catalyst, so that the overpotential of the catalyst in the carbon dioxide electro-reduction is significantly reduced.
Owner:CATARC AUTOMOTIVE TEST CENT TIANJIN CO LTD +1

A single-atom nickel-modified electrode material, its preparation method and reactor

This invention relates to the field of electrochemical technology, and particularly to a single-atom nickel-modified electrode material, its preparation method, and a reactor. An embodiment of this invention provides a method for preparing a single-atom nickel-modified electrode material, comprising: S1, subjecting a carbon felt to a surface hydrophilic treatment to obtain a hydrophilic carbon felt; S2, immersing the hydrophilic carbon felt in a first solution containing Ni ions, and adding a second solution containing organic matter, allowing for a complete reaction, and then growing a nickel-containing metal-organic framework material in situ on the hydrophilic carbon felt; S3, calcining the hydrophilic carbon felt containing the nickel-containing metal-organic framework material to obtain the single-atom nickel-modified electrode material. This invention provides a single-atom nickel-modified electrode material, its preparation method, and a reactor, which can provide a cathode material that combines efficient microbial colonization with interfacial stability.
Owner:HARBIN INST OF TECH

Rapid analysis method of polyethylene glycol additive in copper electrodeposition solution

PendingCN122361331Ashort analysis timecaused by interferencePhosphomolybdic acidCopper interconnect
This invention relates to the field of electroplating solution analysis technology, and in particular to a rapid analytical method for polyethylene glycol (PEG) additives in copper electrodeposition solutions. The method involves protonated PEG forming a macromolecular complex colloid with phosphomolybdate under acidic conditions of pH 1.0–2.0. This colloid exhibits maximum absorption at 372 nm, and the absorbance value is directly proportional to the PEG concentration in the formed complex colloid. This allows for quantitative analysis of PEG in the copper electrodeposition solution. Because the phosphomolybdate-PEG complex colloid selected in this invention has excellent selectivity, and no sample pretreatment is required, this invention offers advantages such as ease of operation, speed, high sensitivity, and good selectivity. It is particularly suitable for intermediate control analysis in production environments, such as for electroplated copper interconnects in chips and printed circuit boards, as well as electrolytic copper foil for negative electrode current collectors and copper-clad laminates in energy storage batteries.
Owner:CHANGZHOU UNIV +1

A split-type laser and its laser output structure

This utility model discloses a split-type laser and a laser output structure, including: a first laser generating structure, comprising a first pump source and a first doped fiber, wherein the first pump source is used to pump the first doped fiber to generate a first laser; a second laser generating structure, comprising a second pump source and a second doped fiber, wherein the second pump source is used to pump the second doped fiber to generate a second laser; and a laser output structure, wherein the laser output structure has a first output channel and a second output channel, the laser output structure being located on the propagation paths of the first laser and the second laser, and the laser output structure being capable of adjusting the ratio of the first laser and the second laser output by the first output channel and the second output channel. Both the first laser generating structure and the second laser generating structure have their own pump sources, making it easier for users to select the light source emitted by the laser.
Owner:SHANGHAI FEIBO LASER TECH CO LTD

Robot sole, robot leg and robot

The utility model discloses a robot foot sole, a robot leg and a robot. The foot sole comprises a foot sole supporting piece, a foot sole mounting piece and an elastic piece. The plantar supporting piece comprises a plantar supporting outer surface far away from one side of the robot and a plantar supporting inner surface close to one side of the robot, and a plantar supporting mounting part is arranged on the plantar supporting inner surface; the plantar mounting piece is detachably connected with the plantar supporting mounting part; the elastic piece is arranged in the sole supporting piece; the foot sole mounting piece is detachably connected with the foot sole supporting mounting part, so that the foot sole supporting piece is convenient to disassemble and assemble, the operation time is greatly shortened, and the maintenance efficiency is greatly improved; the elastic piece is arranged in the sole supporting piece, the mechanical damping function is achieved, the sole supporting piece can be made of a hard material, then the abrasion resistance of the sole supporting piece is improved, meanwhile, it is guaranteed that the sole has the good buffering performance through the arrangement of the elastic piece, and the selection contradiction problem of damping performance and durability in a traditional structure is solved.
Owner:WUHAN MENGKAITE TECHNOLOGY DEVELOPMENT CO LTD

Preparation method and application of bimetallic nano-enzyme induced MOFs (at) CDs material

The invention discloses a preparation method and application of a bimetallic nano-enzyme induced MOFs (at) CDs material, and the preparation method at least comprises the following steps: I, dissolving FeCl3, CoCl2 and 2-aminoterephthalic acid in N, N '-dimethylformamide to form a mixed solution I, and carrying out a reaction I to obtain a bimetallic MOFs material; step II, mixing tricarballylic acid and m-phenylenediamine, and carrying out a reaction II to obtain carbon dot powder; step III, dissolving the carbon dot powder obtained in the step II in methanol, and adding rhodamine B dye to obtain a CDs material; and IV, dissolving the bimetallic MOFs material obtained in the step I and the CDs material obtained in the step III in water, stirring, and drying to obtain the MOFs (at) CDs material. The synthesized nano-enzyme is simple to prepare and high in catalytic activity, the carbon dot material is encapsulated into the MOFs material, the fluorescence characteristic of the MOFs material is enhanced, and the carbon dot material is combined with o-phenylenediamine to be used for detecting H2O2.
Owner:DALIAN INSTITUTE OF CHEMICAL PHYSICS CHINESE ACADEMY OF SCIENCES

Dual-mode detection kit for high-sensitivity detection of ERalpha based on HRP-streptavidin

The invention discloses a dual-mode detection kit for highly sensitive detection of ERalpha based on HRP-streptavidin. The dual-mode detection kit comprises the following raw materials: a glassy carbon electrode, 1-AP-CNHs, AuNPs, Sh-Apt, MCH, Bio-Ab, and HRP-streptavidin. The invention successfully constructs an electrochemical detection kit for detecting ERalpha with high sensitivity on the basis of the 1-AP-CNHs / AuNPs composite material. According to the invention, due to the redox activity of HRP-streptavidin, the HRP-streptavidin and H2O2 are subjected to redox reaction to generate a current signal; in addition, hydrogen peroxide can be catalyzed to generate. OH free radicals, and the free radicals can oxidize TMB to generate blue products, so that colorimetric reaction is initiated, and ERalpha can be detected more accurately. The electrochemical-colorimetric dual mode of the 3D 1-AP-CNHs / AuNPs composite material and the HRP-streptavidin for high-sensitivity detection of the ERalpha disclosed by the invention greatly improves the detection accuracy. The kit has the advantages of good selectivity, strong stability, high sensitivity, anti-interference performance, environmental protection and the like.
Owner:HENAN UNIV OF CHINESE MEDICINE

A ruthenium-based catalyst based on Ta2O5 support, its preparation method and application

This invention discloses a ruthenium-based catalyst based on a Taâ‚‚Oâ‚… support, its preparation method, and its applications, belonging to the field of electrode materials technology. The invention employs a process combining hydrothermal loading and high-temperature calcination, using water as the reaction solvent and tantalum pentoxide as the support for ruthenium, applying it to the hydrogen evolution reaction in seawater electrolysis. This catalyst utilizes Lewis acid sites on the Taâ‚‚Oâ‚… surface to promote the dissociation of water molecules, providing a continuous proton supply for the hydrogen evolution reaction, thereby enhancing both catalytic activity and long-term stability in seawater systems. The method employed in this invention is simple and the structure is controllable, demonstrating excellent application potential in seawater electrolysis and possessing significant research and engineering value for promoting the practical application of ruthenium-based catalysts.
Owner:HAINAN UNIV

A method for solvent-free catalytic selective oxidation of cyclohexylbenzene by molecular oxygen to prepare 1-cyclohexylbenzene hydroperoxide

The application relates to the field of thermal catalysis, and discloses a method for preparing 1-cyclohexylbenzene hydrogen peroxide by solvent-free thermal catalytic selective oxidation of cyclohexylbenzene with molecular oxygen. The method uses a metal bromide as a catalyst, azobisisobutyronitrile or t-butyl hydroperoxide as an initiator, and pure oxygen as an oxidant, and can effectively selectively oxidize cyclohexylbenzene (CHB) into 1-cyclohexylbenzene hydrogen peroxide under normal pressure, solvent-free conditions and at a temperature above 90 DEG C. The catalytic system has the advantages of low cost, simple operation process, high catalytic oxidation efficiency and high selectivity of the target oxidation product.
Owner:HUNAN NORMAL UNIVERSITY

Method for preparing phenyl acetate with high selectivity

The invention discloses a method for preparing phenyl acetate with high selectivity. A phosphoric acid solution is added into a magnesium chloride solution, stirring and heating are performed to obtain a suspension, the suspension is dried to constant weight to obtain a white solid, the white solid is ground to obtain powder, and the powder is calcined to obtain the catalyst. Then mixing phenol and a catalyst, placing the mixture in an oil bath for reflux reaction, dropwise adding acetic anhydride, distilling after the reaction is finished, and collecting a fraction at 190-195 DEG C, namely phenyl acetate. According to the magnesium chloride loaded phosphoric acid type catalyst (MgCl2-H3PO4) prepared by the method disclosed by the invention, phenol and acetic anhydride react without a solvent, MgCl2-H3PO4 is a solid catalyst, can be recycled only by filtering and can be repeatedly used after being washed, and MgCl2-H3PO4 also improves the selectivity of phenyl acetate and reduces the production cost.
Owner:QINGDAO UNIV OF SCI & TECH

A metal oxide-supported active metal catalyst, a method for preparing the same, and use thereof

The application provides a metal oxide supported active metal catalyst, a preparation method and application thereof. The metal oxide supported active metal catalyst comprises a metal oxide carrier and active metal particles supported on the metal oxide carrier; the loading amount of the active metal is 0.1wt%-5wt% based on 100% of the mass of the metal oxide carrier. It is tested that the hydrogenation reaction of carbonates to prepare formate by using the metal oxide supported active metal catalyst provided by the application as a hydrogen source or using gaseous carbon monoxide with different concentrations and water to provide in-situ hydrogen source for the water gas shift reaction realizes the hydrogenation reaction of carbonates to prepare formate, the yield of the obtained formate is high, the selectivity is above 99%, there is no attenuation after 6 cycles, and the metal oxide supported active metal catalyst has excellent bifunctional effect. In addition, the preparation method of the metal oxide supported active metal catalyst is simple, the operation condition is mild, and the cost is low, so that large-scale production can be realized.
Owner:UNIV OF SCI & TECH OF CHINA

Wedge-shaped amphiphiles, biomimetic ion-conducting membranes, and methods of making the same

PendingCN122277452AImprove controllable transmissiongood choiceCell membraneMicroparticle
This invention relates to the field of ion-conducting membrane technology, and particularly to a wedge-shaped amphiphilic molecule, a biomimetic ion-conducting membrane, and its preparation method. The biomimetic ion-conducting membrane utilizes the self-assembly behavior of the wedge-shaped amphiphilic molecule to form a columnar mesocrystalline phase containing transport channels. This columnar structure is fixed within a membrane framework composed of methacrylate polymers using ultraviolet graft copolymerization to form an ion-transfer membrane. This membrane exhibits strong ion selectivity and conductivity, and its mechanism of action is similar to that of biological cell membranes. It can be used for the transport and separation of microparticle materials such as ions, small molecules, and micro-electronic conductors, showing broad application prospects in fields such as biology, medicine, and environmental analysis. Furthermore, its ion conductivity and chemical stability also demonstrate its potential application in proton exchange membrane fuel cells.
Owner:GUANGDONG VOCATIONAL & TECHNICAL COLLEGE +1

Air curtain machine with multiple communication modes

The utility model discloses an air curtain machine with multiple communication modes. The air curtain machine comprises a control module, a first wired module, a second wired module, a wireless module and a configuration module, the configuration module comprises a first dial switch and a second dial switch; one end of the first dial switch is connected with a first general IO port of the control module, and one end of the second dial switch is connected with a second general IO port of the control module; the first dial switch and the second dial switch generate configuration signals through dial and transmit the configuration signals to the control module; the control module selects the wireless module, the first wired module or the second wired module as a communication module for communication according to the configuration signal. According to the utility model, different communication modes are set in the air curtain machine. And the configuration module is utilized to facilitate selection of a proper communication mode by installation personnel, so that later networking is facilitated. And the installation and networking convenience of the whole air curtain machine is improved. The ventilation device is mainly used in the technical field of ventilation equipment.
Owner:FOSHAN NANHAI NANYANG ELECTRIC APPLIANCE & MOTOR CO LTD +1

A palladium ion extractant material and a method of making the same

The application provides a palladium ion extractant material and a preparation method thereof, and the pyridine-oxadiazole ligand is used as the extractant, most Pd 2+ in the aqueous phase can be extracted into the organic phase in a short time, and has a very high extraction rate; selective extraction separation of Pd 2+ under acidic conditions can be realized, the applicable range of acidity is wide, and excellent extraction capacity is achieved in the range of 0.2-4M nitric acid concentration; the extractant has excellent selectivity to Pd 2+ in the aqueous phase containing various metal ions; the pyridine-oxadiazole extractant has a good application prospect in the separation and recovery of Pd 2+ in high-level radioactive waste; the m-nitro-trifluorotoluene is used as a diluent of the extraction system, has good solubility to the organic ligand and the extractant, and the 2-bromohexanoic acid can increase the lipophilicity of the extractant.
Owner:GUANGDONG SHUO CHENG TECH CO LTD +1

A method for lithium-ion recovery using a pendulum-type electronically controlled lithium-ion recovery device

A method for lithium-ion recovery using a pendulum-type electronically controlled lithium-ion recovery device is disclosed. This method addresses the poor separation performance and stability of existing ion-imprinted materials, as well as the problem of decreased adsorption capacity. The recovery method involves sequentially preparing an ion-imprinted polymer, an ion-imprinted polymer / polypyrrole composite, and Li... + -IIP@pyy hybrid film coating electrode, Li + The IIP@pyy hybrid membrane-coated electrode is fixed at the lower end of the swing arm in a pendulum-type electronically controlled lithium-ion recovery device to react with Li in the brine of a salt lake. + Adsorption and desorption. This invention achieves intermittent adsorption and desorption of lithium ions by controlling the potential. Adsorption occurs only when the electrode is immersed in the brine of the salt lake, and desorption occurs in the deionized water regions on both sides, thereby enriching lithium ions. The device has a simple structure, avoids acid washing, and improves adsorption capacity.
Owner:NORTHEAST DIANLI UNIVERSITY

MOF-on-MOF composite material, aptamer probe and preparation method and application thereof

The invention provides an MOF-on-MOF composite material, an aptamer probe as well as a preparation method and application of the aptamer probe. The MOF-on-MOF composite material comprises an HKUST-1 material, the surface of the HKUST-1 material is coated with a Cu-BDC nanosheet; the synthesized HKUST-1 (at) Cu-BDC / Apt aptamer probe can specifically recognize AFB1, the aptamer probe can directly capture the AFB1 and adsorb the AFB1 to active sites on the surface of a material to reduce the nano-enzyme activity of the AFB1, so that quantitative colorimetric detection of the AFB1 is realized, and the aptamer probe has low detection limit, wide detection range, good selectivity and anti-interference performance on the AFB1 and can be used for detecting the AFB1. The AFB1 in a food sample can be rapidly, sensitively and selectively detected. In addition, the composite material has an adsorption effect and high catalytic activity on fungaltoxin, and AFB1 can be efficiently removed through the adsorption effect and the catalytic action.
Owner:KUNMING UNIV OF SCI & TECH

Preparation method and synthesis method of catalyst for preparing 1-hexyl methyl acetate through addition of n-heptene and acetic acid

The invention relates to a preparation method of a catalyst for preparing 1-hexyl methyl acetate by addition of n-heptene and acetic acid, which comprises the following steps: impregnating a carrier sulfonic acid group strong acid resin into a heteropoly acid solution, stirring at 20-50 DEG C for 8-24 hours, and controlling the mass ratio of the sulfonic acid group strong acid resin to the heteropoly acid solution to be (10: 1)-(1: 3); and after stirring, filtering, and drying a solid obtained after filtering at 80-140 DEG C to obtain a finished product. The invention also provides a synthetic method for synthesizing 1-hexyl methyl acetate by using the catalyst. The supported solid acid catalyst can be recycled from reaction slurry through simple liquid-solid separation means such as filtration and centrifugation, and good product selectivity can be obtained.
Owner:YIXING HENGXING FINE CHEM

A micro nectar collecting device with multi-specification capillary

The utility model discloses a miniature nectar collection device with multi-specification capillary, which comprises: multi-specification collection modules, power control modules and detachable nectar collection modules connected vertically in sequence; the power control module comprises: a power pump and a control assembly, the power pump is used to deliver the nectar collected by the collection module to the collection module, and the control assembly is used to regulate the working state of the device; the detachable nectar collection module is used to collect the nectar delivered by the power pump; the multi-specification collection module comprises: a hollow rotating drum, a plurality of sliding blocks and a plurality of multi-specification capillary tubes, one end of the rotating drum is movably connected to the power control module; the inner wall of the rotating drum is fixed with a capillary tube mounting rack, the plurality of multi-specification capillary tubes are vertically mounted on the capillary tube mounting rack, one end of the plurality of sliding blocks is connected to the capillary tubes one by one, the lateral wall of the rotating drum is provided with a sliding groove for the sliding blocks to slide in the vertical direction, and the other end of the sliding blocks is mounted in the sliding groove. The device realizes efficient, clean, portable and adjustable collection of nectar.
Owner:ZHEJIANG ACADEMY OF AGRICULTURE SCIENCES

Single-molecule fluorescent probe based on phenothiazine structure as well as preparation method and application of single-molecule fluorescent probe

The invention belongs to the technical field of fluorescent probes, and particularly relates to a single-molecule fluorescent probe based on a phenothiazine structure as well as a preparation method and application of the single-molecule fluorescent probe. The preparation method comprises the following steps: firstly introducing an alkyl chain to a nitrogen atom of a raw material to obtain the phenothiazine structure-based single-molecule fluorescent probe, then carrying out regioselective formylation on the raw material to obtain the phenothiazine structure-based single-molecule fluorescent probe, then treating the raw material by adopting aluminum trichloride to realize O-demethylation, and finally carrying out intramolecular cyclization reaction on the raw material and 1H-benzimidazole-2-acetonitrile to obtain the phenothiazine structure-based single-molecule fluorescent probe. The single-molecule fluorescent probe based on the phenothiazine structure prepared by the invention is compatible with orthogonal chemical reaction activity and maintains controllable electron transfer, so that different chemical events are converted into specific optical signals, and selective and mechanism specific fluorescent response to phosgene, copper ions and hypochlorite is realized.
Owner:PUTIAN UNIV

TEMPO-CNT composite membrane based on layer-by-layer assembly, preparation method and application

The invention discloses a TEMPO-CNT composite membrane based on layer-by-layer assembly, a preparation method and application, and belongs to the technical field of preparation of electrochemical wastewater treatment materials. According to the composite membrane, a layer-by-layer assembly process is adopted, a carbon-based conductive adsorption layer and a TEMPO catalytic function layer are sequentially constructed on a substrate layer, and an ordered layered structure is formed. According to the structure, the high specific surface area and conductivity of the carbon material are fully reserved, TEMPO active sites are uniformly exposed, and efficient cooperation of pollutant adsorption and electrocatalytic degradation is achieved. The composite membrane prepared by the invention can be adapted to various electrochemical systems such as direct current and alternating current (pulse), trace organic pollutants in wastewater can be efficiently removed with low energy consumption by applying corresponding voltage, and the composite membrane has the advantages of flexible operation, wide application scene, good environmental compatibility and the like.
Owner:ZHEJIANG FORESTRY UNIVERSITY

A lithium ion separation membrane based on intercalated large-size graphene oxide and a preparation method and application thereof

The application discloses an intercalation large-size graphene oxide-based lithium ion separation membrane and a preparation method and application thereof, and belongs to the technical field of membrane filtration and ion separation. The preparation method comprises the following steps: blending an oxidized graphene solution with an intercalation agent, standing to obtain a mixed solution, depositing the mixed solution on a base film, and drying to prepare a salt water lithium extraction membrane. The application also discloses the application of the graphene oxide-based salt water lithium extraction membrane prepared by the preparation method in the extraction of lithium ions from salt water. The interlayer spacing of the graphene oxide membrane can be adjusted by a specific intercalation agent to realize selective filtration of specific ions. With the increase of the size of the graphene oxide, the mechanical properties and film-forming properties of the large-size graphene oxide are improved, the stability of the membrane is improved, the membrane can be kept stable at a relatively thin thickness, and therefore, the lithium ions in salt lakes or brine can be stably extracted with high selectivity and high flux.
Owner:NORTHWESTERN POLYTECHNICAL UNIV

Sepiolite-based lithium ion imprinted polymer, preparation method and application in low-grade brine lithium ion adsorption separation

PendingCN122647654Ahighly selective adsorptionstable coordination structureFunctional monomerPhysical chemistry
The present application belongs to the technical field of high-value utilization of mineral resources and water treatment adsorption separation materials, and relates to a sepiolite-based lithium ion imprinting polymer, a preparation method and application in adsorption and separation of lithium ions in low-grade brine. The sepiolite is activated and pretreated, mixed with a lithium ion template, a functional monomer, a crosslinking agent and an initiator in a solvent system, and then subjected to a polymerization reaction, elution of the template ion, filtration, washing and drying to obtain the sepiolite-based lithium ion imprinting polymer. The sepiolite-based lithium ion imprinting polymer has good structural stability, lithium ion recognition selectivity and cyclic regeneration performance, and is suitable for efficient enrichment and separation of lithium ions in low-grade brine.
Owner:SHANDONG UNIV

Synthesis method of trifluoromethanesulfonate radical promoted amidino nickel complex

The invention discloses a synthesis method of a trifluoromethanesulfonate radical promoted amidino nickel complex. The preparation method comprises the following steps: reacting N, N '-dialkyl substituted amidino alkali metal salt with a nickel precursor, adding trifluoromethanesulfonate as an accelerant, and regulating the reaction rate and selectivity by utilizing the coordination effect of trifluoromethanesulfonate so as to efficiently prepare the amidino nickel complex. In the process, an ether compound is used as a solvent, the reaction is carried out at 0-70 DEG C for 1-48 hours, the reaction yield can reach 90% at most, and the product purity is gt; and 98%. The method has the characteristics of easily available raw materials, simplicity and convenience in operation, mild reaction conditions, good target product selectivity, high synthesis efficiency, convenience in post-treatment and the like, and has industrial application prospects.
Owner:DALIAN INSTITUTE OF CHEMICAL PHYSICS CHINESE ACADEMY OF SCIENCES +1

A method for preparing electronic-grade hydrofluoric acid

ActiveCN118598080Breduce usageRealize secondary useHydrogen fluorideDistillationThiol group
This invention relates to a method for preparing electronic-grade hydrofluoric acid. The invention utilizes a microchannel reactor for the fluorine oxidation reaction, significantly reducing fluorine consumption and safety hazards during production. Furthermore, the microchannel reactor enhances the gas-liquid two-phase mass transfer during the oxidation reaction, further improving impurity removal and product quality. The addition of multi-effect distillation to the distillation process not only enables secondary heat utilization but also saves on the use of high-temperature heating media at the bottom of the column, effectively reducing energy consumption. In the modified liquid, DMF serves as the solvent, cobalt nitrate provides cobalt ions, and vinylguanidine provides guanidine functional groups and amino groups. Ammonia and propanethiol are used as plasma gases to introduce amino and thiol groups onto the membrane surface. These groups help improve membrane selectivity, effectively separating metal and non-metal ions, as well as acidic impurities in the raw materials.
Owner:TIANJIN UNIV +2

A color-protection and color-anti-bleeding compound additive, a preparation method and application thereof

This application relates to the field of laundry detergent processing technology, specifically disclosing a color-protecting and color-preserving compound additive, its preparation method, and its application. The color-protecting and color-preserving compound additive is mainly composed of the following raw materials in parts by weight: 10-20 parts polyvinylpyrrolidone, 15-25 parts modified starch, 3-5 parts dihydrazine adipic acid, 15-25 parts sodium carbonate, 6-10 parts sodium carboxymethyl cellulose, 8-12 parts zeolite 4A, 8-12 parts sodium sulfate, and 11-15 parts water. The modified starch is obtained by first grafting starch with 3-chloro-2-hydroxypropyltrimethylammonium chloride and 1-chlorohexane-5-en-2-ol, and then polymerizing it with diacetone acrylamide. This color-protecting and color-preserving compound additive, with the addition of polyvinylpyrrolidone to the raw materials, synergistic effects with the modified starch, and cross-linking with dihydrazine adipic acid, exhibits high color-protecting and color-preserving effects, maintaining the original color of clothing, extending the service life of clothing, and meeting market demand.
Owner:NAFINE CHEMICAL IND GROUP CO LTD YUNCHENG