2979 results about "Peroxide" patented technology

The invention relates to a bioelectrochemical sensor used for detecting hydrogen peroxide and a manufacturing method of the bioelectrochemical sensor. The novel bioelectrochemical sensor is a sensor with a three-electrode system, wherein the counter electrode is a platinum electrode, the reference electrode is saturated calomel electrode and the working electrode is gold electrode. The sensor is based on orientation combination of a polypeptide horse radish peroxidase with characteristic sequence, the promotion effect of the polypeptide horse radish peroxidase on the activity of the enzyme and the characteristic of high sensitivity of electrochemical detection methods. The sensitivity of hydrogen peroxide sensors is effectively improved and satisfactory results are obtained.

The invention relates to the technical field of optical sensing, in particular to a copper-carbon quantum dot nano-enzyme and a preparation method and application thereof. Poria cocos and Cu < 2 + > are taken as raw materials, and the copper-carbon quantum dots with excellent peroxidase activity are prepared by adopting a one-pot hydrothermal method and can be used for sensitively, accurately and selectively detecting glyphosate. Cu < 2 + > is combined with oxygen-rich and nitrogen-rich components in poria cocos to generate an oxidation-reduction reaction, CuCDs with Cu < 2 + > / Cu < + > are obtained, Cu < 2 + > doping changes electron cloud distribution of the CDs, the electron transmission capability of the CuCDs is enhanced, and Cu < 2 + > and the CDs have a synergistic effect to generate three ROS (. OH,. O2 <-> and < 1 > O2), so that excellent peroxidase activity is exerted. The glyphosate is chelated with hydroxyl, amino, carbonyl, carboxyl and Cu on the surface of the CuCDs to occupy active sites, so that the active sites are poisoned, the peroxidase activity of the CuCDs is selectively inhibited, and a powerful choice is provided for simply, quickly, sensitively and selectively detecting the glyphosate.

The preparation method of the silicon-carbon composite material comprises the following steps: uniformly mixing a carbon source, a pore forming agent and a cross-linking agent, and introducing peroxide gas into a tubular furnace for sintering to obtain porous carbon; uniformly mixing the porous carbon with liquid silane and a surfactant, and transferring the mixture into a high-pressure reaction kettle for reaction to obtain a silicon-carbon precursor; and introducing the obtained material into a carbon source gas containing a heteroatom gas for deposition to obtain the silicon-carbon composite material. The obtained material generates porous carbon with high strength and high pore volume by utilizing the cross-linking agent and the pore-forming agent thereof, so that the expansion is reduced; and the liquid silane has the characteristics of low decomposition temperature, low cost and high safety performance, so that the specific capacity is improved, and the cost is reduced.

The invention relates to a composite hydrogel dressing for promoting wound healing as well as preparation and application thereof, and belongs to the technical field of biological medicines. The hydrogel disclosed by the invention is prepared by mixing gelatin, oxidized dextran and metal ion modified metal-organic framework compounds (MOF-Ag and MOF-Cu). In the mixed solution, amino groups in the gelatin and aldehyde groups of the oxidized dextran are subjected to a Schiff base cross-linking reaction, and the composite hydrogel is formed after standing. The loaded MOF-Ag has antibacterial and anti-biofilm effects on staphylococcus aureus and escherichia coli, and the loaded MOF-Cu has similar superoxide dismutase activity and similar glutathione peroxidase activity, so that excessive active oxygen can be removed, and inflammatory response can be relieved. The obtained hydrogel has good biocompatibility, proper mechanical properties and biological adhesion, stable rheological properties, excellent antibacterial and anti-inflammatory functions and a certain hemostatic function.

The invention provides a preparation method of medicinal liquor and application of the medicinal liquor in preparation of antioxidant and anti-aging products, and relates to the technical field of medicinal preparations. The preparation method comprises the following steps: (1) crushing; (2) extracting; (3) standing and separating; and (4) freezing and filtering to obtain the medicinal liquor. The medicinal liquor is obtained by extracting the traditional Chinese medicine components through the steps of crushing in batches, mixing and extracting, standing, freezing and separating the supernate and the suspension in different separation modes, and the medicinal liquor can better improve the space exploration capability of a mouse aged due to D-galactose, can reduce malondialdehyde MDA, and can improve the immunity of the mouse. The activity of superoxide dismutase (SOD) and glutathione peroxidase (GSH-Px) is improved, and the obvious anti-oxidation and anti-aging effects are achieved.

The invention discloses a copper-based nano-enzyme, a preparation method thereof and application of the copper-based nano-enzyme in organophosphorus pesticide detection, and belongs to the technical field of pesticide residue detection. The copper-based nano-enzyme has a netted-like structure, a high specific surface area and many active sites, the valence state of a copper element is zero-valence Cu, Cu < + > and Cu < 2 + >, the copper-based nano-enzyme has high peroxidase-like activity and laccase-like activity, the detection limit is low, and glyphosate can be sensitively detected; and glyphosate, glufosinate-ammonium and isazofos can be well distinguished from six organophosphorus pesticides with medium concentration, and the method has high selectivity. The nano enzyme provided by the invention is prepared from ammonium citrate and copper nitrate in an N, N-dimethylformamide (DMF) solution by using a solvothermal method; the preparation process of the nano enzyme is simple.

Systems and methods are provided for etching molybdenum in a wet ALE process. The methods disclosed herein use a wide variety of techniques and wet etch chemistries to oxidize a molybdenum surface and form a self-limiting, molybdenum oxide passivation layer in a surface modification step of the wet ALE process. For example, the methods use: (a) ultra-violet (UV) photolysis of peroxide oxidizers to create oxidizing radicals, which limit oxidation of the molybdenum surface and provide quasi-self-limiting oxidation behavior, (b) steric hinderance of oxidizers having large reactant molecules to achieve better self-limiting oxidation behavior, and / or (c) ligand-assisted oxidation to change the surface chemistry of the molybdenum oxide passivation layer and ensure self-limiting oxidation behavior. After forming the molybdenum oxide passivation layer using one or more of the oxidation techniques disclosed herein, the passivation layer is selectively removed in a dissolution step of the wet ALE process to etch the molybdenum surface.

The invention relates to the field of biomedical materials, and particularly discloses a manganese dioxide nano-enzyme for treating inflammatory bowel disease as well as a preparation method and application of the manganese dioxide nano-enzyme. The preparation method of the manganese dioxide nano-enzyme comprises the following steps: uniformly mixing an organic solution containing manganese nitrate hexahydrate with a montmorillonite aqueous solution to obtain a mixed reaction solution; the pH value of the mixed reaction solution is adjusted to be under the alkaline condition through alkali liquor, a synthetic reaction is carried out, then centrifugation and washing are carried out, the montmorillonite-loaded manganese dioxide nano-enzyme is obtained, and the manganese dioxide nano-enzyme is of a lamellar structure with the length being 20-400 nm. The manganese dioxide nano enzyme has excellent activity similar to superoxide dismutase, catalase and glutathione peroxidase; meanwhile, the compound also has the capability of removing various free radicals such as DPPH and ABTS, can be used for treating the inflammatory bowel disease, and has a wide application prospect.

The invention discloses a metal-doped carbon quantum dot as well as preparation and application of the metal-doped carbon quantum dot in a nano antibacterial agent, citric acid, urea and tea polyphenol are taken as precursors, metal salt is added, carbon dot synthesis and metal ion doping are synchronously completed in one step through a hydrothermal method, and the metal-doped carbon quantum dot is prepared; the surfaces of the metal-doped carbon quantum dots are negatively charged, and the metal-doped carbon quantum dots have peroxidase-like activity and catalase-like activity at the same time; the metal ions adopt any one of Fe < 3 + >, Cu < 2 + > and Ce < 3 + >; the metal-doped carbon quantum dots are in a sphere-like shape. The metal-doped carbon quantum dots prepared by the preparation method disclosed by the invention have peroxidase-like activity and catalase-like activity at the same time through precise doping of metal ions, and the two activities have a synergistic effect in an oral periodontitis microenvironment, so that a good antibacterial effect is achieved.

The invention provides a photovoltaic wastewater resource utilization method and system, and the method comprises the following steps: sequentially carrying out peroxide removal treatment and filtration treatment on photovoltaic wastewater to obtain filtered effluent; carrying out silicon element separation treatment on the filtered effluent to obtain sodium-rich wastewater and silicon-rich wastewater; carrying out heavy metal removal treatment and anion removal treatment on the sodium-rich wastewater to obtain a product alkali liquor; the peroxide removal treatment comprises the step of enabling the photovoltaic wastewater to be in contact with a catalytic filler, wherein the catalytic filler comprises at least one of manganese sand, ferric oxide and aluminum oxide; the silicon element separation treatment comprises the step of treating the filtered effluent by using a silicon element separation membrane element; the silicon element separation membrane element is selected from at least one of polysulfone, polyamide, sulfonated polyethersulfone or sulfonated polysulfone. The photovoltaic wastewater resource utilization method provided by the invention has the technical effects of cyclic utilization of the photovoltaic wastewater and relatively low cost.

The invention relates to the technical field of photovoltaics, in particular to a method for testing the grafting rate of silane grafted polyolefin for a photovoltaic packaging adhesive film. Comprising the following steps: S1, extracting a silane grafted polyolefin grafting material in an organic solvent to remove unreacted silane or residual peroxide, washing for multiple times after extraction is completed, and drying for later use; and S2, weighing and recording the mass of the crucible and the extracted silane grafted polyolefin colloidal particles, then putting the crucible filled with the colloidal particles into TGA for calcination, weighing the total mass of the crucible and the sample after calcination is finished, and converting the relative grafting rate by using the ash content of the TGA. According to the invention, the grafting rate of silane grafted polyolefin can be timely and effectively tested and evaluated, so that the grafting stability in the grafting material production process can be truly reflected. Meanwhile, the grafting rate testing method is high in efficiency, simple and reliable to operate.

The invention provides aluminum-doped hematite, a preparation method of the aluminum-doped hematite and application of the aluminum-doped hematite in catalyzing peroxides to degrade organic pollutants or remove pathogenic bacteria. The preparation method of the aluminum-doped hematite comprises the following steps: adding ferric iron salt and aluminum salt into deionized water, reacting, precipitating to separate out a product, washing, drying and grinding to obtain a precursor; calcining the precursor, and then washing and drying to obtain the aluminum-doped hematite. The preparation method is simple, cheap and easily available in raw materials, low in cost, green, safe and environment-friendly; the aluminum element is introduced into the hematite, so that the catalytic activity of the hematite is improved, and the catalytic condition is easy to realize; the aluminum-doped hematite disclosed by the invention has excellent capability of activating peroxide, so that the aluminum-doped hematite shows excellent performance in the aspects of removing environmental organic pollutants and sterilizing.

The preparation method comprises the following steps: synthesizing gold nanostars (GNS) by using a seed growth method, coating mesoporous cerium dioxide (mCeO2) by using a template method, and loading a photosensitizer indocyanine green (ICG), so as to form a nano enzyme diagnosis and treatment system with chemical activity, photoactivity and photothermal effects. In the system, the gold nanostars have a good photo-thermal effect due to the multi-branched structure of the gold nanostars; on one hand, the mesoporous cerium dioxide coated on the outer layer has a chemical effect due to the nano-enzyme effect, and on the other hand, the mesoporous structure of the mesoporous cerium dioxide can better load the photosensitizer indocyanine green. All the components have good stability and biological safety, also have peroxidase simulation activity and a drug loading function, can improve the level of reactive oxygen species (ROS) in a tumor microenvironment and load photosensitizer drugs, and have an excellent anti-tumor effect and small side effects.

The invention relates to the technical field of electronic materials, in particular to a preparation method of low-halogen alkali-soluble photosensitive resin and solder resist ink. Comprising the following steps: adding amino resin, alcohol olefin and a catalyst A into a solvent, mixing, and carrying out an ether exchange reaction to obtain an initial etherified product; adding peroxide into the initial etherification product, and carrying out epoxidation reaction to obtain an epoxy resin intermediate; adding an olefine acid compound, a catalyst B and a polymerization inhibitor into the epoxy resin intermediate, and carrying out ring-opening esterification reaction to obtain an epoxy acrylate intermediate; and adding acid anhydride into the epoxy acrylate intermediate, and carrying out carboxylation reaction to obtain the low-halogen alkali-soluble photosensitive resin. The problem of high halogen content of the existing alkali-soluble photosensitive resin is solved, and the solder resist ink prepared from the alkali-soluble photosensitive resin has high sensitivity, high resolution, high heat resistance, high acid and alkali resistance and high electrical insulation property.

The invention provides a uric acid detection material Ce-UiO-66-X based on cerium-based UiO-66 as well as a preparation method and application of the uric acid detection material Ce-UiO-66-X, and belongs to the technical field of uric acid detection. The uric acid detection material Ce-UiO-66-X is prepared on the basis of a cerium-based metal organic framework material, and Ce-UiO-66-X can convert uric acid into allantoin and generate hydrogen peroxide at the same time. In the presence of hydrogen peroxide, Ce-UiO-66-X can be changed from white to orange, rapid quantitative analysis of uric acid concentration is carried out, one-step colorimetric rapid detection analysis of uric acid can be realized without participation of natural urate oxidase, peroxidase and a color developing agent, and the detection time is only 3 minutes. Moreover, a green and efficient uric acid detection material Ce-UiO-66-X water phase synthesis strategy is developed by using a carboxylic acid regulator, a material basis is provided for constructing a novel enzyme-free uric acid rapid detection method, and the method is safe and environmentally friendly.

The invention relates to the technical field of nano-drugs, in particular to an acoustic / chemical power synergistic anti-tumor nano-drug as well as a preparation method and application thereof. The invention provides an acoustic / chemical power synergistic anti-tumor nano-drug, which takes hollow mesoporous MnO2 nano-particles as a carrier, and is loaded with vitamin C and a sound-sensitive agent chlorin e6. Vc can generate abundant H2O2 to provide a raw material for CDT, and MnO2 is used as a peroxidase-like enzyme to catalyze H2O2 to generate O2, so that tumor hypoxia is effectively relieved, and the effect of sonodynamic therapy is enhanced. Besides, GSH induces MnO2 degradation, GSH consumption is caused to enhance CDT, GSH depletion can cause glutathione peroxidase 4 (GPX4) activity reduction, ROS generation and GPX4 activity reduction have a synergistic effect, lipid peroxides (LPOs) are increased, and finally ferroptosis of tumor cells is caused.

According to the method, phosphomolybdic acid, copper chloride and ferric chloride serve as precursors, copper and iron-containing phosphomolybdic acid nano-enzyme (Cu, Fe-PMs) with peroxidase-like activity is synthesized through a microwave method, under the acidic condition, on one hand, the surface of Cu and Fe-PMs carries negative charges, high affinity is generated between Cu and Fe-PMs and a substrate TMB with positive charges, and on the other hand, the surface of Cu and Fe-PMs has negative charges; on the other hand, Cu / Fe / Mo three-metal redox couple accelerates the regeneration of Fe < 2 + > and plays an important role in the activity of peroxidase, and meanwhile, due to the introduction of sodium dehydroacetate, Cu and Fe in Cu and Fe-PMs and pyranoid ring and keto O in sodium dehydroacetate interact through coordinate bonds to cause electron interaction, so that the peroxidase-like activity of Cu and Fe-PMs is enhanced, and the peroxidase-like activity of Cu and Fe-PMs is improved. And the Fenton reaction is enhanced through transfer of electrons among the sodium dehydroacetate, the Cu and the Fe-PMs. When Cu and Fe-PMs oxidize TMB and H2O2, sodium dehydroacetate enhances the absorbance of the system, and on the basis, a novel colorimetric rapid detection method of sodium dehydroacetate is established.

The invention discloses a preparation method and application of a zinc-bromine flow battery positive electrode material, and belongs to the field of zinc-bromine flow batteries. The preparation method comprises the following steps: dissolving aniline and a dithio compound in an acidic ice bath, dropwise adding a peroxy strong oxidant to generate a polyaniline-disulfide bond copolymer, dialyzing, and freeze-drying to obtain powder; then heating soluble silver salt, a reducing agent, a hydrophilic dispersing agent and an organic sulfydryl silane coupling agent to prepare functionalized nano-silver particles; the powder and nano-silver particles are dispersed in N-methyl pyrrolidone for ultrasonic treatment, and dynamic self-repairing coating slurry is prepared; and performing acid pretreatment on the carbon fiber paper, and performing electrochemical deposition on the slurry to prepare the zinc-bromine battery positive electrode material. According to the zinc-bromine battery positive electrode material, the coulombic efficiency and the voltage efficiency of a zinc-bromine flow battery are remarkably improved and the cycle life of the zinc-bromine flow battery is remarkably prolonged through methods of dynamic covalent bonds, nano-silver catalysis, a hierarchical pore structure, carbon fiber pretreatment and the like, and the zinc-bromine flow battery positive electrode material has chemical stability, efficient bromine adsorption capacity and excellent catalytic activity.

The invention provides a colorimetric / fluorescent dual-mode sensor, a preparation method of the colorimetric / fluorescent dual-mode sensor and application of the colorimetric / fluorescent dual-mode sensor in histamine detection. The colorimetric / fluorescent dual-mode sensor comprises a horseradish peroxidase-loaded metal organic framework (HRP-AIE-MOF), hydrogen peroxide and a chromogenic substrate o-phenylenediamine (OPD), horse radish peroxidase (HRP) in the HRP-coated AIE-MOF can oxidize colorless OPD into yellow 2, 3-diaminophenazine (DAP), an ultraviolet absorption peak is generated at 425 nm, a strong fluorescence emission peak is generated at 555 nm, the HRP-coated AIE-MOF has a strong fluorescence emission peak at 450 nm, and the HRP-coated AIE-MOF and a fluorescence signal of the DAP can form a ratio fluorescence sensor. According to the invention, the excellent catalytic ability of natural enzyme and the luminescence characteristic of AIE-MOF are integrated in one system, and high-sensitivity histamine detection is realized.

The invention provides a medical packaging material and a preparation method thereof.The preparation method comprises the steps that S100, polypropylene, maleic anhydride grafted co-polypropylene, peroxide and filler are mixed, then melt extrusion and two-way stretching are conducted, and a printing layer is obtained; s200, respectively preparing a barrier layer and a heat sealing layer; and S300, the heat sealing layer, the blocking layer and the printing layer are sequentially stacked from inside to outside, and the packaging material is obtained. Through the preparation method of the packaging material, the prepared packaging material has excellent barrier property and antibacterial property while resisting high temperature, and can meet the requirements of the medical field.

The invention discloses a high-viscosity silicone rubber composite material and a preparation method thereof.The preparation method comprises the steps that a silicon-based polymerization solution and a silane raw material are mixed on the basis of a rotary dropper, and a silicon-based liquid compound containing a spiral laminated layer is obtained; the preparation method comprises the following steps: dispersing a nano-filler into a silicon-based liquid compound for synthesis treatment, carrying out crosslinking treatment on the obtained primary compound and peroxide to obtain a crosslinked compound, mixing the crosslinked compound with a fiber compound, and carrying out plasma treatment to obtain a fiber-reinforced compound; performing secondary cross-linking treatment on the fiber reinforced compound and a peroxide silicone oil solution in a vacuum high-temperature environment to obtain a secondary cross-linked compound; and immersing the secondary cross-linked compound into a turbid liquid containing nano aluminum oxide, and carrying out heating treatment to obtain a finished product of the high-viscosity silicone rubber composite material. According to the invention, the problem of compatibility between the filler and the matrix material is solved, the processability is improved, and the performance of the material in multiple aspects such as high temperature resistance and aging resistance is further improved.

The invention relates to the technical field of rubber compounds, and particularly discloses a bio-based and circulating material synergistically modified EPDM rubber compound and a preparation method thereof. The invention discloses a bio-based and circulating material synergistically modified EPDM rubber compound. The rubber compound is prepared from the following components: 100 parts of bio-based EPDM rubber, 100 to 130 parts of a reinforcing agent, 40 to 60 parts of paraffin oil, 5 to 7 parts of magnesium oxide, 0.5 to 1.5 parts of stearic acid, 6 to 8 parts of BIPB-40 peroxide, 2 to 5 parts of a Si-69 silane coupling agent, 1 to 3 parts of a dispersing agent and 1 to 3 parts of an assistant crosslinking agent, the reinforcing agent is composed of fast extruding furnace black N550, rice hull ash white carbon black and thermal cracking carbon black; and the assistant cross-linking agent is prepared from diallyl terephthalate and triallyl isocyanurate. The rubber compound prepared by utilizing the technical scheme provided by the invention can meet and maintain the mechanical property requirements, and meanwhile, carbon emission of the product in the whole life cycle is reduced from the aspects of formula and process.

The invention relates to the technical field of peroxide crosslinked polyethylene pipe manufacturing, and discloses a peroxide crosslinked polyethylene pipe manufacturing system and a crosslinking furnace thereof.The crosslinking furnace comprises a first furnace body, a second furnace body and a third furnace body, the first furnace body is provided with a first crosslinking cavity with a front opening and a rear opening, and a pipe can penetrate through the first crosslinking cavity; the first infrared emitter is arranged on the first furnace body, and infrared rays of the first infrared emitter are emitted into the first cross-linking cavity; the second furnace body is provided with a second cross-linking cavity with front and back openings, the second cross-linking cavity can allow the pipe to penetrate through, and the first furnace body and the second furnace body are sequentially arranged in the movement direction of the pipe; the second infrared emitter is arranged on the second furnace body, infrared rays of the second infrared emitter enter the second cross-linking cavity, and the wavelength of the infrared rays emitted by the second infrared emitter is smaller than that of the infrared rays emitted by the first infrared emitter. The inner layer and the outer layer of the pipe can be synchronously heated through infrared rays with different wavelengths, so that the cross-linking reaction of the pipe is more uniform, and the quality of the pipe is improved.

The invention discloses application of iron ruthenium nano-enzyme in preparation of nucleic acid detection products, and belongs to the technical field of biological detection and nano-materials. The RIN has stable peroxidase-like (POD) activity, and can catalyze a chromogenic reaction between 3, 3 ', 5, 5'-tetramethyl benzidine (TMB) and hydrogen peroxide (H2O2). The catalytic activity of the nano-enzyme can be selectively inhibited by pyrophosphate (PPi) generated in a nucleic acid amplification reaction, so that visual colorimetric analysis on whether target nucleic acid exists or not is realized. In combination with a polymerase chain reaction (PCR) system, the invention constructs a new nucleic acid detection strategy which does not need fluorescence labeling, is simple and convenient to operate and has high sensitivity. Through verification, the system can be widely applied to rapid on-site screening and visual interpretation of related nucleic acid of drug-resistant pathogens (such as ESKAPE flora) and the like, and has a good application prospect.

The invention discloses peroxidase and application thereof, and relates to the field of bioengineering. The peroxidase POD-8 provided by the invention has very good enzyme activity for oxidizing phenol substrates, especially has the highest enzyme activity for 2, 6-DMP, has very good persistence, and can keep stable enzyme activity within 10 minutes; the resistance to various metal ions is relatively high, and the enzyme activity of 90% or above can still be kept in the presence of various metal ions with various concentrations; the POD-8 has a strong decolorizing capability on a plurality of dyes, especially has a decolorizing efficiency of about 25% on Congo red and amino black 10B in 24 h, and has a good application prospect in the aspect of dye wastewater treatment.

The invention relates to the technical field of sealing strips, in particular to an anti-aging ethylene propylene diene monomer rubber sealing strip and a preparation method thereof. Comprising the following components in parts by weight: 150-180 parts of ethylene propylene diene monomer, 60-90 parts of carbon black, 8-12 parts of white carbon black, 3-8 parts of a peroxide vulcanizing agent, 6-12 parts of zinc oxide, 12-16 parts of magnesium-aluminum hydrotalcite, 10-18 parts of a plasticizer, 1-3 parts of a crosslinking aid, 1-3 parts of calcium stearate, 1-3 parts of an anti-aging agent and 1-3 parts of a silane coupling agent. The anti-aging agent is a mixture of an anti-aging agent AN245 and an anti-aging agent MBZ. By adding the anti-aging agent, the aging resistance of the ethylene propylene diene monomer can be remarkably improved by inhibiting oxidation and delaying the aging process, a high-crosslinking-density three-dimensional network is formed through the peroxide vulcanizing agent, breakage of molecular chains at high temperature is reduced, thermal aging is delayed, and the ethylene propylene diene monomer sealing strip with excellent aging resistance is prepared.

The invention discloses a high-temperature-resistant ethylene-tetrafluoroethylene copolymer as well as a preparation method and application thereof. The copolymer comprises the following raw materials: 10-30 parts of ethylene; 60 to 80 parts of tetrafluoroethylene; and 6 to 30 parts of 4-(trifluoromethyl) styrene. The preparation method comprises the following steps: adding a perfluorocarbon solvent and 4-(trifluoromethyl) styrene into a reaction kettle, stirring, and keeping the temperature at 30-50 DEG C; and adding a mixed gas of ethylene and tetrafluoroethylene and a perfluorobutyryl peroxide compound in a molar ratio of 1: 1 into the system to initiate a polymerization reaction under the reaction pressure of 1-4MPa for 15-30 minutes. The application comprises the following steps: adding the prepared high-temperature-resistant ethylene-tetrafluoroethylene copolymer into an extruder; extruding at the temperature of 260-300 DEG C to coat the outer surface of the electric wire or the cable; and carrying out annealing treatment on the wire or the cable coated with the high-temperature-resistant ethylene-tetrafluoroethylene copolymer at the annealing temperature of 120-180 DEG C for 12-24 hours. The preparation method of the high-temperature-resistant ethylene-tetrafluoroethylene copolymer is simple, low in cost and convenient for large-scale production and application.

The invention belongs to the technical field of biosensing instant detection, and relates to DAAO / HRP-MAF-7 hydrogel as well as a preparation method and application thereof. The hydrogel is formed by immobilizing horse radish peroxidase (HRP) and D-amino acid oxidase (DAAO) in a hydrophilic metal organic framework MAF-7, and then loading the prepared DAAO / HRP-MAF-7 biological composite material and a color developing agent TMB in PEG-DA hydrogel together. The DAAO / HRP-MAF-7 hydrogel can be used as a biosensor to be applied to detection of D-amino acid.

The invention relates to a method for degrading nitrobenzene pollutants by using a humus-synergistic enhanced Fenton system, which comprises the following steps: adding a peroxide oxidant, a Fe (III) catalyst and a water-soluble organic reducing agent with Fe (III) reducing capacity into soil containing nitrobenzene pollutants, uniformly mixing to form a Fenton system, adding humus, and uniformly mixing to form the nitrobenzene pollutants. Mixing and reacting to obtain the soil for degrading the nitrobenzene pollutants. Compared with the existing Fenton technology, the method has the advantages that the overall catalytic efficiency can be improved, the initial pH does not need to be adjusted, and the method is green, safe and environmentally friendly.

A process to form a crosslinked composition, the process comprising thermally treating a composition that comprises the following components: a) at least one olefin / silane interpolymer comprising at least one Si—H group, b) at least one peroxide, c) at least one crosslinking coagent, and d) an additive component comprising a filler and a plasticizer. A composition that comprises the following components: a) at least one olefin / silane interpolymer comprising at least one Si—H group, b) at least one peroxide, c) at least one crosslinking coagent, and d) an additive component comprising a filler and a plasticizer.