528 results about "Epoxy acrylate" patented technology

The invention relates to the field of electric heating materials, and provides a graphene-based heating coating and a preparation method thereof. The coating is prepared from functionalized graphene, a surface modified bismuth telluride nanobelt, polyaniline, bisphenol A epoxy acrylate, polyurethane acrylate, a dispersing agent, a flatting agent, a silane coupling agent, a defoaming agent and a propylene glycol methyl ether acetate / N-methyl pyrrolidone mixed solvent. The functionalized graphene is obtained by modifying a hyperbranched polyolefin-acryloyl-POSS copolymer, and carrying out ultrasonic stripping, centrifugal separation, gradient washing and vacuum drying; the surface-modified bismuth telluride nanobelt is modified by an amino silane coupling agent, so that the interfacial compatibility is improved. The preparation method comprises the steps of solvent premixing, nanofiller dispersion, ultrasonic homogenization, coupling agent modification, ultraviolet curing and thermocuring. The heating coating provided by the invention has high conductivity, excellent thermal stability and adhesive force, and can be widely applied to heating electric appliances and intelligent temperature control equipment.

The invention provides a gradient crosslinking process of photosensitive resin for photocuring 3D printing, and relates to the technical field of photocuring 3D printing materials. The gradient crosslinking process of the photosensitive resin for photocuring 3D printing comprises the following steps: S1, based on double-initiator system design, adopting molecular dynamics simulation screening, respectively adding a 405nm sensitive type TPO-L initiator and a 365nm sensitive type I TX initiator into an epoxy acrylate prepolymer, and verifying initiation energy barrier matching through quantum chemistry calculation, and generating a pre-initiation gradient resin formula. Through molecular dynamics simulation, initiator combinations are screened, energy barrier matching is verified, the ratio of dual-wavelength sensitive initiators is optimized, and accurate triggering of surface layer and deep layer cross-linking reaction is ensured. And a three-roller grinding and dispersing process is combined with ultrasonic oscillation to eliminate nanoparticle aggregation, so that the mechanical uniformity and light scattering effect of a resin system are improved.

The invention relates to a heat-resistant, water-resistant and flame-retardant backboard composite material as well as a preparation method and application thereof. The heat-resistant, water-resistant and flame-retardant backboard composite material comprises a phosphorus-containing epoxy acrylate oligomer, common epoxy resin, toughened epoxy resin, phosphorus-containing epoxy resin, a filler, an additive flame retardant, a dicyandiamide curing agent, an accelerant, nitrogen-containing phenolic resin, a latent curing agent, a UV absorbent and an antioxidant. The phosphorus content in the material is improved by synthesizing the phosphorus-containing epoxy acrylate oligomer, so that the flame retardant property of the product is improved, and the problem of low flame retardant efficiency caused by direct addition of a phosphorus flame retardant is solved.

The invention relates to the technical field of electronic materials, in particular to a preparation method of low-halogen alkali-soluble photosensitive resin and solder resist ink. Comprising the following steps: adding amino resin, alcohol olefin and a catalyst A into a solvent, mixing, and carrying out an ether exchange reaction to obtain an initial etherified product; adding peroxide into the initial etherification product, and carrying out epoxidation reaction to obtain an epoxy resin intermediate; adding an olefine acid compound, a catalyst B and a polymerization inhibitor into the epoxy resin intermediate, and carrying out ring-opening esterification reaction to obtain an epoxy acrylate intermediate; and adding acid anhydride into the epoxy acrylate intermediate, and carrying out carboxylation reaction to obtain the low-halogen alkali-soluble photosensitive resin. The problem of high halogen content of the existing alkali-soluble photosensitive resin is solved, and the solder resist ink prepared from the alkali-soluble photosensitive resin has high sensitivity, high resolution, high heat resistance, high acid and alkali resistance and high electrical insulation property.

The invention discloses high-temperature photoetching silver paste suitable for narrow line width and line spacing, which is prepared from the following components in parts by weight: 20-40 parts of photosensitive resin, 20-40 parts of ethoxylated 1, 2, 4-trimethyl-1, 3-pentanediol monoisobutyrate, 20-30 parts of a solvent and 1- The invention relates to a photocurable conductive coating which is prepared from the following components in parts by weight: 10 to 30 parts of 1, 6-hexanediol diacrylate, 5 to 15 parts of a photoinitiator, 0.5 to 1 part of an antioxidant, 0.5 to 1 part of 2-hydroxy-4-n-octyloxybenzophenone, 0.5 to 1.5 parts of a defoaming agent, 0.5 to 1.5 parts of a flatting agent, 0.5 to 1.5 parts of a dispersing agent, 5 to 20 parts of an organic solvent, 60 to 85 parts of conductive filler and 0.5 to 5 parts of glass powder. The selected photosensitive resin is formed by mixing alkali-soluble epoxy acrylic resin and alkali-soluble polyurethane acrylic resin according to the weight part ratio of 10: (2-6). According to the high-temperature photoetching silver paste suitable for the narrow line width and line distance, the five steps of printing, baking, photoetching, developing and sintering are achieved, patterns which cannot be manufactured in a traditional printing mode can be manufactured, and a high-density circuit with the line width and the line distance reaching 20 micrometers / 20 micrometers can be manufactured.

The invention relates to the technical field of protective glue, in particular to extreme high and low temperature impact resistant UV (ultraviolet) photocuring electronic protective glue which is prepared from the following raw materials in parts by weight: 30-50 parts of synergistically modified epoxy-urethane acrylate oligomer, 20-35 parts of composite active monomer, 1.5-5 parts of composite photoinitiator and 10-20 parts of core-shell structure inorganic composite filler, 0.6 to 2.2 parts of a silane coupling agent, 0.12 to 1.1 parts of an antioxidant and 0.11 to 1 part of a leveling agent; the preparation method of the synergistically modified epoxy-urethane acrylate oligomer comprises the following steps: reacting resin acid modified epoxy resin with phosphoric acid di (hydroxyethyl acrylate) ester at 80-90 DEG C, and introducing a phosphate group to obtain a phosphate modified epoxy acrylate intermediate; the protection glue unifies rigidity, flexibility and flame retardance on the molecular level through the cooperation of the hybrid oligomer and the core-shell filler, realizes high heat conductivity, strong adhesion and extremely low internal stress, and has extreme temperature impact resistance, long-term damp-heat aging resistance and high-reliability protection performance.

The present disclosure belongs to the field of UV glues, and refers to a high-reliability fast-curing UV glue for outer layer protection of a power battery, and a preparation method and application thereof. The high-reliability fast-curing UV glue contains an acrylate oligomer, a monofunctional acrylate monomer, a difunctional acrylate monomer, a trifunctional acrylate monomer, an acidic functional group-containing acrylate monomer, a photoinitiator and an optional auxiliary agent, where the acrylate oligomer simultaneously contains a dibasic acid-modified bisphenol A epoxy acrylate, a tetrafunctional branched polyester acrylate and a polyurethane acrylate with the polyester diol as a main chain.

The invention discloses a low-temperature fast-curing two-component resin adhesive and a preparation method thereof, and belongs to the technical field of high polymer materials. The resin adhesive is formed by mixing a component A and a component B, the component A comprises epoxy-acrylate hybrid resin, a reactive diluent, a nano reinforcing filler and the like, and the component B comprises a modified aliphatic amine curing agent, a microcapsule low-temperature efficient accelerant, a Mannich base curing agent and the like. Through the synergistic effect of a quaternary curing system and in combination with the rigid-flexible balance design of the hybrid resin, rapid curing at low temperature is achieved, and high strength, high toughness and good storage stability are achieved. The resin adhesive is suitable for the fields of bonding of automobile parts, packaging of electronic elements, repairing of wind power blades, sealing of building structures and the like, and particularly solves the problems that a traditional resin adhesive is slow in low-temperature curing and insufficient in performance.

The invention discloses an HPVC power cable protection pipe and a preparation method thereof, and relates to the technical field of cable protection pipes. The HPVC power cable protection tube is at least prepared from the following raw materials in parts by weight: 100 parts of high-strength polyvinyl chloride, 35 to 45 parts of epoxy acrylate rubber, 5 to 8 parts of vinyl chloride-g-acrylate copolymer, 8 to 12 parts of epoxidized soybean oil, 3 to 5 parts of calcium-zinc composite stabilizer, 5 to 15 parts of modified hydrotalcite, 0.1 to 0.5 part of beta-diketone, 0.8 to 1.5 parts of calcium stearate and 10 to 20 parts of flame retardant. 12 to 15 parts of modified nano calcium carbonate, 5 to 8 parts of talcum powder, 0.6 to 1.2 parts of antioxidant, 1 to 2 parts of anti-aging agent 4010 and 0.5 to 1.5 parts of ultraviolet light absorber UV531; the modified hydrotalcite is obtained by adding a mixed solution of calcium nitrate and lanthanum nitrate, a sodium hydroxide solution and a sodium bicarbonate solution into a lauryl sodium sulfate solution, mixing and aging, and then carrying out a post-treatment process. The HPVC power cable protection tube prepared by the invention has relatively high strength, good mechanical properties, weather resistance and cold resistance, and long service life.

The invention discloses an aluminum substrate UV matt finish paint and a preparation process thereof, and relates to the technical field of paints.The aluminum substrate UV matt finish paint is prepared from, by mass, 10%-20% of modified polyurethane acrylate, 25%-32% of high-functionality aliphatic polyurethane acrylate, 18%-30% of special modified epoxy acrylate resin, 0.5%-2% of dispersing agent, 0.1%-0.5% of defoaming agent, 1%-3% of anti-settling powder and the balance water. The paint is prepared from the following components in percentage by weight: 10 to 15 percent of magnesium silicate mineral, 1 to 10 percent of matting powder, 0.2 to 1 percent of 1-hydroxycyclohexyl phenyl ketone, 0.5 to 3 percent of trimethylbenzoyl-diphenyl phosphine oxide, 1 to 3 percent of acrylate flatting agent, 0.2 to 1.2 percent of polyurea modified polyurethane rheological agent and 5 to 15 percent of trimethylolpropane triacrylate. According to the UV matte finishing paint disclosed by the invention, through compounding of ternary resin and enhancement of nano silicon dioxide, a rigid and tough cross-linked network is constructed, a paint film is free of cracks when being bent at 180 degrees, the adhesive force reaches grade 0, and a coating is resistant to acid and alkali etching liquid and free of corrosion by cooperating with a silane coupling agent and a light stabilization system, and the color difference is delta Elt after the UV matte finishing paint is subjected to high temperature of 260 DEG C; and 1.5, the anti-yellowing performance is excellent.

The invention discloses an energetic slurry toughening and photocuring 3D printing method, relates to a preparation method of energetic slurry, and aims to solve the problems that an existing energetic material is poor in mechanical property, poor in toughness and easy to crack; the particles are fast to settle in the light-cured resin, the stability is poor, and the printing precision is poor. The invention develops a photocuring high-energy resin for photopolymerization additive manufacturing. The composition contains a high-energy filler, an acrylate adhesive, whiskers and an inert plasticizer. The material has the characteristics of compatibility, printability and mechanical property, and the possibility of printing increasingly complicated high-energy articles is proved through experiments. The preparation method of the light-cured resin comprises the following steps: adding the low polymer bisphenol A epoxy acrylate and the six-functionality polyurethane acrylate; diluting monomers including 1, 6-hexanediol diacrylate and trimethylolpropane triacrylate; uniformly mixing an auxiliary agent, a thickening agent and a dispersing agent, and magnetically stirring for 30 minutes to obtain the light-cured resin. A preparation method of the energetic slurry comprises the following steps: mixing light-cured resin, whiskers, an inert plasticizer, energetic particles, a photoinitiator and a light absorber, and uniformly stirring to obtain the energetic slurry; after the energetic slurry is used for 3D printing, a sample piece is obtained, the yield reaches 95%-100%, the cost is low, preparation is easy, and the method can be applied to the field of energetic slurry 3D printing.

The invention relates to the technical field of UV coatings, in particular to a waterproof wear-resistant UV coating for a floor and a preparation method of the waterproof wear-resistant UV coating. The waterproof and wear-resistant UV coating for the floor is prepared from the following raw materials in parts by mass: 30 to 60 parts of polyurethane acrylate, 20 to 40 parts of fluorinated epoxy acrylate oligomer, 20 to 40 parts of pentaerythritol tetraacrylate, 1 to 5 parts of tetraethoxysilane, 15 to 25 parts of hollow glass beads, 1 to 3 parts of ammonia water, 1 to 2 parts of trifluoropropane trimethoxysilane and 1 to 2 parts of amino-terminated polyamidoamine. The coating is prepared from 1-3 parts of graphene oxide, 1-2 parts of a photoinitiator, 1-2 parts of polytetrafluoroethylene wax, 0.5-1.5 parts of a dispersing agent, 1-2 parts of a flatting agent and 1-2 parts of a defoaming agent. The waterproof coating is excellent in waterproof effect, high in adhesive strength and excellent in dimensional stability; when the coating is subjected to mechanical actions such as friction and impact, the surface of a coated object is comprehensively protected, the wear rate is remarkably reduced, and the wear resistance is improved.

The invention discloses a high-weather-resistance photocuring coating with radar infrared stealth and intelligent anti-counterfeiting functions and preparation, and relates to the technical field of special functional materials. According to the coating, stealth, anti-counterfeiting and extreme environment tolerance are realized through multi-component collaborative design: matrix resin is prepared by compounding organic fluorine modified epoxy acrylate and polyurethane acrylate, and trifluoro propyl trimethoxy silane and polyoxyethylene ether block copolymer are introduced, so that weather resistance is improved; the photo-initiation system contains a free radical / cation composite initiator and a low-temperature initiator, and supports wide-temperature-range curing. The functional filler comprises a core-shell complex and carbon nanotube / graphene composite powder, and uniform dispersion of the filler is realized through a gradient grinding process. The method is suitable for military equipment camouflage, aerospace protection and criminal investigation anti-counterfeiting, 800-1400 [mu] m thermal radiation matching, radar wave absorption and mobile phone camera readable encryption information are achieved, and an innovative solution is provided for high-end equipment protection and information safety.

The invention relates to the technical field of basalt scales, and discloses a modified basalt scale material. The invention discloses a modified basalt flake material, which comprises 70-85% of basalt flake, 5-8% of amino silane, 3-5% of nanometer titanium dioxide, 0.5-2% of self-repairing monomer, 3-5% of microcapsule material, 2-4% of environmental response material, 1-2% of nanometer silicon particle and 1-4% of chemical sensing molecule, and the invention also provides a preparation method of the modified basalt flake material. The preparation method comprises the following steps: S1, carrying out high-temperature melting treatment on basalt scales, wherein the melting temperature is 1350-1450 DEG C; through the composite coating of the microcapsule material and the epoxy acrylate, the coating can be automatically repaired after being damaged. Compared with a traditional coating self-repairing capability scheme, the material provided by the invention can quickly activate a repairing monomer when cracks occur, has a quick and continuous self-repairing function, and effectively avoids the problems that the coating repairing process is slow and the effect is short.

The invention discloses a two-component photoinduced energy storage diffuse reflection nano coating as well as a preparation method and application thereof, and belongs to the technical field of building materials. Comprising prime paint and surface paint, the prime paint comprises 45-55 parts of paint emulsion, 30-40 parts of titanium dioxide, 5-10 parts of precipitated barium sulphate powder, 5-10 parts of pearl powder, fumed silica, an anti-settling agent, a light stabilizer, a dispersing agent and a coalescing agent; the surface layer coating is prepared from 55 to 65 parts of coating emulsion, 20 to 30 parts of alkaline earth aluminate, 10 to 15 parts of hollow glass beads, 5 to 10 parts of pearl powder, an anti-settling agent, a light stabilizer, a dispersing agent and a coalescing agent; the coating emulsion comprises acrylic resin and epoxy acrylate; the coating disclosed by the invention has excellent photoinduced energy storage performance and a good diffuse reflection effect, and can meet illumination requirements in environments such as underground parking lots, underground commercial plazas, traffic tunnels, civil air defense projects or military underground facilities.

The invention belongs to the technical field of insulating materials, and particularly relates to a high-voltage-resistant wear-resistant insulating photocureable coating, a preparation method thereof and a power battery shell coating. The high-pressure-resistant wear-resistant insulating photocureable coating is formed by mixing sulfonated bisphenol A epoxy acrylate, modified polyurethane acrylate and a photoinitiator; the sulfonated bisphenol A epoxy acrylate is prepared by carrying out epoxy ring-opening reaction on bisphenol A epoxy resin and 2-acrylamide-2-methylpropanesulfonic acid under the catalytic action; and the modified polyurethane acrylate is bifunctional organic silicon grafted polyurethane acrylate. A coating for a power battery shell, which is formed by the high-voltage-resistant wear-resistant insulating photocureable coating disclosed by the invention, is excellent in insulating property, can meet the insulating requirement of the power battery shell under a 800V framework at the present stage, and in addition, the formed coating has excellent wear resistance and shows good application and popularization prospects.

The invention particularly relates to a UV-cured epoxy resin material for 3D printing and a preparation method of the UV-cured epoxy resin material. The epoxy resin material is prepared from the following raw materials in parts by weight: 60 to 65 parts of epoxy acrylate resin, 30 to 35 parts of epoxy resin, 2 to 5 parts of ANFs / graphene / MoS2 composite lubricant, 4 to 6 parts of flexibilizer, 3 to 5 parts of repairing agent, 3 to 5 parts of spiro orthoester, 1 to 3 parts of initiator, 0.6 to 1.5 parts of tetrahydrofuran acrylate and 0.1 to 1 part of rheology modifier. The UV-cured epoxy resin material for 3D printing obtained by the scheme has good toughness, impact resistance and wear resistance, and has good self-recovery capability and high long-term reliability under a heating condition for conditions such as slight scratches and cracks in 3D printing application.

The invention provides LED-UV (Light Emitting Diode-Ultraviolet) curing ink as well as a preparation method and application thereof, and the LED-UV curing ink is prepared from the following components in parts by weight: 30 to 50 parts of modified polyurethane acrylate resin, 15 to 30 parts of modified epoxy acrylate resin, 10 to 15 parts of amino resin, 15 to 30 parts of acrylate monomer, 6 to 10 parts of photoinitiator, 1 to 3 parts of adhesion promoter, 2 to 4 parts of coupling agent, 0.5 to 1 part of defoaming agent and 1 to 2 parts of flatting agent. The modified polyurethane acrylate resin is hydroxyl and / or carboxyl modified polyurethane acrylate resin; the modified epoxy acrylate resin is polyurethane modified epoxy acrylate resin. After the ink is photo-cured, a paint film has good flexibility, adhesive force and chemical resistance; the hardness, the curing speed and the chemical resistance of a paint film can be improved; the adhesive force to a base material can be promoted; and the water resistance and the wine soaking resistance of a paint film are enhanced.

The invention discloses a UV-cured high-weather-resistance optical thin film and a preparation method thereof, and relates to the technical field of optical thin films. The optical film is prepared by taking polyethylene glycol terephthalate as a base material and coating the base material with a UV curing coating, and the UV curing coating comprises the following raw materials in parts by weight: 15-20 parts of aliphatic polyurethane acrylate, 5-8 parts of perfluorobutyl ethyl acrylate, 8-12 parts of hydroxyethyl acrylate, 6-10 parts of 1, 2, 4-trimethyl-1, 3-pentanediol monoisobutyrate, 1-3 parts of 1, 2, 4-trimethyl-1, 3-pentanediol monoisobutyrate, 1-3 parts of 1, 2, 4-trimethyl-1, the invention relates to a UV (ultraviolet)-resistant coating which is prepared from the following raw materials in parts by weight: 1-2 parts of 2, 6-hexanediol diacrylate, 5-8 parts of trimethylolpropane triacrylate, 30-40 parts of modified epoxy acrylate, 1-2 parts of a silane coupling agent KH-570, 2-3 parts of a photoinitiator 1173, 0.5-1.2 parts of a modified ultraviolet absorbent UV-327, 0.8-1.5 parts of a hindered amine light stabilizer 540, 0.3-0.8 part of an antioxidant 1010, 0.09-0.12 part of an ultraviolet absorbent Tinuvin400 and 0.2-0.5 part of polyether modified polydimethylsiloxane. According to the UV-cured high-weather-resistance optical thin film, polyethylene glycol terephthalate is used as a base material, key raw materials such as a UV-cured coating with a scientific formula, modified epoxy acrylate and the like are finely prepared, a two-stage curing process is adopted, and the weather resistance is excellent.

The invention discloses nano UV light-cured printing ink and a preparation method thereof, and relates to the technical field of printing ink preparation. The nano UV light-cured printing ink is prepared from nano UV light, the invention discloses a UV (ultraviolet) photoinitiator, which is prepared from the following raw materials in parts by weight: 20 to 40 parts of polyurethane acrylate oligomer, 15 to 30 parts of modified bisphenol A type epoxy acrylate, 10 to 15 parts of tripropylene glycol diacrylate, 5 to 10 parts of ethoxylated trimethylolpropane triacrylate, 5 to 15 parts of modified nano titanium dioxide, 3 to 8 parts of nano silver wire, 2 to 5 parts of photoinitiator 1173 and 1 to 3 parts of benzoin dimethyl ether. The invention relates to a silver-loaded zirconium phosphate composite material which is prepared from the following components in parts by weight: 0.5-2 parts of polyether modified polydimethylsiloxane, 0.3-1 part of a defoaming agent, 1-3 parts of a dispersing agent, 1-5 parts of silver-loaded zirconium phosphate, 0.5-2 parts of an antioxidant 1010, 0.5-2 parts of a coupling agent KH-550 and 10-25 parts of propylene glycol methyl ether acetate. The raw materials are scientifically proportioned and contain various modified components, and parameters of each step are clear. The preparation method is reasonable in process, the performance of the ink is improved through multi-step modification, and the obtained ink is good in dispersity and compatibility, high in curing efficiency and excellent in comprehensive performance and has good practicability and innovativeness.

The invention relates to high-adhesion weather-resistant water-based ink and a preparation process thereof, and relates to the field of ink materials and preparation, and the high-adhesion weather-resistant water-based ink is prepared from the following raw materials in parts by mass: 25-40 parts of waterborne polyurethane, 10-20 parts of waterborne acrylate, 35-50 parts of water-based color paste, 1-4 parts of auxiliaries and water; the water-based acrylate is obtained through emulsion polymerization, and polymeric monomers comprise epoxy acrylate, hydroxyethyl acrylate, pentaerythritol tetraacrylate and acrylic acid; the epoxy acrylate comprises fatty acid modified epoxy diacrylate. The preparation method comprises the following steps: adding the water-based polyurethane resin and the water-based acrylate into water, stirring, adding the water-based color paste, stirring, adding the auxiliary agent, stirring, adjusting the viscosity, stirring, and filtering to obtain the high-adhesion weather-resistant water-based ink. The water-based ink has the effect of improving the adhesive force and weather resistance of the water-based ink.

The invention discloses a UV-curable conductive polyurethane acrylate coating and a preparation method thereof, and relates to the technical field of photocureable coatings. The invention relates to a UV curing conductive polyurethane acrylate coating, which comprises a light-cured resin, a polyaniline coated carbon nanotube, a reactive diluent, a photoinitiator, an organosilicon leveling agent and a defoaming agent, the light-cured resin is prepared by mixing a polyurethane prepolymer, an epoxy acrylate resin and dihydroxy acrylate, and the polyurethane prepolymer is prepared by mixing the polyurethane prepolymer, the epoxy acrylate resin and the dihydroxy acrylate. The polyaniline coated carbon nano tube is formed by coating and modifying a carbon nano tube by aniline and a doping agent. By adopting the scheme, not only can the conductivity of the coating be improved through the polyaniline coated carbon nanotubes, but also the light-cured resin and the polyaniline coated carbon nanotubes can form a three-dimensional network structure of a conductive filler / resin base material, so that the mechanical property of the coating can be improved; further, the preparation of the UV curing conductive coating with high conductivity and mechanical property is facilitated.

The invention provides a notebook keyboard composite skin-touch paint film and a preparation process thereof. The notebook keyboard composite skin-touch paint film comprises a primer layer, a middle paint layer and a UV skin-touch finish paint layer which are sequentially arranged on the surface of a notebook keyboard base material, the primer layer is prepared from the following components in percentage by weight: 20 to 30 percent of hydroxy acrylic resin, 15 to 25 percent of modified epoxy acrylate, 5 to 10 percent of vinyl modified fumed silica, 5 to 10 percent of fluorosilicone resin, 5 to 10 percent of epoxy phosphate, 5 to 10 percent of filler, 15 to 25 percent of solvent A, 2 to 4 percent of curing agent, 0.1 to 0.3 percent of flatting agent and 0.1 to 0.3 percent of defoaming agent; the middle paint layer is prepared from the following components: 40 to 50 percent of acrylic polyurethane resin, 12 to 16 percent of filler, 1 to 3 percent of cerium oxide, 7 to 12 percent of laser carving toner, 1 to 3 percent of dispersing agent, 20 to 30 percent of solvent B, 0.1 to 0.3 percent of plasticizer, 0.1 to 0.3 percent of flatting agent and 0.1 to 0.3 percent of defoaming agent; the UV skin-touch finish paint layer is prepared from the following components: 52 to 55 percent of polyurethane acrylate resin, 15 to 25 percent of reactive diluent, 2 to 4 percent of photoinitiator, 10 to 15 percent of skin-touch additive, 5 to 10 percent of filler, 0.1 to 0.3 percent of flatting agent and 0.1 to 0.3 percent of antioxidant. The paint film provided by the invention has the advantages of favorable wear resistance, favorable adhesive force and favorable hand feeling.

A high-reliability fast-curing UV adhesive for outer layer protection of a power battery, a preparation method therefor, and a use thereof. The UV adhesive contains an acrylate oligomer, a monofunctional acrylate monomer, a bifunctional acrylate monomer, a trifunctional acrylate monomer, an acrylate monomer containing an acidic functional group, a photoinitiator, and an optional additive, wherein the acrylate oligomer simultaneously contains dibasic acid-modified bisphenol A epoxy acrylate, tetrafunctional branched polyester acrylate, and polyurethane acrylate with polyester diol as a backbone. The resulting UV adhesive has a high curing rate, can be cured by means of an LED, is suitable for a high-precision ink-jet process, meets reliability requirements, such as insulation, voltage resistance, boiling resistance in water, and salt spray resistance, and bonding strength requirements, can replace a PET blue film as an insulating protective layer for outer layer packaging of a power battery, and leaves room for lightweight battery design.

The embodiment of the invention provides a UV-cured matte skin-touch coating as well as a preparation method and application thereof. The UV-cured matte skin-touch coating is prepared from the following raw materials in parts by weight: 30-55 parts of urethane acrylate; 20 to 35 parts of epoxy acrylate; 3 to 6 parts of a photoinitiator; 5 to 10 parts of tris (2-hydroxyethyl) isocyanuric acid triacrylate; 3 to 8 parts of fluorosilicone modified acrylate; 4-7 parts of modified boron nitride; wherein the modified boron nitride is silane coupling agent surface modified boron nitride. According to the UV-cured matte skin-touch coating disclosed by the embodiment of the invention, based on the combined action of the (2-hydroxyethyl) isocyanuric acid triacrylate, the fluorosilicone modified acrylate and the modified boron nitride, the coating has ultra-low gloss and also has high hardness, high temperature resistance and fine and smooth skin touch.

The invention relates to the technical field of coatings, and discloses a composition for a polyurethane waterproof coating, the polyurethane waterproof coating as well as a preparation method and application of the polyurethane waterproof coating. The composition contains a main agent and an auxiliary agent, the main agent is formed by polymerizing raw material components including polyol, diisocyanate A, bisphenol A epoxy acrylate and a prepolymer; the prepolymer is prepared by a method comprising the following steps: in the presence of a polymerization catalyst, carrying out contact reaction on bisphenol A epoxy resin, polyaspartic acid ester, diisocyanate B and an isocyanate tripolymer to obtain the prepolymer, the use amount molar ratio of the bisphenol A epoxy resin to the polyaspartic acid ester to the diisocyanate B to the isocyanate tripolymer is 1: (0.6 to 1.5): (0.5 to 1): (0.05 to 0.5). The coating provided by the invention is high in modulus, and has higher tensile strength, hardness and waterproof performance.

The invention discloses a near-infrared light cured conductive adhesive and a preparation method thereof, and belongs to the field of micro-nano electronic packaging and semiconductor materials. The problems that an existing conductive adhesive is high in curing temperature, long in curing time and poor in curing effect are solved. Silver-coated copper powder and silver nanowires serve as conductive filler and are mixed with epoxy acrylate resin, a reactive diluent, a photoinitiator, a thermal initiator, a defoaming agent and a flatting agent, grinding, defoaming and near-infrared light curing are conducted, and the conductive adhesive is obtained. The thermal initiator and the photoinitiator are combined, the near-infrared light is adopted for irradiation, the high-energy density of the near-infrared light directly permeates into the conductive adhesive film layer, the conductive adhesive film layer is heated at the same time and is not absorbed by the substrate, rapid curing of the conductive adhesive can be achieved, and when the radiation power is 120-300 W, the radiation time is 30-600 s and the irradiation frequency is 1-10 times, the conductive adhesive can be rapidly cured. And the cured conductive adhesive is low in volume resistance and high in bonding strength.

The invention provides a novel photovoltaic module UV adhesive as well as preparation and application thereof. The photovoltaic module UV adhesive obtained by the method provided by the invention adopts the carbon dioxide-based polyol as a raw material, and compared with the traditional polyurethane acrylate, the strength is higher, and the anti-tear effect is better; compared with traditional epoxy acrylate, the epoxy acrylate has the advantages of higher flexibility, no aromatic benzene ring characteristic in structure, excellent weather resistance and yellowing resistance and better carbon emission reduction effect.

The invention belongs to the technical field of UV ink formula design and digital printing application, and particularly relates to scratch-resistant UV ink, a preparation method thereof and application of the scratch-resistant UV ink to digital printing. The scratch-resistant UV ink comprises the following raw materials in parts by weight: 15-25 parts of epoxy acrylate; 10 to 20 parts of polyurethane acrylate; 15 to 25 parts of a bifunctional monomer; 5-10 parts of a monomer with three functional groups and more than three functional groups; 3 to 5 parts of an alpha-hydroxy ketone photoinitiator; 2 to 4 parts of an acyl phosphorus oxide photoinitiator; 2 to 5 parts of organically modified nano silicon dioxide; 0.1 part to 0.5 part of a flatting agent; 0.5 to 1.5 parts of a dispersing agent; 10 to 15 parts of pigment; the bifunctional monomer is tripropylene glycol diacrylate; the monomer with three functional groups and more than three functional groups is trimethylolpropane triacrylate. The ink has pencil hardness greater than or equal to 3H and excellent flexibility, the adhesive force on substrates such as PC, PET, metal and the like reaches 0 level, the printing process is simplified, and the ink is suitable for digital printing in various scenes.

The invention relates to the technical field of high-end packaging and printing, and discloses a base material back coating and a preparation method thereof, and the base material back coating comprises the following components in parts by weight: 55-70 parts of mixed matrix resin formed by polar modified epoxy acrylate and perfluoropolyether acrylate according to a weight ratio of 4 / 1-9 / 1, according to the invention, self-stratification power generated by viscosity reduction in a heat leveling stage is utilized to drive the components to migrate directionally and construct a gradient interpenetrating network structure, so that the self-stratification effect is improved, and the self-stratification effect is improved; the coating is subjected to continuous chemical transition from the bottom anchoring layer to the surface shielding layer, interface stress concentration generated by physical layering is eliminated, and the interface bonding stability is improved on the premise that the protection strength of the ultrathin coating is guaranteed.