12045 results about "Acrylate ester" patented technology

The invention discloses an OCA optical adhesive and a preparation method thereof, and relates to the technical field of adhesives, and the OCA optical adhesive is prepared from the following raw materials in parts by weight: 35-45 parts of acrylate-terminated hyperbranched organosilicon modified polyurethane, 2-4 parts of allyl succinimido carbonate, 1-3 parts of hexafluorobisphenol A diacrylate, 1-3 parts of 1, 2, 4-trimethyl-1, 3-pentanediol monoisobutyrate, 1-3 parts of 1, 3-pentanediol monoisobutyrate, 1-3 parts of 1, 3-pentanediol monoisobutyrate, 1-3 parts of 1, 3-pentanediol The invention relates to a photocurable adhesive, which is prepared from the following components in parts by weight: 20 to 30 parts of a diluent, 0.6 to 1.2 parts of a photoinitiator, 0.5 to 1 part of an antioxidant and 0.5 to 1 part of a de-foaming agent. The photocurable adhesive is prepared from the following components in parts by weight: 1 to 5 parts of 1, 3-bis (oxiranyl methyl)-5-(2-propenyl)-1, 3, 5-triazine-2, 4, 6 (1H, 3H, 5H)-triketone, 3 to 5 parts of 2, 2 '-bis (trifluoromethyl) diaminodiphenyl, 6 to 8 parts of other polymerizable monomers, 20 to 30 parts of the diluent, 0.6 to 1.2 parts of the photoinitiator, 0.5 to 1 part of the antioxidant and 0.5 to 1 part of the de-foaming agent. The OCA optical adhesive is good in bonding performance, sufficient in weather resistance and environmental protection performance and good in oil resistance.

The invention discloses a high-bio-based PHA-acrylate emulsion paint as well as a preparation method and application thereof, and belongs to the technical field of water-based paints. The film former of the latex paint comprises 60% to 90% of polyhydroxyalkanoate (PHA) with a moderate crystallinity of 40% to 60%, and 10% to 40% of a specific bio-based acrylate copolymer with a Tg of not higher than 5 DEG C. According to the invention, a core-shell microstructure in which a rigid PHA phase is wrapped by a flexible acrylate phase is constructed through a key process including ultrasonic treatment. According to the structure, low-temperature film forming can be achieved without a VOC coalescing agent, the bio-based content of an obtained paint film is higher than 70%, the VOC content is lower than 0.5 g / L, the scrub resistance is larger than 7000 times, and the technical problem that high bio-based content and high performance of a PHA coating are difficult to achieve at the same time is solved.

The invention relates to the technical field of folding screen supporting films, and particularly discloses a double-layer buffering supporting film for a flexible folding display screen and a preparation method of the double-layer buffering supporting film. The double-layer buffer supporting film for the flexible folding display screen sequentially comprises a release film layer, a first adhesive layer, a first stainless steel layer, a second adhesive layer, a second stainless steel layer and a protective film layer from top to bottom, the first adhesive layer and the second adhesive layer are prepared by curing the same pressure-sensitive adhesive composition; the pressure-sensitive adhesive composition is prepared from the following raw materials: acrylate copolymer, hydrogenated rosin glyceride, hyperbranched polyesteramide-dopamine conjugate, acylhydrazone bond modified siloxane, a curing agent and a silane coupling agent; the protective film layer comprises the following raw materials: PET particles, nano silicon dioxide, an ethylene-vinyl acetate copolymer and an antioxidant. The double-layer buffer supporting film has the advantages of being high in supporting rigidity and interlayer peel strength, and serious folds caused by long-term repeated folding of the folding screen can be relieved.

The invention discloses an adhesive, lithium battery negative electrode slurry, a lithium battery negative electrode and a lithium battery. The adhesive comprises an acrylic copolymer; polymeric monomers of the acrylic copolymer comprise an acrylic monomer, an acrylonitrile monomer, an acrylamide monomer and a selective acrylate monomer; the preparation method of the acrylic acid copolymer comprises the following steps: mixing an acrylic acid monomer with water, adding alkali for neutralization until the neutralization degree is greater than or equal to 50% and less than 100%, then adding an acrylamide monomer and an acrylonitrile monomer, selectively adding an acrylic ester monomer, heating to a reaction temperature in a protective atmosphere, and carrying out a reaction for 2-4 hours to obtain the acrylic acid copolymer. Adding an initiator to initiate an aqueous solution polymerization reaction to generate an acrylic copolymer; practice shows that the binder has higher molecular weight and better electrical performance, when the binder is applied to the negative electrode of the lithium battery, excellent binding power and battery cycle performance can be obtained while the use amount of the binder is reduced, and the binder can be used for preparing the lithium battery, related electrodes and the like.

The invention discloses a scalp essence capable of controlling oil and removing dandruff and a preparation method thereof, and provides the scalp essence capable of controlling oil and removing dandruff. The formula consists of the following raw materials: water, saccharomycetes / rice fermentation product filtrate, butanediol, phenoxyethanol, caprylic acid / capric triglyceride, galactose yeast-like bacterium fermentation product filtrate, allantoin, a saccharomycetes / zinc fermentation product, nicotinamide, arginine, polysorbate-20, hydrogenated lecithin, acrylic acid (ester) / C10-30 and an alkanol acrylate cross-linked polymer. Hydrolyzed sodium hyaluronate and trace components. According to the oil-controlling and dandruff-removing scalp essence disclosed by the invention, through the synergistic interaction among the raw materials, the effects of replenishing water, preserving moisture, controlling oil and removing dandruff are increased, the effects of relieving, recovering oil-water balance, recovering skin elasticity and delaying senescence are also achieved, the effects of preventing hair loss and nourishing hair are also achieved, and meanwhile, the oil-controlling and dandruff-removing scalp essence has the advantage of being stable in storage.

The invention belongs to the technical field of flame retardants, and particularly relates to a high-thermal-stability polyphosphate flame retardant and a preparation method thereof. The DOPO is modified through the polyethylene glycol acrylate, methyl methacrylate and dicumyl peroxide composite solution, double bonds of the polyethylene glycol acrylate and P-H bonds of the DOPO can be subjected to nucleophilic addition to form stable C-P bonds, and thermal migration of the DOPO is hindered; dOPO has polymerization double bonds of methyl methacrylate and long carbon chains of polyethylene glycol acrylate, so that the compatibility of the polyphosphate flame retardant and a polymer substrate is improved, and phase separation is avoided; maleic anhydride grafted silicone oil is connected to the surface of an amino modified gamma-cyclodextrin-modified DOPO inclusion compound, so that the polyphosphate flame retardant has high thermal stability and high compatibility after long-chain alkyl modification; amino groups in the modified gamma-cyclodextrin react with maleic anhydride grafted silicone oil to generate an amido bond cross-linked network, so that the thermal migration of DOPO is reduced together, and the high thermal stability of the polyphosphate flame retardant is improved.

The invention discloses an embolism part for peripheral arteriovenous vessels, the embolism part comprises an anchoring part and a blocking part fixedly connected with the anchoring part, the blocking part adopts polyurethane shape memory foam, the expansion rate of the polyurethane shape memory foam is 50-100 times, and a preparation method of the polyurethane shape memory foam comprises the following steps: step 1, preparing a polyurethane shape memory foam material; the preparation method comprises the following steps: preparing a polyurethane acrylate prepolymer from macromolecular polyol, diisocyanate, a chain extender containing disulfide bonds, other micromolecular chain extenders and an acrylate end-capping reagent; and 2, uniformly mixing the polyurethane acrylate prepolymer, a foaming agent, a foaming promoter and a photoinitiator to obtain a foaming solution, and sequentially carrying out light curing and foaming on the foaming solution to obtain the polyurethane shape memory foam. According to the embolism part, the polyurethane shape memory foam is adopted as the blocking part, the blocking part applies radial acting force to the wall of the blood vessel all the time based on the expansion trend of the blocking part, and the blocking part and the anchoring part jointly act and can be stably maintained in the blood vessel.

The invention provides a gradient crosslinking process of photosensitive resin for photocuring 3D printing, and relates to the technical field of photocuring 3D printing materials. The gradient crosslinking process of the photosensitive resin for photocuring 3D printing comprises the following steps: S1, based on double-initiator system design, adopting molecular dynamics simulation screening, respectively adding a 405nm sensitive type TPO-L initiator and a 365nm sensitive type I TX initiator into an epoxy acrylate prepolymer, and verifying initiation energy barrier matching through quantum chemistry calculation, and generating a pre-initiation gradient resin formula. Through molecular dynamics simulation, initiator combinations are screened, energy barrier matching is verified, the ratio of dual-wavelength sensitive initiators is optimized, and accurate triggering of surface layer and deep layer cross-linking reaction is ensured. And a three-roller grinding and dispersing process is combined with ultrasonic oscillation to eliminate nanoparticle aggregation, so that the mechanical uniformity and light scattering effect of a resin system are improved.

The invention relates to an insulating weather-resistant powder coating and a preparation method thereof, and belongs to the technical field of coatings, and the powder coating comprises composite modified resin, a dual curing agent, a functional filler, a polyacrylate leveling agent, fumed silica, a benzotriazole ultraviolet light absorber, polytetrafluoroethylene wax powder and the like. A core-shell structure of the composite modified resin is designed, high insulativity is kept through a silane modified epoxy core layer, a weather-proof barrier is provided through an acrylic acid shell layer, and the phase separation problem is solved through interface chemical bonding; a dual-curing mechanism is designed, and isocyanate and acrylic hydroxyl react to form an interpenetrating network while an epoxy core layer is cured by anhydride; a filler synergistic effect is designed, silane coupling agent modified nano boron nitride forms a three-dimensional heat-conducting insulating network, and rutile type titanium dioxide is coated with silicon dioxide, so that ultraviolet aging is resisted. All the components cooperate with one another, so that the coating has excellent insulativity, weather resistance, adhesiveness and the like at the same time.

The invention relates to the technical field of PVC pipe production and processing, and particularly discloses a PVC pipe composition and a preparation method of a PVC pipe. PVC resin and PE resin are compounded, the problem of PVC decomposition caused by high temperature in the processing process is reduced, meanwhile, the PE resin has good flexibility, and by compounding the PVC resin and the PE resin, the PVC resin and the PE resin have good flexibility, so that the PVC pipe composition is more stable in performance. The mechanical property of the PVC pipe can be improved; 4-carboxyphenylboronic acid in the composite modified attapulgite provided by the invention forms a B-O-B cross-linked network structure at a high temperature, the 4-carboxyphenylboronic acid can have a synergistic effect with composite metal oxides (zinc oxide and manganese oxide), the thermal stability and compactness of a carbon layer are improved, and the flame retardant property of the PVC pipe is further improved; a flexible alkyl long-chain structure is formed through copolymerization of 1, 4-diol, reversible deformation occurs under the action of external force, and the mechanical property of the PVC pipe is further improved.

The invention belongs to the technical field of synthetic resin, and particularly relates to a high-transparency weather-resistant PMMA (polymethyl methacrylate) resin toughening agent with a core-shell structure and a preparation method of the PMMA resin toughening agent. The preparation method comprises the following steps: preparing core-layer latex from an acrylate monomer and a vinyl aromatic monomer through emulsion copolymerization, then preparing a shell layer with the refractive index completely consistent with that of PMMA resin on the surface of the core-layer latex through graft polymerization, and finally preparing the PMMA resin toughening agent with the core-shell structure. The toughening agent can effectively toughen the PMMA resin on the premise that the light transmittance of the PMMA resin is not lower than 85%, so that the elongation at break of the PMMA resin is remarkably improved, and the film drawing requirement of the PMMA resin can be met.

The invention relates to the field of textile materials, and particularly discloses a graphene enhanced polyester yarn and a preparation method thereof.The preparation method comprises the following steps that silicon dioxide aerogel serves as a porous carrier to be loaded with graphene, and a graphene-porous carrier composite material is prepared; the graphene-porous carrier composite material is subjected to modification treatment through vinyl trimethoxy silane and 3-amino propyl triethoxy silane, and then a modified graphene composite material is prepared; reacting the modified graphene composite material, a styrene monomer, an acrylate monomer and an initiator to prepare modified graphene; mixing the prepared modified graphene with polyester chips, and then carrying out melt spinning to prepare graphene enhanced polyester yarns; the invention further discloses the graphene enhanced polyester yarn prepared by adopting the preparation method. The preparation method has the characteristics that the dispersion of the graphene in the polyester is improved, and the direct interface compatibility of the graphene and the polyester fiber is improved, so that the mechanical property of the polyester yarn is improved.

The invention discloses a self-repairing polymer electrolyte, a preparation method and application thereof, and a polymer lithium battery, the self-repairing polymer electrolyte comprises the following preparation raw materials by mass: 50-100 parts of polysiloxane diacrylate, 1-10 parts of disulfide diacrylate, 10-40 parts of a cross-linking agent, 60-120 parts of a plasticizer, 60-120 parts of a lithium salt, and 1-10 parts of a photoinitiator. According to the self-repairing polymer electrolyte disclosed by the invention, a thiol-ene click reaction can be carried out between carbon-carbon double bonds in polysiloxane diacrylate and disulfide diacrylate and sulfydryl of the cross-linking agent, so that a dynamic disulfide bond and hydrogen bond network structure is endowed to the self-repairing polymer electrolyte; and the dynamic disulfide bond and the hydrogen bond can enable the electrolyte membrane to realize self-healing at room temperature without external stimulation.

The invention belongs to the technical field of cement manufacturing, and particularly relates to high-strength weather-resistant environment-friendly cement and a preparation method thereof. The environment-friendly cement is prepared from the following raw materials in parts by mass: 40 to 55 parts of Portland cement, 15 to 25 parts of fly ash, 10 to 15 parts of slag powder, 6 to 12 parts of biomass reinforced composite mineral material, 2 to 4 parts of nano silicon dioxide, 1 to 4 parts of modified polymer emulsion and 1 to 3 parts of additive. The biomass reinforced composite mineral material is prepared from zeolite, bentonite, sepiolite and chitosan; the modified polymer emulsion comprises a modified polyacrylate emulsion and a modified polystyrene-butadiene emulsion in a mass ratio of (1-3): 1; the additive is prepared from basalt fiber, sodium lignin sulfonate, a rosin thermopolymer and sodium gluconate. The environment-friendly cement prepared by the invention not only has high strength and good weather resistance, but also remarkably reduces carbon footprint and saves natural resources.

The invention belongs to the field of pesticides, and relates to a 2-cyano-3-disubstituted phenyl acrylate compound as well as a preparation method and application thereof in pesticides. Carrying out alcoholysis reaction on the benzonitrile compound a and a hydrogen chloride absolute ethyl alcohol solution to obtain an intermediate b; carrying out condensation reaction on the intermediate b and ethyl cyanoacetate under the action of alkali to obtain an intermediate c; the intermediate c and a substituted compound are subjected to a substitution reaction under the action of alkali and a catalyst, and the 2-cyano-3-disubstituted phenyl acrylate compound I is obtained. The 2-cyano-3-disubstituted phenylacrylate compound provided by the invention has good bactericidal activity, and has relatively high bactericidal activity on pathogenic bacteria of chlorosclerotium, fusarium, acrocyst, colletotrichum, cercospora, verticillium and black beancurd skin; the compound can be used for preparing bactericides in the fields of agriculture, horticulture, industry and the like, and has the advantages of broad spectrum, high efficiency, low toxicity and environmental friendliness.

A preparation method for a stable fatty alcohol emulsion. A silane coupling agent is used for carrying out surface modification on silicon dioxide to finally obtain modified silicon dioxide, and the modified silicon dioxide is adsorbed on the interface of defoaming active substances and water, so that the active substances are dispersed, the problem of product creaming caused by aggregation is avoided, and the defoaming performance of the product is improved; in addition, during emulsification, a non-ionic surfactant and an acrylate polymer act synergistically to emulsify the active substances, so that the stability of the emulsion is further improved.

The invention relates to the technical field of adhesives, in particular to a UV-thermal dual-curing adhesive and a preparation method thereof. The UV-thermal dual-curing adhesive provided by the invention comprises the following components in parts by weight: 10-30 parts of an acrylate monomer; 5-15 parts of epoxy resin; 5 to 15 parts of epoxy modified N substituted maleimide resin; 1-4 parts of a photoinitiator; 10-25 parts of a latent curing agent; 0.5-2 parts of a stabilizer; 15 to 30 parts of thiol; 1-3 parts of a silane coupling agent; 1-5 parts of a thixotropic agent; and 15-30 parts of a filler. By adding the epoxy modified N-substituted maleimide resin, on one hand, excellent flexibility can be brought to a system; on the other hand, the maleimide ring can enable the system to have excellent humidity and heat resistance, and the prepared adhesive can be applied to adhesion of camera modules in various application scenes.

The invention provides a low-swelling low-temperature adhesion polyacrylate water-based binder as well as a preparation method and application thereof. The polyacrylate water-based binder is a core-shell polymer obtained by polymerizing a polymeric monomer, polymeric monomers of a core polymer of the core-shell polymer comprise the following monomers in percentage by weight: 50-90% of a hard monomer, 5-30% of a soft monomer and 1-20% of a functional monomer; polymeric monomers of a shell polymer of the core-shell polymer comprise the following monomers in percentage by weight: 35-85% of a hard monomer, 15-60% of a soft monomer and 0-5% of a functional monomer. The polyacrylate aqueous binder provided by the invention is suitable for the lithium ion battery diaphragm, and solves the problems of low adhesion, high energy consumption, no environmental protection, high price and the like of the current binder for the lithium ion battery diaphragm.

The invention relates to the field of adhesives, and particularly discloses an OCA optical adhesive for a folding screen and a preparation method of the OCA optical adhesive. The OCA optical adhesive for the folding screen is prepared from the following raw materials in parts by weight: 60 to 80 parts of urethane acrylate, 15 to 25 parts of organic silicon grafted glycidyl ether, 20 to 30 parts of a diluent, 5 to 10 parts of a photoinitiator and 1 to 2 parts of an antioxidant, the organic silicon grafted glycidyl ether is prepared by reacting vinyl siloxane, pentaerythritol triallyl ether, allyl glycidyl ether and a catalyst. The OCA optical cement for the folding screen prepared by the invention is applied to the folding screen, and can keep relatively good elasticity, bending resistance and bonding strength in the long-term repeated folding use process, and wrinkles and bubbles are not easy to appear.

The invention discloses an antibacterial water-resistant aluminum-plastic composite hose and a preparation method thereof, and belongs to the technical field of aluminum-plastic composites.The antibacterial water-resistant aluminum-plastic composite hose comprises a hose head and a hose body, the hose body is formed by lap joint of antibacterial water-resistant aluminum-plastic composite sheets, and the antibacterial water-resistant aluminum-plastic composite sheets are arranged on the hose head. The antibacterial waterproof aluminum-plastic composite sheet sequentially comprises an outer-layer PE film, a hyperbranched copolymer, an aluminum foil, an ethylene-methacrylic acid copolymer and an inner-layer PE film, the hyperbranched copolymer and the ethylene-methacrylic acid copolymer are formed by cross-linking and copolymerizing an acrylate cross-linking agent and a sulfydryl-silyl ether cross-linking agent. The hyperbranched copolymer provided by the invention can be used as a bonding layer to meet the requirement of the aluminum-plastic composite hose on peel strength, and the aluminum-plastic composite hose also has good tensile strength, water-proof and oil-proof effects and antibacterial performance.

The specification relates to a wash-off label (100, 200) comprising a face (101, 301) and a pressure sensitive adhesive (102, 302) adjoined to the face, wherein the face (101, 301) comprises corona discharged filmic material and the pressure sensitive adhesive (102, 302) has a composition including at least one acrylic polymer comprising acrylic monomer(s) and / or non-acrylic comonomer(s) having a carbonyl group capable of undergoing a crosslinking reaction, amount of the acrylic monomer(s) and / or non-acrylic comonomer(s) having a carbonyl group capable of undergoing a crosslinking reaction being from 0.1 to 5 wt. % of monomer composition, and a crosslinking agent with dihydrazide functionality, amount of the crosslinking agent being from 20 to 150% with respect to the amount of the carbonyl groups capable of undergoing a crosslinking reaction. The wash-off label (100, 200) is detachable from a surface when exposed to an alkaline washing solution at a temperature of 85 degrees C. the detachability being such that the pressure sensitive adhesive (102, 302) remains attached to the face (101, 301). Further, the specification relates to a labelled item and use of the wash-off label for labelling an item. Still further, the specification relates to a label laminate web and a method of manufacturing the wash-off label as well as to a pressure sensitive adhesive composition for a wash-off label.

The present invention relates to the technical field of coatings. Disclosed are a coating composition having mold-proof and antibacterial properties and a preparation method therefor. The coating composition comprises the following raw materials: an acrylic resin emulsion, a curing agent, a coalescing agent, a defoaming agent, and a leveling agent, wherein the acrylic resin emulsion is prepared from an acrylate monomer, a cross-linking agent, and fluorine-containing silicone oil by means of free radical polymerization under the action of an initiator. A gemini-type quaternary ammonium salt functional group in the structure of the cross-linking agent can enable the coating to have good mold-proof and antibacterial effects, the presence of the ether bond can enable the coating to have better adhesive force, and the presence of the fluorine-containing silicone oil can enable a coating film formed by curing the coating to have a super-hydrophobic surface, thereby avoiding surface moisture which promotes bacterial growth and reproduction, and endowing the coating with antifouling and self-cleaning effects. In addition, the silicon-oxygen bond in the silicone oil can effectively enhance the heat resistance of the coating, thereby facilitating further application of the coating in indoor decoration.

The invention relates to the technical field of flexible display devices, in particular to a high-impact-resistance coating for ultra-thin glass, a preparation method and an assembly layer. The invention discloses a high-impact-resistance coating for ultra-thin glass. The high-impact-resistance coating is mainly prepared from a precursor, a cross-linking agent and a photoinitiator in a solvent-free condition in a UV curing manner, the precursor comprises a polyether urethane acrylate oligomer with Tg of-70 DEG C to-40 DEG C; the Tg of the coating is 30-60 DEG C; and in a temperature scanning test with the temperature range of-40 to 80 DEG C and the frequency of 1Hz, the peak value of the loss factor of the coating is 0.7 to 1.2. The high-impact-resistance coating provided by the invention has good adhesion and excellent optical performance, also has good elongation at break and good flexibility, has a high dissipation effect on mechanical stress, and can enhance the impact resistance of the ultra-thin glass. In addition, the high-impact-resistance coating is prepared through a UV photocuring method and does not contain a solvent, the VOC emission in the production and preparation process is low, and the coating is green and efficient.

The invention discloses a waterborne epoxy resin coating, a preparation method and application in bridge protection, and belongs to the technical field of coatings. The water-borne epoxy resin coating comprises the following raw material components in parts by weight: 15-25 parts of epoxy composite resin emulsion, 100 parts of emulsified asphalt, 3-5 parts of a curing agent and 6-10 parts of water, wherein the epoxy composite resin emulsion is obtained by carrying out a composite reaction on 30-60 parts by mass of epoxy resin, 2-3 parts by mass of an emulsifier, 6-9 parts by mass of an acrylate composition and 1.4-1.6 parts by mass of a co-stabilizer; the acrylate composition is prepared by prepolymerizing 15 to 16 parts by mass of butyl methacrylate, 10 to 12 parts by mass of 2-isopropenyl aniline, 5 to 7 parts by mass of allyl glycidyl ether and 1 to 1.2 parts by mass of allyl polyhedral oligomeric silsesquioxane and then combining the prepolymerized materials with 1 to 3 parts by mass of acrylic acid.

The invention provides a solid electrolyte slurry, an electrode slurry, a solid electrolyte sheet, an electrode sheet, a solid battery monomer, a battery device and a power utilization device.The solid electrolyte slurry comprises a sulfide solid electrolyte material, a solvent and a binder dissolved in the solvent, and the solvent is a non-polar solvent, a weak-polar solvent or a mixed solvent of the non-polar solvent and the weak-polar solvent; the binding agent comprises a polyacrylate binding agent and a non-polar polyolefin binding agent. The slurry disclosed by the invention has high dispersity, high suspension property and good cohesiveness, and can enable the solid-state battery monomer to have high initial coulombic efficiency when being used in the solid-state battery monomer.

The invention relates to the field of quantum dot ink, and discloses diffusion plate printing quantum dot ink and a preparation method thereof.The diffusion plate printing quantum dot ink comprises acrylic resin, hyperbranched polyester resin, a quantum dot material, modified boron nitride, a reactive diluent, a photoinitiator, a wetting agent and a defoaming agent; the hyperbranched polyester resin is prepared by reacting hyperbranched polyester acrylate and a sulfydryl-terminated silicon-containing reaction monomer, wherein the hyperbranched polyester acrylate is prepared by reacting pentaerythritol with 2, 2-dimethylolpropionic acid and then carrying out esterification reaction with acrylic acid; the sulfydryl-terminated silicon-containing reaction monomer is prepared by reacting eugenol with 1, 1, 3, 3-tetramethyldisiloxane and then carrying out esterification reaction with 3-mercaptopropionic acid; the modified boron nitride is prepared by modifying a cationic polymer which is prepared by carrying out a Mannich reaction on triethylene tetramine, formaldehyde and acetone and then carrying out a condensation polymerization reaction with formaldehyde. After the ink prepared by the invention is cured, a coating film is high in hardness, adhesive force and heat conductivity coefficient, and good in flexibility, heat resistance and migration barrier property.

The invention discloses a water-based lithium battery positive electrode adhesive, a preparation method and application. The adhesive is of a single-layer or multi-layer shell core-shell structure formed by polar monomers such as acrylic acid, acrylate monomers, cross-linking monomers, self-emulsifying monomers and water through core-shell emulsion polymerization; by controlling the mass percent of acrylate monomers, polar groups and the like in the core layer structure and the shell layer structure and selecting proper types and dosages of cross-linking monomers and self-emulsifying monomers, the adhesive has proper surface tension, shows excellent adhesion and wettability to the current collector, has high peel strength, and is suitable for the current collector. According to the present invention, the lithium ion battery pole piece has the low glass-transition temperature so as to ensure the high toughness, the high surface density, the excellent electrolyte resistance, the excellent electrical property, the excellent coating property and the like of the pole piece, and the raw materials are all non-fluorine materials so as not to produce hydrogen fluoride and other harmful gases during the lithium battery recovery; water is used as a solvent, recycling is not needed, environment friendliness and low carbon are achieved, the manufacturing process is simplified, and the application range is widened.

Provided in the present invention are a polyacrylic acid or polyacrylate water-based binder, and a preparation method therefor and the use thereof. The polyacrylic acid or polyacrylate water-based binder is a polymer obtained by polymerizing polymeric monomers, the polymeric monomers comprising a hard monomer, a soft monomer and a functional monomer. The polyacrylic acid or polyacrylate water-based binder provided by the present invention has relatively high binding power and relatively good flexibility and electrochemical stability, and has good application prospects in the field of negative electrode sheets of lithium-ion batteries.

The invention relates to a flexible aqueous binder for a lithium battery negative electrode and a preparation method thereof. The preparation method comprises the following steps: firstly, preparing a flexible polyurethane prepolymer containing vinyl by taking hydroxyl-terminated polybutadiene, isocyanate and hydroxyl acrylate as main raw materials; vinyl-containing compounds such as water-soluble acrylic acid (salt) or acrylamide, oil-soluble acrylic ester or acrylonitrile and the like are used as monomers and are combined with a flexible polyurethane prepolymer to prepare the negative water-based binder with flexible cross-linking points through free radical polymerization. The aqueous binder prepared by the technical method provided by the invention can realize point-to-point and point-to-line bonding modes with a pole piece active substance on a microstructure, so that the bonding strength of the active layer material and a copper foil is improved on the premise of not influencing the electrolyte resistance of the binder; and the flexibility of the negative pole piece and the subsequent processing stability are obviously improved.

The invention discloses a hydrophobic and oleophobic modified epoxy resin, which is prepared from the following components in parts by mass: 2 to 5 parts of thiolactone terminated fluorinated prepolymer, 15 to 16 parts of 4, 4 '-diaminodiphenylmethane, 0.13 to 0.14 part of base catalyst, 25 to 26.5 parts of epoxy resin and the balance of tetrahydrofuran solvent, wherein the thiolactone-terminated fluorinated prepolymer is prepared from thiolactone acrylamide, fluorinated acrylate and a photoinitiator in a mass ratio of (2-3): 1: (0.07-0.09) through a free radical polymerization copolymerization chemical reaction under the induction of ultraviolet light, and the thiolactone-terminated fluorinated prepolymer is obtained; wherein thiolactone acrylamide is prepared from DL-homocysteine thiolactone hydrochloride, a NaHCO3 solution and acryloyl chloride according to the mass ratio of 1: (1.3-1.5): (1.1-1.3), the oleophobic and hydrophobic modified epoxy resin provided by the invention effectively solves the problem that an epoxy resin coating in the prior art is poor in oleophobic performance and hydrophobic performance, and the oleophobic and hydrophobic modified epoxy resin has the advantages that the oleophobic and hydrophobic properties of the epoxy resin coating are improved; therefore, the oleophobic and hydrophobic properties of the epoxy resin coating are improved.