1196 results about "Calcium" patented technology

The invention provides an acetylacetone-based composite thermal stabilizer which is a mixture obtained by mixing zinc acetylacetonate, calcium acetylacetonate or magnesium acetylacetonate and hydrotalcite pro rata. The composite thermal stabilizer is suitable for chloride-containing high polymer, such as polyvinyl chloride, chlorinated polyethylene, chlorinated polyvinyl chloride, copolymer of vinyl chloride-ethylene or copolymer of vinyl chloride-vinyl acetate, has better thermal stability, prolongs the thermal aging time of the chloride-containing high polymer, and overcomes the shortcomings of poor long-term performance of single stabilizer of zinc acetylacetonate, poor transparency of stabilizer of calcium acetylacetonate, and poor initial colorability of stabilizer of hydrotalcite. The composite thermal stabilizer has low cost, good initial colorability, excellent long-term performance and good transparency, and is an efficient composite thermal stabilizer.

The invention discloses piggy creep feed containing composite flavone. The piggy creep feed is prepared from the following raw materials in parts by weight: 13 to 20 parts of expanded corn, 10 to 25 parts of corn, 6 to 13 parts of broken rice, 8 to 12 parts of flour, 8 to 15 parts of whey mist, 3 to 8 parts of soy protein concentrate, 5 to 10 parts of extruded soybean, 0.7 to 3 parts of soya-bean oil, 7 to 12 parts of 46.5-percent bean pulp, 2 to 5 parts of fish meal, 2 to 5 parts of plasma protein powder, 0.3 to 0.7 part of mountain flour, 0.5 to 1.0 part of calcium hydrophosphate, 0.05 to 0.5 part of lysine, 0.05 to 0.3 part of threonine, 0.1 to 0.3 part of sodium chloride, 0.1 to 0.8 part of compound flavone premix compounds, 0.15 to 0.3 part of zinc oxide, 0.03 to 0.06 part of calcium propionate, 0.02 to 0.04 part of ethoxyquin and 1.0 part of suckling pig premix compounds. The invention also discloses a preparation method. The intestinal tract health and the production performance of weaned pigs can be improved.

The invention discloses a catalyst used for preparing acrylic acid and butyl ester by the dehydration of butyl lactate and a preparation method thereof. The catalyst is a composite catalyst, comprising a main catalyst A and auxiliary catalysts B, C, D and E, wherein, A is calcium sulphate, B is sulphuric acid, C is phosphate, D is alkaline matter and E is promoter. The preparation method comprises the steps as follows: five compositions A, B, C, D and E are sufficiently mixed, baked for 2-10 hours at the temperature of 200-800DEG C and formed for standby. The catalyst has high catalytic activation; under the catalysis of the catalyst, the molar yield reaches 75.1 percent and the molar selectivity of the acrylic acid and butyl ester reaches 71.5 percent. The preparation method has the advantages that the crystal structure of the main catalyst can be improved so as to be beneficial for carrying out the reaction; and the introduction of different auxiliary catalysts and quantities is helpful to improve the conversion ratio of the raw material and the product selectivity and is beneficial for improving the strength of the catalyst.

The invention relates to the technical field of cementing materials, in particular to an early-strength type freeze-thaw cycle-resistant cementing material and a preparation method thereof. The cementing material comprises the following raw materials in parts by mass: 50 parts of steel slag, 32-42 parts of blast furnace slag, 11-17 parts of desulfurized gypsum, 22-30 parts of fly ash, 3-5 parts of calcium chloride, 4-7 parts of a composite alkali activator and 11-17 parts of an interface treating agent. Through the combined action of the composite alkali activator and the interface treating agent, the mechanical strength and the freeze-thaw cycle resistance of the cementing material are improved at the same time, and particularly, the early strength and the freeze-thaw cycle resistance are improved at the same time, so that the cementing material can be applied to high-humidity and cold regions.

The invention relates to the technical field of mineral processing data processing, in particular to a preparation method of a high-calcium fluorite and barite paragenic ore combined inhibitor, which comprises the following steps: collecting multi-source process mineralogy data output by an X-ray fluorescence spectrometer, an automatic mineral analyzer and the like, converting the multi-source process mineralogy data into a structured format, and constructing a process mineralogy database; based on historical data of a database, a random forest algorithm is adopted to train a correlation model, the correlation rule of mineral characteristics such as calcite content, fluorite particle size distribution and barite monomer dissociation degree and the inhibitor ratio is learned, and parameters of the optimization model are fed back through a flotation test. The combined inhibitor solves the problem of selective separation caused by similar surface properties through a synergistic effect of covering active sites of fluorite calcium by modified water glass, regulating active sites of barite barium by citric acid and assisting in enhancing inhibition by modified starch, and solves the problem of low efficiency of multi-source data integration through structured data processing and model closed-loop optimization; the flotation separation efficiency and the concentrate grade are improved.

The invention relates to an anorthite material and a preparation method thereof. The adopted technical proposal comprises the following steps of: according to (ZL200510019664.3) patent technology, namely a method for preparing titanium and a titanium alloy by utilizing titanium-containing furnace slag, taking molten tailings which is extracted with the titanium alloy as a raw material, adding 20 to 50 weight percent of silica, 0 to 60 weight percent of clay and 0 to 40 percent aedelforsite, and cooling a melt to obtain the anorthite material after the mixture is completely molten and a bath composition is uniform; or taking cold tailings extracted with the titanium alloy as the raw material, adding 20 to 50 weight percent of the silica, 0 to 60 weight percent of the clay and 0 to 40 percent the aedelforsite, carrying out mix grinding on the raw material and the admixture until the particle size is less than 0.1 mm, performing blank compression, and calcining the mixture at a temperature of between 1,200 and 1,400 DEG C to obtain the anorthite material. The method takes the tailings extracted with the titanium as the raw material, saves precious bauxite resources, has low cost, ensures that industrial residue is utilized with high added value, is environment-friendly and has simple process.

The invention relates to the technical field of sludge reduction and resource utilization, in particular to a method for resource utilization of sludge gasification slag. According to the method, municipal sludge gasification slag is smashed and then subjected to acid leaching, acid leaching liquid and acid leaching slag are obtained, iron in the acid leaching liquid is recycled, meanwhile, the acid leaching slag is subjected to alkaline leaching, under the strong alkaline condition, a calcium source is added into alkaline leaching liquid, then calcium phosphate sediment can be obtained, and iron in alkaline leaching separation liquid is recycled; a calcium ion solution can be generated in the processes of recovering iron in the pickle liquor and refining calcium phosphate, and the obtained calcium ion solution can be used as a calcium source for comprehensive utilization. The method disclosed by the invention can be used for realizing extraction and resource utilization of phosphorus, iron, aluminum and calcium in the sludge gasification slag, and has important significance on environmental protection and resource saving.

The present invention provides a glass sheet having soda-lime-silica glass composition with a high visible light transmittance (LtC) of at least 89% with a dominant wavelength (DW) from about 490 to 505 nanometers and purity (Pe) of no more than 1% for control thickness of 5.66 mm and methods of making the same. The glass composition comprising a low iron raw material, a total iron oxide (Fe2O3) of 0.02 to 0.06 wt. %, ferrous (FeO) from 0.006 to 0.02 wt. %, redox (FeO / Fe2O3) from about 0.30 to 0.55, Cr2O3 from about 0.3 to 10 ppm, TiO2 from about 50 to 500 ppm, SnO2 from about 10 to 500 ppm, and a critical amount from about 0.10 to 0.25 wt. % of SO3. The low content of iron oxide is achieved by the partial substitution of regular raw materials by low iron raw materials, with a complete substitution of regular dolomite by a low iron dolomite with a maximum content of 0.020 wt. % Fe2O3.

The invention discloses a high-temperature dechlorinating agent for removing hydrogen chloride gas and a preparation method of the high-temperature dechlorinating agent, and belongs to the technical field of dechlorinating, and the preparation method of the high-temperature dechlorinating agent for removing the hydrogen chloride gas comprises four steps of preparing sepiolite-loaded active calcium powder, preparing copper-aluminum coated calcium carbonate whiskers, forming and roasting. According to the high-temperature dechlorinating agent for removing the hydrogen chloride gas, the penetration chlorine capacity is 78.5 to 81.7 percent, the crushing strength is 142 to 160N. Cm <-1 >, and the abrasion rate is 0.8 to 1.2 percent.

The present invention belongs to the technical field of petroleum fracturing production enhancement and modification, and specifically discloses a fracturing fluid pre-fluid for optimizing the size of in-situ autogenous proppant and its application, which is used to solve the problem of small particle size of proppant particles generated by hydrothermal reaction of formation minerals. The fracturing fluid pre-fluid is suitable for calcium-rich reservoirs and is composed of clean water, phosphate, pH regulator and Ca 2+ The chelating agent composition comprises 1 to 10 parts by weight of phosphate relative to 100 parts by weight of clean water, a volume molar concentration of the pH regulator is 1 to 5 mol / L, and Ca 2+ The molar concentration of the chelating agent is 0.001~1mol / L; the pH regulator is urea, ammonia, propionamide, etc. 2+ The chelating agent is EDTA, glutamic acid, etc. The present invention increases the average particle size of proppant particles generated by hydrothermal reaction of formation minerals, thereby improving the supporting effect thereof in micro-fractures of the formation.

The invention discloses a phosphogypsum leachate-carbonate rock dynamic corrosion reaction analysis method based on numerical simulation, and aims to research a migration-corrosion coupling mechanism of acid leachate in a carbonate rock fracture network. The method comprises the following steps: firstly, acquiring a two-dimensional image sequence of a rock core sample through CT (Computed Tomography) scanning, carrying out operations such as threshold segmentation, membrane enhancement and a light shading algorithm on an image by utilizing AVIZO software, extracting fracture structure parameters and establishing a high-precision three-dimensional model; then, multiple groups of simplified models with different fracture widths are constructed in COMSOL Multiphysics, a Darcy flow field and a solute concentration field are coupled on the basis of the Darcy law and a dilute matter transfer theory, and the dynamic corrosion effect under the multi-field coupling effect is quantitatively represented by setting hydraulic gradient boundary conditions and chemical reaction kinetic parameters; the dynamic corrosion reaction process of calcium ions, hydrofluoric acid, sulfuric acid and phosphoric acid in the ardealite leachate and carbonate rocks with different crack widths is accurately simulated.

The invention belongs to the technical field of industrial solid waste resource recycling, and discloses a nano composite filling material based on in-situ acid-base mutual modification enhancement and application thereof. According to the nano composite filling material, the alkalinity of the red mud and the acidity of the desulfurized gypsum are used for neutralization, the alkalinity of a system is reduced, a synergistic reaction is excited, a large number of ettringite crystals playing a key enhancing role are generated under the regulation and control of a nano material, and the ettringite crystals and a geopolymer form an interpenetrating network structure. The obtained slurry is low-viscosity and high-fluidity Newtonian fluid (diffusivity gt and 250 mm), the 7-day strength is larger than 2.0 MPa, the pH value is 7-9, and the fluorine ion concentration is lt; and the leaching of heavy metal ions is qualified, and the method is environment-friendly and safe. Efficient resource utilization of the red mud and the desulfurized gypsum is achieved, and the method is simple in process, low in cost and especially suitable for mine filling and engineering backfilling.

The invention provides a carbon dioxide capture system based on a calcium-based granular material and a control method of the carbon dioxide capture system. The system comprises a reactor, a decomposition bin, a conveying branch and an input branch, the input branch inputs raw flue gas to the reactor; the conveying branch conveys a calcium-based particle material to the reactor by using the heated flue gas; the reactor is used for controlling the internal temperature by selecting the raw flue gas input by the input branch so as to control the adsorption reaction; the decomposition bin is used for controlling the movement of the supporting plate under the mechanical action and the air pressure action so as to guide the flowing of the materials and further control the desorption reaction. A set of complete and ingenious heat circulation process and material circulation process is constructed, the circulation processes are linked with each other, the structural design is ingenious and practical, and while efficient adsorption and desorption of carbon dioxide are guaranteed, the energy utilization efficiency is improved, the energy consumption is reduced, and the equipment maintenance cost and the energy purchase cost are reduced.

The invention discloses a calcium-based incrustation deposition experimental device and experimental method. The device comprises a reaction container, a sensor module, a control unit, an automatic solution supply device and a carbon dioxide gas supply unit. The sensor module monitors the pH value of the reaction liquid and the concentration of calcium hydroxide in real time; the control unit receives the data and compares the data with a preset threshold value to control the supply device to automatically add the calcium hydroxide solution so as to maintain the stability of chemical parameters; gas is introduced into the carbon dioxide supply unit at a controllable flow rate. The experimental method comprises the following steps: setting and initializing parameters; starting constant temperature and gas introduction; the system automatically runs, and the conditions are kept stable through real-time monitoring, threshold comparison and automatic supply; and after the experiment is finished, sampling and analyzing the sediment, and exporting process data for analysis. According to the method, the problems of parameter drift and frequent manual intervention in a traditional method are solved, and the repeatability and automation level of experiments and the scientificity of data are remarkably improved.

The invention relates to the technical field of building materials, in particular to a cementing material for a fabricated wall prepared from multi-element solid waste and a preparation method of the cementing material. The preparation method comprises the following steps: 25-55 parts of fly ash, 25-65 parts of blast furnace slag, 8-10 parts of lime, 1-5 parts of desulfurized gypsum, 3-6 parts of a first mixture, 2-5 parts of a second mixture and 5-8 parts of an alkali activator; the mass ratio of the metakaolin to the bentonite to the superfine calcium carbonate in the first mixture is 3: 2: 1; the mass ratio of the vermiculite to the expanded perlite to the glass beads in the second mixture is 2: 2: 1. Through the synergistic excitation effect of Ca < 2 + > and Na < + > and the addition of the first mixture and the second mixture, the cementing material forms a more stable microstructure. A hydration product SEM figure shows that C-S-H and C (N)-A-S-H gel are symbiotic to form a three-dimensional network, pores are filled with needle-like ettringite crystals, and in combination with the brucite phase anchoring effect, the mechanical properties, such as strength and durability, of the material are remarkably improved.

The invention relates to the technical field of mine water treatment, and discloses a method for treating high-calcium-hardness mine water through induced crystallization. The method comprises the following steps: adding coal gangue and sodium phosphate or sodium hydrogen phosphate into the mine water to carry out first induced crystallization so as to remove calcium ions in the mine water; according to the method provided by the invention, the concentration of calcium ions in the mine water after calcium removal can be stabilized for a long time, and the removal rate of the mine water is improved to a certain extent. The method provided by the invention can effectively ensure that the Ca < 2 + > content of the effluent quality of the mine water reaches the standard, and can also reduce secondary environmental pollution.

The invention discloses a calcium-based CO2 adsorbent as well as a preparation method and application thereof. The calcium-based CO2 adsorbent comprises a CaAl12O19-CaSiO3 reticular skeleton structure, and the CaAl12O19-CaSiO3 reticular skeleton structure is enclosed to form a pore cavity; and a plurality of CaO particles dispersed within the pore cavity. The possibility that the calcium-based CO2 adsorbent is caked in high-temperature CO2 capture circulation can be effectively reduced, and the adsorption performance and the circulation stability of the calcium-based CO2 adsorbent are better improved.

A steel sheet, coated with a metallic coating including, by weight percent, from 7.5 to 9.0% of zinc, from 1.1 to 4.0% of silicon, from 1.1 to 8.0% of magnesium, up to 3.0% of iron, optional elements chosen from Pb, Ni, Zr, or Hf, the content by weight of each element being less than 0.3%, optionally up to 100 ppm of Calcium and unavoidable impurities up to 0.02%, a balance being aluminum, and wherein the coating weight of the metallic coating is from 50 to 500 g / m2 for the sum of both sides of the-steel sheet.

The invention belongs to the technical field of carbon dioxide sequestration, and particularly discloses a method for sequestration of CO2 in a mine goaf through mineralization grouting, which comprises the following steps of: filling and mining by adopting a short-wall working surface strip to form a closed goaf; water swelling rubber slurry is injected into the filling body, and a sealing layer with the thickness larger than or equal to 0.5 m is formed after swelling; an impermeable layer is formed through a top plate reconstruction technology; cO2 is injected into the closed goaf, a calcium ion release source reacts with CO2 to generate calcium carbonate, and chemical sequestration is achieved. The coal mine goaf CO2 sealing device can achieve coal mine goaf CO2 sealing, CO2 leakage is effectively prevented, and the environment and safety are guaranteed.

The invention discloses an ardealite resource comprehensive utilization method and application thereof, and belongs to the technical field of ardealite resource utilization. The method comprises the following steps: S1, mixing ardealite and a reducing agent to obtain a mixture; s2, performing high-temperature decomposition treatment on the mixture in an inert atmosphere to obtain decomposed gas and a decomposed product; s3, sulfuric acid and / or carbon disulfide are / is prepared with the decomposition gas as the raw material, and the decomposition product is used for metallurgical steelmaking; according to the method, ferrous sulfide is used as a reducing agent, under the inert atmosphere, phosphogypsum is reduced into calcium oxide and calcium ferrite, generated sulfur dioxide tail gas is recycled, and comprehensive utilization of calcium and sulfur resources of phosphogypsum solid waste is achieved; the recycled sulfur dioxide can be used for preparing sulfuric acid and / or carbon disulfide, meanwhile, calcium oxide and calcium ferrite can serve as an adhesive and a slag former to be used for efficient metallurgical steelmaking, and the comprehensive utilization method for ardealite resources has a good application prospect.

The invention relates to a preparation method of an in-situ hydrothermal biomass synergistic modified calcium-based absorbent. The preparation method of the calcium-based absorbent comprises the following steps: 1) calcining a calcium-based raw material to obtain a raw material containing calcium oxide; 2) adding the raw material containing calcium oxide, biomass and water into a hydrothermal reaction kettle, and mixing to obtain mixed slurry; (3) carrying out in-situ hydrothermal reaction on the mixed slurry to obtain slurry; and 4) filtering the slurry to obtain a filter cake, drying the filter cake, and calcining to obtain the calcium-based absorbent. According to the method, the calcium-based absorbent is modified through the in-situ hydrothermal reaction of the cheap biomass, and the prepared calcium-based absorbent is fluffy in tissue, large in specific surface area, rich in mesopores, not prone to sintering inactivation and capable of being used for circularly absorbing greenhouse gas CO2 in flue gas for multiple times.

The application discloses a kind of synchronous denitrification and phosphorus removal light materials and its preparation and application method, belong to environmental functional materials and sewage treatment technical field.The application is obtained by fully melting and dispersing sulfur and iron-based component, and the iron-based component is a mixture of pyrite and calcium-magnesium carbonate.The molten mixture is foamed to form a synchronous denitrification and phosphorus removal light material.The synchronous denitrification and phosphorus removal light material has high porosity, large specific surface area, light weight and high reactivity.The light material is used as a microbial carrier and an electron donor for biochemical reactions, and is applied to fixed bed, fluidized bed and other reactors for sewage treatment.The light material has good microbial adhesion performance, high denitrification rate and good phosphorus removal effect.

The invention discloses a self-repairing synchronous grouting material and a preparation method thereof, and belongs to the technical field of grouting materials. The self-repairing synchronous grouting material comprises a cement base material, a microbial capsule and chitosan calcium salt, the concrete comprises the following raw materials in parts by mass: 7-12 parts of Portland cement, 20-28 parts of fly ash, 40-55 parts of quartz sand, 20-30 parts of water, 2-7 parts of bentonite, 1-5 parts of microbial capsules and 1-5 parts of chitosan calcium salt. The self-repairing synchronous grouting material disclosed by the invention is combined with a microorganism self-repairing technology, and mineral substances such as calcium carbonate and the like can be generated through metabolic activity of microorganisms when the material has cracks, so that the cracks are automatically filled, and expansion of the cracks on the surface of a concrete material can be effectively prevented; the grouting material can continuously repair microcracks caused by environmental changes or construction stress in the long-term use process, and the integrity and stability of the structure are kept.

The invention discloses a method for recovering iron in tailings of copper separation from copper smelting slag through combination of microwave-assisted oxidizing roasting and magnetic separation, and belongs to the technical field of metallurgical solid waste resource utilization. The method comprises the steps that high-temperature copper smelting slag is subjected to water quenching, crushing and ore grinding, flotation and copper removal to obtain tailings containing silicon iron, after a calcium-based additive is added for ball milling and mixing, microwave oxidizing roasting is conducted under the oxygen-enriched condition, roasting products are subjected to high-gradient magnetic separation after crushing and ore grinding, and iron ore concentrate and magnetic separation tailings are obtained. According to the method, the strong wave-absorbing characteristic of fayalite is utilized, the roasting temperature and energy consumption are reduced through microwave heating, iron-silicon separation is achieved through a calcium-based additive, and iron is recycled through magnetic separation in one step. The final magnetic separation iron recovery rate reaches 85% or above, the iron ore concentrate grade exceeds 60%, magnetic separation tailings can be used as building materials, the process is simple, the cost is low, environment friendliness is achieved, the defects of a traditional process are overcome, and high-value utilization of solid waste is achieved.

The invention discloses an ardealite modified catalyst and application thereof, an ardealite-based low-carbon cementing material and a preparation method of the ardealite-based low-carbon cementing material. The modified catalyst comprises triethanolamine, a calcium-based compound, aluminum salt, glycerin, polyethylene glycol, zeolite powder and P.042.5 cement. The modified ardealite is prepared by mixing ardealite and the modified catalyst; the modified phosphogypsum is mixed with S95-grade mineral powder, I-grade or II-grade fly ash, an ultrafine admixture and limestone powder to prepare the phosphogypsum-based low-carbon cementing material. The preparation method has the beneficial effects that the modified catalyst adopts an organic-inorganic-mineral ternary composite catalytic system for the first time, impurity passivation, crystal reconstruction and in-situ reaction can be synchronously realized, a micro-nano crystal nucleus material is generated, and the modified phosphogypsum-based low-carbon cementing material can completely replace cement for use; according to the present invention, the strength of the cementing material can be adjusted, the carbon emission is reduced by more than 75% compared with the traditional cement, and the maximum consumption of the phosphogypsum in each ton of the cementing material product can be up to 300 kg.

The invention discloses a hardness removal method and system for a sulfate-based mine water concentrated solution, and the method comprises the following steps: sequentially introducing the sulfate-based mine water concentrated solution into a coagulating basin and a flocculation basin for chemical treatment, and allowing the treated mine water concentrated solution to enter a sedimentation basin for standing to obtain softened effluent; wherein lime or sodium hydroxide and a coagulant are put into the coagulating basin, and the coagulating basin is used for carrying out coagulating treatment on the mine water concentrated solution; sodium carbonate, a coagulant aid and an inducer seed crystal are put into the flocculation basin and used for carrying out flocculation treatment and precipitation reaction on the mine water concentrated solution subjected to coagulation treatment, the standing time of the flocculation basin is 14-45 minutes, the precipitation reaction time is 6-30 minutes, and the excessive amount of sodium carbonate is 1.5-2.5 mmol / L. According to the invention, the hardness of calcium in softened water can be lower than 20mg / L.

The invention relates to the technical field of carbon dioxide mineralization and absorption, in particular to a coal-based solid waste whole-process deep mineralization and storage CO2 system and method.The system comprises a pretreatment system, a PH detection system, an ultrasonic generation system and a mineralization reaction system, and the ultrasonic generation system and the PH detection system are both connected with the mineralization reaction system; the method comprises the following steps: S1, feeding a mixture of fly ash and desulfurized gypsum into a ball mill; according to the method, fly ash or a mixture of fly ash and desulfurized gypsum treated by a chemical leaching reaction liquid in physical modes such as ball milling, high-temperature calcination and hydration is sent to a vortex type mineralization reaction device, and surface inerting layers of fly ash and desulfurized gypsum are destroyed by utilizing an ultrasonic cavitation effect in the mineralization reaction process; leaching of alkali metal ions such as calcium and magnesium in the slurry is promoted, and the gas-solid mass transfer efficiency is improved; under the conditions that the CaO content of the fly ash is limited and no additive is added, the carbon dioxide sealing and absorbing capacity of the fly ash is improved to the maximum extent.

The invention belongs to the technical field of mineral flotation separation, and particularly relates to a complexing inhibitor and application thereof in mineral flotation separation of smithsonite and calcium-containing gangue. The complexing inhibitor provided by the invention is prepared by complexing a flavonoid organic compound and aluminum ions, is used for flotation separation of smithsonite and calcium-containing gangue minerals, can be selectively adsorbed on the surface of the calcium-containing gangue, effectively inhibits the floatability of the calcium-containing gangue, and has the advantages that compared with a traditional agent, the complexing inhibitor is simple in preparation method and low in cost; the method has the advantages of being high in separation efficiency, small in reagent dosage, environmentally friendly and the like, the grade and the recovery rate of smithsonite can be remarkably improved, and the method has important significance on efficient recycling of zinc oxide resources.

The invention relates to a calcium-based difunctional composite material and a preparation method and application thereof, the calcium-based difunctional composite material is applied to pollution control in a sludge-low-rank coal co-pyrolysis process, the calcium-based difunctional composite material is composed of Ca2Fe2O5 and an adsorptive material, and the mass ratio of Ca2Fe2O5 to the adsorptive material is 1: 1. According to the calcium-based bifunctional composite material, the fixation rate of sulfur in pyrolytic carbon is remarkably increased, conversion of heavy metal to a more stable form is facilitated, and the leaching capacity and potential ecological risks of the heavy metal are remarkably reduced.

According to the method, sodium carbonate, limestone and coke are used as sintering aids and are uniformly mixed with the high-iron Bayer process red mud, the mixed material is sintered by adopting a one-step low-calcium reduction sintering process, and the sintered clinker is subjected to water leaching and dissolution to obtain a sodium aluminate crude solution and filter residues. And returning the sodium aluminate crude liquid to an aluminum oxide industrial production line to prepare aluminum oxide, and carrying out a hydrolysis alkali recovery process on filter residues to obtain industrial sodium carbonate. The hydrolysis residues are subjected to magnetic separation and recovery to obtain fine iron powder, and the remaining tailings are completely harmless and can be used as raw materials of building materials or used for soil backfilling. The process is characterized in that the one-step low-calcium reduction sintering temperature is 200-300 DEG C lower than the sintering temperature of a sintering method, and the energy consumption is low; na2CaSiO4 is a sintering target product, Ca2SiO4 generally generated by a traditional sintering method is not generated, the situation that Ca2SiO4 is hydrolyzed in the water leaching process to inhibit dissolution of aluminum oxide is avoided, and the recycling rate of aluminum oxide is increased while the using amount of limestone is greatly reduced. The technological process is simple, efficient, energy-saving and free of three-waste emission, and the method is a novel method capable of treating the high-iron red mud in a large-scale and reduction mode.