8671 results about "Electrolyte" patented technology

The invention discloses a refined disassembly system and method for a battery monomer, and belongs to the technical field of battery disassembly. The production line comprises a perforating device, a cutting device, a cutting device, a scattering device, a sorting device, a color sorting device, a defluorination device and a powder removal device. The method comprises the following steps: perforating a battery to discharge electrolyte, separating a shell from an inner core by a cutting device, cutting the inner core by a cutting device, scattering by a scattering device, sorting a diaphragm by a sorting device, sorting positive and negative electrode materials by a color sorting device, and respectively removing fluorine by a defluorination device. And finally, the metal foil and the powder are separated through the powder removing device, the damage degree of the crystal structure of the black powder can be reduced, the black powder and the metal fragments are efficiently separated according to the density difference, the metal foil and the black powder are not likely to be excessively mixed, the separation purity is high, the secondary treatment situation is reduced, efficient separation and recycling of the electrode material are achieved, and the production cost is reduced. And the comprehensive function and the resource utilization rate of the system are obviously improved.

A positive electrode material of the present disclosure includes: a positive electrode active material; and a first solid electrolyte material coating at least partially a surface of the positive electrode active material, wherein the first solid electrolyte material includes Li, Ti, M1, and F, and the M1 is at least one element selected from the group consisting of Ca, Mg, Al, Y, and Zr.

A nanocomposite electrode and a supercapacitor device including said nanocomposite electrode. The nanocomposite electrode includes a mixture of at least one binding compound, at least one conductive additive, and at least one molybdenum doped carbon material coated onto a substrate. The supercapacitor device includes two nanocomposite electrodes disposed facing one another, wherein the substrate of each nanocomposite electrode is coated with the mixture on an inside facing surface and the outer surfaces of the nanocomposite electrodes are not coated with the mixture, and the inside facing surfaces are separated by at least one electrolyte.

The invention relates to the technical field of batteries, in particular to a gel electrolyte prepolymerization solution, a lithium battery and a preparation method of the lithium battery. The gel electrolyte prepolymerization liquid comprises the following components: an electrolyte which accounts for 70%-99% of the total mass of the gel electrolyte prepolymerization liquid; the cross-linking monomer accounts for 1%-10% of the total mass of the gel electrolyte prepolymerization liquid; an initiator accounting for 0.3-5% of the total mass of the crosslinking monomer; the fluorocarbon surfactant accounts for 0.01%-5% of the total mass of the gel electrolyte prepolymerization liquid, the fluorocarbon surfactant comprises a perfluoroalkyl chain CnF2n + 1, and n is larger than or equal to 6. According to the invention, the fluorocarbon surfactant is introduced into the gel electrolyte pre-polymerization liquid, so that the electrode / electrolyte interface composition and structure are improved, the wettability is improved, the interface stability is improved, the loss of the electrolyte is inhibited, the accumulation of by-products of the positive electrode under high voltage and in the circulation of the negative electrode is reduced, and the cycle life and the stability of the battery are remarkably improved.

The invention relates to the technical field of polymer electrolyte, in particular to a self-repairing type gel polymer electrolyte membrane, a preparation method and application in an energy storage battery, the self-repairing type gel polymer electrolyte membrane is prepared by the following steps: dissolving amino-terminated polyethylene glycol in an organic solvent, adding trimesic acid under the protection of an inert atmosphere, heating, stirring and reacting to form a pre-polymerized solution, cooling, and then adding trimesic acid into the pre-polymerized solution to prepare a self-repairing type gel polymer electrolyte membrane; the preparation method comprises the following steps: adding glyoxylic acid and glacial acetic acid, carrying out a constant temperature reaction to obtain a solution A, adding LiTFSI into the solution A, carrying out ultrasonic dispersion to a homogeneous phase, pouring the obtained slurry onto a template, and carrying out a drying curing reaction to obtain the self-repairing gel polymer electrolyte membrane. A rigid aromatic cross-linking agent is used for inhibiting polymer crystallization and improving mechanical integrity, an imine bond-based dynamic covalent network is introduced to realize an autonomous interface repairing function at the working temperature of the battery, and meanwhile, a polyethylene glycol ether oxygen chain is used for constructing an efficient lithium ion transmission channel; therefore, the technical boundary that the conductivity, the mechanical strength and the interface stability of the traditional GPE are difficult to collaboratively optimize is broken through.

The invention relates to the technical field of food fresh-keeping materials, in particular to a chitosan-curcumin nano-composite fresh-keeping agent and a preparation method thereof.The chitosan-curcumin nano-composite fresh-keeping agent comprises nano-particles of a chitosan-sodium alginate-oxidized sodium alginate interpenetrating network structure, according to the nanoparticles, protonated amino groups of chitosan and carboxyl groups of sodium alginate form a polyelectrolyte compound core, aldehyde groups of oxidized sodium alginate and amino groups of chitosan are subjected to a Schiff base reaction to form a chemical cross-linked network, and zinc ions, amino groups of chitosan, carboxyl groups of sodium alginate and carboxyl groups of oxidized sodium alginate form coordination cross-linking; curcumin and epigallocatechin gallate form a compound through a hydrogen bond and a hydrophobic effect, the compound is embedded in an interpenetrating network structure, beta-diketone groups of curcumin and zinc ions form chelating coordination, a chitosan-sodium alginate-oxidized sodium alginate ternary interpenetrating network is constructed, and the chitosan-sodium alginate-oxidized sodium alginate ternary interpenetrating network structure is formed. The stability is improved by utilizing the synergistic effect of triple mechanisms of electrostatic interaction, Schiff base chemical bonds and zinc ion coordination.

The lithium secondary battery comprises a positive electrode, a negative electrode, a diaphragm and a polymer electrolyte, the polymer electrolyte contains the flame-retardant microcapsule, the flame-retardant microcapsule has a core-shell structure, a copolymer material containing one or more of an amide group, an ester group and an ether group is taken as a shell layer, and a flame retardant is taken as a core; the rupture collapse temperature of the flame-retardant microcapsule shell material is 60-120 DEG C, the melting point of the flame retardant is 20-120 DEG C, and the rupture collapse temperature of the copolymer material is higher than the melting point of the flame retardant. The lithium secondary battery disclosed by the invention has excellent flame retardance, the flame-retardant microcapsule added in the lithium secondary battery can be broken and collapsed when the battery is in thermal runaway, and the flame retardant is quickly released, so that the thermal runaway is actively defended in advance from the interior of the battery, and the electrochemical performance of the battery is not reduced.

The present invention provides a negative electrode active material that can reduce the generation of ionic substances and suppress excessive decomposition of the electrolyte, thereby improving the battery cycle characteristics. [Solution] A negative electrode active material having negative electrode active material particles, the negative electrode active material particles including a porous carbon structure as a base material, the porous carbon structure having Si-C bonds inside and amorphous low-valent nano-silicon oxide dispersed in the surface layer, and at least a portion of the low-valent nano-silicon oxide having tetravalent silicon oxide capable of absorbing and desorbing Li.

The invention discloses a preparation method of a rare earth element doped nickel-based selenide nano-material and application of the rare earth element doped nickel-based selenide nano-material in electro-catalysis water full-hydrolysis reaction. According to the method, nickel salt, cerium salt, selenium dioxide and potassium chloride are prepared into electrolyte, and the electrolyte is subjected to electro-deposition on a foamed nickel substrate to obtain Ce-doped Ni0.85Se nanoparticles growing on foamed nickel. The crystal structure and electron distribution of Ni0.85Se are optimized by doping trace rare earth element cerium, so that the HER and OER performances of the Ni0.85Se are greatly improved. The prepared catalyst is self-supporting closely-packed nanoparticles, the formed amorphous structure is easy to expose more active sites, the catalyst has good electrocatalytic hydrogen evolution and oxygen evolution performance under alkaline conditions, the overpotential in electrocatalysis of nickel-based selenide is greatly reduced, and the electrocatalytic performance of nickel-based selenide is improved. And excellent electro-catalytic activity is shown in electro-catalytic water full hydrolysis. And the self-supporting electrode is not easy to fall off due to generation of bubbles in the reaction process, so that the working stability of the catalyst is improved.

The method comprises the following steps: weighing an oxide precursor of metal indium, an oxide precursor of metal M, an ammonium salt and a lithium salt according to a chemical formula of indium-based halide, fully mixing, and calcining in an inert atmosphere to obtain the indium-based halide solid electrolyte. Forming an indium-based halide solid electrolyte through a solid-phase reaction; wherein M is selected from at least one of magnesium, calcium, strontium, barium, aluminum, gallium, indium, bismuth, scandium, yttrium, zinc, germanium, tin, lanthanum, cerium, samarium, gadolinium, holmium, erbium and ytterbium. The method can greatly simplify the synthesis process, reduce the raw material cost and realize industrial batch preparation.

The invention relates to the technical field of water-based energy storage batteries, in particular to a two-phase electrolyte for a water-based zinc ion battery and a preparation method of the two-phase electrolyte, and the two-phase electrolyte comprises soluble zinc salt, water and quaternary ammonium nitrate; the soluble zinc salt comprises one of zinc trifluoromethanesulfonate, zinc bis (trifluoromethylsulfonyl) imide, zinc acetate, zinc sulfate and zinc chloride, and the molar concentration of the soluble zinc salt is 1-5 mol / L; the quaternary ammonium nitrate is one or more than two of tetramethylammonium nitrate, tetraethyl ammonium nitrate, tetrabutyl ammonium nitrate, hexadecyl trimethyl ammonium nitrate and octadecyl trimethyl ammonium nitrate, and the molar concentration of the quaternary ammonium nitrate is 1-3 mol / L. The preparation method is simple, convenient and efficient, the reversibility of the zinc anode is optimized, the method is crucial for promoting the design of a practical water-based zinc ion battery, and the application of the zinc-based battery in the field of energy storage is further accelerated.

The invention discloses an electrolyte cylinder curled edge measurement and defect detection device, and relates to the field of electrolyte cylinder detection. The detection table is arranged below the carrier plate, and the electrolyte cylinder is conveyed to the detection table through the carrier plate; the jacking mechanism is arranged on the detection table at the lower part of the carrier plate and comprises a plurality of groups of jacking rollers which are symmetrically arranged and a driving mechanism; when the electrolyte cylinder is conveyed to the position over, the electrolyte cylinder is jacked up from the carrying plate through the jacking rolling wheels, and a cylinder body of the electrolyte cylinder is lifted; the detection mechanism is mounted above the carrier plate through a bracket and comprises two groups of camera lenses, and the camera lenses are aligned to the curled edges on the two end surfaces of the electrolyte cylinder; when crimping images are shot, the driving mechanism drives the jacking roller to rotate, the electrolyte cylinder is driven to circumferentially roll at the position of the detection table, and the camera lens continuously shoots the crimping images of the two end faces of the electrolyte cylinder. The problems that traditional manual detection is low in efficiency and poor in precision are solved, and the device has the advantages that all-round continuous detection of the curled edge of the electrolyte cylinder is achieved, and the measurement precision and efficiency are improved.

The application relates to a cylindrical battery monomer, a battery and a power utilization device. The cylindrical battery monomer comprises electrolyte, an electrode assembly and a shell. The shell contains the electrolyte and the electrode assembly. The electrolyte comprises an electrolyte salt, and the electrolyte salt comprises a hexafluorophosphate. The shell comprises a shell body and a film layer. The film layer is arranged on at least a surface of the shell body facing the electrode assembly. The base element of the film layer is a nickel element. The use reliability and the cycle performance of the cylindrical battery monomer in the embodiment can be improved.

The invention discloses a secondary battery and an electric device, and belongs to the technical field of secondary batteries. The secondary battery comprises a positive electrode plate, a negative electrode plate and an electrolyte, the positive electrode plate comprises a positive electrode material layer, the positive electrode material layer comprises a positive electrode material, the positive electrode material comprises lithium iron phosphate, the electrolyte comprises a cyclic sulfate compound, the cyclic sulfate compound comprises an electron donating group, and the cyclic sulfate compound comprises an electron donating group. The negative electrode plate comprises a negative electrode material layer, and when the secondary battery is charged to a full charge state, the negative electrode material layer comprises an iron element and LiC6. By regulating and controlling the mass percentage content a% of electron donating groups in the electrolyte, the mass percentage content b% of LiC6 in the negative electrode material layer and the mass content cppm of the iron element in the negative electrode material layer, b / (10a1 / 2 + c) is within a suitable range, active lithium is effectively compensated, and side reactions between the electrolyte and the positive electrode and the negative electrode can be reduced, so that the cycle life and the safety of the battery are both considered.

The invention relates to viologen-anthraquinone composite electrochromic liquid and a preparation method thereof, the viologen-anthraquinone composite electrochromic liquid comprises 1.2-2.5 parts by mole of viologen salt, 0.8-1.5 parts by mole of anthraquinone derivative and 8-12 parts by mole of electrolyte; the viologen salt is ethyl viologen tetrafluoroborate or heptyl viologen tetrafluoroborate or octyl viologen tetrafluoroborate; the anthraquinone derivative is 1-ethylamino-4-hydroxy anthraquinone or acid blue 43; the preparation method comprises the following steps: preparing an electrolyte solution; adding purple refined salt and anthraquinone derivatives according to the formula; fully dissolving the electrochromic material to form uniform and transparent initial liquid; and degassing the initial liquid to remove oxygen dissolved in the initial liquid. The electrochromic liquid has the advantages that after the purple refined salt and the anthraquinone derivative are added into the dissolving solution according to the proportion of the formula, the two color-changing materials are jointly dissolved in the electrolyte, and when the two color-changing materials are reduced at the same time, spectrum superposition absorbed by the two color-changing materials can cover the whole visible region, so that black and white switching of the electrochromic liquid is realized, and the use effect is good.

The embodiment of the invention relates to the technical field of electrolytes, and provides a preparation method of a hydrogel electrolyte, the hydrogel electrolyte and a zinc ion battery, and the preparation method comprises the following steps: preparing a chitosan aqueous solution with a first preset concentration; the preparation method comprises the following steps: adding a certain amount of genipin into a chitosan aqueous solution, so that the genipin and chitosan in the chitosan aqueous solution are crosslinked at a first preset temperature; coating the cross-linked slurry on a substrate of a preset material, and drying and demolding at a second preset temperature to obtain a hydrogel electrolyte dry film; and soaking the hydrogel electrolyte dry film in a liquid electrolyte with a second preset concentration to absorb the liquid until the liquid is saturated, thereby obtaining the hydrogel electrolyte. Chitosan and genipin used in the embodiment of the invention are natural substances and are non-toxic and harmless, so that the prepared hydrogel electrolyte belongs to an environment-friendly electrolyte material, the problem that a cross-linking agent in a traditional electrolyte material is relatively high in toxicity is effectively avoided, and the problem of side reaction caused by using water as an electrolyte solvent is also avoided.

The application relates to an electrolyte, a secondary battery and a power device, wherein the components of the electrolyte comprise a functional compound shown in formula (1), T1-T3 are independently selected from any one of the following groups: alkyl with 1-10 carbon atoms, alkenyl with 2-10 carbon atoms, alkynyl with 2-10 carbon atoms and groups shown in formula (a)-(f); and at least one of T1-T3 is selected from the group shown in formula (a), and at least one is selected from the group shown in formula (b), (c), (d) or (e). The functional compound shown in formula (1) can capture oxidation products in the charging and discharging process of the electrolyte, improve the toughness of the formed SEI film, and further improve the cycle performance of the secondary battery.

The invention provides an additive composition, an electrolyte thereof and a battery. The additive composition comprises a first additive and a second additive, the first additive comprises a compound with a structure as shown in a formula 1, and the second additive comprises a silane additive. When the additive composition provided by the invention is applied to the electrolyte, the cycle performance and the high-temperature performance of the battery can be improved.

The invention belongs to the technical field of sodium ion battery negative electrode material preparation, and particularly relates to an asphalt-based hard carbon material and a preparation method and application thereof, a negative electrode material and a preparation method thereof, and a sodium ion battery. In order to realize controllable preparation of high-value conversion, highly disordered and low-cost hard carbon of coal pitch, asphalt is used as a precursor material, modified asphalt is synthesized under the action of a solvent, a cross-linking agent and a catalyst, the hard carbon material is prepared through carbonization, and the hard carbon material is large in interlayer spacing and high in disordered degree and is accompanied with defects and closed pores, so that the high-value conversion, highly disordered and low-cost hard carbon is prepared. The preparation method is beneficial to reversible storage of sodium ions and improvement of the electrochemical performance of the sodium-ion battery, so that the sodium-ion battery is fully mixed with a conductive agent, an adhesive and deionized water to prepare slurry, the slurry is uniformly coated on a copper foil in a blade coating manner and is subjected to vacuum drying to prepare a negative electrode material, and the negative electrode material is matched with a corresponding counter electrode, electrolyte and a diaphragm to assemble the battery. The battery is low in cost, high in safety performance, relatively long in cycle life, high in rate capability and good in environmental sustainability.

The invention belongs to the field of batteries, and particularly relates to a lithium supplement negative plate, a preparation method thereof and a battery. The lithium supplementing negative plate comprises a negative current collector and negative active material layers arranged on two sides of the negative current collector; the negative active material layer comprises two lithium supplementing layers and an active material layer arranged between the lithium supplementing layers; the lithium supplementing layer comprises carbon aerogel, and a lithium supplementing agent and a conductive agent which are dispersed in the carbon aerogel. A lithium supplement agent and a conductive agent are dispersed in carbon aerogel, and the lithium supplement agent and the conductive agent are uniformly dispersed in holes of the carbon aerogel by virtue of a three-dimensional network structure of the carbon aerogel; the high adsorbability of the carbon aerogel is beneficial to the tight bonding of the active substance layer and the negative electrode current collector on the two sides of the carbon aerogel layer, so that the stripping force of the active substance is improved; the contact area of the second lithium supplementing layer on the outer side of the active material layer and the electrolyte is large, and the porous structure can improve the electrolyte retention coefficient of the battery; and the lithium supplementing layers are coated on two sides of the active material layer, so that expansion of the silicon negative electrode in the circulation process can be inhibited to a certain extent.

The invention belongs to the field of functional material preparation, and relates to an MOFs crystal film and a preparation method and application thereof. According to the MOFs crystal film, a porous polymer supporting film is used as a carrier, a high-crystallinity, compact and continuous rigid MOFs crystal layer grows on the surface of the porous polymer supporting film in situ, and a solid / quasi-solid electrolyte system is formed by matching polymer electrolyte or electrolyte. The MOFs ordered pore channel ion screening effect and metal ion sites are used for limiting anions, so that the ion transference number is increased; a physical-chemical synergistic dendritic crystal inhibiting mechanism is realized by utilizing high mechanical strength and a high crystal structure; the low-tortuosity compact ordered MOFs crystal film is used for improving the conductivity, the MOFs electrolyte with wide temperature range stability and high voltage resistance is obtained, and a support is provided for realizing a secondary battery with high energy density and high safety.

The invention discloses wide-temperature-range self-repairing gradient ceramic fire extinguishing foam, a preparation method and application of the foam in an electrochemical energy storage device, and belongs to the technical field of new energy battery safety. Aiming at the technical bottleneck of a traditional fire extinguishing material in coping with a thermal runaway fire disaster of an electrochemical energy storage device, the defects of an existing material in the aspects of extreme temperature adaptability, electrolyte compatibility and long-acting flame retardance are overcome through unique three-layer gradient structure design and material innovation; the technical bottlenecks of wide temperature range stability, an intelligent response mechanism and after-combustion blocking capacity are broken through, the ultra-wide temperature range structural stability from-50 DEG C to 1600 DEG C is achieved, millisecond-level response to different electrolytes is achieved, and a self-repairing barrier after fire extinguishment can be built. The innovation point is that the gradient ceramic structure design, the dynamic response mechanism and the self-repairing circulating system are adopted, so that the equal-depth fire reignition rate of the lithium battery can be obviously reduced, and the application prospect is wide.

A preparation method for a dual-enhanced interface solid polymer electrolyte by means of step-by-step polymerization, the preparation method comprising: mixing a matrix monomer and a first photoinitiator to obtain a mixed slurry, and illuminating same to obtain a pre-polymerized slurry; adding a lithium salt and a second photoinitiator to the pre-polymerized slurry, mixing same to obtain a polymer slurry, dividing the polymer slurry into a first polymer slurry and a second polymer slurry, adding a nitrogen-containing functional monomer to the first polymer slurry to obtain a polymer slurry A, and adding a fluorine-containing functional monomer to the second polymer slurry to obtain a polymer slurry B; and pouring the polymer slurry A on a first face of a base membrane, performing a treatment on same, pouring the polymer slurry B on a second face of the base membrane, and performing a treatment on same, so as to obtain a stepwise-polymerized dual-enhanced interface solid polymer electrolyte. The solid polymer electrolyte is prepared by means of using a step-by-step polymerization method, thereby optimizing a positive electrode side interface and a negative electrode side interface, and realizing continuous large-scale production of a solid polymer electrolyte.

The invention relates to the field of water treatment, and discloses a scale and corrosion inhibitor for seawater circulating cooling water, which is prepared from phosphonic acid grafted maleic anhydride-acrylic acid copolymer, hydroxyethylidene diphosphonic acid, amino trimethylene phosphonic acid, N, N-dimethylformamide, N, N-dimethylformamide, N, N-dimethylformamide, N, N-dimethylformamide, N, N- The anti-corrosion coating is prepared from the following raw materials: N, N-diethylaminomethyl-benzotriazole, gamma-aminopropyltriethoxysilane, zinc salt and a polyoxyethylene-polyoxypropylene block copolymer. The core of the invention is that all the raw material components form the thermo-sensitive polyelectrolyte compound through a self-assembly process. The compound is stably dispersed at low temperature by utilizing the cloud point effect of the block copolymer, and is subjected to phase change and preferential deposition on a high-temperature heat exchange surface, so that targeted and efficient delivery of various active components is realized. According to the invention, the problems of incompatibility of components and poor stability of a traditional compound agent are solved, the product has excellent storage stability, and efficient and synergistic corrosion and scaling control can be realized under high-temperature and high-salinity working conditions.

The electrochemical device includes: a case including a recessed container having a bottom and a side wall, and a cap covering the opening of the recessed container; a power generation element including a laminate having an electrode layer, an electrode layer and a solid electrolyte layer laminated together and contained in the interior space of the case such that the bottom and electrode layer face each other; and a conductive plate located adjacent to the opening of the recessed container and positioned between the electrode layer and cap. The recessed container includes insertion holes with openings in the upper end surface of the side wall. The conductive plate includes elastic locking portions located on edges thereof and corresponding in position to the insertion holes. With each elastic locking portion inserted in an insertion hole, the tip portion of the elastic locking portion presses a side surface of the insertion hole.

The invention provides a sulfide solid electrolyte with an MOF structure, and a preparation method and application thereof, the process is designed from a molecular level, and lithium ions and sulfur elements are used as basic components for constructing an MOF skeleton through in-situ combination of excellent ion conduction capability of the sulfide electrolyte and structural advantages of an MOF material; the bulk sulfide electrolyte with a regular three-dimensional multi-channel crystalline MOF structure is directly synthesized and constructed by taking a sulfur element as an inherent component of an MOF skeleton in a breakthrough manner, so that the intrinsic design of the sulfide MOF skeleton electrolyte is realized, and the problems of interface bonding, performance stability and ion transmission path are fundamentally solved; a sulfur element in the electrolyte is derived from sulfur atoms (such as-SH and-S-) of a ligand and participates in construction of an MOF skeleton, the electrolyte has the advantages of good interface stability, regular ion transmission channels, adjustable mechanical properties and the like, and the problems of poor interface stability, irregular ion transmission paths and the like of a sulfide electrolyte in the prior art are solved.

The invention relates to the technical field of secondary batteries, and discloses a secondary battery, a negative active layer in a negative plate comprises a negative active material and a negative adhesive, the negative active material comprises a silicon-based material, the negative adhesive comprises a polymer, and the raw material of the polymer comprises a hard segment monomer and a soft segment monomer; the electrolyte comprises carbonic ester substances and lithium salt; on the basis of the total mass of the raw materials of the polymer, the mass content of the soft segment monomer is r%; on the basis of the total mass of the electrolyte, the mass content of the carbonic ester substance is t%; t / r is greater than or equal to 0.234 and less than or equal to 1.770. According to the secondary battery provided by the invention, the chemical structure of the adhesive is optimized and the composition of the electrolyte solution is adjusted, so that the excellent electrochemical performance of the battery is ensured, the swelling effect of the electrolyte on the adhesive is reduced, the cycle life of the battery is prolonged, and the safety of the battery is improved.

This application relates to the field of hydrogel electrolyte technology, specifically disclosing a modified sodium alginate crosslinked hydrogel electrolyte, its preparation method, and its applications. This application reduces environmental toxicity and pollution by introducing modified sodium alginate as a crosslinking agent into the hydrogel electrolyte. The interaction between sodium alginate and zinc ions inhibits zinc dendrite formation, regulates the interfacial growth between the negative electrode and the electrolyte, and thus extends battery life; it also has a certain inhibitory effect on hydrogen evolution reaction. This application can prepare the modified sodium alginate crosslinked hydrogel electrolyte using a simple free radical polymerization method. Furthermore, compared to conventional aqueous batteries, the hydrogel electrolyte can better control the interfacial growth of the positive and negative electrodes.

The invention discloses a secondary battery, and belongs to the technical field of batteries, according to the secondary battery, cyclic sulfate is introduced into an electrolyte, and meanwhile, the content of the cyclic sulfate in the electrolyte, the nuclear magnetic displacement value of central carbon atoms of the electrolyte and the passivation capability of a negative pole piece are cooperatively regulated and controlled, so that the first-effect performance of the secondary battery can be effectively improved; and meanwhile, the low level of battery impedance can also be considered.

The invention relates to a composite diaphragm, a preparation method thereof and a battery. The composite diaphragm comprises a base membrane, a first functional layer arranged on at least one side surface of the base membrane in the thickness direction, and a second functional layer arranged on one side surface, far away from the base membrane, of the first functional layer, the first functional layer comprises ceramic particles and a high-temperature-resistant polymer; the thermal decomposition temperature of the high-temperature-resistant polymer is higher than that of the base membrane and lower than the melting point of the ceramic particles; the second functional layer comprises a functional additive, and the functional additive comprises a polyether polymer; the contact angle between the second functional layer and the electrolyte is smaller than or equal to 50 degrees. Therefore, through the synergistic effect of the first functional layer and the second functional layer, the thermal stability of the composite diaphragm and the wettability of the composite diaphragm to electrolyte are improved at the same time.