1547 results about "Tungsten" patented technology

The invention relates to the technical field of welding wire preparation, in particular to a nickel-based alloy flux-cored wire for 9Ni steel welding and a preparation method of the nickel-based alloy flux-cored wire. A nickel-based alloy flux-cored wire for 9Ni steel welding comprises a flux core, and the flux core comprises, by weight, 26%-34% of titanium dioxide, 3%-5% of ferrozirconium, 8%-12% of ferrotitanium, 1%-3% of rare earth ferrosilicon, 15%-20% of tungsten powder, 1%-2% of polytetrafluoroethylene and the balance pretreated mixed powder. The nickel-based alloy flux-cored wire for 9Ni steel welding has the advantages that low-melting-point eutectic is not prone to being formed, the hot crack sensitivity is reduced, the nickel-based alloy flux-cored wire is suitable for welding of restrained large structures, the deoxidation and denitrification capacity is enhanced, and the pore sensitivity is reduced.

Metallization schemes involve atomic layer deposition (ALD) of molybdenum (Mo) and in some embodiments, ALD of Mo in a feature without a barrier layer. In some embodiments, deposition of the ALD Mo film may be followed by chemical vapor deposition (CVD) or physical vapor deposition (PVD) of a Mo film. In some embodiments, the CVD or PVD Mo film is part of the metallization stack. In other embodiments, the CVD or PVD Mo film is deposited as a sacrificial overburden layer. In some embodiments, deposition of the ALD Mo film may be followed by CVD or PVD of another metal such as tungsten (W). In some embodiments, the CVD or PVD W film is part of the metallization stack. In other embodiments, the CVD or PVD W film is deposited as a sacrificial overburden layer.

The invention belongs to the technical field of nickel-based alloy welding wires, and discloses a corrosion-resistant nickel-based alloy welding wire and a production process thereof, and the corrosion-resistant nickel-based alloy welding wire comprises the following components in percentage by mass: 50-65% of nickel, 16-24% of chromium, 8-10% of molybdenum, 3.5-5.5% of niobium and tantalum, 3-4.5% of copper, 3-4% of tungsten, 0.5-1.0% of tin, 0.1-0.3% of rare earth element, 0.1-0.5% of grain boundary optimizer, 2-5% of nano reinforced phase and the balance of Fe and other inevitable impurities. Through multi-element alloying design, nano reinforced phase compounding and gradient coating synergistic effect, comprehensive improvement of corrosion resistance, high-temperature mechanical property and welding manufacturability is achieved; a welding wire base body is based on nickel, a compact and self-repairing gradient oxidation film is formed by accurately regulating and controlling the atomic proportion of chromium, molybdenum and tungsten, and the chloride ion permeation resistance and the high-temperature oxidation resistance are remarkably improved; therefore, the welding wire has excellent corrosion resistance, high-temperature strength and welding adaptability.

The invention belongs to the technical field of tungsten smelting, and particularly discloses a method for recycling tungsten from tungsten smelting soda boiling slag through reselection, tungsten in the slag is recycled through a physical mineral separation method, a large number of acid-base reagents are not introduced, acid-base wastewater is not generated, and high-energy-consumption roasting or high-temperature acid-base leaching is not needed. The process is simple, large-scale treatment can be achieved, reagent consumption is low, energy consumption is low, closed-loop circulation of mineral separation water can be achieved, no wastewater is discharged, the process is environmentally friendly and free of pollution risks, meanwhile, indexes of the soda boiling residues subjected to innocent treatment can reach industrial solid waste, hazardous waste is converted into common solid waste, and the economic benefit is high. The environment-friendly treatment cost is low.

Provided herein are methods and apparatuses for reducing line bending when depositing a metal such as tungsten, molybdenum, ruthenium, or cobalt into features on substrates by periodically exposing the feature to nitrogen, oxygen, or ammonia during atomic layer deposition, chemical vapor deposition, or sequential chemical vapor deposition to reduce interactions between metal deposited onto sidewalls of a feature. Methods are suitable for deposition into V-shaped features.

Provided herein are methods and apparatuses for reducing line bending when depositing a metal such as tungsten, molybdenum, ruthenium, or cobalt into features on substrates by periodically exposing the feature to nitrogen, oxygen, or ammonia during atomic layer deposition, chemical vapor deposition, or sequential chemical vapor deposition to reduce interactions between metal deposited onto sidewalls of a feature. Methods are suitable for deposition into V-shaped features.

Alloy elements are reasonably matched, N and nitrides are added to form elements such as tungsten W, vanadium V, niobium Nb, cobalt Co, rare earth RE and the like for microalloying smelting, a forged and rolled material finished product is subjected to proper heat treatment, and the stainless steel subjected to heat treatment has good heat treatment performance through metallographic observation. According to the stainless steel, nanoscale carbides are separated out in a solid solution state, and fine particles mainly containing nitrides are dispersed and separated out in crystals in a thermodynamic state, so that the material is strengthened and does not diffuse to a crystal boundary, and the room-temperature mechanical property and the high-temperature mechanical property of the material are greatly improved; and when the stainless steel material produced by the method is used for manufacturing related products, the thickness of the stainless steel material can be reduced, and the overall input of the stainless steel material is greatly reduced, so that the large-scale application of noble metal strategic resource nickel is saved, and the aims of saving resources, energy and investment are fulfilled.

The invention provides a method for recovering tungsten and rhenium from tungsten-rhenium alloy waste, which comprises the following steps: S1, collecting the tungsten-rhenium alloy waste, and crushing to obtain tungsten-rhenium alloy waste powder; s2, the cleaned tungsten-rhenium alloy waste powder is put into a reactor, and then a strong alkaline solution containing hydrogen peroxide is added into the reactor for a reaction; in the strong alkaline solution, the concentration of OH <-> dissociated by the strong alkaline substance is 2.0-4.0 mol / L, and the mass fraction of hydrogen peroxide in the strong alkaline solution is 5-15%; in the reaction process, synchronously and continuously introducing oxidizing gas into the reactor and applying ultrasonic treatment; and S3, after the reaction is finished, carrying out solid-liquid separation, collecting a leaching solution, then separating tungsten-containing ions and rhenium-containing ions in the leaching solution to respectively obtain a tungsten-containing ion solution and a rhenium-containing ion solution, and carrying out subsequent treatment to obtain tungsten salt or metal tungsten and rhenium salt or metal rhenium. According to the method, the passivation problem can be effectively solved, and the leaching rate and recovery rate of W and Re can be increased.

The invention relates to the technical field of heat sink materials, in particular to a modified gold tin-hard gold plated heat sink material and a preparation method and application thereof. Comprising a first heat sink layer, a nickel plating layer, a gold plating layer, a gold-tin solder layer, a gold plating layer, a nickel plating layer, a second heat sink layer, a nickel plating layer, a hard gold plating layer and a modified gold-tin-silicon solder layer which are sequentially connected from bottom to top. The first heat sink layer is made of oxygen-free copper, the second heat sink layer is made of molybdenum copper or tungsten copper, and the hard gold plating layer comprises a nickel plating layer and a tungsten titanium gold plating layer which are sequentially connected from bottom to top. Tungsten and titanium are introduced into the gold-plated layer on the surface of the heat sink material, so that the hardness and corrosion resistance of the gold-plated layer are remarkably enhanced; a small amount of silicon is doped into the gold-tin solder, so that the shaping processing performance of the gold-tin brittle solder is improved; one-time forming of the solder-heat sink composite material is achieved in a vacuum thermocompression welding mode, and the problem of cavities or overflow caused by solder size errors in the welding process is solved.

Improved electrocatalysts for promoting a hydrogen evolution reaction (HER) or an oxygen evolution reaction (OER) from alkaline fresh water and seawater are disclosed. By incorporating metals, such as tungsten and rare earth elements, into the nickel molybdenum nitride framework, Ni1-xMoxN, the disclosed electrocatalysts demonstrate improved catalytic activity and stability compared to the original Ni&Ni0.2Mo0.8N catalysts, particularly under high-current alkaline conditions, in water electrolysis for hydrogen and oxygen production.

The invention relates to the technical field of electroplating, and particularly discloses a nickel-tungsten-phosphorus plating layer electroplating process which comprises the following steps: S1, preparing a nano composite electroplating solution which comprises nickel salt, tungstate, hypophosphite, nano silicon carbide powder, ZIF-67 (at) MXene core-shell nanosheets, a composite complexing agent and water; s2, plasma mixed gas is adopted for conducting etching treatment on the surface of the workpiece to be plated; s3, electroplating the to-be-electroplated workpiece subjected to surface treatment under the action of pulse current and an alternating magnetic field, and performing ultrasonic stirring on the composite electroplating liquid in the electroplating process; and S4, under nitrogen protection, the workpiece is subjected to annealing treatment. According to the electroplating process, through the synergistic effect of the nano SiC and the ZIF-67 (at) MXene, the component uniformity and the structural compactness of the nickel-tungsten-phosphorus coating can be effectively improved, and then the corrosion resistance of the nickel-tungsten-phosphorus coating in the complex oil gas environment is effectively improved.

The invention deals with a non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001% ≤ Carbon ≤ 0.007 % 0.15% ≤ Manganese ≤ 0.7% 3% ≤ Silicon ≤ 3.6% 0.7% ≤ Aluminum ≤ 1.3 % Phosphorus ≤ 0.15 % Sulfur ≤ 0.006% Nitrogen ≤ 0.09% with 3.85% ≤ Si+Al+Mn ≤ 5.5% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1% 0% ≤ Titanium ≤ 0.1% 0% ≤ Vanadium ≤ 0.1% 0% ≤ Chromium ≤ 1% 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten≤ 0.1% 0% ≤ Cobalt ≤ 1% 0% ≤ Arsenic ≤ 0.05% 0.001% ≤ Calcium ≤ 0.01% 0% ≤ Copper ≤ 1% 0% ≤ Nickel ≤ 1% 0 % ≤ Boron ≤ 0.05% 0 % ≤ Lead ≤ 0.2% 0% ≤ Tin≤ 0.2% 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110microns and having a percentage of eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, from 30 to 40% when calculated in accordance with Bertotti method.

The invention relates to the field of design and preparation of powder metallurgy friction materials, in particular to a copper-based powder metallurgy friction material and a preparation method thereof. Raw materials used in the method comprise, by mass, 45%-55% of copper powder, 8%-20% of iron powder, 6%-15% of ferrochromium, 16%-22% of graphite, 0.5%-4% of molybdenum disulfide, 0.5%-4% of tin sulfide and 0.5%-4% of nickel-coated tungsten disulfide, and the mass ratio of the tin sulfide to the nickel-coated tungsten disulfide is (1-2): (1-2). In the nickel-coated tungsten disulfide, the content of nickel is 5-40%; the sum of the total amount of molybdenum disulfide, nickel-coated tungsten disulfide and tin sulfide is less than or equal to 5%. The preparation method comprises the following steps: weighing raw material powder according to the designed components, mixing, pressing and sintering to obtain the product. The composition design has the characteristics of scientificity, simple and controllable process and the like, and the obtained product has excellent tribological performance and completely meets the friction braking requirement of high-speed heavy-load equipment of 400km / h and above.

The invention relates to a method for extracting tungsten and molybdenum from low-grade tungsten-molybdenum ore, belongs to the technical field of non-ferrous metal hydrometallurgy, and solves the problems of harsh conditions, low extraction efficiency, high cost and environmental pollution when tungsten and molybdenum are extracted from low-grade tungsten-molybdenum ore in the prior art. The method comprises the following steps: leaching the low-grade tungsten-molybdenum ore by adopting sulfuric acid, and carrying out solid-liquid separation to obtain a leaching solution and leaching residues; extracting molybdenum from the leachate by adopting a cationic extraction agent to obtain tungsten-containing molybdenum extraction raffinate and a negative molybdenum organic phase; and extracting tungsten from the tungsten-containing molybdenum extraction raffinate by adopting a neutral extraction agent to obtain tungsten extraction raffinate and a negative tungsten organic phase. The method is carried out at normal temperature and normal pressure, the complexing characteristic of molybdenum to tungsten in the low-grade tungsten-molybdenum mixed ore under the acidic condition is ingeniously utilized, synergistic leaching of tungsten and molybdenum is achieved, the tungsten and molybdenum extraction efficiency is high, operation is easy and convenient, complexing agents such as phosphoric acid do not need to be added, and the leaching cost is greatly reduced; and the method is clean and environment-friendly, and development and utilization of low-grade tungsten-molybdenum ore are promoted.

The invention discloses a preparation method of a copper-tungsten composite material, which comprises the following steps: material preparation: taking a copper rod and a tungsten rod, and carrying out oil removal and ultrasonic cleaning on the copper rod and the tungsten rod; a tungsten rod is placed in a forming hole of a graphite mold, then a copper rod is placed on the top of the tungsten rod, the bottom end of the copper rod is provided with a circular truncated cone part, and an obtuse angle alpha is formed between the side face of the circular truncated cone part and the side face of the tungsten rod; feeding into a furnace: feeding the graphite mold with the copper rod and the tungsten rod into a vacuum furnace; vacuumizing is conducted, specifically, the vacuum furnace is vacuumized, and the vacuum degree is 10 <-3 >-10 <-5 > Pa; vacuum melting: heating a vacuum furnace to carry out vacuum melting, wherein the melting temperature is 1200-1320 DEG C; keeping high temperature: keeping the temperature at 1200-1320 DEG C for 5-10 minutes; controlled cooling: cooling to obtain a composite material; and post-treatment: carrying out heat treatment and machining on the composite material. Compared with the prior art, preparation of the high-quality copper-tungsten composite material can be achieved.

The invention discloses a preparation method of a tungsten ditelluride film based on a temporary Van der Waals buffer layer. The method comprises the following steps: growing a WTe2 thin film by adopting a low-temperature co-deposition method, annealing to form a Bi2Te3 / WTe2 vertical heterojunction, continuously raising the temperature, annealing to gradually decompose a Bi2Te3 buffer layer until the Bi2Te3 buffer layer disappears, and finally forming the high-quality WTe2 thin film on a substrate. The Bi2Te3 film serves as a temporary buffer layer to provide an atomic-scale flat surface for WTe2 growth, and compared with a WTe2 film directly grown on a substrate, the method has the advantages that the quality is excellent, the coverage degree is high and continuous, the thickness is uniform, the orientation is ordered, and no stress exists, so that the method has obvious advantages when the Bi2Te3 is used as the buffer layer to grow the WTe2 film. The method can be popularized to growth of a thin film material which is poor in quality and grows on a buffer layer directly, and favorable conditions are created for high-quality preparation and large-scale application of the thin film.

The invention discloses a hydrophobic micro-nano flexible thin film structure and a characterization method, relates to the technical field of thin film structure characterization, and aims to solve the problems of poor supporting performance of a flexible thin film and inaccurate standard data acquisition. Different acceleration voltages and currents are set for the coarse thinning stage and the fine thinning stage, fine removal of materials can be achieved, the accuracy of the thinning thickness is guaranteed, the thickness, the surface fluctuation amplitude and the microstructure feature size of a thin film in a measured image are measured with the help of a scale tool, and the measurement accuracy is improved. The morphological characteristics of the hydrophobic micro-nano flexible film can be converted into accurate data, rigid support is provided for the film by utilizing high hardness, high chemical stability and good thermal conductivity of tungsten, the upper side and the lower side of a target area are milled, hole digging is conducted on surrounding materials to form a preliminary sheet contour, then U-shaped milling and back-splashing material cleaning are conducted, and the thin film is obtained. The sample form is effectively controlled, and damage of processing stress to the sample structure is reduced.

The invention relates to the technical field of heavy metal recovery, in particular to a method for recovering heavy metal from metal waste. Comprising the following steps: preparing silicon-tungsten composite acid salt; preparing heteropolyacid powder; preparing a resin heteropolyacid composite material; heavy metals are recovered from metal wastes by a resin adsorption method. The silicon-tungsten composite acid salt is prepared under mild conditions through reaction of sodium metasilicate, sodium tungstate and potassium chloride, the operation is simple, the conditions are easy to control, the silicon-tungsten composite acid salt has rich active sites and a large specific surface area, the surface of the silicon-tungsten composite acid salt carries negative charges, and the surface of the silicon-tungsten composite acid salt is not prone to damage. Compared with a traditional chemical precipitation method, the method for extracting the heavy metal by using the silicon-tungsten composite acid salt does not need to add a large number of chemical reagents, and secondary pollution is reduced.

The invention deals with a double cold rolled non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001% ≤ Carbon ≤ 0.007 % 0.2% ≤ Manganese ≤ 0.24% 3.1% ≤ Silicon ≤ 3.5% 0.8% ≤ Aluminum ≤ 1.1% Phosphorus ≤ 0.15 % Sulfur ≤ 0.006% Nitrogen ≤ 0.09% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1% 0% ≤ Titanium ≤ 0.1% 0% ≤ Vanadium ≤ 0.1% 0% ≤ Chromium ≤ 1% 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten≤ 0.1% 0% ≤ Cobalt ≤ 1% 0% ≤ Arsenic ≤ 0.05% 0.001% ≤ Calcium ≤ 0.01% 0% ≤ Copper ≤ 1% 0.001% ≤ Nickel ≤ 0.01 0 % ≤ Boron ≤ 0.05% 0 % ≤ Lead ≤ 0.2% 0% ≤ Tin≤ 0.2% 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110microns and having a percentage of eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, less from 30% to 35% when calculated in accordance of Bertotti method and simultaneously having a magnetic polarization at 5000A / m (J50) from 1.645T to 1.660T.

The invention deals with a double cold rolled non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001% ≤ Carbon ≤ 0.007 % 0.1% ≤ Manganese ≤ 0.2% 3.1% ≤ Silicon ≤ 3.6% 0.8% ≤ Aluminum ≤ 1.1% Phosphorus ≤ 0.15 % Sulfur ≤ 0.006% Nitrogen ≤ 0.09% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1% 0% ≤ Titanium ≤ 0.1% 0% ≤ Vanadium ≤ 0.1% 0% ≤ Chromium ≤ 1% 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten≤ 0.1% 0% ≤ Cobalt ≤ 1% 0% ≤ Arsenic ≤ 0.05% 0.001% ≤ Calcium ≤ 0.01% 0% ≤ Copper ≤ 1% 0.001% ≤ Nickel ≤ 0.01 0 % ≤ Boron ≤ 0.05% 0 % ≤ Lead ≤ 0.2% 0% ≤ Tin≤ 0.2% 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110 microns and having a percentage of eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, is from 35% to 45% when calculated in accordance of Bertotti method and simultaneously having a magnetic polarization at 5000A / m (J50) from 1.64T to 1.66T.

The invention deals with a non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001 % ≤ Carbon ≤ 0.007 % 0.09% ≤ Manganese ≤ 0.15% 2.5% ≤ Silicon ≤ 3% 0.1 % ≤ Aluminum ≤ 0.5 % Phosphorus ≤ 0.15 % Sulfur ≤ 0.006% Nitrogen ≤ 0.09% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1 % 0% ≤ Titanium ≤ 0.1 % 0% ≤ Vanadium ≤ 0.1 % 0% ≤ Chromium ≤ 1 % 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten≤ 0.1 % 0% ≤ Cobalt ≤ 1 % 0% ≤ Arsenic ≤ 0.05% 0.001 % ≤ Calcium ≤ 0.01 % 0% ≤ Copper ≤ 1 % 0% ≤ Nickel ≤ 1 % 0 % ≤ Boron ≤ 0.05% 0 % ≤ Lead ≤ 0.2% 0% ≤ Tin≤ 0.2% 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110microns and having a percentage of eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, from 35% to 45% when calculated in accordance of Bertotti method.

The invention deals with a non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001% ≤ Carbon ≤ 0.007 % 0.15% ≤ Manganese ≤ 0.25% 2.9% ≤ Silicon ≤ 3.4% 0.7% ≤ Aluminum ≤ 1.3 % 0.05% ≤ Nickel ≤ 1% Phosphorus ≤ 0.15 % Sulfur ≤ 0.006% Nitrogen ≤ 0.09% with 3.85% ≤ Si+Al+Mn ≤ 5.5% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1% 0% ≤ Titanium ≤ 0.1% 0% ≤ Vanadium ≤ 0.1% 0% ≤ Chromium ≤ 1% 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten≤ 0.1% 0% ≤ Cobalt ≤ 1% 0% ≤ Arsenic ≤ 0.05% 0.001% ≤ Calcium ≤ 0.01% 0% ≤ Copper ≤ 1% 0 % ≤ Boron ≤ 0.05% 0 % ≤ Lead ≤ 0.2% 0% ≤ Tin≤ 0.2% 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110microns and having a percentage of eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, less than 35% when calculated in accordance of Bertotti method.

The invention provides a skarn type polymetallic deposit prospecting exploration method and system based on three-dimensional modeling, and relates to the field of geological prospecting, and the method comprises the steps: obtaining deposit data of an area where a deposit is located, and carrying out the preprocessing of the data of the mined skarn type polymetallic deposit; selecting a multi-scale convolutional neural network as a deep learning model for training so as to predict the position where an ore deposit possibly exists in the unmined area; generating a geologic feature coefficient according to the predicted geologic features of the unmined area; generating a mineral characteristic coefficient through the mineral characteristic data of the three-dimensional model; comparing the mineral characteristic coefficient with a preset weight, and judging whether tungsten-tin ore exists or not; generating a mineral type judgment coefficient according to the content of mineral elements in the sample; generating a comprehensive prediction value through the geologic characteristic coefficient and the mineral characteristic coefficient, and judging the type of the ore deposit according to the comprehensive prediction value and the type judgment coefficient. The method improves the accuracy and efficiency of ore deposit prediction.

The invention deals with a double cold rolled non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001% ≤ Carbon ≤ 0.007 % 0.1% ≤ Manganese ≤ 0.3% 3.1% ≤ Silicon ≤ 3.8% 0.6% ≤ Aluminum ≤ 0.8% Phosphorus ≤ 0.15 % Sulfur ≤ 0.006% Nitrogen ≤ 0.09% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1% 0% ≤ Titanium ≤ 0.1% 0% ≤ Vanadium ≤ 0.1% 0% ≤ Chromium ≤ 1% 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten≤ 0.1% 0% ≤ Cobalt ≤ 1% 0% ≤ Arsenic ≤ 0.05% 0.001% ≤ Calcium ≤ 0.01% 0% ≤ Copper ≤ 1% 0.001% ≤ Nickel ≤ 0.01 0 % ≤ Boron ≤ 0.05% 0 % ≤ Lead ≤ 0.2% 0% ≤ Tin≤ 0.2% 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110microns and having a percentage of eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, of 40 to 50% when calculated in accordance with Bertotti method and simultaneously having a magnetic polarization at 5000A / m (J50) from 1.66T to 1.7T.

The invention relates to the technical field of materials, in particular to preparation of an amphiphilic tungsten disulfide nano material and application of the amphiphilic tungsten disulfide nano material in preparation of an oil displacement agent. The oil-displacing agent prepared from the amphiphilic tungsten disulfide nano material can reduce the interfacial tension of an oil-water interface, and can be quickly adsorbed to the oil-water interface to layer oil and water; the surface wettability of the rock is changed, the lipophilicity of the rock is changed into weak hydrophilicity, and the pore throat cannot be blocked due to excessive hydrophilicity while the oil phase is stripped. The nano oil-displacing agent disclosed by the invention can still have an enough stable use effect after being frozen at a low temperature and then unfrozen.

The invention deals with a non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001% ≤ Carbon ≤ 0.007 % 0.17% ≤ Manganese ≤ 0.4% 3% ≤ Silicon ≤ 3.6% 0.7% ≤ Aluminum ≤ 1.3 % Phosphorus ≤ 0.15 % Sulfur ≤ 0.006% Nitrogen ≤ 0.09% with 3.85% ≤ Si+Al+Mn ≤ 5.5% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1% 0% ≤ Titanium ≤ 0.1% 0% ≤ Vanadium ≤ 0.1% 0% ≤ Chromium ≤ 1% 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten≤ 0.1% 0% ≤ Cobalt ≤ 1% 0% ≤ Arsenic ≤ 0.05% 0.001% ≤ Calcium ≤ 0.01% 0% ≤ Copper ≤ 1% 0% ≤ Nickel ≤ 1% 0 % ≤ Boron ≤ 0.05% 0 % ≤ Lead ≤ 0.2% 0% ≤ Tin≤ 0.2% 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110microns and having a percentage of eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, less than 25% when calculated in accordance of Bertotti method.

The invention deals with a non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001% ≤ Carbon ≤ 0.007 % 0.21% ≤ Manganese ≤ 0.7% 3% ≤ Silicon ≤ 3.6% 0.7% ≤ Aluminum ≤ 1.3 % Phosphorus ≤ 0.15 % Sulfur ≤ 0.006% Nitrogen ≤ 0.09% with 3.85% ≤ Si+Al+Mn ≤ 5.5% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1% 0% ≤ Titanium ≤ 0.1% 0% ≤ Vanadium ≤ 0.1% 0% ≤ Chromium ≤ 1% 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten≤ 0.1% 0% ≤ Cobalt ≤ 1% 0% ≤ Arsenic ≤ 0.05% 0.001% ≤ Calcium ≤ 0.01% 0% ≤ Copper ≤ 1% 0% ≤ Nickel ≤ 1% 0 % ≤ Boron ≤ 0.05% 0 % ≤ Lead ≤ 0.2% 0% ≤ Tin≤ 0.2% 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110microns and having a percentage of eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, from 35% to 45% when calculated in accordance of Bertotti method and simultaneously having a magnetic polarization at 5000A / m (J50) from 1.63T to 1.66T.

The invention relates to the technical field of metal smelting wastewater treatment, in particular to an electrochemical treatment method and system based on tungsten smelting wastewater detection.The method comprises the steps that workshop wastewater of a tungsten smelting plant is obtained; pre-constructed pretreatment equipment is used for conducting filtering control operation based on arsenic and fluorine on the workshop wastewater, and pretreated wastewater is obtained; carrying out electrocatalytic oxidation operation on the pretreated wastewater based on COD (Chemical Oxygen Demand) and ammonia nitrogen by utilizing pre-constructed electrochemical treatment equipment to obtain oxide wastewater; performing oxide separation operation on the oxide wastewater to obtain to-be-discharged wastewater, and performing content detection of a preset substance type on the to-be-discharged wastewater to obtain a wastewater component table; judging whether the wastewater component table belongs to a preset target-grade discharge standard or not; and when the wastewater component table belongs to the target-grade discharge standard, obtaining to-be-discharged wastewater meeting the target-grade discharge standard. The method can improve the tungsten smelting wastewater purification grade and reduce the wastewater treatment cost.

The invention belongs to the technical field of powder metallurgy, and particularly relates to a high-toughness hard alloy and a preparation method and application thereof.The preparation method comprises the steps that tungsten powder is subjected to high-energy ball milling, and then treated tungsten powder is obtained; the preparation method comprises the following steps: dissolving water-soluble lanthanum salt, cerium salt and chromium salt, and performing spray drying to obtain La-Ce-Cr composite powder; the treated tungsten powder, titanium dioxide powder, cobalt powder, La-Ce-Cr composite powder and carbon powder are mixed, and mixed powder is obtained; sintering the mixed powder to obtain alloy powder; the tungsten carbide and the alloy powder are flexibly mixed, and a mixture is obtained; and pressing and sintering the mixture to obtain the high-toughness hard alloy. The high-toughness hard alloy is a plate-shaped crystal hard alloy and is uniform in organization structure, the hardness HV10 is larger than or equal to 1620, and the fracture toughness KiC is larger than or equal to 24 MPa.m < 1 / 2 >.

The invention belongs to the field of metal materials, and particularly relates to a niobium alloy material which mainly comprises the following elements in percentage by weight: 4%-8.5% of tantalum, 4%-8.5% of tungsten, 1%-3% of molybdenum, 0.8%-2.5% of zirconium, 0-0.2% of carbon and the balance of niobium. The invention further relates to a method for preparing the niobium alloy material. The compactness of the niobium alloy material and the tensile property at the room temperature and the high temperature are obviously improved.