1726 results about "Nano silicon" patented technology

The present invention provides a negative electrode active material which has negative electrode active material particles, the negative electrode active material being characterized in that: the negative electrode active material particles each include a porous carbon structure; amorphous low valence nano silicon oxide is dispersed inside the porous carbon structure; the low valence nano silicon oxide includes the states where SiOx:x < 1.0 is satisfied; and the low valence nano silicon oxide has an average particle diameter of 50 nm or less as determined by image processing of a cross-sectional TEM image thereof. As a result, a negative electrode active material which is capable of increasing the capacity while maintaining the battery characteristics is provided.

The invention relates to the technical field of low-dielectric heat-conducting functional materials, in particular to a nano silicone rubber composite material as well as a preparation method and application thereof. According to the preparation method, a modified vinyl silsesquioxane coupling agent is taken as a bridge, and boron nitride nanosheets, silicon carbide nanowires and the modified vinyl silsesquioxane coupling agent are covalently connected through hydrolysis reaction, so that a heterostructure is constructed, and the nano heat-conducting filler is obtained; the preparation method comprises the following steps: dispersing a nano heat-conducting filler in vinyl silicone oil, and constructing a covalent cross-linked network through addition cross-linking reaction and curing treatment to obtain the nano composite silicone rubber material. According to the processing method, the filling amount, the dielectric constant and the dielectric loss can be reduced, meanwhile, the heat conduction capacity is improved, and the problems that in the prior art, the dielectric constant and the dielectric loss are low due to simple mixing of the boron nitride nanosheets and the silicon carbide nanowires are solved.

The invention discloses a pre-lithiated silicon-carbon negative electrode material as well as a preparation method and application thereof. The pre-lithiated silicon-carbon negative electrode material comprises composite particles and a surface coating layer coating the outer surfaces of the composite particles, the mass of the composite particles accounts for 85%-99% of the total mass of the pre-lithiated silicon-carbon negative electrode material; the composite particles are compounds of pre-lithiated porous carbon and nano silicon particles; the composite particles are obtained by uniformly depositing nano silicon particles in pores of pre-lithiated porous carbon; the mass of the pre-lithiated porous carbon accounts for 15-95% of the total mass of the composite particles; the pre-lithiated porous carbon comprises lithium metal particles and porous carbon, and the lithium metal particles are attached to the surfaces of pores of the porous carbon; the mass of the lithium metal particles accounts for 0.1-10% of the total mass of the pre-lithiated silicon-carbon negative electrode material; when the pre-lithiated silicon-carbon negative electrode material is applied to the lithium battery, the first-circle coulombic efficiency of the lithium battery can be improved.

The invention discloses a silicon-carbon negative electrode material, porous carbon and a preparation method, the porous carbon is prepared by mixing ammonium fluoride and a pre-carbonized material to prepare a premix; and putting the premix in an inert atmosphere, and carrying out pre-activation, drying, carbonization, activation and crushing treatment to obtain the composite material. And uniformly depositing the nano silicon particles into the porous carbon skeleton through a mature CVD (Chemical Vapor Deposition) process to obtain the silicon-carbon composite material. Fluorine and nitrogen co-doping modification can increase the defect degree of a carbon skeleton, efficiently relieve mechanical stress accompanied by lithium storage volume expansion of the silicon negative electrode in a micro scale, provide abundant lithium ion transport and mass transfer channels and enhance the conductivity of porous carbon, and ammonium fluoride is used as a supplementary activator besides water vapor, so that the porosity of the porous carbon is further improved, and the conductivity of the porous carbon is improved. An effective space is provided for uniform deposition of silicon, the fluorine-containing carbon layer can induce formation of a high-stability SEI film rich in LiF on the surface of the nano silicon material, and the interface stability and coulombic efficiency of the silicon negative electrode are further improved.

The invention discloses a lithium battery diaphragm coating based on a nano material and application thereof, and relates to the technical field of lithium battery diaphragms. The coating comprises the following raw materials in parts by weight: 15-25 parts of polystyrene maleic anhydride copolymer modified polyvinylidene fluoride, 10-20 parts of polystyrene, 2-4 parts of nano silicon nitride, 3-6 parts of a boehmite / aluminum oxide and silicon dioxide composite material, 1-2 parts of a dispersing agent and 65-90 parts of a solvent, according to the lithium battery diaphragm coating provided by the invention, the wettability and absorptivity of a diaphragm to an electrolyte are remarkably improved, meanwhile, the lithium battery diaphragm coating also has excellent thermal stability, and the diaphragm can be effectively prevented from thermal shrinkage or melting under a high-temperature condition, so that the safety performance of a battery is remarkably enhanced.

The invention discloses metal element-doped nano silicon carbon as well as a preparation method and application thereof, and relates to the field of negative electrode materials. The nano silicon carbon takes porous carbon as a carbon skeleton, and the porous carbon is sequentially attached with nano silicon and coated with a carbon material layer through a chemical vapor deposition method; the porous carbon is prepared by carbonizing resin containing metal nitride after alkali activation and pore forming, and the resin containing the metal nitride is prepared by condensation polymerization of a phenolic compound, an aldehyde compound and the metal nitride in the presence of a catalyst. The porous carbon is doped with the metal nitride in the resin polycondensation process, the conductivity of the nano silicon carbon is effectively improved, the powder resistance is reduced, holes in the surface of the porous carbon provide more expansion space for deposited nano silicon, a carbon material layer formed by subsequent deposition and coating provides a protection effect, the reaction between silicon and an electrolyte can be inhibited, and the service life of the nano silicon carbon is prolonged. A stable SEI film is formed, the cycling stability of the material is improved, the volume expansion rate of a pole piece is inhibited, and the cycling life and the stability of the battery are improved.

The invention relates to a silicon-carbon composite material and a preparation method and application thereof.The preparation method comprises the steps that a porous graphite raw material is subjected to acid pickling and smashing to obtain pretreated porous graphite, then the pretreated porous graphite is soaked in a carbon precursor solution in a vacuum mode, carbonization treatment is conducted after centrifugal separation, pores of the porous graphite are filled with carbides, physical activation is conducted, and the silicon-carbon composite material is obtained; the preparation method comprises the following steps: forming pores in a carbide to form a graded pore structure to obtain a porous graphite composite material, then carrying out silicon deposition in a fluidized bed to obtain a uniform nano silicon layer, and then carrying out carbon coating treatment to obtain a silicon-carbon composite material; the graphite with relatively low cost is adopted as a matrix, high capacity and long cycle performance of the graphite-based silicon-carbon negative electrode material are realized through hierarchical pore structure design, carbonization-activation synergistic pore forming and interface deposition process optimization, and the graphite-based silicon-carbon negative electrode material can be applied to the fields of power batteries and high-energy-density energy storage, especially the field of lithium ion batteries and has wide application prospects. The expansion rate of the battery can be reduced, and the specific capacity, cycling stability and safety of the lithium ion battery can be improved.

The invention discloses a preparation process of an aluminum oxide ceramic material, which comprises the following steps: S1, pretreatment of aluminum oxide powder: taking alpha-Al2O3 powder as a raw material, adding a dispersion medium, carrying out ball milling, transferring into an ultrasonic dispersion machine, dispersing, and further carrying out vacuum drying to obtain pretreated aluminum oxide powder; s2, chemical activation treatment: weighing pretreated aluminum oxide, magnesium oxide, nano silicon dioxide, calcium oxide, zirconium dioxide, titanium dioxide and modified nano silicon carbide in parts by weight, mixing, sequentially adding a dispersing agent absolute ethyl alcohol and a KH550 silane coupling agent, stirring at a high speed, adding a polyvinyl alcohol binder, and continuously stirring to obtain ceramic slurry; s3, sieving the ceramic slurry, filling the ceramic slurry into a mold, and performing isostatic pressing to obtain a ceramic green body; and S4, putting the ceramic green body into a box-type sintering furnace, sintering step by step, and cooling to room temperature along with the furnace to obtain the aluminum oxide ceramic material. The prepared aluminum oxide ceramic material has high compactness, excellent dielectric strength and mechanical property, low energy consumption and great application potential.

The invention belongs to the technical field of material surface plating, and particularly relates to an aero-engine blade and a preparation method thereof. According to the preparation method, the component nano silicon carbide of the blade material is subjected to modification treatment, meanwhile, the carbon fiber composite material is introduced for common use, and the composite coating is formed on the surface through spraying treatment, so that the aero-engine blade is prepared, the cold and heat cycle resistance is effectively improved, and meanwhile, good erosion resistance is obtained.

The invention relates to the technical field of electrode materials, in particular to a silicon-carbon negative electrode material and a preparation method and application thereof. The silicon-carbon negative electrode material comprises a plurality of silicon-carbon composite particles, each silicon-carbon composite particle comprises porous carbon, nano silicon particles and phosphorus element which are attached in pores of the porous carbon, and coating carbon for coating the porous carbon, and n-type doping of the phosphorus element is formed at the joint of the nano silicon particles and the porous carbon. The preparation method comprises the following steps: (1) adsorbing phosphoric acid in porous carbon, and carrying out a heating reaction in a protective gas atmosphere to generate phosphorus-infiltrated porous carbon; (2) introducing a gaseous silicon source in a protective gas atmosphere, and carrying out silicon deposition on the phosphorus-infiltrated porous carbon by adopting a chemical vapor deposition method to obtain a phosphorus-doped silicon carbon material; and (3) carrying out carbon coating on the phosphorus-doped silicon carbon material to obtain the phosphorus-doped silicon carbon material. According to the method, the rate capability of the silicon-carbon negative electrode material can be remarkably improved while high first efficiency and high gram capacity are ensured.

The invention relates to a silicon-carbon composite material capable of improving the cycling stability of a battery, a preparation method of the silicon-carbon composite material, a negative pole piece and a lithium ion battery. The carbon-silicon composite particle comprises a silicon-carbon inner core and a carbon coating layer, nano-silicon is attached in holes and / or on the surface of a porous carbon matrix to form the silicon-carbon inner core, and the carbon coating layer is coated on at least part of the surface of the inner core; the porous carbon matrix and the carbon coating layer are both doped with halogen. According to the silicon-carbon composite material, the electron conductivity of the silicon-carbon composite material is improved by doping the halogen in the porous carbon matrix inside the silicon-carbon composite material and the carbon coating layer outside the silicon-carbon composite material; and meanwhile, the porous carbon matrix, the inner core composed of the nano silicon and the carbon coating layer are mutually matched and have synergistic interaction, so that the volume expansibility and defects of the silicon-carbon composite material are reduced, and the cycle stability is improved.

A silicon-carbon material, a preparation method therefor, a secondary battery, and an electric device. The silicon-carbon material comprises silicon-carbon composite particles; the silicon-carbon composite particles comprise a porous carbon material, nano-silicon grains and a silicon carbide material layer; the porous carbon material is provided with through pores, the nano-silicon grains are located in the through pores, and the silicon carbide material layer is partially located on through pore walls; the grain size of the nano-silicon grains is not smaller than the average pore diameter of the porous carbon material. The silicon-carbon material is used as an active material of a negative electrode sheet, thereby improving the cycle performance of batteries.

The invention provides nano-silicon-based high-strength concrete and a preparation method thereof, and belongs to the technical field of concrete.The concrete is prepared from cement, mineral powder, fly ash, machine-made sand, first-class gravel, second-class gravel, an additive, nano-silicon or a nano-silicon composite modified material and water; the additive is a polycarboxylic acid water reducer and / or a polyether air entraining agent. According to the prepared concrete, the nano silicon material with good dispersity is added, so that the cement consumption can be reduced, the cost can be reduced, and the workability, the strength and the durability can be improved; and the preparation process is simple and convenient, is suitable for large-scale production, and can be widely applied to the engineering fields of high-rise buildings, bridges, tunnels and the like.

The invention provides a negative plate and a battery. The negative plate comprises a negative current collector and a coating, and the coating is divided into an inner layer and an outer layer; the inner layer is close to the surface of the negative current collector and the outer layer is away from the surface of the negative current collector; the first negative electrode active substance of the inner layer comprises a silicon-based negative electrode material, and the silicon-based negative electrode material comprises at least one of silicon oxide, silicon carbide, nano silicon and silicon alloy. The second negative electrode active material of the outer layer comprises a carbon negative electrode material, and the carbon negative electrode material comprises at least one of natural graphite, artificial graphite, hard carbon, soft carbon, mesocarbon microbeads and graphene. By adopting the specific double-layer active material layer structure, the performance of the negative electrode is effectively improved, and the energy density and the fast charging performance of the battery are improved. Meanwhile, due to the special multi-layer structural design, the volume expansion effect of the silicon-based negative electrode material can be effectively relieved, the structural stability of the negative electrode is optimized, the structural stability of the negative electrode can be kept for a long time in the charge-discharge cycle, and then the battery performance is optimized.

The invention provides a negative electrode material and a preparation method thereof. The negative electrode material comprises an inner core and a coating layer coating the surface of the inner core, the inner core comprises a porous carbon matrix and amorphous nano silicon particles dispersed in the porous carbon matrix; pores in the porous carbon matrix comprise micropores, the pore diameter of the micropores is less than 2nm, and the quantity of the micropores accounts for more than or equal to 80% of the total quantity of the pores. According to the negative electrode material, a silicon-carbon material core is coated with a coating layer, and the number of micropores in a porous carbon matrix is adjusted, so that on one hand, direct contact reaction between high-activity nano silicon and an electrolyte is effectively avoided; and on the other hand, the particle size of the amorphous nano silicon particles in the negative electrode material is relatively small, the dispersity in the porous carbon matrix is relatively good, and the negative electrode material has relatively low expansion rate and relatively high initial coulombic efficiency, rate capability and cycle performance.

The invention provides a composite silicon-carbon negative electrode material as well as a preparation method and application thereof. The composite silicon-carbon negative electrode material comprises a composite silicon-carbon inner core and a carbon coating layer arranged on the surface of the composite silicon-carbon inner core, the composite silicon-carbon inner core comprises a porous carbon skeleton and nano silicon particles, modified holes are formed in the porous carbon skeleton, graphite microcrystalline layers are arranged around openings of the modified holes, and the nano silicon particles are arranged on the surface of the porous carbon skeleton and in the modified holes. The modified holes are formed in the composite silicon-carbon negative electrode material, silicon particles can be properly deposited in the modified holes, and the graphite microcrystalline layer is arranged around the modified holes, so that the resistivity of the material can be greatly reduced, and the electrical property of the silicon-carbon negative electrode material is improved.

The present invention is a negative electrode active material comprising negative electrode active material particles. The negative electrode active material is characterized in that: the negative electrode active material particles include porous carbon structures; silicon and a silicon oxide are dispersed in the interiors of the porous carbon structures; a low-valent nanosilicon oxide in an amorphous state is dispersed in at least surface-layer portions of the interiors of the porous carbon structures; the low-valent nanosilicon oxide is SiOx, where x is less than 1.0; and nanosilicon with a crystalline structure is dispersed at least in deep layer portions of the interiors of the porous carbon structures, such portions being deeper than where the low-valent nanosilicon oxide is dispersed. Due to this configuration, it is possible to provide a negative electrode active material that can increase capacity while maintaining battery characteristics.

The invention discloses a LiAlO2 fast ion conductor coated silicon-carbon composite material as well as a preparation method and application thereof, and belongs to the technical field of lithium ion battery materials. The LiAlO2 fast ion conductor coated silicon carbon composite material has a core-shell structure; an inner core of the composite material is a silicon-carbon composite material, the silicon-carbon composite material is formed by coating a three-dimensional carbon material with an amorphous carbon layer and loading a nano silicon compound, a shell of the composite material is a LiAlO2 fast ion conductor layer, and the silicon-carbon composite material with a three-dimensional network structure is constructed, and the surface of the silicon-carbon composite material is coated with the LiAlO2 fast ion conductor layer, so that the composite material is obtained. According to the present invention, with the LiAlO2, the volume expansion of the nanometer silicon during the charge-discharge process can be effectively relieved, the stability of the silicon-carbon composite material structure can be improved so as to significantly improve the cycle performance of the battery, and the LiAlO2 can provide the rapid channel for the transmission of the lithium ion during the charge-discharge process so as to improve the rate performance of the battery;

The invention provides a silicon-carbon negative electrode material, a preparation method thereof and a lithium ion battery. The silicon-carbon negative electrode material comprises a porous carbon substrate, nano silicon deposited on the surface and in pores of the porous carbon substrate, and a conductive polymer layer coated on the surface of the nano silicon, the porous carbon matrix is formed by taking zinc gluconate as a carbon source through high-temperature pyrolysis and carbonization. According to the silicon-carbon negative electrode material, the preparation method thereof and the lithium ion battery provided by the invention, the silicon-carbon negative electrode material has high specific surface area, excellent conductivity and stable cycle performance, and shows excellent cycle stability and relatively high reversible capacity in the charge-discharge process when being used for the lithium ion battery; the energy density and the cycle life of the lithium ion battery are effectively improved, a new technical approach is provided for preparation of the silicon negative electrode material of the lithium ion battery, and the preparation method has a wide application prospect.

The invention provides a silicon-carbon negative electrode material as well as a preparation method and application thereof, and relates to the technical field of lithium ion batteries. The silicon-carbon negative electrode material comprises an inner core and double coating layers, nanometer silicon and graphite sheets are tightly combined through electrostatic interaction to form the inner core, and the outer surface of the inner core is sequentially coated with a graphene carbon coating layer and a titanium dioxide coating layer from inside to outside. The nanometer silicon and the graphite flake in the inner core of the silicon-carbon negative electrode material are tightly combined through electrostatic interaction, so that the stability of the inner core is enhanced, and the conductivity of the negative electrode material is also enhanced; the graphene carbon coating layer and the titanium dioxide coating layer are used as protective shells to inhibit volume expansion of silicon and ensure good contact between nano silicon and graphite flakes, so that side reactions are reduced; through the synergistic effect of the inner core and the double coating layers, the silicon-carbon negative electrode material has high specific capacity, good cycle performance and high capacity retention rate. The preparation method is simple, raw materials are easy to obtain, cost is low, and the method is suitable for industrial production.

The invention relates to a silicon-carbon composite material, a preparation method thereof and a lithium ion battery. The preparation method comprises the following steps: adding porous carbon into a fluidized bed, heating and introducing alkaline mixed gas to obtain amino porous carbon; transferring the amino porous carbon into fluidized bed equipment, vacuumizing, heating, and introducing hydroxyl silane gas for nano silicon deposition; after deposition, introducing ultraviolet light for polymerization and oxidation to obtain a modified silicon-carbon precursor material; transferring the modified silicon-carbon precursor material into a tubular furnace, introducing inert gas to discharge air in the tube, and performing first carbonization to obtain a silicon-carbon material; and adding the resin into an organic solvent, adding the fast ion conductor and the silicon carbon material to be uniformly dispersed, performing spray drying, and performing secondary carbonization to obtain the fast ion conductor coated silicon carbon composite material. The preparation method provided by the invention is simple and efficient, and the prepared silicon-carbon composite material can improve the fast charging performance and is suitable for a negative electrode material of a high-energy-density lithium ion battery.

The invention relates to the field of battery materials, in particular to a preparation method and application of a modified porous carbon material for nano silicon CVD (chemical vapor deposition). According to the invention, the non-porous two-dimensional lamellar material is self-assembled on the porous carbon material, so that the modified porous carbon material for CVD deposition of nano-silicon is obtained, when high-speed carrier gas passes through the surface of the porous carbon material, the two-dimensional lamellar material on the surface of the porous carbon material is stressed intensively, and is not dispersed due to a pore channel structure on the surface of the porous carbon material; therefore, under the same fluidization condition, the modified porous carbon material shows better fluidization characteristics, deposition of nano silicon is more uniform after silane or organic gas is subsequently introduced, the content of floating silicon on the surface is extremely low, silicon enrichment can be reduced while the capacity of the negative electrode material is ensured, and the service life of the negative electrode material is prolonged. Furthermore, the electrochemical performance of the obtained nano silicon-carbon composite negative electrode material is more prominent, and the performance stability of negative electrode materials produced in different batches is also good.

The invention relates to the field of ceramic materials, in particular to a high-temperature-resistant composite ceramic material and a preparation method thereof.The high-temperature-resistant composite ceramic material is prepared from, by weight, 80-100 parts of zirconium oxide, 10-20 parts of silicon carbide, 5-10 parts of aluminum nitride, 1-5 parts of a sintering aid and 5-10 parts of modified silicon powder; the modified silicon powder takes nano silicon powder as a core body, the core body is sequentially coated with a transition metal organic polymer and oxidized asphalt, and the prepared composite ceramic material is good in mechanical strength and excellent in high temperature resistance and has important application value in the field of aerospace.

The invention discloses a high-conductivity bridged silicon-carbon composite material as well as a preparation method and application thereof, and belongs to the technical field of lithium ion batteries. The high-conductivity bridged silicon-carbon composite material comprises a core-shell structure with an inner core and an outer shell, the inner core is porous carbon and a carbon nano tube growing on the surface of the porous carbon in situ, and a nano silicon layer is attached to pores and surfaces of the porous carbon and the carbon nano tube; and the shell is a carbon coating layer. According to the high-conductivity bridged silicon-carbon composite material provided by the invention, the carbon nanotubes are grown on the surface of the porous carbon in situ, and contact among particles is similar to bridging, so that a point-line conductive network is formed, the intrinsic conductivity of the composite material is improved, and the electron transfer rate is accelerated. Meanwhile, the carbon nanotubes have extremely high strength and hardness, the mechanical strength of the porous carbon substrate can be remarkably improved by introducing the carbon nanotubes into the porous carbon material, expansion of nano silicon in the charging and discharging process can be better restrained, and the performance of high capacity, high first efficiency, long circulation and high magnification is shown.

The invention discloses a high-strength nano composite stiffening filling master batch and a preparation method thereof, and relates to the technical field of high polymer materials, the raw materials comprise a nano filler, a matrix material and a functional additive; the nano filler comprises nano diamond, nano silicon carbide and bio-based nano cellulose, the base material comprises polyimide, polyether-ether-ketone and bio-based polylactic acid, and the functional additive comprises a hindered phenol antioxidant, a nano aluminum hydroxide flame retardant, a nano silicon dioxide reinforcing agent, an ultraviolet light absorber, a carbon nano tube and nano silver particles. Nano-diamond, nano-silicon carbide and bio-based nano-cellulose are adopted as nano-fillers, polyimide, polyether-ether-ketone and bio-based polylactic acid are combined as base materials, and a plurality of functional additives are added, so that the preparation of the high-strength nano-composite stiffening filling master batch is realized; and the problems of poor dispersibility, mechanical property damage, insufficient hardness and poor interface bonding of the traditional filler master batch can be solved.

The invention provides low-carbon premixed concrete based on industrial solid waste synergistic activation and a preparation method of the low-carbon premixed concrete. The low-carbon premixed concrete is prepared from the following components: a nano silicon-based anti-corrosion early strength agent, a cementing material, recycled aggregate, electric furnace tailings, waste carbon fibers, a polycarboxylate superplasticizer and water, the preparation method comprises the following steps: S1, preparing a nano silicon-based anti-corrosion early strength agent through silane hydrolysis and modification reaction of nano silicon dioxide; s2, preparing a cementing material: mixing fly ash, steel slag, mineral slag and Portland cement, calcining, grinding, spraying a composite alkali activator, and aging; s3, mixing and forming: wet-mixing the cementing material, the recycled aggregate, the iron tailing sand, the waste fibrilia, the nano silicon-based anti-corrosion early strength agent, the polycarboxylate superplasticizer and water, and pre-injecting and forming; and S4, carbonization curing. According to the invention, efficient utilization of industrial solid waste is realized, and the low-carbon environmental protection performance and mechanical property of the concrete are improved.

The invention relates to a silicon-carbon composite material with a porous structure and a preparation method thereof, and the silicon-carbon composite material with the porous structure comprises an N / P co-doped porous carbon skeleton with micropore, mesopore and macropore channel networks, and amorphous or low-crystalline nanometer silicon particles which are uniformly loaded in the porous carbon skeleton and have the average particle size of 15-40nm, the mass percent of silicon in the composite material is 40-60%, and good interface bonding is formed between silicon and carbon. The preparation method mainly comprises the following steps: firstly, preparing an N / P co-doped porous carbon skeleton through a template method in combination with high-temperature carbonization and N / P source co-pyrolysis; and hydrolyzing an organic silicon source in the carbon skeleton to form silicon dioxide, and performing low-temperature metal thermal in-situ reduction to obtain the nano-silicon loaded composite material. Through a unique porous carbon skeleton design and a precise in-situ composite strategy of nano silicon, the prepared material shows high specific capacity, high initial coulombic efficiency and excellent cycling stability and rate capability when being used as a negative electrode of a lithium ion battery.

The invention provides a rare earth heat insulation coating and a preparation method thereof. The coating comprises the following components in parts by weight: 50-60 parts of acrylic resin, 10-15 parts of polyurethane modified epoxy resin, 5-8 parts of nano rare earth powder, 3-5 parts of filler, 0.5-1 part of a coalescing agent, 1-2 parts of a defoaming agent, 1-3 parts of a dispersing agent, 0.5-1 part of an ultraviolet light absorber and 1-2 parts of a silane coupling agent. Wherein the nano rare earth powder comprises lanthanum oxide powder, cerium chloride powder and yttrium hexaboride powder, and the filler comprises nano hollow microspheres, nano calcium carbonate and nano aluminum silicate. The rare earth heat insulation coating has excellent heat insulation effect and mechanical property, and can be applied to various scenes.

The invention relates to the technical field of lithium ion batteries, in particular to a carbon source mixed gas CVD coated silicon-carbon negative electrode material, a preparation method and a lithium ion battery. The preparation method comprises the following steps: 1) preparation of a silicon-carbon material: placing porous carbon in equipment, regulating and controlling the gas speed and the dynamic rotation speed of the equipment to uniformly disperse the porous carbon, heating to 380-650 DEG C, and introducing silane mixed gas with the concentration of 5-50% to form the silicon-carbon material; and 2) coating the silicon-carbon material with mixed gas carbon: introducing mixed gas sources with different proportions into equipment, regulating and controlling the gas speed and the dynamic rotation speed of the equipment to uniformly disperse the mixed gas sources, and heating to 450-700 DEG C to realize uniform carbon coating on the surface of the silicon-carbon material. According to the invention, the problem of explosion caused by self-polymerization reaction of single acetylene is solved; and moreover, the uniform carbon coating isolates the side reaction problem caused by direct contact between the electrolyte and the nano silicon, and the stability of the silicon-carbon material is improved.

The invention provides a phenolic resin-based spherical silicon-carbon composite material as well as a preparation method and application thereof, and belongs to the technical field of lithium battery materials. The preparation method comprises the following steps: preparing spherical phenolic resin by adopting a suspension polymerization method, curing to obtain phenolic resin microspheres, preparing porous carbon spheres by taking the phenolic resin microspheres as a carbon precursor in a carbonization and alkali activation manner, carrying out CVD vapor deposition on nano silicon, and carrying out carbon coating to obtain the phenolic resin-based spherical silicon-carbon composite material. The phenolic resin is utilized to form a highly cross-linked network structure after curing, the carbon spheres obtained after carbonization have good mechanical strength and rigidity, the porous structure of the porous carbon spheres provides a volume change buffering structure for nano-silicon, the lithium ion path is shortened, the spherical structure is beneficial to uniform dispersion, nano-silicon particles are prevented from gathering, and the performance of the lithium ion battery is improved. And the porous carbon spheres with high specific surface area can also improve the interface reaction activity, so that the problems of high volume expansion, low conductivity and slow ion diffusivity of silicon are solved.