1764 results about "Peroxide" patented technology

The invention relates to a bioelectrochemical sensor used for detecting hydrogen peroxide and a manufacturing method of the bioelectrochemical sensor. The novel bioelectrochemical sensor is a sensor with a three-electrode system, wherein the counter electrode is a platinum electrode, the reference electrode is saturated calomel electrode and the working electrode is gold electrode. The sensor is based on orientation combination of a polypeptide horse radish peroxidase with characteristic sequence, the promotion effect of the polypeptide horse radish peroxidase on the activity of the enzyme and the characteristic of high sensitivity of electrochemical detection methods. The sensitivity of hydrogen peroxide sensors is effectively improved and satisfactory results are obtained.

The invention provides a preparation method of medicinal liquor and application of the medicinal liquor in preparation of antioxidant and anti-aging products, and relates to the technical field of medicinal preparations. The preparation method comprises the following steps: (1) crushing; (2) extracting; (3) standing and separating; and (4) freezing and filtering to obtain the medicinal liquor. The medicinal liquor is obtained by extracting the traditional Chinese medicine components through the steps of crushing in batches, mixing and extracting, standing, freezing and separating the supernate and the suspension in different separation modes, and the medicinal liquor can better improve the space exploration capability of a mouse aged due to D-galactose, can reduce malondialdehyde MDA, and can improve the immunity of the mouse. The activity of superoxide dismutase (SOD) and glutathione peroxidase (GSH-Px) is improved, and the obvious anti-oxidation and anti-aging effects are achieved.

The invention discloses a copper-based nano-enzyme, a preparation method thereof and application of the copper-based nano-enzyme in organophosphorus pesticide detection, and belongs to the technical field of pesticide residue detection. The copper-based nano-enzyme has a netted-like structure, a high specific surface area and many active sites, the valence state of a copper element is zero-valence Cu, Cu < + > and Cu < 2 + >, the copper-based nano-enzyme has high peroxidase-like activity and laccase-like activity, the detection limit is low, and glyphosate can be sensitively detected; and glyphosate, glufosinate-ammonium and isazofos can be well distinguished from six organophosphorus pesticides with medium concentration, and the method has high selectivity. The nano enzyme provided by the invention is prepared from ammonium citrate and copper nitrate in an N, N-dimethylformamide (DMF) solution by using a solvothermal method; the preparation process of the nano enzyme is simple.

The invention discloses a metal-doped carbon quantum dot as well as preparation and application of the metal-doped carbon quantum dot in a nano antibacterial agent, citric acid, urea and tea polyphenol are taken as precursors, metal salt is added, carbon dot synthesis and metal ion doping are synchronously completed in one step through a hydrothermal method, and the metal-doped carbon quantum dot is prepared; the surfaces of the metal-doped carbon quantum dots are negatively charged, and the metal-doped carbon quantum dots have peroxidase-like activity and catalase-like activity at the same time; the metal ions adopt any one of Fe < 3 + >, Cu < 2 + > and Ce < 3 + >; the metal-doped carbon quantum dots are in a sphere-like shape. The metal-doped carbon quantum dots prepared by the preparation method disclosed by the invention have peroxidase-like activity and catalase-like activity at the same time through precise doping of metal ions, and the two activities have a synergistic effect in an oral periodontitis microenvironment, so that a good antibacterial effect is achieved.

The preparation method comprises the following steps: synthesizing gold nanostars (GNS) by using a seed growth method, coating mesoporous cerium dioxide (mCeO2) by using a template method, and loading a photosensitizer indocyanine green (ICG), so as to form a nano enzyme diagnosis and treatment system with chemical activity, photoactivity and photothermal effects. In the system, the gold nanostars have a good photo-thermal effect due to the multi-branched structure of the gold nanostars; on one hand, the mesoporous cerium dioxide coated on the outer layer has a chemical effect due to the nano-enzyme effect, and on the other hand, the mesoporous structure of the mesoporous cerium dioxide can better load the photosensitizer indocyanine green. All the components have good stability and biological safety, also have peroxidase simulation activity and a drug loading function, can improve the level of reactive oxygen species (ROS) in a tumor microenvironment and load photosensitizer drugs, and have an excellent anti-tumor effect and small side effects.

The invention relates to the technical field of electronic materials, in particular to a preparation method of low-halogen alkali-soluble photosensitive resin and solder resist ink. Comprising the following steps: adding amino resin, alcohol olefin and a catalyst A into a solvent, mixing, and carrying out an ether exchange reaction to obtain an initial etherified product; adding peroxide into the initial etherification product, and carrying out epoxidation reaction to obtain an epoxy resin intermediate; adding an olefine acid compound, a catalyst B and a polymerization inhibitor into the epoxy resin intermediate, and carrying out ring-opening esterification reaction to obtain an epoxy acrylate intermediate; and adding acid anhydride into the epoxy acrylate intermediate, and carrying out carboxylation reaction to obtain the low-halogen alkali-soluble photosensitive resin. The problem of high halogen content of the existing alkali-soluble photosensitive resin is solved, and the solder resist ink prepared from the alkali-soluble photosensitive resin has high sensitivity, high resolution, high heat resistance, high acid and alkali resistance and high electrical insulation property.

The invention discloses a preparation method and application of a zinc-bromine flow battery positive electrode material, and belongs to the field of zinc-bromine flow batteries. The preparation method comprises the following steps: dissolving aniline and a dithio compound in an acidic ice bath, dropwise adding a peroxy strong oxidant to generate a polyaniline-disulfide bond copolymer, dialyzing, and freeze-drying to obtain powder; then heating soluble silver salt, a reducing agent, a hydrophilic dispersing agent and an organic sulfydryl silane coupling agent to prepare functionalized nano-silver particles; the powder and nano-silver particles are dispersed in N-methyl pyrrolidone for ultrasonic treatment, and dynamic self-repairing coating slurry is prepared; and performing acid pretreatment on the carbon fiber paper, and performing electrochemical deposition on the slurry to prepare the zinc-bromine battery positive electrode material. According to the zinc-bromine battery positive electrode material, the coulombic efficiency and the voltage efficiency of a zinc-bromine flow battery are remarkably improved and the cycle life of the zinc-bromine flow battery is remarkably prolonged through methods of dynamic covalent bonds, nano-silver catalysis, a hierarchical pore structure, carbon fiber pretreatment and the like, and the zinc-bromine flow battery positive electrode material has chemical stability, efficient bromine adsorption capacity and excellent catalytic activity.

The invention provides a colorimetric / fluorescent dual-mode sensor, a preparation method of the colorimetric / fluorescent dual-mode sensor and application of the colorimetric / fluorescent dual-mode sensor in histamine detection. The colorimetric / fluorescent dual-mode sensor comprises a horseradish peroxidase-loaded metal organic framework (HRP-AIE-MOF), hydrogen peroxide and a chromogenic substrate o-phenylenediamine (OPD), horse radish peroxidase (HRP) in the HRP-coated AIE-MOF can oxidize colorless OPD into yellow 2, 3-diaminophenazine (DAP), an ultraviolet absorption peak is generated at 425 nm, a strong fluorescence emission peak is generated at 555 nm, the HRP-coated AIE-MOF has a strong fluorescence emission peak at 450 nm, and the HRP-coated AIE-MOF and a fluorescence signal of the DAP can form a ratio fluorescence sensor. According to the invention, the excellent catalytic ability of natural enzyme and the luminescence characteristic of AIE-MOF are integrated in one system, and high-sensitivity histamine detection is realized.

The invention discloses a high-viscosity silicone rubber composite material and a preparation method thereof.The preparation method comprises the steps that a silicon-based polymerization solution and a silane raw material are mixed on the basis of a rotary dropper, and a silicon-based liquid compound containing a spiral laminated layer is obtained; the preparation method comprises the following steps: dispersing a nano-filler into a silicon-based liquid compound for synthesis treatment, carrying out crosslinking treatment on the obtained primary compound and peroxide to obtain a crosslinked compound, mixing the crosslinked compound with a fiber compound, and carrying out plasma treatment to obtain a fiber-reinforced compound; performing secondary cross-linking treatment on the fiber reinforced compound and a peroxide silicone oil solution in a vacuum high-temperature environment to obtain a secondary cross-linked compound; and immersing the secondary cross-linked compound into a turbid liquid containing nano aluminum oxide, and carrying out heating treatment to obtain a finished product of the high-viscosity silicone rubber composite material. According to the invention, the problem of compatibility between the filler and the matrix material is solved, the processability is improved, and the performance of the material in multiple aspects such as high temperature resistance and aging resistance is further improved.

The invention relates to the technical field of rubber compounds, and particularly discloses a bio-based and circulating material synergistically modified EPDM rubber compound and a preparation method thereof. The invention discloses a bio-based and circulating material synergistically modified EPDM rubber compound. The rubber compound is prepared from the following components: 100 parts of bio-based EPDM rubber, 100 to 130 parts of a reinforcing agent, 40 to 60 parts of paraffin oil, 5 to 7 parts of magnesium oxide, 0.5 to 1.5 parts of stearic acid, 6 to 8 parts of BIPB-40 peroxide, 2 to 5 parts of a Si-69 silane coupling agent, 1 to 3 parts of a dispersing agent and 1 to 3 parts of an assistant crosslinking agent, the reinforcing agent is composed of fast extruding furnace black N550, rice hull ash white carbon black and thermal cracking carbon black; and the assistant cross-linking agent is prepared from diallyl terephthalate and triallyl isocyanurate. The rubber compound prepared by utilizing the technical scheme provided by the invention can meet and maintain the mechanical property requirements, and meanwhile, carbon emission of the product in the whole life cycle is reduced from the aspects of formula and process.

The invention relates to the technical field of peroxide crosslinked polyethylene pipe manufacturing, and discloses a peroxide crosslinked polyethylene pipe manufacturing system and a crosslinking furnace thereof.The crosslinking furnace comprises a first furnace body, a second furnace body and a third furnace body, the first furnace body is provided with a first crosslinking cavity with a front opening and a rear opening, and a pipe can penetrate through the first crosslinking cavity; the first infrared emitter is arranged on the first furnace body, and infrared rays of the first infrared emitter are emitted into the first cross-linking cavity; the second furnace body is provided with a second cross-linking cavity with front and back openings, the second cross-linking cavity can allow the pipe to penetrate through, and the first furnace body and the second furnace body are sequentially arranged in the movement direction of the pipe; the second infrared emitter is arranged on the second furnace body, infrared rays of the second infrared emitter enter the second cross-linking cavity, and the wavelength of the infrared rays emitted by the second infrared emitter is smaller than that of the infrared rays emitted by the first infrared emitter. The inner layer and the outer layer of the pipe can be synchronously heated through infrared rays with different wavelengths, so that the cross-linking reaction of the pipe is more uniform, and the quality of the pipe is improved.

The invention discloses application of iron ruthenium nano-enzyme in preparation of nucleic acid detection products, and belongs to the technical field of biological detection and nano-materials. The RIN has stable peroxidase-like (POD) activity, and can catalyze a chromogenic reaction between 3, 3 ', 5, 5'-tetramethyl benzidine (TMB) and hydrogen peroxide (H2O2). The catalytic activity of the nano-enzyme can be selectively inhibited by pyrophosphate (PPi) generated in a nucleic acid amplification reaction, so that visual colorimetric analysis on whether target nucleic acid exists or not is realized. In combination with a polymerase chain reaction (PCR) system, the invention constructs a new nucleic acid detection strategy which does not need fluorescence labeling, is simple and convenient to operate and has high sensitivity. Through verification, the system can be widely applied to rapid on-site screening and visual interpretation of related nucleic acid of drug-resistant pathogens (such as ESKAPE flora) and the like, and has a good application prospect.

The invention discloses peroxidase and application thereof, and relates to the field of bioengineering. The peroxidase POD-8 provided by the invention has very good enzyme activity for oxidizing phenol substrates, especially has the highest enzyme activity for 2, 6-DMP, has very good persistence, and can keep stable enzyme activity within 10 minutes; the resistance to various metal ions is relatively high, and the enzyme activity of 90% or above can still be kept in the presence of various metal ions with various concentrations; the POD-8 has a strong decolorizing capability on a plurality of dyes, especially has a decolorizing efficiency of about 25% on Congo red and amino black 10B in 24 h, and has a good application prospect in the aspect of dye wastewater treatment.

The invention relates to the technical field of sealing strips, in particular to an anti-aging ethylene propylene diene monomer rubber sealing strip and a preparation method thereof. Comprising the following components in parts by weight: 150-180 parts of ethylene propylene diene monomer, 60-90 parts of carbon black, 8-12 parts of white carbon black, 3-8 parts of a peroxide vulcanizing agent, 6-12 parts of zinc oxide, 12-16 parts of magnesium-aluminum hydrotalcite, 10-18 parts of a plasticizer, 1-3 parts of a crosslinking aid, 1-3 parts of calcium stearate, 1-3 parts of an anti-aging agent and 1-3 parts of a silane coupling agent. The anti-aging agent is a mixture of an anti-aging agent AN245 and an anti-aging agent MBZ. By adding the anti-aging agent, the aging resistance of the ethylene propylene diene monomer can be remarkably improved by inhibiting oxidation and delaying the aging process, a high-crosslinking-density three-dimensional network is formed through the peroxide vulcanizing agent, breakage of molecular chains at high temperature is reduced, thermal aging is delayed, and the ethylene propylene diene monomer sealing strip with excellent aging resistance is prepared.

The invention relates to a method for degrading nitrobenzene pollutants by using a humus-synergistic enhanced Fenton system, which comprises the following steps: adding a peroxide oxidant, a Fe (III) catalyst and a water-soluble organic reducing agent with Fe (III) reducing capacity into soil containing nitrobenzene pollutants, uniformly mixing to form a Fenton system, adding humus, and uniformly mixing to form the nitrobenzene pollutants. Mixing and reacting to obtain the soil for degrading the nitrobenzene pollutants. Compared with the existing Fenton technology, the method has the advantages that the overall catalytic efficiency can be improved, the initial pH does not need to be adjusted, and the method is green, safe and environmentally friendly.

An adsorbent composition comprising: a plurality of particles of an acid-activated clay with a predetermined particle size. Each particle may have a surface comprising metal oxides or metal hydroxides and each particle may have a surface modified by coupling the metal oxides to ligands comprising amino-silane coupling agents configured to adsorb impurities. Each amino-silane coupling agents may comprise an alkoxysilane group and an amine group. The alkoxysilane group may couple to the metal oxide or metal peroxide of each particle. The adsorbent composition may comprise the amino-silane coupling agent and the acid-activated clay with a wight ratio between 2:2 and 3:1 (the acid-activated clay: the amino-silane coupling agent). The acid-activated clay may comprise a plurality of pore with a predetermined diameter formed between particles.

A continuous process for preparing a multimodal polyolefin composition made from or containing one or more antioxidants, including the steps of: preparing a multimodal polyolefin in form of a polyolefin powder, having a mass-median-diameter D50 in the range from 300 μm to 2500 μm, in a series of polymerization reactors; mixing the polyolefin powder and an organic peroxide without melting the polyolefin powder; melting and homogenizing the mixture within an extruder device; adding one or more antioxidants to the molten polyolefin composition; homogenizing the combination of molten polyolefin composition and antioxidant, thereby forming an antioxidant equipped molten polyolefin composition; and pelletizing the antioxidant equipped molten polyolefin composition.

The purpose of the present invention is therefore to provide a thermally conductive composite tape which is in a form of sheet and, therefore, easy to handle, excellent in strength and electrical insulation, easily stick to an element or heat release-member, and shows strong adhesion to the heat-release member. The present invention provides a thermally conductive composite comprising a first thermally conductive adhesive layer, a reinforcing layer (A) layered on one surface of the first thermally conductive adhesive layer, and a second thermally conductive adhesive layer layered on a free surface of the reinforcing layer (A), wherein the first and second thermally conductive adhesive layers comprise, independently of each other, a silicone composition comprising the following components (a) to (e): 100 parts by mass of (a) linear or branched organopolysiloxane, 1,000 to 3,000 parts by mass of (b) thermally conductive filler, 100 to 500 parts by mass of (c) silicone resin, 1 to 10 parts by mass of (d) organohydrogenpolysiloxane, and 0.5 to 5 parts by mass of (e) organic peroxide.

The invention relates to the technical field of high polymer materials, and discloses a conductive shielding material for a high-voltage cable. Comprising the following components in parts by weight: 40 to 70 parts of main body polyolefin resin, 10 to 30 parts of ethylene-vinyl acetate copolymer, 5 to 15 parts of maleic anhydride grafted polyolefin, 20 to 40 parts of surface modified conductive carbon black, 0.5 to 2 parts of peroxide cross-linking agent, 0.5 to 3 parts of functionalized silane coupling agent, 0.1 to 1 part of processing aid and 0.1 to 1 part of antioxidant, the surface modified conductive carbon black is high-structure conductive carbon black which is subjected to plasma oxidation treatment, solution graft polymerization and surface coupling agent pretreatment. The conductive carbon black is subjected to multi-step surface modification including plasma oxidation, solution graft polymerization and surface coupling agent pretreatment, and the in-situ chemical bonding effect of maleic anhydride grafted polyolefin is matched, so that the agglomeration problem of the conductive carbon black caused by high surface energy is effectively solved.

The invention belongs to the technical field of graphene and functional rubber composite materials, and particularly relates to a simplified preparation process of high-tear-strength graphene modified natural rubber with an interpenetrating double-crosslinking network structure constructed on the basis of double vulcanizing agents. Sulfur quickly forms a carbon-sulfur bond cross-linked network-C-Sx-C-with high cross-linking density in the natural rubber composite material to form a mechanical bearing skeleton between natural rubber main chains, so that the natural rubber composite material is endowed with high tear strength and fatigue resistance; the vulcanization rate of peroxide is relatively slow, the peroxide is slowly decomposed in a relatively low temperature region to generate free radicals, and a stable-C-C-crosslinking bond secondary crosslinking network between tail end chain segments of a carbon-sulfur bond main network is constructed outside a sulfur vulcanization skeleton network, so that the three-dimensional structural integrity of the vulcanization network is improved, and the loss modulus of rubber is reduced; and thus, heat generated during dynamic compression of the rubber is reduced. The tear strength of the natural rubber vulcanized rubber is effectively improved based on the synergy of nanofiller enhancement and an interpenetrating double-crosslinking network structure.

The application provides a crosslinked polyethylene insulating material with intrinsic self-repairing and recyclable characteristics, a preparation method and application thereof, and relates to the technical field of cable materials.The crosslinked polyethylene insulating material with intrinsic self-repairing and recyclable characteristics is prepared from the following components in parts by weight: 99.7 parts by weight of low-density polyethylene, 1.0-2.6 parts by weight of peroxide, 0.1-0.5 parts by weight of antioxidant, 5-20 parts by weight of maleimide monomer, 0.35-0.7 parts by weight of catalyst, 0.5-3.0 parts by weight of ligand and 0.5-3.0 parts by weight of furan-based small molecule.The low-density polyethylene is functionally modified through catalytic amination reaction, so that the chain breaking and crosslinking in the modification process are avoided, and the mechanical properties, insulating properties and dielectric properties of the crosslinked polyethylene are enhanced through the post-absorption of the introduced peroxide.Meanwhile, the dynamic reversible Diels-Alder reaction introduced by the post-absorption of the furan-based small molecule enables the polyethylene insulating material to have good intrinsic self-repairing effect on mechanical damage and electrical damage.

The invention relates to the technical field of mineral materials and nano-enzyme catalysis, in particular to an iron-containing layered silicate mineral nano-enzyme as well as a preparation method and application thereof. The preparation method comprises the following steps: carrying out ball milling on the iron-containing layered silicate mineral, carrying out centrifugal washing, and drying to obtain the iron-containing layered silicate mineral nano-enzyme. According to the method, silicate minerals with a layered structure and rich iron content are adopted as raw materials, the ball-milled layered silicate mineral nano-enzyme is successfully prepared through a ball milling method, the crystallinity of the minerals is reduced, the surface acidity of the minerals is improved, and low-spin iron is generated, so that the affinity of the ball-milled minerals to H2O2 is enhanced; h2O2 is catalyzed to generate singlet oxygen and superoxide free radicals, so that the peroxidase-like activity of the ball-milled minerals is improved. The enzyme-like activity is improved by 10 times, high catalytic activity can still be kept under the neutral condition, and the method can be used for colorimetric sensing and antibacterial application of small biological molecules such as glucose, hydrogen peroxide and glutathione.

The invention discloses a method for detecting organophosphorus pesticides through a colorimetric sensor array, and relates to the technical field of organophosphorus pesticide detection and separation. The detection effect is improved; comprising the following steps: synthesizing a ZrMOF (at) Pt (at) ZrMOF composite material with a hierarchical structure; catalyzing an enzymatic reaction between a chromogenic substrate and hydrogen peroxide by using the composite material; and an organophosphorus pesticide identification mode is constructed through multi-channel colorimetric signal change. The ZrMOF (at) Pt (at) ZrMOF composite material with a three-layer structure (inner-layer ZrMOF, middle-layer PtNPs and outer-layer ZrMOF) is used as a sensing element, the inner-layer ZrMOF provides a larger anchoring surface area for PtNPs and reduces aggregation, and the outer-layer MOF further stabilizes PtNPs and promotes charge transfer in a catalytic reaction process, so that the composite material shows higher peroxidase-like activity, and the sensing element has a good application prospect. The affinity to a substrate is good.

The invention discloses a cross-linked polyethylene insulating material for middle and high voltage cables and a preparation method of the cross-linked polyethylene insulating material. Comprising the following raw material components in parts by weight: 100 parts of a polyethylene base material, 1.0-2.5 parts of a peroxide cross-linking agent, 0.05-0.5 part of an anti-scorching agent, 0.1-5.0 parts of a water tree resistant additive, 0.1-1.0 part of a main antioxidant, 0.1-1.0 part of an auxiliary antioxidant, 0-2.0 parts of a processing aid and 0-0.5 part of a metal deactivator. The cross-linked polyethylene insulating material for the middle-high voltage cable is suitable for manufacturing a power cable insulating layer with the rated voltage of 10 kV or above. And the method is particularly suitable for application scenes with high requirements on processing stability, long-term reliability and energy efficiency.

The invention relates to the technical field of electromagnetic shielding materials, in particular to an electromagnetic shielding gap material. The electromagnetic shielding gap material comprises the following raw materials in parts by mass: 100 parts of methyl vinyl silicone rubber, 15-16 parts of graphene nanosheets, 3-5 parts of carbon nanotubes, 4-6 parts of nano Fe3O4, 3-5 parts of a coupling agent, 2-5 parts of hydroxyl silicone oil, 1 part of zinc stearate, 0.5-1 part of peroxide and 10-15 parts of diatomite. According to the invention, conductive fillers such as expensive silver powder and the like are not needed, the electromagnetic shielding effect and the conductivity of the rubber electromagnetic shielding gap material are improved in a mode of compounding the graphene nanosheets, the carbon nanotubes, the nano Fe3O4 and the diatomite, and meanwhile, the mechanical property of the rubber material is prevented from being reduced. The electromagnetic shielding gap material disclosed by the invention has relatively good shielding effectiveness in a high frequency band (1-18GHz waveband), and has important practical application significance.

The present invention relates to a method for co - processing and resource utilization of overhaul slag, fly ash, and desulfurized gypsum. The method comprises the following steps: Step 1) dehydrate and then dry the desulfurized gypsum, add calcium carbonate to the dried desulfurized gypsum, and collect SO3 gas; Step 2) carry out an autoclave reaction on the SO3 gas obtained in Step 1, water, and fly ash. After solid - liquid separation, silicon dioxide and an aluminum sulfate solution are obtained; Step 3) crush and ball - mill the overhaul slag, and carry out first - stage roasting with a peroxide at high temperature to obtain clinker 1; leach out sodium fluoride from clinker 1 by water immersion, and then add it to the aluminum sulfate for second - stage roasting to obtain clinker 2; Step 4) mix clinker 2 with water for leaching to obtain a filtrate and a filter residue; Step 5) calcine calcium oxide and the filter residue to obtain calcium aluminate. The beneficial effect of the present invention aims to synergistically utilize the sodium, aluminum, fluorine, and lithium elements, the aluminum and silicon elements of fly ash, and the calcium element in desulfurized gypsum to achieve the purpose of resource conversion.

The invention discloses a wear-resistant composite rubber packing sealing material for an oil pumping unit and a preparation method, and the sealing material is prepared from the following raw materials in parts by weight: a main body rubber material, which comprises 70-90 parts by weight of nitrile rubber and 10-30 parts by weight of polyurethane rubber, based on the total weight of 100 parts; 3-5 parts of zinc oxide; 2-3 parts of stearic acid; 30 to 60 parts of carbon black; 5 to 15 parts of graphite; 20-40 parts of an inorganic nano wear-resistant filler; 3-6 parts of an active agent; 5-10 parts of a softening agent; 2-3 parts of an anti-aging agent; 2-6 parts of an effective vulcanization cross-linking agent and 2-5 parts of a peroxide cross-linking agent; wherein the effective vulcanization cross-linking agent is a mixture of an accelerant and sulfur, and the peroxide cross-linking agent is dicumyl peroxide. According to the wear-resistant composite rubber packing sealing material for the oil pumping unit provided by the invention, by balancing the tensile strength, tearing strength, oil resistance and wear resistance of the material, the comprehensive performance of the material is remarkably improved, and the service life of the material is prolonged.

The invention discloses a high-whiteness EVA chemical foaming sole material and a preparation method thereof, and belongs to the technical field of footwear products. The EVA chemical foaming sole material is formed by chemical foaming of an EVA composite raw material. The EVA composite raw materials mainly comprise 50 to 70 parts of EVA, 20 to 40 parts of an olefin thermoplastic elastomer, 0.4 to 0.7 part of a peroxide cross-linking agent, 2 to 4 parts of an AC foaming agent, 1 to 2 parts of zinc oxide, 0.3 to 0.8 part of 6-hydroxy-1, 2, 3, 4-tetrahydroquinoline, 0.5 to 1 part of nano zinc carbonate and 0.5 to 1 part of pentaerythritol tetrastearate. The whitening effect of the sole material can be realized on the premise of protecting the EVA foaming-crosslinking structure; therefore, the attractiveness of the product is improved, the durability is better, the mechanical properties and other properties of the EVA foamed sole are not influenced, and the high-quality requirements of elasticity, pressure resistance, comfort and the like of sports shoes can be met.

The invention provides a synthesis process of tert-amyl peroxy-2-ethylhexyl carbonate, and relates to the technical field of organic synthesis.The synthesis process comprises the following steps that S1, caustic soda liquid and water are pumped into a reaction kettle; s2, tert-amyl hydroperoxide is added into the reaction kettle for a salt forming reaction; s3, after the salt forming reaction is finished, adding a catalyst, dropwise adding isooctyl chloroformate, and carrying out condensation reaction to obtain a crude product of tert-amyl 2-ethylhexyl peroxide; and S4, carrying out alkali washing and water washing on the peroxide 2-ethylhexyl tert-amyl carbonate crude product to obtain a finished product. The catalyst is a tree-shaped structure catalyst of a silica gel carrier, and has the advantages of high conversion rate and high yield.

The invention provides a quality detection device and method for edible oil production. The method comprises the following steps: collecting spectral data and peroxide value of each edible oil sample; extracting a frequency doubling absorption peak during stretching vibration of each chemical bond from each spectral data, and performing cross validation on the oxidation process of the edible oil according to all the frequency doubling absorption peaks and all the peroxide values to obtain a plurality of chemical characteristic variables related to oxidation of the edible oil; establishing an oxidation kinetic model of the edible oil according to all the chemical characteristic variables, and predicting the optimal oxygen flow rate of oxidation of the edible oil through the oxidation kinetic model; performing oxidation stability detection on the edible oil, and when the optimal oxygen flow rate is greater than the oxygen flow rate in the oxidation stability detection, correcting the oxidation stability detection result according to the optimal oxygen flow rate to obtain the oxidation induction time of the edible oil. By adopting the scheme of the invention, the detection error caused by the mismatching of the oxygen flow rate in the oxidation stability detection can be eliminated.