4294 results about "Citric acid" patented technology

The invention relates to the technical field of high polymer material preparation, and discloses a bamboo fiber graft modified full-biodegradable composite membrane material preparation process which comprises the following steps: firstly, performing hot mixing and cooling on dried bamboo fiber powder, anhydrous citric acid, choline chloride, activated zinc oxide and pentaerythritol to prepare a bamboo fiber modified premix; then mixing the biodegradable polyester resin with the premix; adding the mixture into an extruder, injecting epoxidized soybean oil into a barrel through a liquid metering device, and performing melt extrusion granulation under a vacuum exhaust condition; and finally carrying out blow molding to form the film. Through in-situ reaction extrusion of multi-component synergism, surface grafting of bamboo fibers, chain extension of a polyester matrix and interface chemical bonding of the bamboo fibers and the polyester matrix are achieved, interface compatibility is effectively improved, degradation of the material in the processing process is inhibited, and the mechanical property and thermal stability of the composite film material are remarkably improved; the process is efficient and environment-friendly, and the cost is controllable.

The invention discloses an easy-to-apply single-component polyurethane waterproof coating and a preparation method thereof, and belongs to the technical field of waterproof coatings. The easy-to-apply single-component polyurethane waterproof coating disclosed by the invention is prepared from the following raw materials: polyol, a plasticizer, a solid filler, isocyanate, a catalyst and a solvent, the polyol comprises polyether glycol and polyether triol; the plasticizer comprises acetyl tributyl citrate; the catalyst comprises a bismuth neodecanoate catalyst and a dimorpholine diethyl ether catalyst. According to the easy-to-apply single-component polyurethane waterproof coating disclosed by the invention, acetyl tributyl citrate is used for replacing traditional plasticizer chlorinated paraffin, and a bismuth neodecanoate catalyst and a dimorpholine diethyl ether (DMDEE) catalyst are compounded, so that the viscosity of the waterproof coating is effectively reduced, and construction is facilitated; meanwhile, the drying speed of the waterproof coating is increased.

A pesticide product having a liquid dispensing system and a pesticidal composition contained within a bottle. The liquid dispensing system includes a bottle having an interior volume and a neck terminating in a rim circumscribing and defining a main opening through the neck to the interior volume. The neck has a first retaining feature. The liquid dispensing fixture includes a housing, a carry handle, an electric motor configured to drive a pump, a dispensing nozzle in fluid communication with the pump, and a spray actuator operatively connected to the pump. The liquid dispensing fixture is configured to engage the first retaining feature of the bottle. The pesticidal composition includes from about 0.5% to about 10% clove oil; from about 0.01% to about 1.5% citric acid; an anionic surfactant; and water.

The invention discloses a potassium fulvate chelated macroelement water-soluble fertilizer with stress resistance and growth promotion functions, and relates to the technical field of water-soluble fertilizers, the potassium fulvate chelated macroelement water-soluble fertilizer comprises the following raw materials by weight: 167-210 parts of mineral source potassium fulvate, 450-460 parts of potassium nitrate, 300-310 parts of urea, 150-160 parts of potassium dihydrogen phosphate, 30-40 parts of potassium sulfate, 15-25 parts of EDTA-disodium, and 5-15 parts of citric acid. 0.5 to 1.5 parts of brassinolide and 4 to 6 parts of polyaspartic acid; according to the potassium fulvate chelated macroelement water-soluble fertilizer with the stress-resistant and growth-promoting functions, through chelation cooperation of potassium fulvate and nitrogen, phosphorus and potassium, the solubility of the chelated phosphorus element in water is increased, and the chelated phosphorus element can be more uniformly distributed in soil; by adopting an EDTA-disodium and citric acid composite chelating system, volatilization and loss of nitrogen elements are reduced, the problem of precipitation of calcium, magnesium and phosphorus is solved, and the soil conditioner is suitable for hard water areas and especially has outstanding performance in saline-alkali soil and arid areas.

The invention discloses an A-site high-entropy solid oxide fuel cell cathode material as well as a preparation method and application thereof, and provides an A-site high-entropy solid oxide fuel cell cathode material Pr < 0.2 > M < 0.2 > La < 0.2 > Ba < 0.2 > Sr < 0.2 > Co < 0.8 > Fe < 0.2 > O < 3-delta > with a perovskite phase. The preparation method comprises the following steps: S1, weighing multi-element metal nitrates, and mixing to obtain a first mixed solution; s2, dissolving ethylenediamine tetraacetic acid in ammonia water to obtain a second mixed solution; mixing the first mixed solution, the second mixed solution and citric acid to form a mixed precursor solution; s3, carrying out second heating treatment on the mixed precursor solution, and adjusting the pH value to form a gel precursor; and S4, carrying out pre-sintering treatment, third heat treatment and calcination treatment on the gel precursor to obtain a high-grade powder precursor, and carrying out ball milling and sieving treatment to obtain the A-site high-entropy solid oxide fuel cell cathode material. The cathode material is high in stability and good in chemical compatibility with a barrier layer GDC, provides high-quality mass transfer channels and active sites for O2 / O- / O2-, and has good electrochemical performance at medium and low temperatures.

The invention discloses a metal-doped carbon quantum dot as well as preparation and application of the metal-doped carbon quantum dot in a nano antibacterial agent, citric acid, urea and tea polyphenol are taken as precursors, metal salt is added, carbon dot synthesis and metal ion doping are synchronously completed in one step through a hydrothermal method, and the metal-doped carbon quantum dot is prepared; the surfaces of the metal-doped carbon quantum dots are negatively charged, and the metal-doped carbon quantum dots have peroxidase-like activity and catalase-like activity at the same time; the metal ions adopt any one of Fe < 3 + >, Cu < 2 + > and Ce < 3 + >; the metal-doped carbon quantum dots are in a sphere-like shape. The metal-doped carbon quantum dots prepared by the preparation method disclosed by the invention have peroxidase-like activity and catalase-like activity at the same time through precise doping of metal ions, and the two activities have a synergistic effect in an oral periodontitis microenvironment, so that a good antibacterial effect is achieved.

The invention relates to the technical field of tunnel engineering building materials, in particular to a double-slurry synchronous grouting material based on shield silty-fine sand and a preparation method of the double-slurry synchronous grouting material based on shield silty-fine sand. The liquid A is prepared from, by weight, 20%-30% of cement, 30%-50% of shield silty-fine sand, 5%-10% of bentonite, 5%-15% of mineral admixture, 0.1%-0.5% of stabilizer and 20%-30% of water, and the stabilizer is a water-soluble high-molecular polymer; the solution B is a water glass solution, and the volume ratio of the solution A to the solution B is (10-15): 1; the double-slurry synchronous grouting material further comprises a retarder and a coagulant, the retarder is citric acid, and the coagulant is a nano Ca (OH) 2 crystal nucleus. Bidirectional and gradient regulation and control of the gelation time between 5s and 100s can be realized through the coagulant and the retarder, and diversified requirements of different geological conditions and construction progress on slurry operation time are met.

The invention discloses a water and fertilizer management method for transplanted high-yield indica type two-line hybrid rice, and belongs to the technical field of rice cultivation. Comprising the following steps: (1) applying citric acid chelated calcium magnesium phosphate fertilizer to soil before transplanting; (2) applying coated controlled-release urea and a silicon-zinc fertilizer on the third day after transplanting; (3) when the tiller number reaches 2650,000-2750,000 plants / hm < 2 >, starting intermittent light field drying for three times, and deeply applying potassium magnesium sulphate before field drying; (4) laterally and deeply applying urea and a boron-humic acid chelate when tips of two inverted leaves are exposed; (5) spraying an aqueous solution in a full heading stage, wherein the aqueous solution comprises monopotassium phosphate, chelated zinc and brassinolide. Through staged precise fertilization, special chelating / controlled release fertilizer and water and fertilizer-field drying cooperation, the method has the advantages that the fertilizer utilization rate is increased, the nutritional requirements of rice in each growth period are precisely matched, and water and fertilizer cooperative management is optimized.

The invention relates to the technical field of polyurethane acrylate, and particularly discloses dual-curing polyurethane acrylate resin and a preparation method thereof. Wherein the dual-curing polyurethane acrylate resin is prepared from the following raw materials: polyester polyol, polyether polyol, diisocyanate, hydroxyl acrylate, a chain extender, a photoinitiator, cardanol glycidyl ether, a polymerization inhibitor and modified nanoparticles. Wherein the citric acid and the polyethyleneimine are adopted to carry out synergistic modification on the nano particles, the dispersion stability of the nano particles is improved, so that the mechanical property of the resin is improved, the cardanol glycidyl ether and the photoinitiator generate a synergistic effect, and the resin can be quickly shaped through photocuring promoted by the photoinitiator; the cardanol glycidyl ether participates in the subsequent thermocuring reaction, so that the curing effect is improved, and the adhesive force between the film layer and the base material is enhanced.

The invention discloses a biodegradable polylactic acid composite material and a preparation method thereof, and relates to the technical field of polylactic acid materials. The method comprises the steps that firstly, chitosan activated through hydrochloric acid is subjected to graft modification through a KH550 silane coupling agent, meanwhile, nano-zinc oxide is subjected to surface modification through stearic acid, the chitosan and the nano-zinc oxide are mixed, spray drying is conducted, and antibacterial composite powder is prepared; the preparation method comprises the following steps: performing hydrochloric acid activation and KH570 silane coupling agent modification on nano silicon dioxide, performing hydroxypropylation modification on alkali lignin, and performing reflux crosslinking reaction on the modified alkali lignin, KH570 modified nano silicon dioxide, polycaprolactone, methyl methacrylate and azodiisobutyronitrile to prepare a heat-resistant reinforcer; uniformly mixing polylactic acid, poly (butylene succinate), the antibacterial composite powder, the heat-resistant reinforcer, tributyl citrate, polyethylene glycol and talcum powder, and extruding and granulating by using a twin-screw extruder to obtain the heat-resistant antibacterial material. The composite material prepared by the invention has excellent antibacterial property, heat resistance and biodegradability.

The invention discloses a cerium-modified manganese-based NH3-SCR (Selective Catalytic Reduction) denitration catalyst as well as a preparation method and application thereof. The catalyst is obtained by uniformly mixing and stirring manganous nitrate, cerous nitrate, polyvinylpyrrolidone, citric acid and deionized water, stirring and evaporating to a gel state, drying to form a precursor, and roasting the precursor in an air atmosphere. Ce is used for modifying MnOx, polyvinylpyrrolidone and citric acid are used as a surfactant and a complexing agent in the preparation process of the catalyst, the interaction between Ce and Mn is enhanced, the phase of the catalyst is adjusted, and under the conditions of high NOx concentration (1000 ppm) and high space velocity (GHSV = 120,000 mL h <-1 > g <-1 >), the catalyst can be used for preparing the catalyst, and the catalyst can be used for preparing the catalyst. The catalyst has excellent low-temperature catalytic activity, a wide working temperature window and good reaction stability, and has good water resistance and sulfur dioxide poisoning resistance.

The invention belongs to the technical field of high polymer materials, and particularly relates to a high-strength papermaking forming net fiber. Comprising the following raw materials in parts by weight: 75-90 parts of polyethylene glycol terephthalate, 5-15 parts of polybutylene terephthalate, 3-10 parts of a modified fiber filler, 2-5 parts of modified graphene, 2-8 parts of silicon dioxide, 0.5-2 parts of a silane coupling agent KH-560, 1-3 parts of an anti-hydrolysis agent, 0.5-1.5 parts of an antioxidant and 0.3-1 part of a lubricant. Wherein the modified fiber filler is prepared by sequentially carrying out modification processes such as silane coupling agent, citric acid-glycerol esterification, iron bismuth oxide loading and the like on glass fibers; the modified graphene is prepared by introducing dopamine, cerium ions and glycidyl methacrylate for modification. The mechanical strength, the hydrolysis resistance and the wear resistance of the fiber are remarkably improved through the synergistic effect of all the components and the melt spinning-multi-stage stretching process, and the fiber is particularly suitable for a forming net of a high-speed paper machine.

The invention relates to a sunken porous magnetic alloy ball wave-absorbing material and a preparation method and application thereof.The wave-absorbing material is prepared through the following steps that S1, citric acid, soluble ferric salt, soluble cobalt salt and soluble nickel salt are dissolved in a mixed solvent of ethylene glycol and water, and the mixture is fully stirred to form a uniform mixed solution; and S2, the mixed solution obtained in the step S1 is subjected to spray drying, obtained precursor powder is placed in the air atmosphere to be calcined to remove the carbon source, then the precursor powder is placed in the H2 / Ar atmosphere to be subjected to heating reduction, and the porous FeCoNi alloy balls with the surface pits are obtained and are the target product. The surface of the prepared alloy microsphere has an obvious concave structure, magnetic anisotropy and magnetic performance are enhanced, a small number of pores are generated in the reduction process, impedance matching of the material is optimized, and effective high-frequency electromagnetic absorption is achieved; and due to the synergistic effect of the recesses and the pores, the obtained alloy microspheres have obvious lightweight characteristic, and have good application prospects in the field of electromagnetic absorption.

The invention provides tartary buckwheat herbal baijiu and a preparation method thereof.The method aims at solving the problems that existing tartary buckwheat baijiu is lost in active ingredient, single in flavor and unstable in baijiu body, firstly, tartary buckwheat submicron powder, radix puerariae submicron powder and rhizoma polygonati submicron powder are put into Maotai-flavor base liquor together, and two-section type closed extraction is conducted at the normal temperature and then at the low temperature, adding a part of citric acid solution to adjust the pH at the initial stage of extraction; squeezing and filtering extract liquor, immediately adding bamboo leaf extract and phytic acid to carry out synergistic anti-oxidation treatment, and carrying out short-term aging; and finally, blending with the residual base wine. According to the preparation method disclosed by the invention, the retention rate of active ingredients such as tartary buckwheat flavone and the stability of the wine body are remarkably improved through staged extraction and dual antioxidant protection, the wine body is successfully endowed with coordinated baking fragrance, sauce fragrance and herbal flavor, and the taste is mellow and mild.

The invention belongs to the technical field of catalysts, and particularly relates to a high-performance palladium-carbon catalyst and a preparation method thereof. The activated carbon is subjected to high-temperature roasting, acid pickling and modification treatment, impurities on the surface of the activated carbon are effectively removed, the specific surface area and the pore structure of the carrier are enlarged, and meanwhile a large number of functional groups are introduced; the activated carbon is modified by adopting an amino compound and a sulfur-containing compound, and amino and sulfydryl are introduced to the surface of the activated carbon, so that the palladium adsorption capacity of the activated carbon is improved; a small amount of citric acid is added into the palladium salt solution, palladium ion precipitation is avoided, large-particle-size palladium particles are formed, and the dispersity of palladium is improved.

The invention relates to the technical field of reverse osmosis membrane maintenance, in particular to a cleaning scale inhibitor special for a reverse osmosis membrane and application of the cleaning scale inhibitor. The cleaning scale inhibitor provided by the invention comprises an agent A, an agent B and an agent C, the agent A comprises the following components in percentage by mass: 10-20% of organic phosphonic acid, 10-20% of polycarboxylic acid polymer, 5-10% of sulfamic acid, 3-8% of sodium gluconate and the balance of water; the agent B comprises 8-15% of an isothiazolinone bactericide, 5-10% of a nonionic surfactant, 3-8% of a chlorine bactericide, 2-5% of sodium dodecyl benzene sulfonate and the balance of water; and the agent C comprises 10-20% of sodium polyacrylate, 8-15% of sodium hexametaphosphate, 5-10% of citric acid, 3-8% of silicate and the balance of water. The cleaning scale inhibitor provided by the invention has an efficient cleaning effect on various pollutants, is environment-friendly, and does not cause chemical damage to a reverse osmosis membrane.

The invention belongs to the technical field of biology, and discloses a yarrowia lipolytica engineering strain for efficiently producing eicosapentaenoic acid based on citric acid metabolism regulation, a method and application of the yarrowia lipolytica engineering strain. Delta9 elongase, Delta8 desaturase, Delta5 desaturase and Delta17 desaturase genes in a fatty acid synthesis route, heterologous ATP-citrate lyase and a mitochondrial citric acid vector are overexpressed. According to the invention, ATP-citric acid lyase and a mitochondrial citric acid carrier gene which are respectively derived from Schizochylene sp. And Saccharomyces cerevisiae are jointly expressed in the yarrowia lipolytica engineering strain, so that the yields of EPA and grease in the yarrowia lipolytica engineering strain are remarkably improved, and compared with a control strain, the yields of the grease and the EPA are respectively improved by 243.35% and 161.85%.

The invention relates to the technical field of fluorite ore beneficiation, discloses a fluorite ore flotation composite collecting agent and a preparation method and application thereof, and aims to solve the problems that an existing collecting agent is limited in applicability, insufficient in selectivity, poor in environmental stability and the like and is difficult to deal with separation of fluorite ore containing various impurities or under complex working conditions. The composite collecting agent is composed of dehydroabietylamine, sodium oleoyl sarcosinate, sodium silicate-citric acid composite salt, ethylene glycol butyl ether and a sodium carbonate-sodium bicarbonate buffer pair, all the components have a synergistic effect, dehydroabietylamine provides selective collecting and fine particle agglomeration functions, sodium oleoyl sarcosinate enhances adsorption stability, the composite salt inhibits gangue in a targeted mode, and therefore the adsorption efficiency is improved. Buffer pairs and ethylene glycol butyl ether guarantee the environmental adaptability of a system. The collecting agent can adapt to various fluorite ores with high sulfur, high silicon, low temperature and the like, can stably play a role under different water quality and working conditions, realizes efficient separation of fluorite and impurities, improves the separation efficiency and the concentrate quality, and is flexible in preparation process and convenient for industrial application.

The invention relates to the technical field of environment-friendly materials, and discloses a high-strength degradable packaging material and application of the high-strength degradable packaging material in cosmetic packaging materials.The preparation method of the high-strength degradable packaging material comprises the steps that polylactic acid, vanillic aldehyde modified polyester, polyadipic acid, triethyl citrate, calcium stearate and an antioxidant are added into a high-speed mixing machine, and the mixture is stirred to be uniform; mixing at 60 to 80 DEG C for 10 to 20 minutes to obtain a mixed material; the mixed material is subjected to melt blending through a double-screw extruder, the blending temperature is 160-180 DEG C, the screw rotating speed is 250-300 rpm, extrusion granulation and drying are conducted, and the high-strength degradable packaging material is obtained. The high-strength degradable packaging material can be applied to cosmetic packaging materials such as bottle bodies, bottle caps, hoses and packaging boxes. The prepared packaging material is high in mechanical strength and has good degradability and flame retardance.

The invention discloses a preparation method of a carbon shell confinement type nickel-bismuth-titanium composite catalyst and application of the carbon shell confinement type nickel-bismuth-titanium composite catalyst in high alcohol synthesis, and belongs to the technical field of catalysts. The preparation method of the carbon shell confinement type nickel-bismuth-titanium composite catalyst comprises the following steps: dissolving nickel salt, titanium dioxide and citric acid in water to form a homogeneous solution; adding bismuth salt into the homogeneous solution, and drying to obtain a precursor; and roasting the precursor to obtain the carbon shell confinement type nickel bismuth titanium composite catalyst. The carbon shell confinement type nickel-bismuth-titanium composite catalyst provided by the invention shows excellent catalytic performance in a reaction system for synthesizing high-carbon alcohol through carbon-carbon coupling of water-phase alcohol molecules. According to the catalyst, the high-carbon alcohol yield can reach 45.04% while high organic phase selectivity is maintained, and compared with a traditional nickel-bismuth-based catalyst, the high-carbon alcohol yield is remarkably improved.

The invention discloses a perovskite type composite metal oxide oxygen carrier catalyst as well as a preparation method and application thereof, and belongs to the field of biomass chemical chain gasification / reforming. The oxygen carrier catalyst is of a La, Fe and Ni co-doped SrTiO3 perovskite structure, and active components Fe and Ni are embedded into a main body SrTiO3 perovskite crystal phase structure in an oxide or simple substance form; the method comprises the following steps: preparing an aqueous solution of lanthanum nitrate, strontium nitrate, nickel nitrate, ferric nitrate and citric acid, adding a mixed solution of tetrabutyl titanate and ethylene glycol into the aqueous solution, heating in a water bath, and stirring to form gel; drying and calcining the gel to obtain intermediate powder; and the intermediate powder is oxidized and reduced to form a high-temperature crystal structure under different atmospheres, and the perovskite type composite metal oxide oxygen carrier catalyst is obtained. The oxygen carrier catalyst provided by the invention has high tar conversion rate and stable cycle activity in the biomass chemical chain gasification / reforming process.

The invention relates to the technical field of agricultural application of nano materials, and discloses a preparation method and application of a photosynthetic accelerant containing carbon quantum dots. Urea and citric acid are adopted as raw materials, and the nitrogen-carbon molar ratio and hydrothermal reaction parameters are optimized, so that efficient doping of nitrogen and accurate regulation and control of the particle size are achieved, and the photosynthetic accelerant containing the carbon quantum dots is obtained. The nitrogen-doped carbon quantum dot photosynthetic promoter with excellent upconversion performance is successfully synthesized, the promoter has good water solubility and biocompatibility, the photosynthetic efficiency of plants can be greatly improved within the concentration range of 0-100 mg / L, a safe application window is defined, and by establishing foliage spraying and water planting dual-mode application specifications, the application range of the nitrogen-doped carbon quantum dot photosynthetic promoter is widened, and the application range of the nitrogen-doped carbon quantum dot photosynthetic promoter is widened. The problems that current crops are insufficient in solar spectrum utilization and low in light energy conversion efficiency are solved in a targeted manner by utilizing an ultraviolet light-photosynthetically active radiation conversion function mediated by the carbon quantum dots and combining the targeted enrichment permeation characteristic of the carbon quantum dots in chloroplast.

The invention discloses a high-barrier polyethylene film and a preparation method thereof, and relates to the technical field of high polymer materials. The invention discloses a high-barrier polyethylene film. The high-density polyethylene composite material is prepared from the following raw materials in parts by weight: 25 to 40 parts of high-density polyethylene, 15 to 30 parts of linear low-density polyethylene, 8 to 16 parts of ethylene-vinyl alcohol copolymer, 3 to 8 parts of nano montmorillonite, 5 to 10 parts of modified layered double hydroxide, 2 to 6 parts of nano silicon dioxide aerogel, 0.2 to 0.6 part of antioxidant 1076, 0.1 to 0.4 part of light stabilizer UV-770, 3 to 7 parts of tributyl citrate and 1 to 3 parts of octadecanamide. 1-3 parts of polyethylene wax, 0.6-1.2 parts of a silane coupling agent KH560 and 7-12 parts of a functional additive. According to the high-barrier polyethylene film disclosed by the invention, by using the modified layered double hydroxide and the functional additive, the barrier property and the antibacterial property are enhanced, the mechanical property is improved, the comprehensive performance is excellent, and the application prospect is good.

The invention belongs to the field of preparation of soil conditioners, and particularly relates to a soil loosening and root promoting soil conditioner and a preparation method thereof. A polymer formed by vinyltriethoxysilane, polyacrylic acid and coumarin under the catalytic action of citric acid is mixed with porous powder obtained after crushing and nutrient organic matter, and freeze-drying is performed to obtain the soil-loosening improved fermentation substrate which can be slowly released in soil; polyaspartic acid and acetylchitosamine are cross-linked under the catalytic action of N-hydroxysuccinimide, root-promoting nutrition powder and auxiliary root-promoting components are mixed, and the obtained composite root-promoting agent can significantly promote the growth of plant root systems; a porous structure contained in the protective stability maintaining agent can provide a relatively stable microenvironment for effective components, and the soil loosening and root promoting agent is mixed with the soil loosening and improving fermentation substrate and the composite root promoting agent, so that the prepared soil loosening and root promoting soil conditioner is remarkable in soil loosening and root promoting effect, long-acting and stable, small in dosage, obvious in effect and stable in conditioning effect after being stored.

The invention relates to the technical field of polymer compositions, and particularly discloses a degradable bio-based food packaging material and a preparation method thereof.The degradable bio-based food packaging material is prepared from polylactic acid, ITA esterified bacterial cellulose, CSL-ITA esterified bacterial cellulose, polycaprolactone glycol, acetyl tributyl citrate, a photoinitiator and tocopherol; the preparation method comprises the following steps: esterifying bacterial cellulose hydrogel with itaconic anhydride, grafting with sodium copper chlorophyllin, dehydrating with gradient ethanol, and drying with supercritical CO2 to obtain modified powder; according to the preparation method, the interfacial compatibility of the bacterial cellulose and the polylactic acid is enhanced through ITA esterification, the illumination antibacterial function is given by utilizing CSL grafting, the polycaprolactone glycol and the acetyl tributyl citrate are synergistically used for toughening and improving the brittleness, the photoinitiator is added, the photoinitiator is added for mixing, and ultraviolet crosslinking curing is performed after film forming. The tocopherol protects the stability of the antibacterial structure of the CSL, the water resistance is improved through photo-crosslinking, and the material is degradable and meets the food packaging requirement.

The invention provides a bio-based composite liquid mulching film and a preparation method thereof. The bio-based composite liquid mulching film comprises a nanocellulose solution, modified starch, modified chitosan, glycerol and calcium carbonate, the modified starch is obtained by modifying starch with citric acid; the modified chitosan is obtained by grafting and copolymerizing chitosan with an acrylic monomer. According to the invention, a plurality of bio-based components such as modified starch, modified chitosan, a nanocellulose solution, glycerol and calcium carbonate are integrated, and natural characteristics of bio-based materials are utilized to form a uniform and degradable film layer; the soil moisture retention film can better isolate air and moisture loss, improves the soil moisture retention ability, ensures sufficient strength and flexibility in the application process, and avoids the problems of early cracking or deformation and the like.

The invention discloses a wood-based composite phase-change material and a preparation method thereof, and belongs to the technical field of phase-change materials.The preparation method of the wood-based composite phase-change material comprises the following steps that wood is cut and then added into delignification liquid to be heated, the wood is taken out and washed with water, and delignified wood is obtained; the delignification wood is added into the modification liquid to be heated, and after being taken out, the delignification wood is washed and dried to obtain pretreated wood; mixing polyethylene glycol, citric acid and boric acid, heating and stirring to obtain a phase change material; dipping the pretreated wood into the phase change material for vacuum dipping, taking out and drying to obtain the phase change material. The modified liquid is prepared from an ethanol water solution, a modified filler, 2-(3, 4-cyclohexene oxide) ethyltrimethoxysilane and triethylamine. The delignification liquid and the modification liquid are adopted for pretreating the wood, so that the wood can be better firmly combined with the phase change material, leakage is prevented, and the finally prepared wood-based composite phase change material has excellent heat management capacity and stability.

The invention relates to the technical field of crude oil decalcification, in particular to a low-corrosivity crude oil decalcification agent and a preparation method thereof. The low-corrosivity crude oil decalcifying agent is prepared from the following raw materials: acetic acid, citric acid, modified chitosan, ethanol and deionized water, wherein the modified chitosan is prepared by synthesizing N-hydroxyacrylamide, performing sulfonation treatment, and grafting poly (N-isopropylacrylamide) with carboxymethyl chitosan. The preparation method comprises the following steps: adding deionized water and modified chitosan into a blending kettle, heating to 65-75 DEG C, stirring, sequentially adding acetic acid and citric acid, continuously stirring, finally adding ethanol, stirring, and cooling to obtain the decalcifying agent. The decalcifying agent can efficiently remove organic calcium, equipment corrosion is reduced through temperature-sensitive film forming, chelate is stable at high temperature, sewage COD is low, the decalcifying agent adapts to an existing electro-desalting process, and industrial application is easy.

The invention belongs to the technical field of lithium ion battery material recovery, and discloses a regeneration, repair and doping method of a waste lithium iron phosphate material and a regenerated positive electrode material. The method comprises the following steps: firstly, immersing waste LiFePO4 powder into a mixed solution of citric acid and ascorbic acid, oscillating to selectively dissolve out Fe < 3 + > impurities, and synchronously reducing Fe < 3 + > on the surface to Fe < 2 + >; then Li2CO3 is added into the leached powder for lithium bit compensation, and ball milling and uniform mixing are carried out; then Al2O3 and TiCl3 are added for aluminum-titanium co-doping, and ultrasonic dispersion is carried out uniformly; and finally, carrying out segmented sintering. In the first stage, sintering is carried out in an air atmosphere at 300-350 DEG C; in the second stage, sintering is performed at 600-700 DEG C in an inert gas atmosphere; and finally obtaining the regenerated positive electrode material. According to the method, waste lithium iron phosphate batteries can be turned into wealth, the lithium iron phosphate positive electrode material with good electrochemical performance is obtained, the complex and expensive impurity removal process is omitted, the cost is low, and possibility is provided for large-scale industrial regeneration and repair of waste lithium iron phosphate active substances.

The invention discloses a preparation method of a composite flocculant based on efficient water treatment, belongs to the technical field of flocculant processing, and aims to solve the technical problem that the flocculation performance and the settling performance of a flocculant need to be further improved in the prior art. The preparation method specifically comprises the following steps: putting acrylamide, diallyldimethylammonium chloride, 2-hydroxypropyl methacrylate and deionized water into a reaction kettle, and uniformly mixing to obtain a mixed monomer; according to the preparation method, citric acid monohydrate and iron nitrate nonahydrate react under a mild acidic condition to form a Fe < 3 + >-citric acid complex, and then 2-hydroxyethylamine is introduced to further participate in complexing to obtain a citric acid complexing solution, so that not only is the flocculation performance of the composite flocculant improved, but also the settling performance of the composite flocculant is improved.