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13337 results about "Acrylate ester" patented technology

Acrylates and methacrylates (the salts and esters of methacrylic acid) are common monomers in polymer plastics, forming the acrylate polymers. Acrylates easily form polymers because the double bonds are very reactive.

Sulfonated block copolymers, method for making same, and various uses for such block copolymers

The present invention is a, solid block copolymer comprising at least two polymer end blocks A and at least one polymer interior block B wherein each A block is a polymer block resistant to sulfonation and each B block is a polymer block susceptible to sulfonation, and wherein said A and B blocks do not contain any significant levels of olefinic unsaturation. Preferably, each A block comprising one or more segments selected from polymerized (i) para-substituted styrene monomers, (ii) ethylene, (iii) alpha olefins of 3 to 18 carbon atoms; (iv) hydrogenated 1,3-cyclodiene monomers, (v) hydrogenated monomers of conjugated dienes having a vinyl content less than 35 mol percent prior to hydrogenation, (vi) acrylic esters, (vii) methacrylic esters, and (viii) mixtures thereof; and each B block comprising segments of one or more polymerized vinyl aromatic monomers selected from (i) unsubstituted styrene monomers, (ii) ortho-substituted styrene monomers, (iii) meta-substituted styrene monomers, (iv) alpha-methylstyrene, (v) 1,1-diphenylethylene, (vi) 1,2-diphenylethylene and (vii) mixtures thereof. Also claimed are processes for making such block copolymers, and the various end uses and applications for such block copolymers.
Owner:KRATON POLYMERS US LLC

Injection molding method for neutral and acidic-group containing (meth)acrylate copolymers

The invention relates to a process for producing mouldings by injection moulding, the steps in the process being A) Melting a mixture made from a) a (meth)acrylate copolymer composed of from 40 to 100% by weight of free-radical-polymerized C1-C4-alkyl esters of acrylic or methacrylic acid and from 0 to 60% by weight of (meth)acrylate monomers having an anionic group in the alkyl radical, where the copolymer comprises b) from 0.1 to 3% by weight of a release agent, and, where appropriate, the mixture may comprise c) from 0 to 50% by weight of a drier, d) from 0 to 30% by weight of a plasticizer, e) from 0 to 100% by weight of additives or auxiliaries, f) from 0 to 100% by weight of an active pharmaceutical ingredient, g) from 0 to 20% by weight of another polymer or copolymer, where the amounts given for components b) to g) are based on the (meth)acrylate copolymer a) and the mixture prior to melting has a content of more than 0.5% by weight of low-boiling constituents with vapour pressure of at least 1.9 bar at 120° C., B) Devolatilizing the mixture in the thermoplastic state at temperatures of at least 120° C., thereby lowering to not more than 0.5% by weight the content of the low-boiling constituents with vapour pressure of at least 1.9 bar at 120° C., C) Injecting the molten and devolatilized mixture into the mould cavity of an injection mould, the temperature of the mould cavity being below the glass transition temperature of the (meth)acrylate copolymer by at least 10° C., cooling the molten mixture, and removing the resultant moulding from the mould.
Owner:PFIZER INC +1

Rubber composition containing resinous nanoparticle

InactiveUS7347237B2Deteriorate controllabilityDeteriorate stabilitySpecial tyresInflatable tyresElastomerEngineering
This invention relates to a tread rubber composition for tires with the addition of crosslinked resinous nanoparticles having a high glass transition temperature (Tg) into elastomeric base polymers. The invention demonstrates greatly improved handling performance without deteriorating controllability and stability during high-speed running. The present invention more specifically discloses a tire which is comprised of a generally toroidal-shaped carcass with an outer circumferential tread, two spaced beads, at least one ply extending from bead to bead and sidewalls extending radially from and connecting said tread to said beads; wherein said tread is adapted to be ground-contacting; and wherein the tread is comprised of a rubber composition comprising: (1) a rubbery polymer; (2) from 1 to 30 parts per hundred parts of rubber by weight of pre-crosslinked polymer particles, wherein the pre-crosslinked polymer particles have a mean number average particle size as determined by light scattering which is within the range of 30 nm to 500 nm, wherein the pre-crosslinked polymer is comprised of repeat units that are derived from at least one monomer selected from the group consisting of acrylate monomers, acrylonitrile monomer, and vinyl halide monomers, wherein the pre-croslinked polymer is in the form of core-shell particles having a core and a shell, and wherein the pre-crosslinked polymer has a glass transition temperature which is within the range of 30° C. to 200° C.; and (3) 10 to 150 parts per hundred parts of rubber by weight of at least one filler selected from the group consisting of carbon black and silica.
Owner:THE GOODYEAR TIRE & RUBBER CO

Switchable volume hologram materials and devices

A new photopolymerizable material allows single-step, fast recording of volume holograms with properties that can be electrically controlled. Polymer-dispersed liquid crystals (PDLCs) in accordance with the invention preferably comprise a homogeneous mixture of a nematic liquid crystal and a multifunctional pentaacrylate monomer, in combination with photoinitiator, coinitiator and cross-linking agent. Optionally, a surfactant such as octanoic acid may also be added. The PDLC material is exposed to coherent light to produce an interference pattern inside the material. Photopolymerization of the new PDLC material produces a hologram of clearly separated liquid crystal domains and cured polymer domains. Volume transmission gratings made with the new PDLC material can be electrically switched between nearly 100% diffraction efficiency and nearly 0% diffraction efficiency. By increasing the frequency of the switching voltage, switching voltages in the range of 50 Vrms can be achieved. The optional use of surfactant allows low switching voltages at lower frequencies than without surfactant. In an alternative embodiment, a PDLC material in accordance with the invention can be utilized to form reflection gratings, including switchable reflection gratings. In still further embodiments, a PDLC material in accordance with the invention can be used to form switchable subwavelength gratings. By further processing, static transmission reflection, and subwavelength PDLC materials can be formed.
Owner:LEIDOS

High solid content latent curing polyurethane acroleic acid hybrid emulsion

The invention relates to a method for preparing a high solid content latent cured polyurethane acrylic acid heterozygous latex and an application thereof. The preparation method comprises the following steps: pre-polymerizing polyester polyalcohol, hydrophilic chain extender and diisocyanate monomer to obtain the polyurethane prepolymer containing a hydrophilic group (carboxyl or sulfo group) and a terminal NCO group; then, neutralizing the polymer into salt and dispersing the salt in water to prepare the polyurethane water dispersoid; finally, using the dispersoid as macro molecular emulsifying agent and reactant to emulsify and disperse the acrylic ester monomer, initiating the polymerization by heating, dropping initiator to perform the latex polymerization, and regulating the pH of the latex by adding a latent curing agent to obtain the high solid content latent cured polyurethane acrylic acid heterozygous latex. The high solid content latent cured polyurethane acrylic acid heterozygous latex has a solid content of above 45%; the storage of the high solid content latent cured polyurethane acrylic acid heterozygous latex is stable; and high hardness film coating can be formed at the room temperature. Compared with acrylic acid latex and polyurethane latex, the high solid content latent cured polyurethane acrylic acid heterozygous latex has better film forming performance, water resistance, alcohol resistance, pollution resistance, dry/wet cleaning resistance and chemical solvent resistance, as well as high hardness.
Owner:SOUTH CHINA UNIV OF TECH
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