2007 results about "Pollution soil" patented technology

The invention discloses ion mineralization stabilizer for treating soil with heavy metal pollution and an application method thereof. The ion mineralization stabilizer comprises, by weight percent, 5-30% of sulfur-based compound, 10-50% of phosphor-based compound, 10-50% of calcium-based compound, and 10-30% of silicon-based compound. The materials are respectively ground into powders with particle size not less than 200 meshes, and the powders are proportionally mixed well. The application method of the ion mineralization stabilizer for treating soil with heavy metal pollution includes: detecting arsenic content and leaching toxicity of the soil to be treated, placing the ion mineralization stabilizers in different proportions on the surface of the soil to be treated according to pollution level, well mixing to form mixed soil by ploughing and stirring, adding water to keep the water content of the mixed soil no less than 25%, covering the mixed soil with moisturizing material, curing for at least 5 days to keep heavy metals in the mixed soil to form stable minerals.

The invention relates to a soil pollution thermal desorption restoration processing system, which belongs to a soil restoration processing system. The system comprises a feed system, a heat source system and a control system, and is characterized by further comprising a thermal desorption system and a tail gas processing device, wherein the thermal desorption system consists of a draught fan and a thermal extraction converter, and the tail gas processing device consists of a dust remover and an absorption tower. When the system is applied to processing polluted soil with main pollutants of volatile / semi-volatile organic compounds, compared with the like products in other countries, the equipment cost is only 1 / 3 to 1 / 5 of the same; the problem of secondary pollution probably brought about in the process of processing the polluted soil is thoroughly avoided; a temperature control system has better practicability; the running cost for each ton of the polluted soil is between 300 and 500 RMB, which is far low than the processing cost for hazardous landfilling and incineration of the polluted soil; and half of the purification effect of processing the polluted soil with the main pollutants of the volatile / semi-volatile organic compounds can reach between 70 and 80 percent.

The outside treating process of polluted soil includes the following steps: excavating the polluted soil, filling the soil inside the treating apparatus, pumping with vacuum pump to form certain vacuum degree in the pumping well while intruding fresh air into soil to promote the volatilization of pollutant and taking out the volatile. The soil may be also heated to speed the volatilization. The treating apparatus consists of exhaust well with exhaust pipeline, temperature controlling sensor and heater embedded into soil pipe. The treated soil may be re-filled or used in other site.

The invention relates to a roller-type reverse thermal desorption system for soil polluted by organic matters. The roller-type reverse thermal desorption system comprises a soil feeding system, wherein the soil feeding system and a heat source system are connected with a reverse thermal desorption system; the reverse thermal desorption system is connected with a dust removing system, a cooling system and an active carbon adsorption system in turn; and control ends of the soil feeding system, the heat source system, the reverse thermal desorption system, the dust removing system, the cooling system and the active carbon adsorption system are connected with a control system. In the roller-type reverse thermal desorption system, hot air is fed into a reverse thermal desorption roller by an ignition system, and polluted soil is fed into the reverse thermal desorption roller by a soil transferring device, wherein the hot air contacts the soil reversely, so that organic pollutants contained in the soil are heated and volatilized; the purified soil is used as backfill soil; and the volatilized tail gas is dedusted by a cyclone dust extractor and an adsorption dust extractor after passing through an induced draft fan, and the dedusted volatilized tail gas is absorbed by a honeycomb-shaped active carbon tower after passing through an atomization cooling tower and a dial plate cooling device, and finally is discharged by a tail gas exhaust device on the basis of meeting the national standard. Materials can be fed into the roller-type reverse thermal desorption system continuously and can be heated directly; and the hot air and the polluted soil are fully mixed, and the roller-type reverse thermal desorption system has high thermal desorption efficiency.

The invention discloses a chemical leaching restoring method for soil polluted by heavy metals. Na2EDTA solution is utilized to perform leaching to the soil polluted by the heavy metals, available cadmium and lead in the soil are effectively removed, Na2S.9H2O is utilized to precipitate the heavy metals in filtrate, Na2EDTA is released again, and repeated recycling of the Na2EDTA solution is achieved. After recycling, the Na2EDTA solution carries out leaching to the soil polluted by the heavy metals, the removing rate of available Cd in the polluted soil reaches 81.6-81.8%, and the removing rate of available Pb reaches 55.9-60.1%. The chemical leaching restoring method for the soil polluted by the heavy metals overcomes the shortcomings that an existing method for the Na2EDTA solution to perform leaching to the soil polluted by the heavy metals causes chemical cost to be large, generated filtrate is much, and the follow-up treatment is troublesome. Simultaneously, the chemical leaching restoring method for the soil polluted by the heavy metals has the advantages of being simple in process, becoming effective quickly, enabling a leaching agent to be reused, and enabling the heavy metals to be effectively eliminated.

The invention discloses slow-release fertilizer with the effect of soil remediation, which is prepared by polyhydroxyalkanoates which can be completely biodegraded, organic and inorganic nutrients and other substances, by slow-releasing the organic and inorganic nutrients, microorganism propagation and sustained and rapid growth of plants can be promoted, the bioactivity and water solubility of polycyclic aromatic hydrocarbons are quickened, and simultaneously, the defects of fertilizer loss and repeated fertilization can be avoided, thereby saving the cost and enhancing the soil remediation efficiency. The invention also discloses a soil pollution remediation method by utilizing the slow-release fertilizer, plants with the remediation effect are planted in the soil with the slow-release fertilizer, and efficient, environment-friendly and sustained remediation of the soil polluted by the polycyclic aromatic hydrocarbons (PAHs) can be realized by utilizing the microorganism-plant remediation technology.

The invention relates to a method for remediation of heavy metals contaminated soil by a plant-microorganism joint direction method. The detailed steps of the method of the invention are that: firstly, resistant bacteria of plant and microorganism is sifted, so as to obtain plant and microorganism bacteria strains with heavy metal resistance; and then the seeds of the resistant plant is soaked and coated in microorganism resistant bacteria solution; finally, the seeds are planted in the soil contaminated by heavy metal, therefore the soil can be remedied. The method has the advantages of good remediation effect, low cost, easy management and operation, no secondary pollution and broad application prospect, therefore, the method is the most important development direction of soil remediation technique.

The invention discloses a bioremediation method for soil polluted by heavy metals. The bioremediation method comprises the following steps of: adding earthworm feeds into the soil polluted by the heavy metals, turning the soil, uniformly mixing, and putting earthworms into the soil and cultivating the earthworms; after the earthworms are cultivated for 28 to 35 days, collecting earthworm excrements in the upper layer soil, collecting adult earthworms by adopting a natural lighting method, and retaining young earthworms and earthworm eggs in the soil; planting plants by adopting a hedge planting method, cradling the parts of the plants growing for 78 to 90 days, which are positioned above the ground, and removing the whole plants after the plants grow for another 50 to 70 days; collecting the adult earthworms and the earthworm excrements for 1 to 3 days by adopting an outdoor collection method every 28 to 35 days during planting of the plants; and after the whole plants are removed, collecting all the adult earthworms and the young earthworms by adopting the natural lighting method, and collecting the earthworm excrements and the earthworm eggs. The soil is subjected to remediationby combining animals, plants and microorganisms according to a proper remediation sequence and a remediation period, so that the bioremediation method is economic, environment-friendly, easy to operate, high in remediation efficiency and easy to popularize, and is particularly suitable for mild or moderate copper, cadmium and lead combined polluted soils.

The invention discloses a composite heavy metal polluted soil conditioner as well as application and an application method thereof. The soil conditioner comprises the following components: plant ash, calcium magnesium phosphate, quicklime, zeolite and organic fertilizers at a weight ratio of (0.3-1.1):(0.1-1.2):(0.4-2.1):(0.1-0.6):(0.008-0.06):(0.4-1.2). Through inorganic components such as quicklime, calcium magnesium phosphate and phosphate in hydroxyapatite as well as potassium carbonate in the plant ash, the soil conditioner can be used for fixing heavy metals in polluted soil and improving the fertility of the polluted soil in combination with organic manures such as the plant ash and the organic fertilizers so as to continuously intensify the restoration of the polluted soil, has the advantages of relatively-high stability, good environmental friendliness and low cost, can be used for inactivating and restoring various heavy metal polluted soil, especially has a good restoration effect on soil pollution caused by waste slag discharged by industrial and mining enterprises, can be used for realizing the treatment goal without generating secondary pollution, and is liable to realize large-area popularization.

The invention relates to an energy-saving type thermal-desorption repairing treatment system for organic polluted soil and aims at providing a system for thermal-desorption repairing treatment of the organic polluted soil, which can recycle waste heat of the system fully and save resources. The energy-saving type thermal-desorption repairing treatment system comprises a feeding system, a soil preheating and heat recycling system, a rotary kiln heating system, a soil cooling and heat recycling system, a soil discharging system, a tail-gas dust removing and temperature reducing system, a sewage treatment and cooling system, an active-carbon absorbing system, an active-carbon regeneration device, a gas exhausting system and a network monitoring system.

The invention relates to a method for combined restoration of organic-contaminated soil, comprising the following steps: (1) adding an aqueous solution of a surfactant to the organic-contaminated soil for solubilization treatment; (2) adding persulfate and an activator, Reaction, after the reaction is completed, separate and dry to obtain the repaired organic matter-contaminated soil. Compared with the prior art, the invention has the advantages of high removal rate of adsorbed organic pollutants, low cost, simple and easy method, and environmental friendliness.

The invention provides an electric complex-strengthening repairing method and device of heavy metal-organic co-contaminated soil. The method provided by the invention comprises the following steps of: filling contaminated soil into an electric repairing device, and then adding an oxidant into a cathode electrolyte and an anode electrolyte or directly spraying the oxidant on the contaminated soil, wherein the oxidant comprises hydrogen peroxide, pypocholoride and persulfate; applying a direct-current electric field on a cathode and an anode, wherein the strength of the electric field is 0.5-2 V / cm; and controlling the pH values of the cathode electrolyte and the anode electrolyte to be 3-11. By selecting the suitable for oxidant and controlling the pH value of the electrolyte, the migration of the heavy metal can be effectively increased and the removing efficiency is improved; and meanwhile, the oxidant is used for effectively degrading organic pollutants when the pollutants are migrated, thereby relieving the post-treatment and simultaneously removing the heavy metal and the organic pollutants.

The invention relates to an in-situ remediation method of heavy metal-organic combined pollution soil. According to the method, a set of electrokinetic remediation device is added with a power switching system, an electrode heating technology is combined with the electrokinetic remediation and chemical oxidization technology, namely, the direct current power is utilized firstly, sodium persulfate used as the oxidizing agent is migrated to soil through electric process, meanwhile, migration and removal of heavy metal ion in the soil are realized. Then the alternating current power is switched, and soil is heated to a certain temperature through the electrode heating method so as to activate the sodium persulfate migrated to soil, and thereby realizing the in-situ degradation of organic pollutant in the soil. The method applies electrode to the electrode heating system and the electrokinetic remediation device at the same time, simplifies the remediation device and saves the system energy consumption while solves the difficulty that oxidant cannot migrate and activate in the soil and improves the remediation efficiency; the method is a combined soil remediation technology with prospect of application and promotion.

The invention provides a safe and reliable compound conditioner for reducing the heavy-metal mobility and bioavailability of soil or sludge compost and a preparation method thereof. The compound conditioner is a powdery compound prepared by adding heavy-metal auxiliary passivating agent to alkaline agent, wherein, the heavy-metal auxiliary passivating agent includes precipitating agent and absorbing agent; and the compound conditioner comprises the following components by the mixing proportion (weight percentage): 78% to 91% of alkaline agent, 5% to 13% of precipitating agent and 4% to 9% of absorbing agent. The preparation method comprises the following steps: (1) drying and pulverizing one, two or more than two substances among soda-manufacturing waste residue, lime and fly ash and sieving by a 60-mesh sieve to obtain an alkaline powdery substance as the alkaline agent; (2) mixing the alkaline agent, the precipitating agent and the absorbing agent by the above mixing proportion; and (3) drying and pulverizing the mixed products and sieving by a 200-mesh sieve to obtain the powdery compound conditioner. The invention can greatly reduce the environmental risk caused by the prior art and realize the sustainable development of green circular economy, industry and agriculture by recycling the industrial waste at the same time.

The invention provides an in-situ restoration device and an in-situ restoration method of organic polluted soil and underground water. The in-situ restoration device designed by the invention comprises a pneumatic source system, an agent dissolving and preparing system, an in-situ injection system and an injection well system. The in-situ restoration device is characterized in that the organic polluted soil and the underground water in a saturation layer and a non-saturation layer can be restored, injection wells are distributed at polluted areas according to the conditions of pollution distribution and hydrogeololgy and the like, and oxidizing agents prepared by the dissolving and preparing system are injected into the polluted areas by certain pressure through the injection system to restore target pollutants. The in-situ restoration device provided by the invention has the advantages that the injection wells are subjected to three-layer sealing by three sealing materials, the integration is good, the disassembly is fast and the economic and fast effects are achieved.

The invention relates to a multi-stage thermal desorption remediation system for organic polluted soil, and belongs to the technical field of soil remediation. The system consists of a first-stage thermal desorption device, a second-stage thermal desorption device, a tail gas treatment device, a secondary combustion chamber and a falling type conveying belt. Soil is preheated and desorbed primarily by high-temperature tail gas generated by thermal desorption; a two-stage or multi-stage polluted soil treatment method is adopted, and the residual heat of the tail gas is utilized fully, so that the comprehensive utilization ratio of heat energy of the system is improved obviously; soil enters a thermal desorption cabin with relatively high temperature under the gravity effect by virtue of the S-shaped falling type conveying belt, so that the energy consumption of a conveying and transmitting device and the conveying process is prevented; meanwhile, the soil conveying path and the conveying time are prolonged, the retention time is prolonged, and thus soil pollutants are desorbed relatively fully. The thermal desorption soil remediation system is reasonable in structure, is simple to operate, is convenient to use, has no secondary pollution, recycles residual heat of tail gas, and has wide application prospect and high practical value.

The invention relates to an in-situ thermal desorption repair system and a method for polluted soil. The system comprises a plurality of in-situ heating electrodes, a plurality of injection wells, a plurality of extraction wells, a plurality of groundwater monitoring wells, electrode power control and adjustment facilities, in-situ temperature and pressure monitoring facilities, sewage treatment facilities and waste gas treatment facilities; each extraction well is provided with an extraction device which is connected with a sewage treatment facility and a waste gas treatment facility; each injection well is internally provided with an injection device which is connected with a material storage box containing a leaching reagent; and the in-situ heating electrodes are arranged in a regulartriangular or regular hexagonal manner. Compared with the prior art, after the leaching reagent is added to dissolve pollutants, the solubility of the pollutants is increased, the speed of the pollutants entering a liquid phase from a soil adsorption phase is increased, and the removal rate and removal efficiency of the pollutants are improved.

The invention relates to soil heavy metal pollution treatment technology, in particular to a chemical leaching restoration method used for heavy metal and arsenic mercury polluted soil. Prior soil chemical leaching restoration methods concentrate on the polluted soil caused by one or a plurality of heavy metals (cadmium, copper, lead and zinc, etc.,), which do not have ideal restoration effect to soil with the pollution of both arsenic in the form of negative ions and mercury which is volatile metal. Aiming at the problem, the method uses the combination of three reagents, namely, Na2EDTA, oxalic acid and KI and leaching method with fractional steps for realizing the chemical restoration of the cadmium, the copper, the lead, the zinc, the arsenic and the mercury, etc., in the polluted soil so that the heavy metal in the polluted soil can reach the environmental safety standards. The soil after the leaching treatment is washed by water, and then is refilled in the original position; therefore, no secondary pollution can be caused.

The invention relates to an in-situ rain leaching repair system for contaminated soil. The in-situ rain leaching repair system at least comprises three parts, namely a rain collection part, a leaching repair part and a waste water treatment part, wherein the rain collection part is provided with water guiding pipes, a water collecting tank and canals, the leaching repair part is provided with an observation well, water collecting pipes and plants planted for the soil phytoremediation, the observation well is built in a middle-upper layer of contaminated soil, and the water collecting pipes are in the middle-lower layer; and the waste water treatment part is provided with a filter tank, a microorganism putting tank, an electric separation tank, a wind power generating set and the like, leaching waste water is firstly filtered by the filter tank, and is then repaired by the microorganism putting tank, and finally, the leaching waste water passes through the electric separation tank to process heavy metal so as to obtain the purified liquid. The in-situ rain leaching repair system establishes a complete contaminated soil simulated repairing system for the soil in an aeration zone, and combines repair technologies of leaching, plants, microorganisms, electric separation and the like. The in-situ rain leaching repair system has the characteristics of energy conservation, emission reduction and no secondary pollution, and is suitable for repairing the soil in a large-area aeration zone with little pollution.

The invention discloses a carbon-based composite material for arsenic and cadmium polluted soil remediation and application of the composite material. The carbon-based composite material disclosed by the invention is prepared by the steps: taking crop straws as raw materials, and charring to prepare charcoal; mixing with an iron salt solution according to a certain solid-liquid ratio, regulating the pH value of the solution in the process so as to realize coprecipitation of the two materials; performing pyrolysis, thereby obtaining the carbon-based composite material. The carbon-based composite material prepared in the invention is applied to arsenic and cadmium compound polluted soil, and methods such as turning over, watering and the like are combined, so that the content of arsenic and cadmium in an effective state can be obviously reduced; therefore, the arsenic and cadmium in the soil can be transferred to a direction with low biotoxicity and migration, the physicochemical properties of the soil can be improved to a certain degree, and the composite material is suitable to be applied to multiple types of soil. The arsenic and cadmium ions in a water body can be effectively removed, the preparation process is simple in operating steps, and the material is wide in source, low in production cost and environment-friendly.

Methods are provided for remediating contaminated soil. The methods may include collecting contaminated soil at a plurality of treatment sites. The contaminated soil at one or more of the plurality of treatment sites may be at least partially contained. Vapors produced from heating soil at one site may be used to heat contaminated soil at another site. A fluid directed to a portion of heated contaminated soil may accelerate heat transfer through the site of contaminated soil or through another site of contaminated soil. A method may include heating contaminated soil from more than one site at substantially the same time. Heating contaminated soil from more than one site at substantially the same time may include in situ and ex situ treatment at a common location.

The invention discloses a system for repairing organic material polluted soil, which comprises a chimney and a rotary kiln reactor, wherein the smoke exhaust port of the rotary kiln reactor is connected with a furnace chamber; the furnace chamber is connected with a cyclone separator; one end of the cyclone separator is connected with a preheating passage; the other end of the cyclone separator is connected with a refeeder; the refeeder is connected with the furnace chamber; the preheating passage is connected with the chimney after passing through a flue gas desulfurization denitration purifier and a bag-type dust remover; an air preheating device is arranged in the preheating passage; one end of the air preheating device is connected with a first blower; the other end of the air preheating device is connected with the rotary kiln reactor and the furnace chamber respectively; and a rotary kiln repaired soil outlet is arranged on the rotary kiln reactor. The invention further discloses a method for repairing organic material polluted soil. According to the invention, the advantages of the thermal desorption technology in the organic material polluted soil repairing process are fully played; and organic material polluted soil, which is difficult to repair, can be repaired fast through the combination of new rotary kiln thermal desorption technology and the circulatory fluidized bed incineration technology.

The invention relates to a system for the ectopic restoration of volatile organic polluted soil and a disposing method thereof. The system for the ectopic restoration of the volatile organic polluted soil comprises a soil restoring bed, a ventilation pipeline system, a liquid charging system, a detecting system, an induced draught system and a closed-circuit tail gas collecting and disposing system. The soil restoring bed is a closed system. The ventilation pipeline system and the detecting system are arranged in the soil restoring bed. The liquid charging system is arranged above the soil restoring bed. The soil restoring bed is connected with the closed-circuit tail gas collecting and disposing system by the induced draught system. Polluted soil is used as a carrier to be connected with the soil restoring bed, the ventilation pipeline system and the detecting system. The system and the method can be used as an economical and feasible ectopic soil ventilation and microorganism degradation coupling restoration device of project application scale and a control method thereof, the control and the restoration technology are organically combined and improved according to local conditions, so as to achieve the unification of the factors such as expense, effect, operability, etc.

The invention belongs to the technical field of water and soil pollution restoration, and discloses a magnesium oxide-rice husk biological carbon composite material as well as a preparation method and application of the magnesium oxide-rice husk biological carbon composite material. The preparation method comprises the following steps: cleaning rice husks, drying the rice husks under a temperature of 80 to 90 DEG C for 10 to 16 hours, carrying out smashing and screening, heating to a temperature of 300 to 400 DEG C under a condition of feeding nitrogen and isolating oxygen at the rate of 3 to 8 DEG C per minute, carrying out thermal cracking for 2 to 4 hours, naturally cooling to a room temperature, cleaning the smashed rice husks, and drying the smashed rice husks to constant weight, so as to obtain rice husk biological carbon; adding the rice husk biological carbon into a magnesium oxide suspension with the mass percentage of 0.6 to 3 percent to obtain a mixed material; carrying out uniform stirring and mixing and then ultrasonic reaction for 1 to 2 hours, putting the mixed material under a condition of 85 to 105 DEG C for 20 to 24 hours, and carrying out thermal treatment at 300 to 400 DEG C for 20 to 60 minutes under a condition of feeding N2 to obtain the magnesium oxide-rice husk biological carbon composite material. The composite material can be applied to adsorbing and removing cadmium from cadmium polluted wastewater or cadmium polluted soil.

The invention relates to an environment-friendly and energy-saving thermal-desorption remediation treatment system for organic contaminated soil and aims to provide the energy-saving, environment-friendly and efficient thermal-desorption remediation treatment system for organic contaminated soil. The system comprises a feeding system, a thermaldesorption system, a soil discharging system, a combustion and tail gas treatment system, a flue gas temperature control system, a tail gas temperature-reduction and dust-removal system and a tail gas exhaust system, wherein the feeding system is led to the thermaldesorption system, the thermaldesorption system is led to the soil discharging system and the combustion and tail gas treatment system respectively, the combustion and tail gas treatment system is led to the flue gas temperature control system, the flue gas temperature control system is led to the thermal desorption system, the thermaldesorption system is led to the tail gas temperature-reduction and dust-removal system, and the tail gas temperature-reduction and dust-removal system is led to the tail gas exhaust system.

The invention relates to a chromium pollution soil in-situ leaching treatment method which is implemented in a way that: the periphery of the soil region in need of leaching treatment is provided with a plurality of groundwater extraction wells; water is sprayed on the ground to leach the polluted soil; the hexavalent-chromium-containing leaching water enters the groundwater; and under the control of a groundwater flow field, the hexavalent-chromium-containing leaching water is sucked to the ground surface; and the water is treated and recycled for ground spraying leaching. The hexavalent chromium content of the soil treated by the method can be reduced from 1000mg / kg to less than 100mg / kg.

The present invention belongs to the technical field of soil heavy metal remediation, specifically discloses a method for preparing the iron-based biochar material, the iron-based biochar material prepared there from and a method for controlling the heavy metal pollution in soil using the iron-based biochar material. For the iron-based biochar material of the present invention, by using a method of high-temperature carbonization, a biomass is used as a raw material and an iron-containing compound is add in the process of preparing biochar, wherein iron is incorporated in a specific ratio, to form the iron-based biochar material with a special structure and function. The material has a simple preparation process, low cost and a short production period; the prepared iron-based biochar material has an unique effect on the arsenic-cadmium combined pollution soil remediation, can effectively reduce the bioavailability of arsenic and cadmium in the soil, significantly reduces the arsenic and cadmium contents in the agricultural products planted in the arsenic-cadmium combined pollution soil, and has no toxic and side effects on the crops, is safe to apply and can be applied to the control of arsenic-cadmium combined pollution soil in a large scale.

The invention discloses an in-situ obstruction governing method of heavy-metal polluted soil. The method comprises the following steps of (1) drilling holes; (2) constructing a bottom obstruction layer; (3) constructing an anti-seepage obstruction wall; (4) pumping out underground water; (5) injecting a heavy metal stabilizer; and (6) building a top comprehensive obstruction layer. Through the way, by adopting the in-situ stabilized obstruction technology, the heavy-metal polluted soil can be in-situ governed efficiently, the governing effect is lasting, the economical cost is low, the application range is wide, whether the polluted soil area contains the underground water can be governed, the soil does not need to be dug in a large area, the risk in the digging process and transport process can be avoided, the secondary pollution and risk dispersion problems in the construction process can be greatly reduced, and the operation process is easy to control.