2428results about "Filament/thread forming" patented technology

The invention relates to the technical field of film material preparation, and discloses a polylactic acid antibacterial packaging film and a preparation method thereof, the polylactic acid antibacterial packaging film comprises the following raw material components by weight: 60-80 parts of polylactic acid, 10-20 parts of polyvinyl alcohol, 10-20 parts of nano zinc oxide, 0.5-1.5 parts of nano cellulose, 1-3 parts of an antibacterial agent, and 10-15 parts of corn starch; the antibacterial agent is prepared from the following components in parts by weight: 5-10 parts of carboxymethylated chitosan and 0.5-2 parts of a dynamic disulfide bond cross-linking agent, the substitution degree of the carboxymethylated chitosan is greater than or equal to 80%, the antibacterial agent is prepared from tea tree essential oil and eugenol, and the dynamic disulfide bond cross-linking agent is bis (3-aminopropyl) disulfide. By adopting a composite system of carboxymethylated chitosan and a dynamic disulfide bond cross-linking agent, the technical effects of humidity-triggered self-repairing and mechanical property synergistic improvement are achieved, and compared with a packaging film with a single polymer base material in the prior art, the problem of antibacterial failure caused by mechanical damage is solved.

The invention discloses a Janus wound dressing with antibacterial and tissue repair promoting functions and a preparation method of the Janus wound dressing, belongs to the technical field of wound dressings, and aims to realize antibacterial, tissue repair promoting and moist wound healing microenvironment through freeze drying and electrostatic spinning technologies. Polycaprolactone (PCL), bioactive glass (BG) and curcumin Cur are used for preparing a hydrophobic inner layer capable of promoting tissue repair, methacrylated gelatin GelMA is used for preparing a hydrophilic outer layer with moisturizing performance, and the PCL-BG-Cur / GelMA composite wound dressing with antibacterial, moisturizing and repair promoting functions is constructed. Animal experiment results show that the dressing loaded with curcumin Cur and bioactive glass BG has multiple functions of synergistic antibiosis, moisturizing and the like, the result shows that the prepared dressing has the performance of promoting epithelization, collagen deposition, new hair follicle formation and the like, and the dressing has a considerable application prospect in the aspect of rapid wound repair.

The utility model discloses a composite fiber which comprises a first component, a second component and a third component, the cross section, perpendicular to the length direction, of the composite fiber comprises a plurality of single-component areas and a plurality of separated double-component areas, and every two adjacent double-component areas are separated by a single-component area. The plurality of single-component areas are separated from one another or are connected with one another in the center of the cross section perpendicular to the length direction; the component of the single-component area is a third component, the component of the double-component area comprises a first component and a second component, the first component and the second component are arranged in parallel, the first component and the second component are respectively in contact with the third component, and the single-component area and the double-component area are detachably in contact connection; the composite fiber not only can be directly used, but also can be split into the superfine fiber and the single-component fiber with specific structures, and the elasticity, the glossiness and the strength such as the tearing strength of the superfine fiber are obviously improved at the same time.

The invention discloses a melt spinning cooling system which comprises a spinning box, a cooling cylinder section, a first heating assembly, a second heating unit and a recovery part, the first heating assembly outputs trace hot nitrogen, anti-oxidation protection of melt trickles is achieved, the oxidation risk possibly caused by direct contact of a traditional cooling medium is avoided, and the cooling efficiency is improved. Meanwhile, the second heating unit is matched to regulate and control the temperature of the cooling cylinder section, so that the whole-process temperature accurate control from oxidation prevention to high-temperature natural cooling and the high-temperature natural cooling and cold air supply-free operation process are realized, and the solidification orientation length and process of the melt trickle can be actively lengthened by combining gradient process temperature control; different from the defect of insufficient orientation caused by too fast cooling in the prior art, key conditions are provided for optimization of a fiber orientation structure; due to the coaxially stacked cooling cylinder sections and nitrogen recovery operation, a stable cooling environment is constructed, fiber shaking is avoided, the nitrogen utilization rate and the environmental safety are improved, and the process stability and economical efficiency are balanced.

The invention discloses a three-fluid three-dimensional flow guide spinning head, electrostatic spinning equipment and a batch preparation method of three-chamber embedded parallel structure nanofibers, three different fluids are synchronously guided into a high-voltage electrostatic field by simultaneously arranging a plurality of nozzle outlets with combined structures, and a plurality of complex combined nozzle outlets are used as macroscopic templates, so that the three-chamber embedded parallel structure nanofibers are prepared under the high-voltage electrostatic field. Through interaction of a high-voltage electrostatic field and fluids, batch preparation of the three-chamber embedded and column-structured nanofibers by multi-fluid common electrospinning is realized. The three spinning solutions are guided to a common outlet through the first series of metal capillary tubes, the second series of metal capillary tubes and the spinning solution insulating container respectively; the first series of metal capillary tubes and the second series of metal capillary tubes are respectively dispersed from respective capillary tube gathering inlets, penetrate through the interior of the spinning solution insulating container to the bottom of the spinning solution insulating container and vertically penetrate out to form a plurality of outlets which are parallel in pairs; a through hole outlet is formed in any parallel outlet at the bottom of the spinning solution insulating container to form a common outlet of the three spinning solutions, and the three-chamber embedded and arrayed nano structure is directly prepared in batches in a single step.

The invention discloses a conductive yarn and a preparation method thereof, relates to the technical field of functional textile materials and composite conductive fiber preparation, and can solve the problems that an existing conductive yarn is poor in flexibility, insufficient in durability, prone to oxidation failure and difficult to integrate multiple functional performances. The preparation method comprises the following steps that S1, PBO yarn is soaked in a dopamine solution, a PDA modification layer is formed on the surface of the PBO yarn through a polydopamine self-polymerization reaction, and the PDA modification layer provides a chelation site and a bonding interface for metal deposition; s2, the PDA modified PBO yarn obtained in the step S1 is subjected to chemical silver plating, silver is deposited on a PDA modified layer to form a continuous conductive layer, and conductive PBO core yarn is prepared; s3, carrying out melt blending and granulation on the low-dielectric-constant flame-retardant filler and thermoplastic polymer resin to prepare flame-retardant composite particles; and S4, spinning by taking the conductive PBO core yarn prepared in the step S2 as a core layer and a melt formed by melting the flame-retardant composite particles prepared in the step S3 as a skin layer to prepare the conductive yarn.

The invention belongs to the technical field of textile, and relates to an efficient antibacterial fabric for preparing underwear and a dyeing and finishing method and application thereof.The provided antibacterial fabric is weft-knitted bird eye double-faced knitted fabric and is composed of polyester, cotton and modal fibers, the surface density is 180 g / m, surface yarn of the antibacterial fabric is hollow polyester fibers with special-shaped sections, and the surface yarn of the antibacterial fabric is hollow polyester fibers with special-shaped sections. The lining yarn is formed by weaving dacron and blended yarn according to the proportion of 2: 1. According to the method, dyeing and finishing of the antibacterial fabric, fabric weaving and ergonomic sewing are combined, the fabric which has efficient antibacterial performance, good moisture permeability and ultraviolet-proof performance and high color fastness is obtained, and the prepared antibacterial clothes are high in quick-drying performance, comfortable to wear and high in environmental adaptability.

The present invention belongs to the technical field of fiber materials, and relates to a composite fiber containing nano natural tea fibers, and a preparation method and application thereof. The raw materials for preparing the composite fiber include nano natural tea fibers and basic fiber pulp, and the nano natural tea fibers are mate nano fiber microemulsions. The present invention integrates nanotechnology into the preparation of natural tea fibers, and adopts a microemulsion method to simultaneously and evenly disperse a variety of effective ingredients in tea in the mate nano fiber microemulsion, so that the multifunctionality of the fabric can be effectively exerted; the microemulsion system has high uniformity and long-term stability, and during the spinning process, the nano tea fibers can be highly dispersed in the spinning solution without the need for additional surfactants, and the effect of the functional fabric finally obtained can be long-lasting. In addition, mate tea is rich in tea polyphenols and unique yerba mate alkaloids, which can further improve the comprehensive performance of the composite fiber.

The purpose of the present invention is to provide: a low-shrinkage fiber; a method for producing the low-shrinkage fiber; an air-blended yarn comprising the polytrimethylene terephthalate fiber; and a fabric comprising the air-blended yarn. The low-shrinkage fiber is substantially composed of polytrimethylene terephthalate, and can be used to produce a precursor for a fabric, which has a soft texture and a low shrinkage rate due to heat. The present invention is characterized in that 90 mol% or more of polytrimethylene terephthalate fibers are composed of trimethylene terephthalate repeating units, the boiling water shrinkage of the polytrimethylene terephthalate fibers is 5% or less, and the elastic modulus of the polytrimethylene terephthalate fibers at an elongation of 20% is 5 cN / dtex or less.

The invention discloses an injectable material for promoting bone regeneration through piezoelectric and conductive integrated nanofiber hydrogel with ultrasonic response and a preparation method of the injectable material. The injectable material is composed of piezoelectric and conductive nanofibers and hydrogel. Wherein the piezoelectric conductive nanofiber is prepared from an inorganic piezoelectric material and a piezoelectric polymer through electrostatic spinning, or is prepared from an inorganic / organic composite piezoelectric material and a biological material with conductive performance through electrostatic spinning.

The utility model discloses a spinneret assembly, which comprises a distribution plate and a spinneret plate provided with spinneret orifices, the distribution plate comprises a first runner used for simultaneously introducing a first component and a second component into the spinneret orifices, and a second runner used for introducing a third component into the spinneret orifices; the number of the first flow channels and the number of the second flow channels are respectively multiple, every two adjacent first flow channels are separated by one second flow channel, the multiple second flow channels are mutually separated or the axial leads of the second flow channels are mutually intersected at the same point, and the orthographic projection of the first flow channels and the orthographic projection of the second flow channels are all located in the orthographic projection range of inlets of the spinneret orifices; the spinneret assembly can continuously and stably eject composite fibers with normal sizes and specific structures on the basis of three components, and superfine fibers with at least one excellent effect in the aspects of elasticity, glossiness, strength such as tearing strength and the like can be obtained by removing single-component fibers in the composite fibers.

The invention belongs to the technical field of spinning, and particularly relates to atmosphere-controllable needleless electrostatic spinning equipment and a method for preparing micro-nano fibers. The equipment comprises a needleless electrode wire, a liquid brushing tank, a direct-current high-voltage power supply, a winding roller, a metal plate, an air inlet, a sliding rail, an air outlet and a closed outer cover. The needle-free electrode wire is connected with the liquid brushing groove in series and connected with the positive electrode of the direct-current high-voltage power source, the metal plate is arranged over the needle-free electrode wire and connected with the negative electrode of the direct-current high-voltage power source or grounded, and the air inlet can reciprocate on the sliding rail. The atmosphere-controllable needleless electrostatic spinning equipment is used for stabilizing jet flow, the fiber forming quality is improved, generated beads are reduced, it is ensured that fibers are uniform and fine, and the mechanical property and stability of the fibers are remarkably improved; one-step preparation of porous fibers and fibers needing secondary reaction modification is achieved, and the consistency of the fibers in the fiber membrane is improved.

The invention discloses an electrostatic ionization device and an array spinning ionization box, and relates to the field of textile processing machinery, the electrostatic ionization device comprises an ionization assembly, the ionization assembly is provided with a backflow groove with a top opening, and a metal wire which is horizontally arranged and can be externally connected with a power supply is arranged above the backflow groove; the reciprocating assembly comprises a liquid supply brush making contact with the upper surface of the metal wire and can drive the liquid supply brush to reciprocate along the axis of the metal wire and coat the surface of the metal wire with a polymer solution used for electrostatic ionization. The liquid supply assembly can store a polymer solution and convey the stored polymer solution to the liquid supply brush, and the backflow groove is communicated with the liquid supply assembly and can collect the polymer solution dripping in the process that the surface of a metal wire is brushed by the liquid supply brush and flow back into the liquid supply assembly. According to the electrostatic ionization device and the array spinning ionization box, the solution utilization rate can be increased, rapid replacement of multiple solution varieties can be achieved, raw material waste is reduced, and the production cost is reduced.

The invention relates to the technical field of sewage treatment, in particular to an electrostatic spinning PVDF nanofiber membrane for sewage treatment and a preparation method and application of the electrostatic spinning PVDF nanofiber membrane. The preparation method comprises the following steps: dissolving PVDF (Polyvinylidene Fluoride) particles in a mixed solvent of DMF (Dimethyl Formamide) and acetone, adding nano TiO2 particles subjected to APTES (Aminopropyltriethoxysilane) surface modification, and adding PVP (Polyvinyl Pyrrolidone) into the solution to obtain a uniform spinning solution; spinning by adopting electrostatic spinning equipment to obtain a PVDF / TiO2 / PVP nanofiber membrane; the nanofiber membrane is soaked in a sodium hydroxide solution, then the membrane is soaked in a Tris-HCl buffer solution containing dopamine, and the final electrostatic spinning PVDF nanofiber membrane is obtained. The average diameter of nanofibers of the nanofiber membrane is 200-300nm, the porosity of the membrane is 70-80%, and the water contact angle is less than 60 degrees; when the nanofiber membrane is used for treating sewage containing organic pollutants and heavy metal ions, the removal rate of the nanofiber membrane on methyl orange can reach 95% or above; the rejection rate of copper ions can reach 90% or above; the removal efficiency of organic pollutants and heavy metal ions is obviously improved.

The invention discloses an MXene / rGO (at) SA coaxial composite fiber based on a core-shell structure and a preparation method and application thereof, and belongs to the technical field of nano composite materials and flexible electronics. The invention solves the problems of many interface defects, unstable performance and the like of the existing coaxial fiber. The MXene / rGO-SA coaxial composite fiber is prepared by adopting a coaxial wet spinning method, a high-performance SA fiber with excellent mechanical properties is used as a tough shell layer, a multi-element nano material MXene / rGO composite fiber is used as a core layer, a calcium chloride-ethanol mixed solution in a certain proportion is used as a coagulating bath, and the coaxial composite fiber is prepared by utilizing a coaxial needle head; the interface bonding force and the conductive network of the MXene / rGO (at) SA coaxial composite fiber are optimized by accurately controlling the core-shell ratio, and the mechanical strength, the conductivity and the stability are synergistically improved.

This invention provides a multifunctional gradient composite filament for 3D printing, its preparation method, and its applications, relating to the field of additive manufacturing materials technology. The filament's cross-section includes at least two structurally or functionally distinguishable regions, each region composed of a thermoplastic polymer with different chemical properties, or a thermoplastic polymer matrix with the same chemical properties but different functional modifications. These at least two regions are arranged in an ordered spatial pattern on the filament's cross-section using a multi-component co-extrusion technique, enabling pre-design and integration of properties. This invention overcomes the inherent limitations of traditional single-material filaments, achieving multifunctionality and performance designability of a single filament. It significantly improves the interlayer bonding performance of multi-component 3D printing and the comprehensive mechanical properties of the printed composite material. Furthermore, it allows for the production of components with both functional gradients and high mechanical properties in a single printhead operation, making it suitable for mass production.

The invention provides a needle-base-free multi-needle electrostatic spinning nozzle which comprises a liquid conveying base, a liquid storage base, a conductive assembly and multiple spinning needles, the distance between every two adjacent spinning needles is 1-3 mm, the inner diameter of each spinning needle is 0.1-0.3 mm, and the outer diameter of each spinning needle is 0.3-0.5 mm. Compared with the prior art, the multiple spinning needle heads are directly connected with the current-conducting plate, so that the distance between the adjacent needle heads is shortened to 1-3 mm, and short-distance ordered array nanofiber preparation is achieved; a plurality of second through holes are formed in the current-conducting plate, so that the array mode of the spinning needle heads on the current-conducting plate can be flexibly adjusted according to production requirements to meet the preparation requirements of different nanofiber arrays.

The invention discloses a method for preparing micro-nano fibers through needle-free electrostatic spinning equipment assisted by an ion blower gun, and belongs to the technical field of spinning. The method specifically comprises the following steps: S1, dissolving a high-molecular polymer in a proper solvent to prepare a spinning precursor solution; and S2, preparing the micro-nano fiber from the spinning solution on a suitable collection surface by using an ion blower gun assisted needleless electrostatic spinning device. Through the synergistic effect of directional airflow generated by the ion blower gun and a controllable electric field, fiber surface charges are effectively neutralized, the jet instability is inhibited, and the controllability of a fiber flight path is improved. Meanwhile, the ionic wind assists in enhancing interface attachment between the fiber and the collector, uniform deposition is promoted, and the compactness and adhesive force of the fiber membrane are remarkably improved. According to the method, chemical modification does not need to be carried out on a material system, the intrinsic performance of the fiber is kept, universality and expandability are achieved, and a new path is provided for continuous preparation of the high-performance micro-nano fiber.

The invention provides a skin-core structure moisture power generation yarn, the yarn at least comprises a metal core layer, a wrap yarn layer and a conductive coating, the wrap yarn layer comprises lithium chloride doped polyvinyl alcohol fibers and tightly wraps the periphery of the metal core layer through conjugate electrostatic spinning, and the conductive coating is nano conductive silver paint. And the conductive coating is not in direct contact with the metal core layer. The preparation method comprises the following steps: firstly, adding lithium chloride powder into deionized water, stirring at normal temperature until complete dissolution, then adding polyvinyl alcohol powder, heating and stirring until complete dissolution, standing and defoaming to prepare a wrap yarn layer spinning solution; performing conjugate electrostatic spinning on the prepared skin layer spinning solution to form nanofiber wrap yarn on the outer layer of the metal core; nano conductive silver paint is sprayed on the surface of the wrap yarn layer, and the wrap yarn layer is dried in the air. The yarn has good flexibility, and has excellent surface waterproof and moisture permeable performance, stability and reusability while forming stable output current and voltage.

The invention provides a woven nerve conduit with piezoelectric performance and a preparation method and application thereof, and belongs to the field of nerve conduits.The preparation method comprises the steps that degummed silk is soaked in a dopamine hydrochloride solution, sodium hydroxide is added to adjust the pH value, and stirring is conducted to obtain polydopamine modified degummed silk; dispersing the polydopamine modified degummed silk, EDOT and FeCl3. 6H2O in an ethanol solution, stirring, centrifuging, washing and drying to obtain PEDOT modified degummed silk; the degummed silk modified by PEDOT is used as weaving yarn, and a nerve conduit skeleton is woven through a three-dimensional weaving technology; preparing a glycine solution, crystallizing and grinding to obtain beta-type glycine; pLLA particles are dispersed in hexafluoroisopropanol to be dissolved, beta-type glycine is added to obtain a PLLA-coated Gly solution, a PLLA-coated Gly fiber membrane is prepared on the surface of a nerve conduit skeleton through electrostatic spinning, and the woven nerve conduit with the piezoelectric property is obtained. The novel nerve conduit is developed by combining the three-dimensional weaving technology and the piezoelectric material, and a better solution is provided for nerve restoration.

The invention discloses a flexible lanthanum zirconate-alumina fiber membrane as well as a preparation method and application thereof, and belongs to the technical field of inorganic nonmetal ceramic fiber materials. The preparation method comprises the following steps: dissolving zirconium oxychloride octahydrate, lanthanum chloride heptahydrate and aluminum chloride hexahydrate into absolute methanol, sequentially adding acetylacetone and triethylamine, stirring, and drying under reduced pressure to obtain a zirconium-lanthanum-aluminum polymer precursor containing triethylamine hydrochloride; soaking the zirconium-lanthanum-aluminum polymer precursor containing triethylamine hydrochloride in acetone, standing, filtering, concentrating under reduced pressure, and drying to obtain a zirconium-lanthanum-aluminum acetylacetone polymer precursor; the preparation method comprises the following steps: preparing a spinning solution from a zirconium-lanthanum-aluminum acetylacetone polymer precursor, absolute methanol serving as a solvent and polyoxyethylene serving as a spinning aid, and carrying out electrostatic spinning on the spinning solution to obtain a lanthanum zirconate-aluminum oxide precursor fiber membrane; and performing heat treatment on the lanthanum zirconate-aluminum oxide precursor fiber membrane to obtain the flexible lanthanum zirconate-aluminum oxide fiber membrane. According to the preparation method, acetylacetone is added into zirconium oxychloride, lanthanum chloride and aluminum chloride for coordination to form a linear zirconium-lanthanum-aluminum acetylacetone polymer, so that the technical problem that lanthanum zirconate long fibers with high strength and good flexibility are difficult to obtain is solved.

Provided is a liquid crystalline polyester fiber capable of achieving improved weatherability without kneading a UV absorber into the fiber or attaching a weatherable UV absorber after fiber spinning. The liquid crystalline polyester is a fiber that consists essentially only of a liquid crystalline polyester, in which the amount of UV absorber used is 5 mass % or less, and the strength retention in the weather fastness test with xenon arc lamp light in accordance with JIS L 0891 is 60% or more.

The invention relates to a bi-component fiber and a preparation method thereof, polyester melt and polyamide melt are extruded from a spinneret plate side by side, cross air blowing cooling is performed to obtain nascent fiber, and then the nascent fiber is sequentially subjected to heat pipe heating, oiling, pre-interlacing, three-roller drafting heat setting and winding to obtain the bi-component fiber. The heat pipe is used for heating nascent fibers, and the temperature of the heat pipe is 90-100 DEG C; the three rollers comprise a first hot roller, a second hot roller and a third hot roller; the temperature of the first hot roller is 70-90 DEG C, the temperature of the second hot roller is 110-130 DEG C, and the temperature of the third hot roller is 140-160 DEG C; the filament number of the prepared bi-component fiber is 2.6-3.5 dtex, the breaking strength is larger than or equal to 3.23 cN / dtex, the elongation at break is 27.45-38.31%, the number of broken ends is smaller than or equal to 2.3 times / (48 bits. 24 hours), and the broken filament rate is stably controlled to be 0.30% or below. According to the preparation method, generation of internal stress is greatly reduced; the mechanical property of the bi-component fiber is improved, and the number of broken ends and the broken filament rate of the fiber are obviously reduced.

The present invention discloses a novel gas-sensitive material, specifically a method for preparing a core-shell nanofiber gas-sensitive material based on a platinum-doped cobalt oxide / tin oxide heterostructure. The present invention utilizes a cobalt source, a tin source, a platinum source, and a polymer as raw materials, and produces a nanoscale platinum-doped cobalt oxide / tin oxide gas-sensitive material with high sensitivity and rapid response to hydrogen sulfide gas via coaxial electrospinning. This gas-sensitive material exhibits excellent gas-sensing properties for H2S gas at room temperature, with a short response time, enabling rapid detection of low-concentration H2S gas, a short recovery time, and excellent cyclic stability. Therefore, the gas-sensitive material of the present invention possesses excellent sensitivity and stability, and has broad application prospects, including applications in environmental monitoring, industrial safety, and gas sensors.

The invention belongs to the technical field of textile materials, and discloses an easy-to-dye composite polyester fiber and a preparation method thereof. The preparation method comprises the following steps: by taking polyethylene glycol terephthalate as a core layer and low-melting-point polyester as a skin layer, carrying out melt spinning to prepare skin-core composite fibers; after heating and melting a skin layer, bombarding by using a titanium dioxide nano particle flow to obtain roughened fibers; after plasma treatment, dipping with an activating solution of triethylamine and 4-methylbenzenesulfonyl chloride to obtain activated fibers; carrying out ultrasonic reaction on the activated fiber and a modifier under the catalysis of tetrabutyl titanate, and washing and drying to obtain the easy-to-dye composite polyester fiber. The prepared composite polyester fiber not only has the advantage of being easy to dye, but also has excellent antibacterial performance and flame retardant performance, and the quality of the composite polyester fiber is effectively guaranteed.

Disclosed herein are embodiments of a non-woven hybrid-scale fiber matrix sheet which can be used to improve wound healing. The non-woven hybrid-scale fiber matrix sheet may be both microporous, due to the hybrid-scale fiber matrix, as well as macroporous through the addition of cuts or perforations in the hybrid-scale fiber matrix sheet. The micro and macroporous sheet can improve biological healing at a wound site.

The invention relates to the technical field of tobacco smoke analysis, and discloses a gas sensor for detecting the content of 3-vinylpyridine in real time and a preparation method of the gas sensor. In order to realize accurate detection of tobacco smoke in the environment, 3-vinylpyridine in environmental gas is taken as a detection object, a SnO2 nanofiber material is further taken as a gas sensitive element, the detection sensitivity of the 3-vinylpyridine is remarkably improved, the SnO2 nanofiber material is arranged on the heating substrate, and the gas sensitive element is arranged on the heating substrate. The gas sensor generates a resistance change signal which linearly changes along with the change of the content of 3-vinylpyridine, so that the environmental tracing of the tobacco smoke is realized. Therefore, the invention provides the gas sensor with high sensitivity and high accuracy for tobacco smoke environment tracing.

The present invention discloses a triaxially spun superelastic and high-temperature resistant composite carbon nanofiber aerogel and a preparation method thereof. The aerogel is formed by interweaving curly fibers with a core layer of carbon and a shell layer of oxide ceramic. The present invention utilizes electrostatic spinning technology to prepare composite carbon nanofiber aerogels. First, an inner layer polyacrylonitrile solution is prepared, and the water / alcohol ratio is adjusted to prepare a middle layer ceramic sol with controllable water content, thereby obtaining a spinning solution with compatibility in the initial spinning stage. The temperature and humidity of the airflow of the outer nozzle are then regulated, and the water content of the ceramic sol is further adjusted during the spinning process, so that the spinning solution becomes incompatible. The spinning solution jet is fast and solidified in advance, thereby obtaining a curly interwoven structure nanofiber aerogel precursor. Finally, the final product is obtained by changing the atmosphere and performing rapid and continuous heat treatment. The present invention solves the problems of insufficient mechanical properties and easy oxidation of carbon nanofiber aerogels. The preparation method is simple and easy to implement, and the process is continuous, and can be carried out on existing electrostatic spinning production equipment.

The invention discloses a high-voltage output elastic self-crimping spiral fiber and a preparation method and application thereof, and belongs to the technical field of fiber preparation. The preparation method comprises the following steps: dissolving a thermoplastic piezoelectric polymer in a first solvent dissolved with metal salt to prepare a first spinning solution; a high-elasticity polymer is dissolved in a second solvent to prepare a second spinning solution, the second solvent is different from the first solvent, and the high-elasticity polymer is incompatible with the thermoplastic piezoelectric polymer; taking the first spinning solution as a shell layer solution and the second spinning solution as a core layer solution, and carrying out electrostatic spinning by adopting a two-component core-shell electrostatic spinning process. The preparation method is simple, and the prepared fiber has excellent mechanical property and enhanced piezoelectric effect and can be applied to flexible electronic devices and intelligent wearable equipment.

The invention provides an electrostatic spinning solution which is prepared from the following raw materials: LLZTO modified by a silane coupling agent MEMO, PVDF-HFP and a solvent, the mass ratio of the silane coupling agent MEMO modified LLZTO to the PVDF-HFP is (15 to 20): 100. The invention also provides a preparation method of the solid-state electrolyte membrane, the PVDF-HFP matrix and the LLZTO filler in the prepared composite solid-state electrolyte membrane are uniformly dispersed by optimizing a formula of an electrostatic spinning solution, improving a lithium salt introduction mode and adopting a step-by-step drying process and a double-layer glass sheet capping process, so that a continuous and efficient ion transmission channel is formed; meanwhile, the lithium salt is uniformly distributed in the electrolyte membrane, so that the ionic conductivity is remarkably improved, the electrolyte membrane has relatively high compactness and stability and is in good interface contact with an electrode material, the charge-discharge performance of the battery is effectively improved, the cycle life of the battery is effectively prolonged, and powerful support is provided for development of a high-performance solid-state battery.