1530results about "Fuel and primary cells" patented technology

The invention belongs to the technical field of magnesium battery electrolytes, and discloses a magnesium battery electrolyte containing an insoluble additive and an application of the magnesium battery electrolyte, the insoluble indium additive is added into the magnesium electrolyte, such as In2O3 nano-particles, In2 (SO4) 3 nano-particles and nano In powder, and the insoluble indium additive is added into the magnesium electrolyte. The non-functionalized sites on the nano-particle cores interact with anions in the magnesium electrolyte to generate a synergistic effect, so that the anions in the electrolyte are fixed, the migration number of Mg < 2 + > and the ion utilization rate are increased, and transmission of magnesium ions is accelerated. The magnesium battery suspension electrolyte is simple in preparation process, low in viscosity and good in stability, the internal resistance of the battery is reduced, the performance of the battery is improved, and the cycle life of the battery is prolonged.

The invention discloses a preparation method and application of a carbon-loaded cobalt nanoparticle and iron monatomic electro-catalytic material, relates to a preparation and regulation method of a zinc air battery cathode catalyst, and solves the problems of low electricity generation performance and poor stability of an existing rechargeable zinc air battery cathode. Specifically, a high-efficiency and stable-catalysis carbon-loaded cobalt nanoparticle and iron monatomic electro-catalysis material is reasonably designed and successfully synthesized by utilizing the adsorption effect of a metal organic framework (MOFs) and polyvinylpyrrolidone as an ion adsorption layer, and under the condition that active sites are not sacrificed, the high-efficiency and stable-catalysis carbon-loaded cobalt nanoparticle and iron monatomic electro-catalysis material can be used for preparing a high-efficiency and stable-catalysis carbon-loaded cobalt nanoparticle / iron monatomic electro-catalysis material. And the dispersity of cobalt nanoparticles and the catalytic activity of iron monatomic are improved. The obtained material is used as a zinc air battery cathode material, the overall performance of a rechargeable zinc air battery can be improved, and efficient and oriented conversion of the zinc air battery is achieved.

The invention discloses a high-interface-stability composite solid electrolyte membrane as well as a preparation method and application thereof. The composite solid electrolyte membrane comprises a gradient aperture three-dimensional porous skeleton formed by sintering inorganic solid electrolyte particles, a polymer electrolyte filled in a pore channel, and a plastic interface stable layer positioned between the electrolyte membrane and an electrode. The preparation method comprises the following steps: preparing a gradient aperture porous framework through a pore-forming agent template method and a tape casting technology, dipping and filling a polymer electrolyte precursor solution in a solution, accelerating in-situ polymerization by adopting electric induction, and performing hot-pressing treatment. The composite solid-state electrolyte membrane has high ionic conductivity, excellent interface compatibility and high mechanical strength, can effectively inhibit the growth of lithium dendrites, can be applied to solid-state batteries such as lithium metal batteries, lithium sulfur batteries and lithium air batteries, and can remarkably prolong the cycle life and improve the safety performance of the batteries, and the preparation process is suitable for large-scale production.

Disclosed in the present invention are a biomass-derived graded porous asymmetric coordination monatomic carbon-based electrocatalyst, and a preparation method therefor and the use thereof. The preparation method for the biomass-derived graded porous asymmetric coordination monatomic carbon-based electrocatalyst comprises the following steps: (1) stirring and mixing de-alkalized lignin with a transition metal salt, a nitrogen-containing compound and a template, i.e., magnesium oxide, in a solvent until uniform, so as to obtain a suspension, wherein the transition metal comprises iron and zinc; (2) heating, evaporating and drying off the suspension, so as to obtain a lignin / metal ion / nitrogen-containing compound / template mixed precursor; and (3) subjecting the mixed precursor to high-temperature pyrolysis under the protection of an inert gas, cooling same, and then sequentially washing and drying same, so as to obtain a monatomic carbon-based electrocatalyst. The monatomic carbon-based electrocatalyst provided in the present invention has graded pores of micropores, mesopores and macropores, a surface nanosheet and an asymmetric coordination structure of Fe-N3O at the same time, and can be applied to fuel cells and metal-air cells.

An electrode stack can include a plurality of anode assemblies, each anode assembly including at least one anode layer attached to an anode tab; a plurality of cathode assemblies, each cathode assembly including at least one cathode layer attached to a cathode tab; a plurality of separators; an anode feedthrough bridge arranged to engage each anode tab of each of the plurality of anode assemblies; a cathode feedthrough bridge arranged to engage each cathode tab of each of the plurality of cathode assemblies; an anode feedthrough terminal coupled to the anode feedthrough bridge; and a cathode feedthrough terminal coupled to the cathode feedthrough bridge, wherein the plurality of anode assemblies and the plurality of cathode assemblies are alternately arranged and separated by the plurality of separators to form an electrode stack. A battery is also presented.

The invention discloses a fluorine-nitrogen-doped carbon-based oxygen reduction electrocatalyst for a zinc-air battery and a preparation method of the fluorine-nitrogen-doped carbon-based oxygen reduction electrocatalyst, and belongs to the technical field of catalysts. According to the method, a fluorocarbon mixture is rapidly treated through Joule heat to achieve efficient fluorine doping, then nitrogen doping is conducted through an ammonia gas plasma technology, and therefore an original carbon precursor is converted into fluorine-nitrogen-doped carbon. The catalyst material is short in preparation time and high in production efficiency, the content configuration of fluorine and nitrogen doped in fluorine-nitrogen-doped carbon finally formed by accurately controlling the temperature and time of Joule heat treatment and the power and time of plasma treatment is controllable, the morphology and the pore structure are controllable, high electro-catalytic performance is guaranteed, and the catalyst material is suitable for industrial production. The preparation method is high in production efficiency and low in cost, and has large-scale amplification potential.

The invention provides a composite diaphragm as well as a preparation method and application thereof, and belongs to the technical field of diaphragms. The composite diaphragm comprises a porous layer, the porous layer comprises organic polymer resin, inorganic particles and polymer fibers, and the polymer fibers are polymer fibers modified with hydrophilic groups.

The invention relates to the technical field of ORR catalyst preparation, in particular to an iron-nitrogen-carbon catalyst and a preparation method and application thereof. The invention provides a preparation method of an iron-nitrogen-carbon catalyst, which is characterized by comprising the following steps: dispersing zinc salt and ferrite in methanol to obtain a mixed solution A; the preparation method comprises the following steps: dispersing 2-methylimidazole and 1, 4-terephthalonitrile in methanol under a heating condition to obtain a mixed solution B; stirring and mixing the mixed solution A and the mixed solution B to obtain precursor powder, and calcining the precursor powder in an inert atmosphere to obtain the iron-nitrogen-carbon catalyst with the hierarchical porous structure. The invention provides a novel preparation method for preparing the iron-nitrogen-carbon catalyst with the hierarchical pore structure, and the iron-nitrogen-carbon catalyst with the hierarchical pore structure is prepared by introducing a 1, 4-terephthalonitrile molecular template.

The invention relates to the technical field of catalytic materials, in particular to a carbon-based monatomic catalyst doped with five non-metallic elements and a preparation method and application of the carbon-based monatomic catalyst doped with the five non-metallic elements. An organic precursor (MOF-coated POSFN-CTP) rich in five non-metallic element heteroatoms is prepared through a simple coprecipitation method at the room temperature; and annealing to obtain the carbon material (POSFNC) doped with five non-metallic elements. On the basis, the POSFNC is further impregnated with a transition metal precursor, annealing is carried out again, and the carbon-based monatomic catalyst doped with five non-metallic elements is successfully synthesized. The carbon-based monatomic catalyst with a hollow porous structure and five non-metallic element heteroatoms uniformly distributed can be constructed through the method, the synthesis process has the advantages of simplicity, convenience, economy and environmental protection, and the ORR activity and stability of the prepared catalyst exceed those of a commercial Pt / C catalyst.

The invention discloses an application of a single-metal Co (at) N-C nanotube with high C and N contents. The Co (at) N-C nanotube is used for a zinc or magnesium metal air battery positive electrode material catalyst. The application of the oxygen reduction catalyst in a primary zinc-air battery, a primary magnesium-air battery and a secondary zinc-air battery is realized. The oxygen reduction catalytic material is characterized by being a monometallic catalyst, and shows relatively high energy density and power density in a metal battery. The half-wave potential of the prepared single-metal catalyst Co (at) NC-1Co (at) NC-1 is 0.85 V, and the half-wave potential exceeds the half-wave potential of commercialized 20% Pt / C; the limit diffusion current density Jd is 5.44 mA cm <-2 >, which is equivalent to that of commercial 20% Pt / C. The power density of a primary zinc air battery taking Co-coated NC-1 as the oxygen reduction catalyst is 202 mW cm <-2 >, and the maximum energy density is 928 Wh kg <-1 > Zn, which is higher than that of a Pt / C-based zinc metal air battery. The catalyst has the advantages of easily available raw materials, simple preparation and low cost, and has potential commercial application value.

The invention discloses a functionalized oxide-loaded noble metal electrocatalyst and a preparation method and application thereof, the preparation method comprises the following steps: (1) adding a transition metal oxide and a silane reagent into absolute ethyl alcohol, heating and stirring, carrying out suction filtration, cleaning a solid, and drying to obtain an amino-functionalized transition metal oxide or a sulfydryl-functionalized transition metal oxide; (2) dissolving a noble metal compound in deionized water, adding a product obtained in the step (1), and carrying out ultrasonic treatment, suction filtration, solid cleaning and drying; and (3) annealing, cleaning and drying the product obtained in the step (2) in inert gas to obtain the functionalized oxide loaded noble metal electrocatalyst. According to the method, the utilization rate of precious metal is increased, the conductivity of the substrate is enhanced, and meanwhile, the bifunctional catalytic performance of transition metal oxide is utilized. The method is simple and easy to operate, and the synthesized catalyst has good catalytic activity and stability in a zinc air battery device.

The invention provides a CoCe-SNC catalyst and a preparation method and application thereof, and belongs to the technical field of hydrogen fuel cell / metal air cell cathode catalysts. The preparation method comprises the following steps: mixing and grinding a metal organic framework ZIF-8 and KSCN, carrying out first pyrolysis, compounding the obtained nitrogen and sulfur-containing co-doped carbon with two metal complexes Co-PM and Ce-PM, and carrying out second pyrolysis to obtain the CoCe-SNC diatomic catalyst. According to the invention, the two-dimensional lamellar structure carbon material and the asymmetric coordination diatomic metal are compounded, so that the catalytic performance of the whole catalyst is improved, and meanwhile, the yield of hydrogen peroxide generated by side reaction is reduced. The catalyst is applied to a hydrogen fuel cell / metal air cell, and the defects that in the prior art, a noble metal catalyst is high in cost, and a non-noble metal catalyst is low in catalytic activity, high in hydrogen peroxide yield, poor in catalyst stability and the like are overcome.

The invention discloses a glue stick type portable air battery monomer device which comprises a rotating mechanism and a shell, the rotating mechanism comprises a knob, a hollow spiral stick is arranged below the knob, an air inlet is formed in the upper end face of the knob, and the rotating mechanism further comprises a spiral cylinder base. A threaded hole matched with the threads of the hollow spiral rod is formed in the spiral cylinder base, a metal anode and an air cathode film are connected to the lower end face of the spiral cylinder base, the air cathode film is arranged below the threaded hole of the spiral cylinder base, and a sliding structure matched with the metal anode and the shell is arranged between the metal anode and the shell. An electrolyte storage cavity is formed in the bottom of the shell, and a positive electrode metal connecting piece and a negative electrode metal connecting piece are arranged in the electrolyte storage cavity. According to the invention, the technical problem that the electrolyte of the air battery is easy to leak is solved, and the portable air battery can be conveniently carried and quickly used in special scenes such as field investigation and emergency rescue.

The invention relates to the technical field of preparation of binuclear cobalt complexes, in particular to a binuclear cobalt complex as well as a preparation method and application thereof. The molecular formula of the binuclear cobalt complex is Co2 (L1) 2X2, the binuclear cobalt complex is composed of two L12-groups, two trivalent cobalt and two X-ions, and X is Cl or OH. The binuclear cobalt complex Co2 (L1) 2Cl2 belongs to a triclinic system, belongs to a P-1 space group, and is a chlorine-bridged binuclear cobalt complex. The binuclear cobalt complex Co2 (L1) 2 (OH) 2 belongs to a monoclinic system, belongs to a P21 / n space group, and is an oxyhydrogen bridging binuclear cobalt complex. The preparation method of the two binuclear cobalt complexes is simple, the cost is lower than that of precious metal, the stability and the selectivity are good, and the binuclear cobalt complexes have certain electrocatalytic oxygen reduction reaction performance.

The invention provides synthesis and oxygen reduction application of a metal cluster / polyphthalocyanine network compounded organic electrocatalytic material. The preparation method comprises the following steps: by taking benzene ring-containing anhydride, chlorate and urea as raw materials, carrying out high-temperature reaction, cooling, and purifying for multiple times, so as to obtain an edge-functionalized polyphthalocyanine network precursor; dispersing the obtained polyphthalocyanine network precursor into a solution A by using a proper solvent; meanwhile, trifluoroacetate and a tert-butyl metal compound are mixed in a proper solvent to form a metal cluster, and the metal cluster compound is dissolved in the solvent to form a solution B; and mixing the two solutions, standing overnight, filtering, purifying, and carrying out ball milling treatment to finally obtain the target metal cluster / polyphthalocyanine network composite organic catalyst. The polyphthalocyanine oxygen reduction organic catalytic material designed by the invention is low in raw material cost and simple to prepare. The test shows that the half-wave potential of the material is 100 mV higher than that of Pt / C, the E1 / 2 reduction value is 30 mV lower than that of Pt / C after accelerated aging for 2500 circles, and the material has high activity and high stability and can be applied to devices such as lithium batteries and fuel batteries related to the oxygen reduction process.

The present invention relates to the technical field of ORR catalyst preparation, and in particular to an iron-nitrogen-carbon catalyst and its preparation method and application. The present invention provides a method for preparing an iron-nitrogen-carbon catalyst, characterized in that it comprises: dispersing a zinc salt and a ferrous salt in methanol to obtain a mixed solution A; under heating conditions, dispersing 2-methylimidazole and 1,4-terephthalonitrile in methanol to obtain a mixed solution B; stirring and mixing the mixed solution A and the mixed solution B to obtain a precursor powder, and calcining the precursor powder under an inert atmosphere to obtain an iron-nitrogen-carbon catalyst with a hierarchical porous structure. The present invention provides a new preparation method for preparing an iron-nitrogen-carbon catalyst with a hierarchical pore structure, which prepares the iron-nitrogen-carbon catalyst with a hierarchical pore structure by introducing a 1,4-terephthalonitrile molecular template.

The invention belongs to the technical field of battery materials, and discloses a nitrogen-doped porous carbon loaded iron-selenium transition metal composite material as well as a preparation method and application thereof. According to the method, Se atoms are innovatively introduced into a Fe monatomic catalyst, and components are uniformly distributed on a nitrogen-doped carbon-based material. By introducing Se, the electron structure and microenvironment of Fe sites can be hybridized and adjusted through a p-d orbit, so that the adsorption / desorption behavior between active sites and intermediates in the ORR process is optimized, the efficient utilization of the catalyst is ensured, and the catalytic efficiency is greatly enhanced through the synergistic effect among iron-selenium particles. In addition, the synthetic method of the composite material is simple and easy to implement, has high economical efficiency, and lays a solid foundation for achieving industrial mass production of the composite material. Compared with a traditional platinum-carbon catalyst, the composite material catalyst has remarkable advantages in electrochemical performance.

The invention provides an alloying modification method of a platinum catalyst, and relates to the field of electrochemical catalysis, and the alloying modification method specifically comprises the following steps: uniformly mixing a 5% platinum-carbon catalyst and a phytic acid solution, carrying out freeze-drying treatment, carrying out primary pyrolysis, sulfuric acid treatment, ultrapure water cleaning and suction filtration, and drying to obtain powder, adding ferrous sulfate and 1, 10-phenanthroline, and uniformly stirring to obtain the platinum-carbon alloy. And carrying out secondary pyrolysis, sulfuric acid treatment, ultrapure water cleaning, suction filtration and drying to obtain the alloying modified carbon-based catalyst. According to the method, the metal platinum and the transition metal are alloyed, so that the activity and the stability of the catalyst are effectively improved, the usage amount of the noble metal platinum is reduced, and the manufacturing cost of the catalyst is effectively reduced; the alloying modified carbon-based catalyst obtained by the method can be used for preparing primary zinc-air batteries, rechargeable zinc-air batteries and other batteries.

The invention relates to the technical field of metal-air solid-state batteries, in particular to a thin-film metal-air battery with a three-dimensional structure, a layer of thin-film solid-state electrolyte structure is arranged between a negative electrode material and a breathing electrode, and the breathing electrode and the negative electrode material are folded and form a three-dimensional straight-hole folded plate structure. The three-dimensional straight-hole folded plate structures are uniformly provided with a plurality of Z-shaped through regular ordered holes, so that the weight of the three-dimensional straight-hole folded plate structures can be reduced to realize light weight, the three-dimensional straight-hole folded plate structures are mutually stacked, and the three-dimensional straight-hole folded plate structures are arranged in an air circulation area of the battery; honeycomb holes with high regularity are formed in the three-dimensional straight hole folded plate structure, and the structure is used in an air circulation area of the air battery, so that the contact surface area of air and an electrode can be greatly increased, which means that more oxygen can be in contact with the electrode at the same time, the supply efficiency of the oxygen is improved, and the reaction of the oxygen and the electrode is promoted.

The invention provides a preparation method of a molybdenum phosphide / titanium nitride composite material and a battery positive electrode material and a lithium-carbon dioxide battery, and belongs to the technical field of new energy materials. And then a titanium nitride conductor layer is deposited on the molybdenum phosphide by using an atomic layer deposition technology to prepare the molybdenum phosphide / titanium nitride, the molybdenum phosphide is combined as a transition metal phosphide to have stable catalytic performance, and the titanium nitride is used as a conductor to have excellent conductivity. The lithium-carbon dioxide battery positive electrode catalyst with high catalytic activity, high conductivity and excellent stability is obtained through the synergistic effect of the two materials, and when the lithium-carbon dioxide battery positive electrode catalyst is applied to a lithium battery, higher energy density, longer cycle life and better rate capability are shown, so that the overall performance of the battery is improved, and the application prospect is wide. The requirements on high-performance batteries in the fields of electric automobiles, energy storage systems and the like are met.

The invention belongs to the technical field of chemical energy, and particularly relates to an ultralow-potential-difference zinc-air battery containing a copper cluster axial coordination iron monatomic catalyst. Benzimidazole and 2-methylimidazole are synthesized into ZIF-7-NH2, the ZIF-7-NH2 reacts with Fe (NO3) 3.9 H2O and Cu (OAc) 2. H2O in an ion exchange mode to obtain FeCu-ZIF-7-NH2, a urea calcination product g-C3N4 is added, stirring is carried out to obtain Fe-ZIF-7-NH2 / g-C3N4, finally, sintering is carried out under argon to obtain g-SAFe-Cin, the ORR activity and the OER activity of the catalyst are remarkably enhanced by constructing the copper cluster axial coordination iron monatomic catalyst, and the catalyst has the advantages of being high in catalytic activity, high in catalytic activity and high in catalytic activity. And the performance of the assembled zinc-air battery in the charge-discharge cycle is improved. Non-noble metal and a low-cost carbon source are used as raw materials, the synthesis cost of the catalyst is reduced, the yield is high, the preparation period is short, and large-scale commercial application potential is achieved.

The invention relates to the technical field of catalytic materials, in particular to a molybdenum sulfide-based electro-catalytic material and a preparation method and application thereof. The invention provides a molybdenum sulfide-based electro-catalytic material, which comprises a transition metal chalcogenide containing chalcogen element vacancies and titanium dioxide quantum dots containing oxygen vacancies compounded on the surface of the transition metal chalcogenide, and a composite interface of the transition metal chalcogenide and the titanium dioxide quantum dots has a heterojunction structure. According to the composite electrocatalytic hydrogen evolution catalyst containing the TiO2 quantum dots and coupled with the double vacancies and the preparation method of the composite electrocatalytic hydrogen evolution catalyst, through the quantum effect and the double vacancy defect effect of the TiO2 quantum dots, the conductivity and the active site density of transition metal chalcogenide catalysts are improved, and the electrocatalytic hydrogen evolution performance is synergistically enhanced.

The invention relates to an iron and phosphorus co-doped Co3S4 hollow polyhedral electrocatalyst as well as a preparation method and application thereof, and belongs to the technical field of electrocatalysis and new energy materials. The electrocatalyst material provided by the invention adopts a hydrothermal-high temperature phosphating combined preparation method, and the synthesis steps comprise: preparing an iron-doped Co3S4 hollow polyhedral precursor in one step by adopting a hydrothermal reaction, and then carrying out high temperature phosphating to obtain the iron and phosphorus co-doped Co3S4 hollow polyhedral point catalyst material. The prepared electrocatalyst material has the characteristics of anion and cation co-doping and hollow porosity, and the oxygen evolution reaction activity of the electrocatalyst is improved through the synergistic effect of multiple active components such as Fe atoms, P atoms and Co3S4 nanoparticles; the preparation method is low in cost, and the obtained material is high in catalytic activity and good in stability and has wide application prospects in the fields of electrolyzed water, metal-air batteries and the like.

The present invention discloses three choline ionic liquids, which are composed of any one or more compounds represented by the following structural formulas:. The present invention also provides a method for synthesizing the above choline ionic liquids and their application as electrolyte additives for magnesium-air batteries. By adding the above choline ionic liquids to the electrolyte, the discharge voltage and specific energy of the magnesium-air battery with high-purity magnesium as the anode are greatly improved. In addition, it is also suitable for magnesium-air battery systems with AM50, AZ31 and ZK61 as the anode, and has good universality. The choline ionic liquid proposed by the present invention has low pollution and a simple synthesis method, can significantly improve the discharge performance of the magnesium-air battery, and has good application prospects.

The invention discloses a rare earth metal doped transition metal electrocatalyst and a preparation method and application thereof, the chemical formula of the catalyst is Eu-CoS1.097, the catalyst is of a crystalline and amorphous structure, and the Eu element exists in a monatomic form; the preparation method comprises the following steps: (1) dissolving polyvinylpyrrolidone and NH2-H2BDC in a solvent to obtain a mixed solution; (2) adding cobalt salt and europium salt into the mixed solution, uniformly mixing, and carrying out hydrothermal reaction to obtain an EuCo-MOF precursor; and (3) adding the EuCo-MOF precursor and thioacetamide into a solvent, and carrying out hydrothermal reaction, so that TAA releases S < 2->, and etching to obtain the rare earth metal doped transition metal electrocatalyst with a hollow spherical structure. According to the catalyst disclosed by the invention, atomic-scale Eu is doped in cobalt sulfide, so that the activity of the transition metal catalyst is effectively improved; the preparation method is simple and efficient.

The present disclosure relates to an air electrode for a metal-air battery including a cobalt-manganese heterostructure, a metal-air battery including the same, and a method of preparing the cobalt-manganese heterostructure. A cobalt-manganese heterostructure according to embodiments of the present disclosure exhibits excellent oxygen reduction reaction (ORR) activity and durability as well as superior oxygen evolution reaction (OER) performances including a high current density to RuO2 OER catalysts.

Provided is a novel composition, in particular, a composition comprising an inorganic-organic hybrid compound. The composition comprises an inorganic-organic hybrid compound and a hydrophobic resin, wherein the inorganic-organic hybrid compound comprises a polyvinyl alcohol-based resin to which a metal oxide is chemically bonded.

The invention belongs to the technical field of solid-state electrolytes, relates to a water-soluble polymer solid-state electrolyte and a preparation method and application thereof, and particularly relates to a water-soluble environment-friendly polymer composite solid-state electrolyte, a preparation method and a solid-state lithium / sodium battery. The water-soluble polymer solid electrolyte is prepared by preparing the water-soluble block polymer, the metal salt and the fast ion conductor into slurry, blade-coating the slurry on the porous fiber skeleton and drying to form a film, and the water-soluble polymer solid electrolyte is low in preparation raw material cost, free of emission of organic pollutants, good in environmental protection property, prepared under the air condition, free of harsh preparation conditions, suitable for industrial production and suitable for industrial production. Meanwhile, the prepared solid electrolyte has the characteristics of high ionic conductivity and good interface stability, and can be applied to electrochemical devices such as solid lithium batteries and solid sodium batteries.

To provide a fuel cell in one-compartment.SOLUTION: In a fuel cell, a cathode electrode made of metallic copper and a metal anode having a lower electrode potential than copper are opposed to each other in an electrolytic solution containing hydrogen peroxide, hydrogen gas is generated on the surface of the copper cathode in an electrolyte containing hydrogen peroxide, and reacts with oxygen supplied from hydrogen peroxide, and causes power generation reaction without supplying hydrogen from the outside. The configuration of the present invention can provide a novel and useful configuration as a one-compartment hydrogen fuel cell or a hydrogen peroxide fuel cell.SELECTED DRAWING: Figure 1

A modified molecular sieve-based solid electrolyte, comprising a molecular sieve-based solid electrolyte and a modifying substance dispersed in the porous structure of the molecular sieve-based solid electrolyte, wherein the modifying substance can generate a coordination effect with carriers in the molecular sieve-based solid electrolyte; and the modifying substance contains one or more of nitrogen, oxygen, and sulfur elements. The modified molecular sieve-based solid electrolyte can well meet the requirements of assembling an all-solid-state battery, and enable the all-solid-state battery to have electrochemical properties superior to those of liquid electrolyte-based energy storage devices.