1608 results about "Halogen" patented technology

The present disclosure provides a solid electrolyte composition that can suppress deterioration in ion conductivity of an ionic solid electrolyte material. The solid electrolyte composition according to the present disclosure contains a sulfur element-free ionic solid electrolyte material and an organic solvent, where the organic solvent includes at least one selected from the group consisting of a hydrocarbon and a compound having a functional group; and the functional group is at least one selected from the group consisting of an ether group, a halogen group, and a Si—O—C group.

Disclosed is a liquid crystal composition. The liquid crystal composition includes liquid crystal molecules including at least one of a liquid crystal compound having an alkenyl group and a liquid crystal compound having an alkoxy group, and a first stabilizer including a compound having a structure represented by Formula 1:where n is 0 or 1; m is 0 or 1; k is 0 or 1; Z1, Z2, and Z3 are each independently a single bond, —C═C—, —OCO—, —COO—, —CF2O—, or a C1 to C5 alkylene group; X1, X2, X3, and X4 are each independently hydrogen or halogen; Y is hydrogen, an alkylene group, an alkoxy group, a hydroxyl group, —NHCOCH3, or ═O; and A and B are cyclic compounds.

The invention provides a sulfide solid electrolyte and a preparation method and application thereof, and relates to the technical field of lithium ion batteries. The preparation method comprises the following steps: S1, carrying out dry ball milling treatment on raw materials Li2S, P2S5 and LiX according to a required stoichiometric ratio, so that the raw materials are amorphized; s2, adding a solvent into the non-crystallized raw material obtained in the step S1, and carrying out wet ball-milling treatment to obtain a precursor with the particle size of 0.05-0.5 mu m; s3, the solvent is removed from the precursor slurry, the sulfide solid electrolyte is obtained through solid-phase sintering, all the steps are carried out in an inert atmosphere, and X is a halogen element. According to the present invention, the non-crystallization of the raw material is achieved through the dry ball milling, the uniform precursor slurry with the small particle size is obtained by combining the wet ball milling, and the sub-micron / nano-scale pure phase electrolyte material can be obtained after the sintering treatment, such that the electrode / electrolyte interface contact is improved, the impedance is reduced, and the battery performance is significantly improved.

The invention relates to an optical monomer and a preparation method and application thereof, the structural general formula of the optical monomer is shown as G1, G2, G3 and G4, R1 and R2 are respectively selected from one of H, C1-C10 alkyl and halogen, A1 is C1-C10 alkyl, R3 is hydrogen or methyl, and n is a positive integer selected from 1-10. The optical monomer provided by the invention has a (methyl) acrylate group with high refractive index and low volume shrinkage property, contains a plurality of aromatic rings with high molar refractive index and low molar volume, and also has sulfur atoms with relatively high molar refractive index, so that the whole molecule of the whole monomer has extremely high refractive index. The whole monomer structure in the invention has at least two functionalities, and can realize fast reaction; the monomer structure also contains more branched chains and carbon chains, and molecules are not easy to agglomerate and have a certain migration rate.

The present invention belongs to the technical field of pesticides and specifically relates to a substituted pyrazole compound containing pyrimidine and a use thereof. The compound is represented by general formula I: where Q represents an aryl group or a heterocyclic group; Y1 and Y2 each independently represent hydrogen, alkyl, or the like; R1 and R2 each independently represent hydrogen, halogen, nitro, or the like; R3 represents hydrogen, alkyl, or the like; R4, R5, R6, and R7 each independently represent hydrogen, alkyl, or halogenated alkyl; and R8 and R9 each independently represent hydrogen, halogen, cyano, alkyl, or the like. The described compound exhibits good control activity against fungi, etc.

The present invention provides a halogen-free flame-retardant multi-color anti-static PC composite material having high fluidity. The composite material comprises the following components in parts by weight: 70-93.4 parts of polycarbonate (PC), 1-10 parts of a toughening agent, 0.5-10 parts of an anti-static agent, 5-20 parts of a flame retardant, 0.05-2 parts of an anti-dripping agent, and 0.05-2 parts of an antioxidant. The present invention has the following beneficial effects: the composite material of the present invention does not contain any dangerous halogen compounds, and therefore the risk of secondary pollution during the recycling thereof can be reduced, environmental protection is achieved, and the anti-static ability of the composite material is improved; moreover, the color can be customized on the basis of product requirements, thereby meeting the market demand for colorful products; and the composite material has good flame retardancy and fluidity.

The invention discloses a dithiocarbamate monomer, a holographic recording medium, a preparation method and a related device, the structural general formula of the monomer is as shown in G1 and G2, R1 represents any one of hydrogen, halogen and C1-C4 alkyl, R3 represents any one of hydrogen, halogen and C1-C4 alkyl, A1 represents C1-C4 alkyl, A2 represents hydrogen or methyl, n is a positive integer, and n = 1-10. The dithiocarbamate monomer provided by the invention has high refractive index, and the holographic recording medium with high sensitivity, high diffraction efficiency and high refractive index modulation degree can be obtained by applying the dithiocarbamate monomer to preparation of the photopolymer holographic recording medium; holographic recording media can be used to prepare volume holographic gratings, holographic optical elements, and optical devices.

The invention provides a non-aqueous electrolyte, a secondary battery and an electric device. The non-aqueous electrolyte comprises an additive, the additive comprises a cyclic sulfate compound with a structure as shown in a general formula (I), R1, R2, R3, R4, R5 and R6 are respectively and independently selected from any one of a group with a structure as shown in a general formula (II), a hydrogen atom, a halogen atom, C1-C6 alkyl, C1-C6 halogenated alkyl, C1-C6 alkoxy, C1-C6 halogenated alkoxy, C2-C6 alkenyl, C2-C6 ester group, cyano and sulfonic acid group, and R1, R2, R3, R4, R5 and R6 are respectively and independently selected from any one of hydrogen atom, halogen atom, C1-C6 alkyl, C1-C6 halogenated alkyl, C1-C6 alkoxy, C1-C6 halogenated alkoxy, C2-C6 alkenyl, C2-C6 ester group, cyano and sulfonic acid group. And n1, n2 and n3 are respectively and independently any integer from 0 to 2. The general formula (I) is a general formula (II).

A pyrolysis method and system are provided that utilizes a multistage dehalogenation method to effectively remove halogen-containing compounds that are present in an initial recycled plastic feedstock. More particularly, the multistage dehalogenation system and process may involve physical sorting the plastic feedstock, melting and separating the feedstock, and subjecting the feedstock a two-stage pyrolysis with intermediate HCl removal.

A method to produce a halogen-depleted gas is described. The method providing a gas derived from and / or including a source of biogas, mixing said gas with a source of hydrogen to produce a processed gas mixture including an acid, and separating said acid from said processed gas mixture. Sulfur, oxygen, carbon dioxide removal processes are integrated into the method. Production of secondary products, and removal thereof, are included. Pre and post processing may be integrated, and production of products is described.

Synthesis reactions are described to efficiently and specifically form compounds of the structure RSnL3, where R is an organic ligand to the tin, and L is hydrolysable ligand or a hydrolysis product thereof. The synthesis is effective for a broad range of R ligands. The synthesis is based on the use of alkali metal ions and optionally alkaline earth (pseudo-alkaline earth) metal ions. Compounds are formed of the structures represented by the formulas RSn(C≡CSiR′3)3, R′R″ACSnL3, where A is a halogen atom (F, Cl, Br or I) or an aromatic ring with at least one halogen substituent, R′R″(R″′O)CSnL3 or R′R″(N≡C)CSnZ3.

The invention belongs to the field of light-emitting diodes, and discloses a preparation method of a blue-light perovskite thin film containing a sulfonate additive and a light-emitting device of the blue-light perovskite thin film. According to the technical scheme, sulfonate functional additives (such as methyl methanesulfonate and the like) with the addition amount being 0.5%-1.5% of the molar weight of lead ions are introduced into a full-inorganic CsPb (BrxCl1-x) 3 perovskite precursor solution, the molar ratio of chlorine to bromine is controlled to be 0.5: 1-2: 1, and the thin film is formed through spin coating and annealing treatment at the temperature of 110-130 DEG C. Sulfonate groups in additive molecules are effectively coordinated with uncoordinated lead ions in perovskite crystals, so that defects of grain boundaries and surfaces are passivated, and a non-radiative recombination center is inhibited; meanwhile, accurate adjustment of the wavelength of the blue light is realized through regulation and control of the halogen proportion. A blue light perovskite light-emitting diode device prepared based on the modified thin film realizes high-brightness, high-efficiency and wavelength-adjustable blue light emission.

The present invention provides an electronic or electrical device or component thereof comprising a cross-linked polymeric coating on a surface of the electronic or electrical device or component thereof; wherein the cross-linked polymeric coating is obtainable by exposing the electronic or electrical device or component thereof to a plasma comprising a monomer compound and a crosslinking reagent for a period of time sufficient to allow formation of the cross-linked polymeric coating on a surface thereof,wherein the monomer compound has the following formula:where R1, R2 and R4 are each independently selected from hydrogen, optionally substituted branched or straight chain C1-C6 alkyl or halo alkyl or aryl optionally substituted by halo, and R3 is selected from:where each X is independently selected from hydrogen, a halogen, optionally substituted branched or straight chain C1-C6 alkyl, halo alkyl or aryl optionally substituted by halo; and n1 is an integer from 1 to 27; and wherein the crosslinking reagent comprises two or more unsaturated bonds attached by means of one or more linker moieties and has a boiling point at standard pressure of less than 500° C.

The invention provides a halogen-free flame-retardant polyolefin cable sheath material composition, a sheath material and a production method. The halogen-free flame-retardant polyolefin cable sheath material composition comprises a polyolefin resin matrix, a silane coupling agent, an inorganic flame retardant and silica, wherein the inorganic flame retardant comprises aluminum hydroxide and magnesium hydroxide. In the application, the silica and decomposition products of the aluminum hydroxide and the magnesium hydroxide can form a compact ceramic layer at high temperature, and the ceramic layer can stably exist in a humid and hot environment for a long time, and can effectively block the permeation of moisture, reduce the erosion of moisture to a base material and improve the moisture aging resistance of the sheath material.

The invention provides a halide solid electrolyte as well as a preparation method and application thereof, and particularly relates to the technical field of lithium batteries. The chemical formula of the halide solid electrolyte is Li < 2.8 > In M X < 6 >, m is a doping element and is selected from at least one of Nb, Ta, Zr, Mo, W, Gd, Al, Sc, Sb, Sn and V; x is halogen and is selected from at least one of F, Cl, Br and I; a and b satisfy 3a + mb = 3.2, wherein m is the valence state of M. According to the halide solid electrolyte provided by the invention, In is partially replaced by the doping element, a cation vacancy is introduced by the high valence state of the doping element, a three-dimensional diffusion channel of lithium ions is expanded, and the ionic conductivity of the solid electrolyte at room temperature is improved; meanwhile, halide generates a stable halogen-rich interface layer on the surface of the positive electrode in situ, so that side reaction is inhibited, and the cycle performance is improved. The halide solid electrolyte is better matched with a positive electrode material, the loading capacity and the reversible capacity of a positive electrode active material can be further improved, and the energy density of the battery is improved.

The invention relates to a halogen-free flame-retardant flexible bending-resistant low-voltage power cable and a manufacturing method thereof. An insulating layer of the cable is made of a core-shell type nano composite phase change material, a core layer is made of a polyethylene glycol / paraffin phase change material, a shell layer is made of polyurethane or modified polyamide nano fibers and nano SiO2 particles, and the cable is prepared by adopting a coaxial electrostatic spinning technology. According to the structure, stress can be effectively dispersed when the cable is bent, crack propagation is reduced, the temperature is adjusted through the phase change material, and local overheating is prevented. The three-dimensional network structure enhances the bending resistance of the cable, the bending life is prolonged by 40%-60%, and the halogen-free flame retardant performance is ensured at the same time. The technology realizes collaborative optimization of temperature adjustment, stress buffering and bending resistance, and is suitable for power cables with high requirements.

The invention provides a copper etching solution and application thereof. The copper etching liquid comprises an inorganic acid, hydrogen peroxide, an azole compound, a halogen ion source and an amine compound, wherein the amine compound is selected from a compound shown in a formula 1 or an ammonium salt with a structural fragment shown in a formula 2. When the copper etching solution is applied to etching treatment on a chemical copper plating seed layer by a semi-additive method, the copper etching solution shows excellent differential etching capability, and has no obvious etching on the side wall of electroplating copper and the seed layer at the bottom of a copper circuit on the basis of effectively removing the seed layer between the copper circuits, so that the etching quality of the copper plating seed layer is improved. The undercut phenomenon can be prevented, the line width reduction amount is small, and the reliability degree of micronized line wiring can be obviously improved.

The invention provides an anion-cation co-doped solid electrolyte, a preparation method thereof, a solid-state battery and electric equipment, and relates to the field of solid electrolytes. The general chemical formula of the anion-cation co-doped solid electrolyte is Li < 2 + > (4-m) x Zr < 1-x > M < x > X < 6-ayAy, 0 < x < = 0.4, 0 < y < = 0.8, m is the valence state of M, and a is the valence state of A; m comprises a metal doping element with the ion radius larger than that of Zr < 4 + > and the valence state lower than that of Zr; x comprises a halogen element; a comprises one or more of O, S, N and P; the ion radius of A is smaller than X; the valence state of M comprises + 2 and / or + 3. The Li2ZrX6 solid electrolyte is subjected to anion and cation co-ion doping, so that the disorder degree of a crystal structure can be increased, a Li < + > transmission channel is widened, and the ionic conductivity is improved.

The invention discloses an air-stable sulfide solid electrolyte as well as a preparation method and application thereof, and relates to the technical field of solid-state lithium batteries. The chemical formula of the sulfide solid electrolyte is Li < 5.4 > P < 1-x > S < 4.4 > M < x > Cl < 1.6-y > X < y >, x is greater than 0 and less than 0.08, y is greater than 0 and less than 1, and M is selected from at least one of Fe, Zn, Ge, Zr, Sn, Ca, Mg, Ti or Ag; x is selected from at least one of F, Cl, Br and I. According to the sulfide solid electrolyte disclosed by the invention, through double-element doping of metal elements and halogen, the surface energy of a material is reduced, water molecule adsorption is inhibited, meanwhile, the ionic conductivity of the sulfide solid electrolyte can be obviously improved, and the conductivity of the sulfide solid electrolyte is not obviously attenuated in a high-humidity environment.

To provide an excellent pest control agent composition that contains a novel agent having a pest control effect and a known pest control agent.SOLUTION: A pest control agent composition prepared by mixing an active ingredient A selected from the group consisting of aryl tetrahydropyridine compounds represented by formula (1) with a known pest control agent. [Q represents Q-1 or the like, Z1 represents a halogen atom, J represents J-1 or the like, A1 represents N, R1 represents a halogen atom or the like, G represents G-1 or the like, Z2 represents a halogen atom or the like, R2 and R3 represent H, X and Y represent O, t4 represents an integer of 0, 1, 2, 3 or 4, and t5 represents an integer of 0, 1, 2, 3, 4 or 5].SELECTED DRAWING: None

Naphtha reforming catalysts are described. The catalyst includes a support comprising a solid solution or a homogenous mixture of atoms in solid state having a single crystal structure comprising AI2O3, and / or 0.01 to 3 wt% of a first metal of Group 2 or Group 15 of the Periodic Table, or a combination thereof. It also includes 0.05 to 5.0 wt% Pt and 0.05 to 5.0 wt% Re; 0.01 to 2 wt% of at least one additional metal from Groups 1, 2, 3, 9, or 15 of the Periodic Table, or combinations thereof; 0.03 to 1.0 wt% S; and 0.5 to 2 wt% of a halogen. The catalyst has an average bulk density in a range of 0.25 - 1.50 g / cc and a surface area in a range of 50-300 m2 / g. Catalytic reforming processes are also described.

The invention relates to the technical field of perovskite, and discloses a perovskite thin film, a preparation method thereof and a perovskite solar cell, the chemical formula of the perovskite thin film is ABX3, A is selected from at least two mixed cations of cesium, formamidine and methyl ammonium, B is lead, and X is mixed halogen of iodine and bromine; the thickness of the film is 300-600 nm, the grain size is 100-500 nm, the surface roughness Ra is smaller than or equal to 10 nm, guanidine thiocyanate is doped, the doping amount is 0.5-2.5% of the total mass of perovskite, and the molar ratio of iodine to bromine in mixed halogen changes in a gradient mode in the thickness direction of the film. By adopting the design of mixed cations and gradient halogen, the grain size of the prepared perovskite thin film is obviously increased, the surface roughness is obviously reduced, and the PL fluorescence lifetime is greatly prolonged, so that the service life of a carrier is obviously prolonged, and the effects of increasing the grain size of the perovskite thin film, reducing surface defects and enhancing thermal stability are achieved.

A method for etching a metal containing material is provided. The metal containing material is exposed to a halogen containing fluid or plasma to convert at least some of the metal containing material into a metal halide material. The metal halide material is exposed to a ligand containing fluid or plasma, wherein at least some of the metal halide material is formed into a metal halide ligand complex. At least some of the metal halide ligand complex is vaporized.

A plasma processing method includes: a first step of forming a pattern by irradiating a molybdenum or ruthenium film with plasma generated using an oxygen gas and a halogen gas; after the first step, a second step of forming a protective film containing carbon on a pattern side wall with plasma using a gas containing carbon; a third step of selectively removing the protective film on a pattern bottom portion and oxidizing the molybdenum or ruthenium film on the pattern bottom portion with plasma generated using an oxygen gas; and a fourth step of etching the oxidized molybdenum or ruthenium film with plasma generated using a halogen gas. The second step to the fourth step are repeated until reaching a predetermined depth. The method can further include a step of removing the protective film containing carbon formed on the pattern side wall and an altered layer with plasma containing hydrogen.

The invention relates to the technical field of cables, and discloses a halogen-free flame-retardant control cable. The halogen-free flame-retardant control cable sequentially comprises a plurality of wire cores, an insulating layer, a shielding layer and an outer protection layer from inside to outside, wherein the outer protection layer is formed by extruding a flame-retardant polyethylene composite material outside the shielding layer; the flame-retardant polyethylene composite material is prepared from the following raw materials in parts by weight: 60 to 80 parts of linear low-density polyethylene, 8 to 12 parts of compatilizer, 8 to 15 parts of modified flame retardant, 0.3 to 0.5 part of dibenzoyl peroxide, 1 to 3 parts of lubricant and 0.5 to 1.5 parts of antioxidant; wherein under the condition that the addition amount of the introduced modified flame retardant is relatively small, the flame retardant property of the cable can still be remarkably improved.

The invention discloses a liquid crystal compound, a liquid crystal composition containing the same and a liquid crystal display device. The liquid crystal compound is shown in the following formula I, X1 and X2 independently represent H, halogen, alkyl with the carbon atom number being 1-10, alkoxy with the carbon atom number being 1-10 or alkenyl with the carbon atom number being 2-10, X1 and X2 do not represent H and halogen at the same time, and when one of X1 and X2 is alkyl, alkoxy or alkenyl, the other is not H. The liquid crystal compound has the advantages that the K value change is small after UV irradiation, the K11 / delta epsilon value change is small, and the response speed at the low temperature is high; the liquid crystal composition containing the liquid crystal compound also has the advantages of small K value change after UV irradiation, small K11 / delta epsilon value change and higher low-temperature response speed, and can be used for developing liquid crystal display devices with stable threshold voltage, stable contrast and higher low-temperature response speed after UV irradiation. I

The application belongs to the technical field of surfactants, and discloses a kind of organic counterion quaternary ammonium salt gemini surfactants without chlorine and a preparation method and application thereof.The organic counterion quaternary ammonium salt gemini surfactants without chlorine are obtained by adding a certain amount of alkyl diamine compound acidified by organic acid into C1-C 18 The alkyl glycidyl ether is subjected to quaternary ammonium reaction by adding a certain amount of alkyl diamine compound acidified by organic acid.The obtained organic counterion quaternary ammonium salt gemini surfactants without chlorine contain two organic counterions and two hydroxyl groups, the synthesis process is simple, the conditions are mild, and no toxic and harmful by-products are produced, which can avoid the corrosion of halogen ions to equipment and environmental pollution during preparation.

This invention relates to the use of compounds of formula (I), or pharmaceutically acceptable salts or solvates thereof, in the treatment or prevention of mycobacterial infections, wherein: one of R2 and R3 is H, and the other is (CR) a R b ) n Y; Y is selected from CO2R c CN and CONR e R f R4 is selected from H, halogens, CN, alkyl and alkoxy groups; R6 is selected from H, F, Br, I, COOH, CN, COR. d CO2R d Alkyl, haloalkyl, alkoxy, haloalkoxy, nitro, OH, SR d SOR d SO2R d SO2NR d R d NHSO2R d aryl and heteroaryl groups, wherein the aryl or heteroaryl group is optionally substituted by one or more substituents selected from alkyl, alkoxy, halogen, haloalkyl, and haloalkoxy groups; R7 is selected from H, halogen, alkyl, and alkoxy groups; R9 is selected from H, COR... d Alkyl, haloalkyl, aryl, CO-aryl, CO-haloaryl, aralkyl and haloaralkyl; R1, R5 and R8 are H; each R a R b R c R d R e and R f The compounds are independently selected from H, alkyl, and haloalkyl groups; n is 1 to 6. Other aspects of the invention relate to subgroups of compounds of formula (Ia), pharmaceutical compositions comprising such subgroups, and their use in the treatment or prevention of mycobacterial infections.

This invention belongs to the field of organic synthesis and relates to a nitrogen-containing [3,2-b]indole derivative, its preparation method, and its application. The nitrogen-containing [3,2-b]indole derivative is a compound, optical isomer, or pharmaceutically acceptable salt thereof, as shown in the following structure: ; wherein R1, R2, R3, and R4 are independently selected from hydrogen atoms, halogens, cyano groups, C1-C8 alkyl groups, and C1-C8 alkoxy groups; R5, R6, R7, and R8 are independently selected from hydrogen atoms, halogens, and C1-C8 alkyl groups; R9 is selected from C1-C8 alkyl groups; when R1, R2, R3, R4, R5, R6, R7, and R8 are all hydrogen atoms, R9 is selected from C1-C2 alkyl groups. The compound exhibits antitumor activity, particularly against HeLa cervical cancer, showing a significant inhibitory effect on its proliferation.

The invention discloses a flame-retardant nylon material which comprises 50-70 parts of PA (polyamide), 1-5 parts of a toughening agent, 3-5 parts of a P-series flame retardant, 3-5 parts of an N-series flame retardant and 10-20 parts of a modified polysilsesquioxane flame retardant, and the modified polysilsesquioxane flame retardant is prepared from raw materials including silsesquioxane A, a compound B and a catalyst in an alkaline environment. The silsesquioxane A comprises at least one epoxy group D, and the compound B contains a phosphorus element P and a nitrogen element N and at least comprises a halogen end group X. The flame-retardant nylon material provided by the invention is excellent in flame retardant property and dielectric property, has good processability and mechanical property, greatly improves the anti-cracking property and anti-dripping effect of the flame-retardant nylon material, and is safe and environment-friendly.