9335results about "Solid waste disposal" patented technology

The invention relates to the technical field of battery recovery monitoring, in particular to a discharge crushing environmental data monitoring system for battery recovery. The system comprises a data acquisition module used for obtaining a sequence corresponding to each dimension based on environment data of different dimensions in the battery crushing equipment; the sample space construction module is used for screening the dimensions to obtain to-be-analyzed dimensions and constructing a sample space; the clustering analysis module is used for clustering the data points in the sample space to obtain clusters; judging whether the data points in each cluster are suspected abnormal data points or not; the abnormal degree acquisition module is used for clustering all the suspected abnormal data points in a time sequence to obtain a time sequence cluster and an abnormal degree; and the monitoring module is used for acquiring the comprehensive abnormal degree and judging whether the discharge breakage of the battery is abnormal or not based on the comprehensive abnormal degree. The condition of the old battery discharge crushing process can be accurately monitored.

The invention discloses a refined disassembly system and method for a battery monomer, and belongs to the technical field of battery disassembly. The production line comprises a perforating device, a cutting device, a cutting device, a scattering device, a sorting device, a color sorting device, a defluorination device and a powder removal device. The method comprises the following steps: perforating a battery to discharge electrolyte, separating a shell from an inner core by a cutting device, cutting the inner core by a cutting device, scattering by a scattering device, sorting a diaphragm by a sorting device, sorting positive and negative electrode materials by a color sorting device, and respectively removing fluorine by a defluorination device. And finally, the metal foil and the powder are separated through the powder removing device, the damage degree of the crystal structure of the black powder can be reduced, the black powder and the metal fragments are efficiently separated according to the density difference, the metal foil and the black powder are not likely to be excessively mixed, the separation purity is high, the secondary treatment situation is reduced, efficient separation and recycling of the electrode material are achieved, and the production cost is reduced. And the comprehensive function and the resource utilization rate of the system are obviously improved.

Chemical recycling facilities for processing mixed plastic waste are provided herein. Such facilities have the capability of processing mixed plastic waste streams and utilize a variety of recycling facilities, such as, for example, solvolysis facility, a pyrolysis facility, a cracker facility, a partial oxidation gasification facility, an energy generation / energy production facility, and a solidification facility. Streams from one or more of these individual facilities may be used as feed to one or more of the other facilities, thereby maximizing recovery of valuable chemical components and minimizing unusable waste streams.

The invention discloses a refined disassembly and recovery production line for retired lithium batteries. Comprising an automatic battery feeding station, a battery pretreatment station, a battery discharging station, an electrolyte collecting station, a battery shell disassembling station, a roll core film removing station, a pole piece separating station, a pole piece conveying station, a crushing feeding station, a crushing station, a crushing conveying station, a first-stage separating station, a high-temperature drying station, a drying discharging station and a second-stage separating station. The automatic battery feeding station is connected with the battery pretreatment station, and the battery pretreatment station is connected with the battery discharging station. The refined disassembly and recovery production line for the retired lithium battery is provided with deep discharge equipment, the safety problem of electrified crushing or manual disassembly is avoided, full-process automation is achieved, the recovery efficiency is high, refined disassembly and recovery are achieved, an aluminum shell, a positive plate, a negative plate and a diaphragm are separated, the recovery rate and purity of valuable metal are improved, the production line process is short, and the production line cost is low. And no secondary pollution is generated.

The invention provides equipment and a process for extracting lithium from lepidolite frame residues and synthesizing urea gypsum, and relates to the technical field of solid waste resource recycling, the equipment comprises a reaction tank, a sealing plate, a reciprocating motion mechanism and a multi-point detection mechanism; the reciprocating motion mechanism comprises a bidirectional threaded lead screw and a threaded block, the bidirectional threaded lead screw is transversely and rotatably connected to the inner wall of the reaction tank, the threaded block is in threaded connection with the bidirectional threaded lead screw, and the bottom of the threaded block is slidably connected with a guide seat. According to the scheme, when the top of a rotating wheel is in contact with a concave position of a convex plate, a rotating seat can drive a sliding rod and a PH detector to move upwards under the action of a spring, so that the bottom end of the PH detector is separated from filtrate, and a plurality of convex parts are arranged on the convex plate, so that the filtrate is subjected to multi-point real-time detection; lithium ion loss caused by co-precipitation of lithium, iron and aluminum due to over-high local pH value of the filtrate is avoided, and the concentration of the lithium solution is effectively improved.

The invention belongs to the technical field of enzyme engineering, and discloses an MHETase-EstD9 mutant and an application of the MHETase-EstD9 mutant. The invention provides an MHETase-EstD9 mutant, the amino acid sequence of the MHETase-EstD9 mutant is shown as SEQ ID No.2, and on the basis of the mutant, the amino acid of the MHETase-EstD9 mutant is further mutated to design five MHETase-EstD9 mutants. At 70 DEG C, compared with wild type MHETase-EstD9, the BHET degradation activity of the MHETase-EstD9 mutant provided by the invention is improved by 15% or more, and the highest BHET degradation activity can be improved by 24 times; meanwhile, the thermal stability of the MHETase-EstD9 mutant is also improved to a certain extent, and the Tm value is maximally improved by 18.0 DEG C. The method can be applied to the fields of degradation of PET, MHET or BHET, preparation of degradation agents of PET and degradation products thereof, TPA recovery and the like, and has important environmental benefits, economic benefits and social benefits.

The invention discloses a pyrolysis recovery system for cooperative treatment of waste wind power blades by a power station boiler, and belongs to the technical field of solid waste recovery. The system comprises a power station boiler, a pyrolyzing furnace, a mixed flue, a nitrogen air flue and a controller. Oxygen is accurately controlled by mixing flue gas at different temperature levels and mixing nitrogen, and a safe and stable heat source is provided for the pyrolyzing furnace; pyrolysis gas returns to a boiler hearth through an outlet flue to be burnt out, and recyclable fibers and residues are conveyed out through a chain grate stoker; and the controller is linked with each sensor to execute oxygen control, temperature regulation, fiber quality protection and safety interlocking operation. The problems that in pyrolysis of the waste wind power blade, heat source adaptability is poor, oxygen concentration is out of control, fiber quality is poor, the risk is high, and pyrolysis gas is difficult to dispose are solved, and gradient utilization of energy, intrinsically safe operation, high-quality and high-purity recovery of fibers and collaborative treatment of pollutants are achieved.

Chemical recycling facilities for processing mixed plastic waste are provided herein. Such facilities have the capability of processing mixed plastic waste streams and utilize a variety of recycling facilities, such as, for example, solvolysis facility, a pyrolysis facility, a cracker facility, a partial oxidation gasification facility, an energy generation / energy production facility, and a solidification facility. Streams from one or more of these individual facilities may be used as feed to one or more of the other facilities, thereby maximizing recovery of valuable chemical components and minimizing unusable waste streams.

The invention belongs to the field of photovoltaic module recovery, and particularly relates to a method for recovering glass and silicon powder from a waste photovoltaic module. The method comprises the following steps: (S1) crushing the waste photovoltaic module, and mixing the obtained powder with water to form slurry; (S2) adjusting the pH value of the slurry to be alkaline to obtain alkaline slurry; (S3) the alkaline slurry is mixed with a collecting agent, an inhibitor and a foaming agent, then flotation separation is conducted, and coarse silicon powder and a glass foam layer are obtained; (S4) cleaning the coarse silicon powder to obtain a silicon powder product; and (S5) sequentially carrying out defoaming, solid-liquid separation and washing on the glass foam layer to obtain a glass product. By optimizing the slurry pH, flotation reagent combination, washing and other process conditions, the separation effect of the silicon powder and the glass powder is improved, the problem that separation is not thorough due to similar surface properties in a traditional physical separation method is solved, the reagent residual quantity on the surface of the silicon powder is reduced, and the subsequent purification cost is reduced.

The invention discloses an emission reduction system for chloride ions in waste incineration fly ash based on machine learning, relates to the technical field of solid waste resourceful treatment, is used for data-driven fly ash multi-stage dosing collaborative removal, and is divided into fly ash pretreatment and data acquisition, online ion monitoring and dosing decision, multi-stage reaction and dynamic feedback, OTA upgrading and cross-plant migration. And removing the multi-dimensional pollutants synergistically. The dosing ratio and the reaction stage are optimized in real time through a gradient boosting tree-reinforcement learning model, and the concentrations of chloride ions, heavy metals and dioxin precursors are monitored on line. According to the system, monitoring and decision-making paths of all stages are stored in a cloud knowledge graph and can be upgraded through OTA, the chloride ion removal rate is increased by more than three percent, the agent dosage is reduced by 25%, the scheme can adapt to the difference of fly ash components in different factories, economy and environmental protection are both considered, and the system has remarkable popularization value in large-scale waste incineration and hazardous waste disposal.

The invention provides a cyclic utilization method of chelated landfill waste fly ash, and belongs to the technical field of household waste fly ash utilization. The cyclic utilization method of the chelated landfill fly ash comprises the following steps: S1, collecting the chelated landfill fly ash, crushing the chelated landfill fly ash to a certain particle size, and adding an acid solvent for dechlorination and decalcification treatment; washing the pretreated fly ash with water, and drying until the water content is 5-20%; s2, an additive is added into the dehydrated pretreated fly ash, the additive comprises a binder, a combustible matter and a combustion improver, and the mixture is pressed into balls after being evenly mixed; through the synergistic effect of acid pickling and high-temperature calcination, the degradation rate of dioxin in the fly ash reaches up to 99.89%, meanwhile, the leaching concentration of heavy metal is reduced to be lower than the standard limit value of hazardous waste, the problems of land occupation and secondary pollution of a traditional landfill method are solved, and long-term harm of hazardous waste to the environment is reduced through recycling of the fly ash; and the solid waste treatment principle of reduction, harmlessness and recycling is met.

The invention relates to an anorthite material and a preparation method thereof. The adopted technical proposal comprises the following steps of: according to (ZL200510019664.3) patent technology, namely a method for preparing titanium and a titanium alloy by utilizing titanium-containing furnace slag, taking molten tailings which is extracted with the titanium alloy as a raw material, adding 20 to 50 weight percent of silica, 0 to 60 weight percent of clay and 0 to 40 percent aedelforsite, and cooling a melt to obtain the anorthite material after the mixture is completely molten and a bath composition is uniform; or taking cold tailings extracted with the titanium alloy as the raw material, adding 20 to 50 weight percent of the silica, 0 to 60 weight percent of the clay and 0 to 40 percent the aedelforsite, carrying out mix grinding on the raw material and the admixture until the particle size is less than 0.1 mm, performing blank compression, and calcining the mixture at a temperature of between 1,200 and 1,400 DEG C to obtain the anorthite material. The method takes the tailings extracted with the titanium as the raw material, saves precious bauxite resources, has low cost, ensures that industrial residue is utilized with high added value, is environment-friendly and has simple process.

The invention discloses a method for producing iron powder by solid reduction treatment of copper smelting slag in a rotary kiln. Copper slag powder is obtained by crushing the copper smelting slag; carrying out solid-state reduction on the pellets containing the copper slag powder in a rotary kiln; carrying out magnetic separation on the reduced material to obtain iron powder and tailings; the pellets are fed into the rotary kiln from the tail of the rotary kiln, air is blown into the rotary kiln from a kiln head, and the reduced materials are discharged from the kiln head; the raw materials of the pellets comprise copper slag powder, limestone powder and pulverized coal. According to the method, the copper smelting slag is subjected to solid-state reduction treatment through the rotary kiln to comprehensively recover and produce the iron powder, and treatment and resource recycling of the copper smelting slag are achieved; the reduction, harmlessness and recycling of the industrial waste residues are realized, the investment is saved, the energy is saved, the consumption is reduced, the operation cost is low, and the popularization is easy.

The invention relates to the technical field of soil remediation, in particular to a soil remediation formula optimization method based on solid waste raw material charcoal improvement, which comprises the following steps: acquiring a coal gangue powder material flow and a sludge material flow, respectively performing component detection on a soil sample set, the coal gangue powder material flow and the sludge material flow to obtain a component content report, performing multi-factor combination on the plurality of biochar, the plurality of microbiota and the plurality of enrichment plants to obtain a plurality of first initial raw material combinations; and constructing a plurality of unit soil remediation experiment groups based on the component content report, the plurality of first initial raw material combinations, the soil sample set, the coal gangue powder material flow and the sludge material flow, and performing a soil remediation experiment on the plurality of unit soil remediation experiment groups based on a preset test pause condition to obtain an optimal scheme. According to the invention, the formula optimization of targeted soil remediation can be realized by utilizing the charcoal, the coal gangue and the municipal sludge.

The invention relates to the technical field of sludge reduction and resource utilization, in particular to a method for resource utilization of sludge gasification slag. According to the method, municipal sludge gasification slag is smashed and then subjected to acid leaching, acid leaching liquid and acid leaching slag are obtained, iron in the acid leaching liquid is recycled, meanwhile, the acid leaching slag is subjected to alkaline leaching, under the strong alkaline condition, a calcium source is added into alkaline leaching liquid, then calcium phosphate sediment can be obtained, and iron in alkaline leaching separation liquid is recycled; a calcium ion solution can be generated in the processes of recovering iron in the pickle liquor and refining calcium phosphate, and the obtained calcium ion solution can be used as a calcium source for comprehensive utilization. The method disclosed by the invention can be used for realizing extraction and resource utilization of phosphorus, iron, aluminum and calcium in the sludge gasification slag, and has important significance on environmental protection and resource saving.

The invention provides a method for recycling a waste lithium iron phosphate battery positive electrode material based on organic solvent soaking. The method comprises the following steps: mixing waste lithium iron phosphate positive electrode material powder and a crown ether chelating type co-dissolving agent to obtain a leaching solution; hydrogen peroxide is added into the leachate, the pH is adjusted, a diammonium hydrogen phosphate solution is added, and iron phosphate and filtrate containing lithium ions are obtained; adding sodium carbonate into the filtrate containing lithium ions, and adjusting the pH value to obtain lithium carbonate; mixing the iron phosphate with a phosphoric acid solution to obtain purified iron phosphate; and mixing the purified iron phosphate, lithium carbonate and acetylene black to obtain the regenerated lithium iron phosphate positive electrode material. According to the method for recycling the positive electrode material of the waste lithium iron phosphate battery based on soaking of the organic solvent, the leaching rate of the lithium element is effectively increased, the selectivity to other metal ions is low, and the regenerated positive electrode material of the lithium iron phosphate battery has relatively high discharge capacity and good cycling stability.

Provided are equipment and methods for intelligent mobile medical waste disposal and flue gas purification, and the equipment includes a vehicle-mounted mobile platform and a skid-mounted standard container; where, the vehicle-mounted mobile platform is composed of a standard semi-trailer truck and a truck carriage base; the vehicle-mounted mobile platform is used for realizing functions of mobile transportation, cargo loading, fuel loading and unloading, power charging and discharging and network information transmission; the skid-mounted standard container is loaded above the truck carriage base of the vehicle-mounted mobile platform; and the skid-mounted standard container consists of a standard container and contents in the standard container; and the contents include: an intelligent collection and transportation feeding system, a medical waste pyrolysis incineration system, an incineration flue gas purification system, and an intelligent management and control system for medical waste disposal.

The invention discloses an echelon utilization method for waste power batteries of new energy vehicles, which comprises the following steps: firstly, collecting and preliminarily classifying and screening retired batteries according to health states, and quickly eliminating potential safety hazards by using infrared thermal imaging and voltage consistency detection; comprehensive performance detection including complementary energy detection, discharge capacity test at different temperatures, direct current internal resistance measurement and charge and discharge temperature rise test is carried out; key parameters are extracted from the detection data, comprehensive performance analysis is carried out in combination with application scene requirements, and a comprehensive evaluation score is generated; selecting similar batteries to form a pre-combination unit according to the score sequence; a grouping result is optimized through a clustering algorithm in the three-dimensional performance coordinate system, and it is ensured that the deviation of core parameters of the same group of batteries is smaller than a set threshold value; the stability and the operation efficiency of the echelon utilization system are improved, the adaptive capacity of the echelon utilization system in different application scenes is enhanced, and a guarantee is provided for stable operation of the echelon utilization battery system.

The invention relates to a waste photovoltaic panel recycling method which comprises the following steps: crushing a waste photovoltaic panel until the size of the waste photovoltaic panel is 80-160 meshes, and preparing powder; carrying out acid leaching treatment on the powder, and respectively collecting a leaching solution and a solid material; an acid leaching solution adopted in the acid leaching treatment is a mixed acid aqueous solution of hydrochloric acid and sulfuric acid; the pH of the leachate is adjusted to be neutral with an alkaline agent, then the leachate is mixed with metal iron to be subjected to a replacement reaction, and metal copper is prepared; the solid material is mixed with water, hydrofluoric acid and a flotation agent are added into the obtained mixture for flotation treatment, floats and precipitates are collected respectively, the floats comprise silicon powder, the precipitates comprise glass powder, and the flotation agent comprises one or two of hexadecyl potassium hydrogen phosphate and sodium dodecyl sulfate. According to the recycling method, the silicon powder, the glass powder and the metal copper can be comprehensively recycled from the waste photovoltaic panel.

The invention relates to the technical field of household garbage treatment, in particular to a rural household garbage classification and resourceful treatment circulation system, which comprises straw, harmful garbage, recyclable garbage, kitchen garbage, large household garbage and sludge; the rural household garbage treatment system comprises a household garbage classification system, a household garbage pyrolysis treatment system, a household garbage recycling treatment system, a harmful garbage recycling treatment system, a kitchen garbage recycling treatment system, a large household garbage classification recycling treatment system and a sludge recycling treatment system. By means of a centralized treatment mode of the rural domestic garbage, the problem that landfill of the rural domestic garbage is difficult is solved, corresponding economic value is brought to the rural area, the idea of waste utilization, circular economy, energy conservation and emission reduction is achieved, the rural environment is better, and the economic benefit of the rural area is improved. And a solid foundation is laid for creating a high-quality living environment in rural areas.

Disclosed in the present application is a disassembly device, comprising a carrying base, and a loading apparatus, a junction box and frame removal apparatus, a glass sheet removal apparatus and a backsheet removal apparatus, which are arranged on the carrying base, wherein the loading apparatus is used for gripping a photovoltaic panel at a loading station; the junction box and frame removal apparatus is arranged downstream of the loading apparatus, and is used for removing a junction box and a frame of the photovoltaic panel conveyed by the loading apparatus; and the glass sheet removal apparatus and the backsheet removal apparatus are both arranged downstream of the junction box and frame removal apparatus, the glass sheet removal apparatus is used for removing a glass sheet of the photovoltaic panel, and the backsheet removal apparatus is used for removing a backsheet of the photovoltaic panel.

The invention discloses a recovery device and a recovery method for a photovoltaic multi-layer stacked assembly. The recovery device comprises a dismounting unit, a pyrolysis unit and a waste gas treatment unit which are arranged in sequence, the pyrolysis unit comprises a tunnel kiln, a bearing assembly and a conveying assembly. The recycling method comprises the steps that S1, the disassembling unit is used for disassembling, and the frame is stripped; s2, the photovoltaic multi-layer laminated assembly is sent to a pyrolysis unit for pyrolysis, and a glue film layer in the photovoltaic multi-layer laminated assembly is removed; and S3, the waste gas is discharged after being treated. By means of the innovative disassembling system, the multi-plate stacking tunnel kiln pyrolysis scheme and the multi-stage waste gas treatment system, the industrial production capacity of treating 1-3 tons of photovoltaic panels per hour can be achieved, the pyrolysis effect is good, the silicon material recovery rate can reach 98.5% or above, energy consumption is low, and the tail gas emission index is superior to the national standard by 50% or above.

The invention discloses a building concrete waste treatment system, which belongs to the technical field of building waste treatment, and is characterized in that a data acquisition module acquires waste physical attributes and inputs the waste physical attributes into a model generation and optimization module; the model generation and optimization module establishes a waste physical characteristic model, dynamically updates the waste physical characteristic model and outputs a dynamic waste physical characteristic model to the strategy generation module; the strategy generation module outputs equipment operation parameters; the strategy mapping module maps the equipment operation parameters into physical execution signals through an equipment instruction mapping model to obtain execution results, and the execution results are input into the strategy feedback optimization module; and the strategy feedback optimization module identifies the execution deviation in the execution result and feeds the execution deviation back to the strategy generation module to optimize the equipment operation parameters. According to the scheme, an intelligent algorithm and physical modeling are combined, the waste treatment process is optimized through real-time data collection and feedback, equipment parameters are adjusted based on different characteristics of the waste, and the problems of excessive treatment and resource waste are avoided.

The invention provides a waste photovoltaic module high-value recovery process based on pyrolysis and wet purification, which comprises the following steps: carrying out pyrolysis decarburization on a waste photovoltaic module to obtain a glass plate, a crystalline silicon battery piece and a copper-tin soldering strip; the method comprises the following steps of: performing alkaline leaching on a crystal silicon cell to obtain a dealuminized crystal silicon wafer, performing acid pickling on the dealuminized crystal silicon wafer to obtain a silver-removed crystal silicon wafer and a silver leaching solution, and extracting a silver elementary substance from the silver leaching solution; removing impurities from the silver-removed crystal silicon wafer through a hydrofluoric acid solution to obtain a high-purity crystal silicon wafer; recovering a copper strip from the copper-tin soldering strip through a high-temperature smelting reduction method; after fluorine-containing pyrolysis gas generated in the pyrolysis process is subjected to combustion and heat exchange, hydrogen fluoride is removed in a two-stage alkali liquor absorption mode, then washing is conducted, and finally obtained flue gas is discharged. According to the wet purification process, the waste crystalline silicon battery piece can be subjected to high-purity recovery, and the crystalline silicon piece, silver and copper with high purity can be obtained. The hydrogen fluoride is removed by adopting a two-stage alkali liquor absorption method, so that the treatment efficiency of the hydrogen fluoride in the pyrolysis gas is improved.

The invention relates to the field of hazardous waste treatment, in particular to a treatment method for mineralization and chlorine fixation of waste incineration fly ash and a waste incineration fly ash solidified body. The treatment method comprises the following steps that S1, the incineration fly ash is subjected to homogenization treatment, and homogenized fly ash is obtained; s2, the homogenized fly ash is detoxified through plasma treatment, dioxin on the surface of the homogenized fly ash is removed, and detoxified fly ash is obtained; and S3, stirring the detoxified fly ash, a mineralizing agent and water, carrying out shock excitation, carrying out pouring molding, standing, and demolding to obtain the waste incineration fly ash solidified body. According to the method, the incineration fly ash is dispersed through homogenization treatment, dioxin on the surface of the homogenized fly ash is removed through plasma treatment, finally, fly ash particles are tightly wrapped and cemented through cooperation of a mineralizing agent and water, a compact network structure is formed, the leaching toxicity of heavy metal is reduced, soluble chloride ions are chemically fixed in crystal lattices of minerals, and the leaching efficiency is improved. The incineration fly ash mineralization and synergistic chlorine fixation effects are realized.

Embodiments disclosed herein provide an organic matter processing apparatus and method for the use thereof to convert organic matter into a ground and substantially dried product. The apparatus uses a bucket assembly that can grind, paddle, and heat organic matter contained therein. The bucket assembly can employ logic to pre-empt inadvertent opening of the lid due to OMPA input pressing up on the lid during OMPA processing.

The invention discloses a treatment device and method for lead electrolysis anode copper removal scum, and relates to the technical field of lead electrolysis anode copper removal scum treatment.The treatment device comprises a cylindrical shell, the outer wall of the cylindrical shell is fixedly sleeved with a pair of annular grooves, a plurality of evenly-distributed exhaust holes are formed in the annular grooves, and material blocking nets are installed in the exhaust holes; the pair of annular grooves are communicated through a gas collecting pipeline; by arranging the shell, a closed space is provided for scum treatment, harmful gas leakage is avoided, the effect that scum and decomposition liquid are fully mixed and reacted is promoted through cooperation of internal structural components of the shell, uniform dispersion and guiding of the scum are achieved by arranging the scum distributing mechanism, the distributing uniformity and continuity are guaranteed, and the service life of the scum is prolonged. And by arranging the scum treatment mechanism, the effects of efficiently decomposing, filtering and separating scum, promoting sufficient mixing of the scum and decomposition liquid, improving the decomposition efficiency, preventing material screening holes from being blocked and ensuring continuous proceeding of the filtering process are achieved.

The invention relates to the technical field of battery pole piece recovery, in particular to a waste lithium iron phosphate battery positive pole piece physical dry recovery method which comprises the following steps: fragmenting waste lithium iron phosphate battery positive pole pieces, carrying out electromagnetic separation, and sequentially carrying out low-temperature embrittlement treatment and two-stage mechanical dissociation, a dissociation material obtained by separating the black powder, the current collector and the high-molecular binder is obtained; then, two-stage screening is adopted, fine black powder smaller than 50 micrometers is obtained through screening, the binder in the fine black powder is fused through pulse hot air and enters a hollow porous ceramic roller along with airflow, the fused binder is adsorbed to the outside of the roller through micropores of the porous ceramic roller according to the surface energy difference, and therefore the binder is removed and recycled; and finally, airflow separation is carried out, and a black powder product and current collector chippings are obtained through separation. According to the method, chemical pollution and high-temperature damage can be avoided, accurate separation of the black powder, the aluminum foil and the binder is efficiently achieved, and the purity of the black powder product is 99% or above.

The invention discloses a high-valued graded utilization method of marine shells, and belongs to the technical field of comprehensive utilization of biological resources and preparation of functional materials. The method comprises the following steps: cleaning, air-drying and superfine grinding marine shell wastes such as abalone shells, and extracting water-soluble organic components in the marine shell wastes by adopting mild water extraction, so that the obtained extract is rich in protein, polysaccharide or small molecule peptide, has good biological activity, and can be used for preparing functional materials such as biomimetic mineralization, tissue repair and the like; extracted shell powder residues are subjected to heat treatment or chemical activation treatment and then compounded with natural polymer materials such as chitosan and sodium alginate, and the composite adsorbent which is loose in structure and large in specific surface area is prepared and can be used for removing dye, heavy metal, antibiotics and other water pollutants. According to the invention, separate utilization of organic components and inorganic framework materials in the marine shells is realized, and the method has the characteristics of environmental protection, efficient resource conversion and multifunctional application, and has a good industrial popularization prospect.

The invention discloses a silicon / graphite / carbon-aluminum oxide composite negative electrode material and a green preparation method thereof, and belongs to the technical field of lithium ion batteries. Aiming at the problems of high volume expansion rate and poor cycling stability of a silicon-based negative electrode and high cost of a traditional process, the invention innovatively provides the following scheme: 1) waste photovoltaic silicon wafer ball-milling liquid and waste graphite are taken as core raw materials, and resource recycling is realized; (2) phenolic resin and chitosan are adopted as double carbon sources, a nitrogen-doped carbon layer (the nitrogen content is 3-5 wt.%) is formed through pH-induced self-assembly, and the conductivity and the Li < + > diffusion rate are synchronously improved; and 3) aluminum nitrate is introduced for pyrolysis to generate 2-5nm aluminum oxide for doping, so that the side reaction of the electrolyte is inhibited, and the volume expansion of silicon is relieved (the expansion rate is less than or equal to 120%). The preparation process comprises the steps of silicon / graphite dispersion, double-carbon-source compounding, ammonia water regulation and control precipitation and gradient calcination. Experiments show that the specific capacity of the optimized material under the current of 0.5 A / g reaches more than 800mAh / g, the 100-time cycle capacity retention ratio is more than 98%, the 1000-time cycle capacity retention ratio is more than 80%, the reversible specific capacity under the multiplying power of 3A / g is more than 550mAh / g, and the raw material cost is reduced by 40%. The invention has the advantages of high capacity, long service life, environmental protection and economy, and provides an innovative solution for the fields of power batteries and energy storage.