2691 results about "Nanofiber" patented technology

The invention discloses a lithium ion battery composite diaphragm, a preparation method and a lithium ion battery, and relates to the technical field of lithium ion batteries. The lithium ion battery composite diaphragm comprises a base membrane and a functional coating arranged on the negative electrode side of the base membrane, the functional coating sequentially comprises an ion conducting layer, a thermal barrier layer and a self-repairing layer from the position close to the base film to the position far away from the base film; wherein the base membrane is a polyimide and aramid nanofiber blended electrostatic spinning membrane; the ion conducting layer comprises a compound of a modified fast ion conductor and polyvinylidene fluoride-hexafluoropropylene; the thermal barrier layer comprises a cross-linked network of boron nitride nanosheets and polybenzimidazole; the self-repairing layer comprises polyurethane microspheres loaded with dynamic disulfide bonds. The composite diaphragm provided by the invention can remarkably inhibit a purple area on the surface of a negative electrode, and enhance high-temperature self-protection and interface self-repairing of the lithium ion battery, so that the cycle and safety performance of the lithium ion battery are remarkably improved.

The invention relates to a device and a method for preparing nanofiber core-spun yarn through batch coaxial electrostatic spinning. The device comprises a needleless dish-shaped spray head, an air blowing auxiliary device, a liquid supply device, an annular twisting device, a high-pressure generator, a negative-pressure air suction device, a winding device and an unwinding device. The core yarn penetrates through the axis of the needleless dish-shaped nozzle, the nanofiber generated by the needleless dish-shaped nozzle coaxially wraps the surface of the core yarn through the whole spinning device, and batch preparation can be achieved. The device is further provided with an air blowing auxiliary device and a negative pressure air suction device, under the air blowing effect of an air blowing nozzle and the adsorption effect of a negative pressure air suction shell, airflow force can be generated to promote jet flow to be further stretched in a straightened mode, under the common influence of electric field force and the airflow force, the jet flow is fully stretched, bending is reduced, and the service life of the jet flow is prolonged. Therefore, the nanofiber bundles can continuously cover the surface of the core yarn in a high-orientation state under the traction of the annular twisting device, and the continuous nanofiber core-spun yarn is formed.

The invention discloses a method for enriching light metal ions in a pore channel based on carbon nanofiber / carbon fiber nano confinement, and belongs to the technical field of sample pretreatment, and the method comprises the following steps: S1, preparing a carbon nanofiber / carbon fiber confinement material; and S2, putting the carbon nanofiber / carbon fiber confinement material obtained in S1 into a light metal ion solution, and stirring. According to the method for enriching the light metal ions in the pore channel based on the carbon nanofiber / carbon fiber nano confinement, the carbon nanofiber / carbon fiber is used as a confinement fluid carrier, ultrapure water, methanol or n-hexane is used as an extracting agent, a chelating agent does not need to be introduced, the method is green and environmentally friendly, the mass transfer rate is increased, and the method is suitable for large-scale industrial production. Therefore, high enrichment of light metal ions in water is realized.

The invention provides a nylon 6 nanofiber virus-removing filtering membrane and a preparation method and application thereof.The nylon 6 nanofiber virus-removing filtering membrane comprises a base material and a nylon 6 nanofiber membrane compounded to the surface of the base material, the average pore size of the virus-removing filtering membrane is 20 nm, the virus-removing filtering membrane plays a role in blocking parvoviruses, the surface of the virus-removing filtering membrane is charged, and the surface of the virus-removing filtering membrane is not prone to being damaged. Proteins with the same charges on the surface can be prevented from adhering to the surface of the fiber. In the preparation process of the virus-removing filtering membrane, the nylon 6 nanofibers with a certain diameter range are selected and compounded on the surface of the base material in a stable dispersion state, the uniform microporous virus-removing filtering membrane is prepared, the effect that parvoviruses are blocked and protein molecules are not easily intercepted is achieved, the hydrophilicity of the nylon 6 nanofibers is relatively good, and the virus-removing filtering membrane has a good application prospect. The non-specific adsorption of the filtering membrane on the protein is reduced; the nylon 6 nanofiber virus-removing filtering membrane can be applied to the field of biological medicine products, and has important significance on separation and purification of biological preparations.

The invention discloses an injectable material for promoting bone regeneration through piezoelectric and conductive integrated nanofiber hydrogel with ultrasonic response and a preparation method of the injectable material. The injectable material is composed of piezoelectric and conductive nanofibers and hydrogel. Wherein the piezoelectric conductive nanofiber is prepared from an inorganic piezoelectric material and a piezoelectric polymer through electrostatic spinning, or is prepared from an inorganic / organic composite piezoelectric material and a biological material with conductive performance through electrostatic spinning.

The invention discloses a novel textile material with eiderdown wrapped by rainbow yarn nanofibers and a preparation method. The novel textile material comprises skeleton fibers located at the axis, an eiderdown component with a heat preservation effect and a rainbow yarn nanofiber reinforcing layer wrapping the outer surface of the eiderdown component. The wrapping reinforcing layer is of a three-dimensional network structure formed by continuous or quasi-continuous nanofibers in a winding, interweaving and lap joint mode, so that stable compounding and structural shaping of down feather components and skeleton fibers are achieved under the condition that the down feather components and the skeleton fibers do not depend on adhesive fixation. The preparation method comprises the following steps: cleaning, drying and opening down for pretreatment; performing melt differential electrostatic spinning on the polymer melt under a high-voltage electrostatic field to form rainbow yarn nanofibers; the down flocs are introduced into the coating area through the framework fibers, so that the rainbow yarn nanofibers are deposited and wound to form a coating reinforcing layer; after being gathered and shaped and twisted into yarns, the yarns can be continuously dragged and wound. The novel textile material has spinnability, structural stability and long-acting thermal insulation performance, and is suitable for spinning, weaving and knitting processing.

The invention discloses a preparation method and application of a composite PVDF-HFP and polylysine nanofiber diaphragm, and belongs to the technical field of lithium batteries. The composite material is prepared by blending polyvinylidene fluoride-hexafluoropropylene (PVDF-HFP) and polylysine and then carrying out an electrostatic spinning process. The PVDF-HFP is utilized to provide excellent mechanical strength and chemical stability, rich polar amino functional groups in a polylysine molecular chain are utilized to improve the lyophilic property of the membrane, and anions in an electrolyte are fixed through an intermolecular acting force, so that the transference number of lithium ions is increased, and the lithium ions are induced to be uniformly deposited. The nanofiber membrane combines the characteristics of PVDF-HFP and polylysine, has high porosity, good thermal stability and excellent interface compatibility, can effectively inhibit the growth of lithium dendrites and prevent the diaphragm from being punctured, and can significantly prolong the cycle life and improve the safety performance of the lithium metal battery when being applied to the lithium metal battery.

The invention relates to the technical field of sewage treatment, in particular to an electrostatic spinning PVDF nanofiber membrane for sewage treatment and a preparation method and application of the electrostatic spinning PVDF nanofiber membrane. The preparation method comprises the following steps: dissolving PVDF (Polyvinylidene Fluoride) particles in a mixed solvent of DMF (Dimethyl Formamide) and acetone, adding nano TiO2 particles subjected to APTES (Aminopropyltriethoxysilane) surface modification, and adding PVP (Polyvinyl Pyrrolidone) into the solution to obtain a uniform spinning solution; spinning by adopting electrostatic spinning equipment to obtain a PVDF / TiO2 / PVP nanofiber membrane; the nanofiber membrane is soaked in a sodium hydroxide solution, then the membrane is soaked in a Tris-HCl buffer solution containing dopamine, and the final electrostatic spinning PVDF nanofiber membrane is obtained. The average diameter of nanofibers of the nanofiber membrane is 200-300nm, the porosity of the membrane is 70-80%, and the water contact angle is less than 60 degrees; when the nanofiber membrane is used for treating sewage containing organic pollutants and heavy metal ions, the removal rate of the nanofiber membrane on methyl orange can reach 95% or above; the rejection rate of copper ions can reach 90% or above; the removal efficiency of organic pollutants and heavy metal ions is obviously improved.

The invention belongs to the related technical field of flexible electrodes, and discloses a preparation method, a product and application of a high-temperature-resistant flexible metallized ceramic nanofiber composite electrode. The method comprises the following steps: carrying out electrostatic spinning on electrostatic spinning sol doped with an organic polymer to obtain a precursor of a flexible ceramic nanofiber membrane; carrying out primary high-temperature calcination on the precursor to remove the doped organic polymer so as to obtain a flexible ceramic nanofiber membrane; growing and coating a metal conductive layer on the surface of the flexible ceramic nanofiber membrane to obtain an electrode precursor; and carrying out secondary high-temperature calcination on the electrode precursor to obtain the required composite electrode. The invention also discloses a product obtained by the preparation method and application. According to the invention, the problem that the flexible sensor is not resistant to high temperature is solved.

The invention belongs to the field of composite materials, and particularly relates to a nanofiber radiation refrigeration heat insulation film with a bionic multilayer structure. The device sequentially comprises a bionic anti-reflection layer, a solar spectrum reflection layer, a nanofiber porous heat insulation layer and an atmospheric window radiation layer from outside to inside, the bionic anti-reflection layer is a sub-wavelength nano bulge array simulating a moth eye structure and is formed on the outer surface of the solar spectrum reflecting layer; the solar spectrum reflecting layer is a polymer film doped with high-reflectivity nanoparticles; the nanofiber porous heat insulation layer is a porous membrane formed by interweaving polymer nanofibers prepared by an electrostatic spinning technology; the atmospheric window radiation layer is a functional layer formed by coating or blending high-emissivity inorganic nanoparticles on the inner surface of the nanofiber porous heat insulation layer; the film integrates bionic antireflection, high sunlight reflection, efficient heat radiation and physical heat insulation, and efficient, stable and flexible daytime radiation refrigeration is achieved.

The invention discloses an inorganic sepiolite nanofiber prepared from epoxy grafted modified sepiolite, and the structural formula of the inorganic sepiolite nanofiber is shown in the specification, wherein R represents a group of epoxy resin; the sepiolite is subjected to multiple modification, so that the specific surface area of the sepiolite is increased, and the stability, dispersity and compatibility of the sepiolite in an organic polymer are improved. The surface of the modified sepiolite has rich epoxy groups, when the sepiolite is used for a waterborne epoxy coating, epoxy on the surface of the modified sepiolite and waterborne epoxy can be reacted and combined together as long as a curing agent is added, the binding force of the sepiolite and the epoxy is further enhanced, the modified sepiolite is dispersed more uniformly in the demulsified epoxy, and the enhancement effect is better. And the modified sepiolite can also be directly used as a coating, only the curing agent needs to be added at the moment, and the curing agent can react with epoxy grafted with the modified sepiolite to form a consolidated sepiolite fiber network.

The invention discloses a method for preparing micro-nano fibers through needle-free electrostatic spinning equipment assisted by an ion blower gun, and belongs to the technical field of spinning. The method specifically comprises the following steps: S1, dissolving a high-molecular polymer in a proper solvent to prepare a spinning precursor solution; and S2, preparing the micro-nano fiber from the spinning solution on a suitable collection surface by using an ion blower gun assisted needleless electrostatic spinning device. Through the synergistic effect of directional airflow generated by the ion blower gun and a controllable electric field, fiber surface charges are effectively neutralized, the jet instability is inhibited, and the controllability of a fiber flight path is improved. Meanwhile, the ionic wind assists in enhancing interface attachment between the fiber and the collector, uniform deposition is promoted, and the compactness and adhesive force of the fiber membrane are remarkably improved. According to the method, chemical modification does not need to be carried out on a material system, the intrinsic performance of the fiber is kept, universality and expandability are achieved, and a new path is provided for continuous preparation of the high-performance micro-nano fiber.

The invention provides unsaturated waterborne polyurethane, a polyurethane composite material as well as a preparation method and application of the unsaturated waterborne polyurethane and the polyurethane composite material. According to the preparation method, isocyanate is introduced into a soft segment through a block process, an unsaturated chain extender is added, unsaturated double bonds are introduced, and waterborne polyurethane with excellent performance is prepared. Meanwhile, cellulose nanofibers are added into the unsaturated waterborne polyurethane, so that the interfacial compatibility and mechanical properties of the unsaturated waterborne polyurethane are improved. The unsaturated waterborne polyurethane provided by the invention has excellent film-forming property, stability and mechanical property.

The invention provides a multi-scale super-amphiphobic anti-wax coating and a preparation method thereof.The preparation method comprises the following steps that S1, cellulose nanofibers are added into an ethyl alcohol-water mixed solution, after ultrasonic treatment and uniform stirring are conducted, sodium methyl silicate is added for stirring reaction, then fluorosilane and tetraethoxysilane are added for hydrolytic condensation reaction, and a mixed solution is obtained; centrifuging and drying to obtain multi-scale fluorinated micro-nano particles; and S2, mixing the multi-scale fluorinated micro-nano particles, an adhesive and a diluent in proportion, performing ultrasonic stirring, spraying the mixture on a base material, and curing to obtain the multi-scale amphiphobic paraffin-proof coating. Hydrophobic modification is carried out on cellulose nanofibers by using fluorosilane, sodium methyl silicate and tetraethoxysilane to form a multi-scale micro-nano multilevel structure, and the structure can effectively capture air and is combined with ground surface energy, so that the coating has excellent super-amphiphobic performance.

The application belongs to the field of separation and specifically relates to a cellulose / PVDF electrostatic spinning oil-water separation membrane and a preparation method thereof. The preparation method comprises the following steps: S1: preparing cellulose stearate; S2: mixing cellulose stearate obtained in step S1 and polyvinylidene fluoride (PVDF) prepared into solutions respectively to obtain a spinning solution; and S3: defoaming the spinning solution obtained in step S2 and then electrostatic spinning to obtain a cellulose stearate / polyvinylidene fluoride (PVDF) hydrophobic oleophilic oil-water separation membrane. The mixed electrostatic spinning nanofiber membrane has better mechanical properties, and due to the addition of modified cellulose, the nanofiber membrane has greater separation flux, higher separation efficiency and greater porosity.

The invention belongs to the technical field of biomedical materials and tissue regeneration, and particularly discloses hydrogel with a self-enhanced piezoelectric effect as well as a preparation method and application of the hydrogel. The hydrogel is prepared by taking microphone (MXene), cellulose nanofiber (CNF), tyramine grafted carboxymethyl cellulose (T-CMC) and regenerated silk fibroin (RSF) as main materials through an enzyme crosslinking reaction of horse radish peroxidase (HRP) and hydrogen peroxide (H2O2). The hydrogel has excellent mechanical properties, biocompatibility and safety, and can realize self-enhancement in vivo and generate stable piezoelectric signals. The piezoelectric stimulation can promote proliferation, migration and differentiation of osteogenesis-related cells and regulate and control a bone tissue microenvironment, so that formation and repair of new bones in a bone defect area are remarkably accelerated. The hydrogel can be used as an injectable or moldable bone tissue repair material, and is suitable for bone fracture, bone defect and other bone tissue regeneration scenes.

The invention belongs to the technical field of gas analysis, and relates to a surface-enhanced Raman scattering flexible substrate material as well as a preparation method and application thereof. The surface-enhanced Raman scattering flexible substrate material comprises a three-dimensional network structure and silver nanoparticles, the three-dimensional network structure is composed of hydroxypropyl methyl cellulose nanofibers, the silver nanoparticles are wrapped in the hydroxypropyl methyl cellulose nanofibers, and the silver nanoparticles are of a polyhedral structure. The surface-enhanced Raman scattering flexible substrate material is used for detecting thiol compounds in a solution, and the detection limit can reach 10 <-19 > M level; after the surface of the silver nanoparticle is modified with the probe, the material can detect trace substances in exhaled air. In addition, after the material is stored for 6 months at room temperature, the SERS signal intensity attenuation is less than or equal to 4%, and the relative standard deviation detected by 20 random sites is only 4.04%.

The invention belongs to the technical field of waterproof and moisture permeable membrane materials, and particularly relates to a bio-based microporous membrane based on a template and a preparation method and application thereof, and the preparation method comprises the following steps: dispersing one of polybenzimidazole, aminated PI and carboxylated PBO and modified CNF into a DMF / water system; performing electrostatic spinning on the high-viscosity spinning solution; carrying out low-temperature vacuum drying treatment on the modified nanofiber self-supporting framework; coating and filling the bio-based polyurethane resin into the bio-based microporous membrane template, and carrying out negative pressure adsorption until the filling is uniform; and carrying out gradient drying on the bio-based wet membrane to obtain the bio-based microporous membrane. Compared with the prior art, the problems that in the prior art, the mechanical property or stability of bio-based polyurethane is insufficient, and a nanofiber reinforcing technology is difficult to combine with the bio-based polyurethane are solved. A nanofiber self-supporting framework with a stable structure is prepared through an electrostatic spinning technology, and then the nanofiber self-supporting framework is compounded with bio-based polyurethane to form a microporous membrane layer with waterproof and moisture permeable functions.

The invention discloses a nanometer fiber yarn-based phytosterol Pickering emulsion as well as a preparation method and application thereof, and the nanometer fiber yarn-based phytosterol Pickering emulsion comprises the following components in parts by weight: 0.5-1 part of nanometer fiber yarn; 1 to 10 parts of phytosterol / phytosterol ester; 95 to 105 parts of a water phase component; 95 to 105 parts of an oil phase component; the nanofibers are extracted from agricultural wastes; according to the invention, the nanofiber is used as the only or main stabilizer of the phytosterol Pickering emulsion, so that the problems of solubility, emulsion stability and bioaccessibility of phytosterol can be solved at the same time; and efficient interface stability and steric hindrance stability are realized by utilizing a unique nano network structure of the nano fiber yarns, and a natural, safe and efficient phytosterol delivery system is provided.

The invention discloses a preparation method and application of samarium-doped lanthanum ferrite nanofibers, and the preparation method is a design thought based on synergistic interaction of'defect engineering 'and'morphology control': samarium (Sm) ions with a specific proportion are creatively introduced to the A site of LaFeO3, and lattice distortion is induced by utilizing radius mismatch between the samarium (Sm) ions and lanthanum (La) ions; therefore, high-concentration gas-sensitive active sites (oxygen vacancies) are generated in the intrinsic structure of the material; and the material is constructed into a one-dimensional nanofiber network with a high specific surface area through an electrostatic spinning technology, so that the exposure efficiency of active sites is maximized.

The invention provides a functional nanofiber material as well as a preparation method and application thereof, and the preparation method comprises the following steps: (1) adding raw materials into water to form an electrostatic spinning solution; performing electrostatic spinning to obtain a nanofiber membrane; (2) cross-linking the nanofiber membrane in an organic solvent under the catalysis of acid to obtain a cross-linked nanofiber membrane; and (3) carrying out grafting reaction on the cross-linked nanofiber membrane in a polyamine cross-linking agent, and then reacting with a sulfur-containing reagent to obtain the functional nanofiber material, the functionalized nanofiber material prepared by the preparation method disclosed by the invention combines good biocompatibility of polyvinyl alcohol, high specific surface area and high porosity of nanofiber and a synergistic adsorption effect of the polyamine cross-linking agent and cysteine, and has the advantages of large adsorption capacity, high adsorption rate, strong selectivity, good biocompatibility, stable structure and the like; the heavy metal ions in the plasma can be efficiently and safely removed, and a plurality of defects of the existing adsorption material are overcome.

The invention relates to the technical field of polymer electrolytes, in particular to a composite solid electrolyte based on aramid nanofibers and a lithium-sulfur battery. The composite solid electrolyte is prepared by taking a composite aramid nanofiber membrane with a double-layer three-dimensional structure as a base material, an upper polyaniline base material provides good interface contact stability with a lithium negative electrode, and a lower aramid nanofiber skeleton provides good mechanical support performance for the fiber membrane; and meanwhile, the electrochemical performance of the composite solid electrolyte is comprehensively improved by doping the special porous structure of the composite solid electrolyte with the core-shell porous carbon.

The invention relates to a covalent organic framework modified cellulose nanofiber composite diaphragm which is characterized in that cellulose nanofiber is used as a matrix, an amide type or amine type covalent organic framework layer is grown on the surface in situ, the loading capacity of a covalent organic framework is regulated and controlled, and a hierarchical pore structure with gradient pore diameter is constructed; the preparation method comprises the following steps: synthesizing a covalent organic framework precursor bonded with an imine bond on the surface of cellulose nanofiber in situ by a one-pot method under an acidic mixed solution and a heating condition, and regulating and synchronously reducing to convert into an amine type covalent organic framework; or after the imine bond bonded covalent organic framework is synthesized in two stages, the imine bond bonded covalent organic framework is selectively converted into an amide type covalent organic framework through oxidation modification; the obtained cellulose nanofiber compound coated with the covalent organic framework is subjected to the processes of film forming, solvent replacement, supercritical drying and the like, and the composite diaphragm is obtained; the diaphragm has excellent electrolyte wettability, high liquid absorption rate, good ionic conductivity and thermal stability, and can promote uniform transmission of lithium ions and inhibit growth of lithium dendrites.

The invention belongs to the field of biological medicine and material science, and particularly relates to an intelligent response type piezoelectric nanofiber dressing and a preparation method and application thereof. According to the preparation method, polyvinylidene fluoride-trifluoroethylene, a high polymer material and inorganic nanoparticles are blended and spun through an electrostatic spinning technology, and then a photo-thermal component coating is subjected to surface in-situ oxidation and self-polymerization, so that the composite fiber membrane is prepared. Under the stimulation of ultrasound (US) and near-infrared laser (Laser), the fiber membrane can cooperatively activate the piezoelectric effect and the photothermal effect, generate a dynamic electric field and local high temperature, realize multi-mode cooperative killing of bacteria (the antibacterial rate exceeds 99%), and simulate an endogenous electric field to promote cell migration and wound healing. The dressing has good mechanical properties (the Young modulus is 15-20 MPa), hydrophilicity (the contact angle is about 30 degrees), biocompatibility and stability, is suitable for treatment of chronic infected wounds such as diabetes mellitus and the like, and has the advantages of on-demand activation and intelligent response.

The invention discloses a high polymer / nanofiber composite material with high mechanical property and high weather resistance as well as a preparation method and application thereof, and belongs to the technical field of polymer / nanofiber composite materials. According to the invention, polyether polyol participates in a prepolymerization reaction and is used for preparing a high-molecular polymer from modified nanofibers, and in the reaction process of a curing agent and isocyanate, the modified nanofibers and organic silicon are used as reinforcing phases to be added into the high-molecular polymer; the mechanical property, the weather resistance, the hydrophobic ice resistance, the chemical corrosion resistance and the wear resistance of the high-molecular polymer material are improved. The high polymer / nanofiber composite material with high mechanical property and high weather resistance provided by the invention is suitable for rain erosion protection of wind power blades. The preparation process is simple and efficient, the tensile strength, the elongation at break and the impact strength of the prepared high polymer / nanofiber composite material are remarkably enhanced, and the high polymer / nanofiber composite material is environment-friendly.

The invention provides a heterostructure salinity difference energy conversion film based on HOF / two-dimensional mesoporous carbon as well as a preparation method and application of the heterostructure salinity difference energy conversion film. The salinity difference energy conversion film comprises a two-dimensional mesoporous carbon layer serving as a hydrophobic layer and a hydrogen bond organic framework layer which covers one surface of the hydrophobic layer and serves as a hydrophilic layer, wherein the two-dimensional mesoporous carbon layer is formed by compounding a two-dimensional mesoporous carbon material with regular nanopores and aramid nanofibers; the hydrogen bond organic framework layer is formed by compounding a hydrogen bond organic framework material and aramid nanofibers; the heterogeneous Janus structure salinity gradient energy conversion membrane is constructed by adopting a hydrogen bond organic framework and a two-dimensional mesoporous carbon material, and when the heterogeneous Janus structure salinity gradient energy conversion membrane is applied to salinity gradient energy conversion, high ion selectivity, high structural stability and high ion migration flux can be considered.

The invention provides a graphene oxide and aramid nanofiber hybrid modified chopped fiber reinforced flexible polymer thermal protection material as well as a preparation method and application thereof, and belongs to the field of advanced materials. Aiming at the problems of huge modulus difference, poor interface compatibility and serious stress concentration between fibers and a flexible matrix, a hybrid interface phase composed of graphene oxide and aramid nanofibers is constructed, so that an inert surface microstructure of the chopped fibers is improved, and a multi-scale mechanical interlocking structure is promoted to be formed between the fibers and the flexible matrix; the modulus mismatch between the fiber and a rubber matrix is effectively relieved, and more uniform and efficient stress transfer of an interface area is realized. In the processes of tensile deformation, dynamic loading, high-temperature ablation and the like, the hybrid interface phase can keep tight interface combination between the fibers and the flexible matrix, the ablation anti-scouring performance and mechanical performance of the flexible composite material are remarkably improved, especially the flexible ablation performance in the high-dynamic and deformation state, and the flexible composite material has good application prospects.

The invention belongs to the technical field of biomedical materials and regenerative medicine, and relates to collagen-based injectable fiber hydrogel as well as a preparation method and application thereof. According to the injectable fiber hydrogel, methacrylated collagen and dithiothreitol are subjected to a thiol-ene click reaction rapidly under the action of a photoinitiator through illumination, a primary cross-linked network is formed, and the injection and in-situ gel forming requirements are met; then under the conditions that the pH is 6.5-8.0 and the temperature is 30-39 DEG C, collagen molecules are self-assembled into a nanofiber structure, and a bionic network similar to a natural extracellular matrix is obtained. The hydrogel disclosed by the invention has the advantages of rapid gelation, structural biomimetic property and biological activity; residual sulfydryl endows the hydrogel with active oxygen scavenging capacity, so that oxidative stress can be relieved, and immune response can be regulated; the fibrotic structure promotes cell adhesion, migration and tissue regeneration.

The invention provides a preparation method of a graphene carbon nanofiber film for oil-water separation, and relates to the field of oil-water separation membranes, and the preparation method comprises the following steps: mixing polyacrylonitrile powder and an N, N-dimethylformamide solution to obtain an electrostatic spinning solution; spinning through an electrostatic spinning machine to obtain a polyacrylonitrile fiber membrane; coating the polyacrylonitrile fiber film with the prefabricated graphene oxide dispersion liquid to obtain a graphene oxide / polyacrylonitrile composite film; carrying out pre-oxidation, activation and carbonization treatment on the composite film to obtain a graphene carbon nanofiber film; according to the method, the waste isostatic pressing graphite which is low in price and easy to obtain is adopted as the raw material, the ammonia activation means is combined, improvement is carried out on the basis of a Hummers method, graphene oxide is prepared, resource recycling is achieved, the isostatic pressing graphite waste generated in the production process is recycled and processed into a product with a high additional value, and therefore the purposes of reducing the production cost and saving resources are achieved.

The application discloses a kind of electrospinning preparation methods of superfine, no adhesion polyether ketone ketone nanofiber membrane: polyether ketone ketone is dissolved in solvent to obtain polyether ketone ketone spinning solution;Polyether ketone ketone spinning solution is loaded in the injector of electrospinning device, and spinning is carried out;The concentration of ethanol or water in spinning environment is improved using solvent atomization between injector needle and collecting device, and polyether ketone ketone jet phase separation is accelerated;The nascent polyether ketone ketone nanofiber is collected into membrane;The fiber membrane collected is soaked in coagulation liquid to make solvent remaining in fiber precipitate, after taking out, dry, obtain polyether ketone ketone nanofiber membrane.The application realizes low concentration electrospinning using the unique interchain topological entanglement of polyether ketone ketone, and promotes phase separation by introducing solvent atomization between spinneret and collecting device, overcome the problem that other polymers are difficult to obtain continuous fiber and fiber is easy to adhere in low concentration electrospinning, and prepare superfine, no adhesion polyether ketone ketone nanofiber membrane.