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233 results about "Diol" patented technology

A diol is a chemical compound containing two hydroxyl groups (−OH groups). An aliphatic diol is also called a glycol. This pairing of functional groups is pervasive, and many subcategories have been identified.

Unsaturated polyester resin for imitation jade handicrafts and preparation method of unsaturated polyester resin

The invention discloses unsaturated polyester resin for imitation jade handicrafts and a preparation method thereof, and belongs to the technical field of polyester resin. Comprising the following components: diethylene glycol, methylpropanediol, propylene glycol, maleic anhydride, phthalic anhydride, an antioxidant, a polymerization inhibitor, paraffin, a stabilizer, an ultraviolet light absorber, a whitening agent and a diluent. The weight ratio of the propylene glycol to the methyl propylene glycol is (1.0-1.3): 1, and the methyl propylene glycol accounts for 20-22% of the total amount of the dihydric alcohol; the weight ratio of maleic anhydride to phthalic anhydride is (0.46-0.52): 1; the preparation method comprises 1) adding the raw materials and the antioxidant into a reactor, carrying out heating, carrying out heat preservation for 0.5-1.0 h and continuing heating, 2) carrying out a reaction for 2-3 h after heating, carrying out dehydration until an acid value is 20-25 mgKOH / g, and 3) carrying out cooling, adding the auxiliary agent and carrying out uniform mixing so that the unsaturated polyester resin is obtained.
Owner:SHANDONG WANGLIN NEW MATERIALS CO LTD +2

Polyurethane coating and preparation method thereof

The invention discloses a polyurethane coating and a preparation method thereof, and belongs to the technical field of antibacterial coatings. The preparation method of the polyurethane coating comprises the following steps: carrying out acyl chloride substitution reaction on a phenolic substance and a chlorine donor to obtain an intermediate reactant, and carrying out conjugate addition reaction on the intermediate reactant and an amine substance with hydroxyl groups at two ends to obtain antibacterial diol; reacting the antibacterial diol with isocyanate to obtain a polyurethane coating; the phenolic substance is selected from at least one of thymol, carvacrol, paeonol, catechol and theaflavin. The antibacterial coating is applied to the aspect of an antibacterial coating of a food contact part, the problem that the antibacterial property of an existing antibacterial coating is difficult to last is solved, and the antibacterial coating has the synergistic antibacterial effect of killing and defending bacteria.
Owner:HISENSE(SHANDONG)REFRIGERATOR CO LTD

An energetic perfluoroborate binder, its preparation method and applications

The present invention relates to an energetic perfluoroborate binder, a preparation method thereof and an application thereof, belonging to the technical field of energetic binders. The structural formula of the binder is:; wherein, n is a positive integer less than or equal to 20. The main raw materials of the binder are 1H,1H,2H,3H,3H-perfluorononane-1,2-diol, boric acid and polyazidoglycidyl ether; boric acid forms a borate bond with 1H,1H,2H,3H,3H-perfluorononane-1,2-diol, and polyazidoglycidyl ether is compounded through the boron-nitrogen coordination action with 1H,1H,2H,3H,3H-perfluorononane-1,2-diol, realizing the controllable preparation of the energetic perfluoroborate binder. The energetic perfluoroborate binder has high energy and stable storage, and can improve the energy and mechanical properties of the propellant.
Owner:BEIJING INST OF TECH

processing liquid

The present invention relates to a processing liquid containing an effective ingredient and water, wherein the effective ingredient contains the following component (A), the following component (B), and the following component (C), • component (A): one or more compounds selected from a specific acetylenic diol and an alkylene oxide adduct thereof, • component (B): a compound containing a copolymerization site of ethylene oxide and another alkylene oxide, and not having a carbon-carbon triple bond, • component (C): a compound containing a copolymerization site of ethylene oxide and another alkylene oxide, not having a carbon-carbon triple bond, and having a higher cloud point than the component (B) at 1 mass% aqueous solution, the content of the component (A) and the total content of the component (B) and the component (C) are in a specific range based on the total amount of the effective ingredient, and the content ratio (A) / (C) of the component (A) and the component (C) and the content ratio (B) / (C) of the component (B) and the component (C) are in a specific range in terms of mass ratio.
Owner:IDEMITSU KOSAN CO LTD

Process for producing l-glufosinate from a diol or diol derivative

A process for making L-glufosinate, the process comprising the following steps: a) reacting a compound according to formula (I), (I), wherein R1 is hydrogen, (C1-C12)-alkyl, (C1-C12)-haloalkyl, (C6-C10)-aryl, (C6-C10)-haloaryl, (C7-C10)-aralkyl, (C7-C10)-haloaralkyl, (C4-C10)-cycloalkyl, or (C4-C10)-halocycloalkyl, with a compound according to formula (II), (II), wherein R2 and R3 are independently from each other (C1-C8)-acyloxy, (C1-C8)-alkoxy or hydroxy, or R2 and R3 form together an epoxide group or an ethylene carbonate group, and optional subsequent acidic treatment to form a diol according to formula (III), (III), b) Oxidizing the diol according to formula (III) to form 2-oxo-4-(hydroxy(methyl)phosphinoyl)butyric acid (PPO); and c) aminating the PPO to L-glufosinate.
Owner:BASF SE

Method for preparing a 1,4:3,6-dianhydrohexitol diester composition

The invention relates to a method for preparing a C13-C29 alkyl diester of 1,4:3,6-dianhydrohexitol, said method comprising:a) a first step of esterification of 1,4:3,6-dianhydrohexitol with a fatty acid having a C13-C29 alkyl chain, said fatty acid being in excess, so as to form a reaction crude comprising a C13-C29 alkyl diester of 1,4:3,6-dianhydrohexitol and unreacted fatty acid;b) a second step of esterification of the unreacted fatty acid with a primary or aromatic diol.
Owner:ROQUETTE FRERES SA

Resin composition, adhesive composition, and laminate

Provided is a resin composition with which it is possible to produce laminates having various kinds of laminate structures that exhibit excellent adhesion and tear-openability without using an aromatic isocyanate, and which does not substantially contain a solvent component and is used as a main agent of a two-liquid curing type adhesive composition capable of being applied in a thin film state. This resin composition is used as a main agent (A) of a two-liquid curing type adhesive composition including the main agent (A) and a curing agent (B) and does not substantially contain a solvent content. The resin composition includes a polyester (a) having hydroxyl groups at molecular terminals at a hydroxy group concentration of 1.0-6.0 mol / kg. The polyester (a) has structural units derived from a dicarboxylic acid (α) and structural units derived from a diol (β). In the structural units derived from the dicarboxylic acid (α), the contained amount of a structural unit derived from an aromatic dicarboxylic acid (α1) is greater than 40 mol%. The melt viscosity of the resin composition at 80°C is 10,000 mPa・s or less.
Owner:DAINICHISEIKA COLOR & CHEMICALS MFG CO LTD

Modified polyester as well as preparation method and application thereof

PendingCN120554621APolyesterPolymer science
The invention relates to the field of polyester, and discloses modified polyester as well as a preparation method and application thereof. The modified polyester contains a structural unit A as shown in a formula (I) and a structural unit B as shown in a formula (II), R1 and R2 are respectively and independently C0-C4 alkylene, and R3, R4, R5, R6, R7, Ra, Rb, Rc and Rd are respectively and independently hydrogen or C1-C4 alkyl. The method comprises the following steps: (1) under an esterification reaction condition, mixing a modified monomer, a binary acid monomer, a dihydric alcohol monomer and a catalyst, and carrying out a first-stage reaction to obtain a prepolymer; (2) under the polycondensation reaction condition, mixing the prepolymer with a stabilizer, and carrying out second-stage reaction; wherein the modified monomer contains polyhydric alcohol with a structure as shown in a formula (I) and polybasic acid with a structure as shown in a formula (II). The modified polyester has excellent explosion-proof performance, excellent puncture resistance and better optical performance. # imgabs0 #
Owner:CHINA PETROLEUM & CHEMICAL CORP +1

Polymerization of diol bis(allyl carbonates) using a mixture of two different peroxy compounds

ActiveUS12679914B2Benzoic acidPolymer science
Provided is a polymerizable composition including (a) a polymerizable component comprising a diol bis(allyl carbonate) and / or a pre-polymer thereof; and (b) a polymerization initiator component including: (i) a di(C6-C10 alkyl) peroxydicarbonate, and (ii) an organic peroxide having one peroxy, one peroxycarbonate, or one peroxybenzoate group and a 1,1-dimethylalkyl group bonded to a peroxy oxygen, where (ii) comprises a molecular weight ranging from 200 to 250 g / mole, the polymerization initiator (b) is free of diisopropyl peroxydicarbonate, (i) comprises an amount ranging from 4.87% to 7.90% by weight relative to the total solids of the polymerizable composition and (ii) comprises an amount within the range defined by the following formula: (4.406X2−0.592X+0.021)≤Y≤(0.726X2−0.121X+0.009) where X corresponds to the weight fraction of (i) and Y corresponds to the weight fraction of (ii). Also provided is a method of making an optical article from the polymerizable composition.
Owner:PPG INDUSTRIES OHIO INC

Preparation method of 1, 5-hexadiene-3, 4-diol

The invention discloses a preparation method of 1, 5-hexadiene-3, 4-diol, which is characterized in that acrolein is used as a raw material, and the 1, 5-hexadiene-3, 4-diol is prepared by reductive coupling reaction in the presence of an ammonium chloride aqueous solution and a zinc powder catalyst. According to the method, the yield reaches up to 92% or above, compared with an existing synthesis method, reaction operation is simplified, the reaction yield is increased, and a novel reduction method is provided; the separation and purification method is simple and efficient, the product quality is high, the commercialized use requirement can be met, and large-scale production is achieved.
Owner:HAISO TECH CO LTD +1

Staining reagent

The invention relates to a staining reagent for carrying out histological and / or hematological stainings, comprising A) at least one solvent in a proportion of 55% by volume to 99.95% by volume, selected from the group consisting of A1) esters of the formula R1-C(=O)-O-R2, A2) ethers of the formula R3-O-R4, A3) sulfoxides of the formula R5-S(=O)-R6, A4) sulfones of the formula R7-S(=O)2-R8, A5) monohydric alcohols in which the alcoholic OH group is bonded to an aliphatic C atom in a hydrocarbon group of 4 to 8 carbon atoms, A6) diols which have 2 OH groups on an aliphatic hydrocarbon radical with 3 to 6 carbon atoms, A7) formals of the formula R9-O-CH2-O-R10, A8) dihydrolevoglucosenone, A9) propylene carbonate, and A10) N-butylpyrrolidone; B) at least one staining pigment in a proportion of 0.05% by volume to 7% by volume; and C) optionally an additional solvent selected from the group consisting of dimethyl sulfoxide, water, monohydric alcohols with 1 to 3 carbon atoms, and sugar alcohols, wherein R1 represents a C4 to C8 alkyl group or a group of the formula R2-O-C(=O)-R-; R2 represents a C1 to C4 alkyl group; R represents a C2 to C6 alkylene group; R3 represents a C2 to C4 alkyl group which can have an OH group; R4 represents a group of the formula -R11-(O-R12-)n-R13; R11 represents a C2 to C4 alkylene group; R12 represents a C1 to C4 alkylene group; R13 represents H, OH or -O-C(=O)-CH3; n represents 0, 1, 2 or 3; and R5 and R6 independently of one another represent a C1 to C4 alkyl group, with the proviso that the sum of the number of carbon atoms in R5 and R6 is 3 or higher, R7 and R8 independently of one another represent a C1 to C4 alkyl group, and R9 and R10 independently of one another represent a C4 to C8 alkyl group.
Owner:BIO-GRAM HEMATOLOGY GMBH

Polyester-based resin, and production method and usage for same

PCT designated stage expiredWO2025110103A1Optical elementsPolyesterPolymer science
Provided is a polyester-based resin that is capable of achieving a highly sufficient balance between mechanical characteristics, heat resistance, optical characteristics, and fabricability. The polyester-based resin is formed from: diol units (A) including a first diol unit (A1) represented by formula (1) (in the formula, A1 and A2 each independently represent an alkylene group, n1 and n2 each independently represent an integer of 0 or greater, R1 and R2 each independently represent a substituent, m1 and m2 each independently represent an integer from 0 to 6, and A3 represents a direct bond (single bond) or an alkylene group), a second diol unit (A2) having a diphenylfluorine skeleton, and a third diol unit (A3) having an alkylene skeleton; and dicarboxylic acid units (B) including a dicarboxylic acid unit (B1) having a fused polycyclic arene ring skeleton. The proportion of the first diol unit (A1) is adjusted to 5-60 mol% of the total of the diol units (A), and the proportion of the dicarboxylic acid unit (B1) is adjusted to 50 mol% or more of the total of the dicarboxylic acid units (B).
Owner:OSAKA GAS CHEM KK

Copper paste

A copper paste according to the present invention contains copper powder and an alcohol solvent, where the alcohol solvent contains a first alcohol composed of at least one type of alcohol selected from the group comprising monohydric alcohols and dihydric alcohols, which has a viscosity of 3 mPa·s or more and 70 mPa·s or less at 25°C; and a second alcohol composed of at least one type of dihydric alcohols and trihydric alcohols, which has a viscosity of 300 mPa·s or more and 1000 mPa·s or less at 25°C, and the viscosity of η10 at a shear rate of 10 s-1at 25°C is 1 Pa·s or more and 50 Pa·s or less, and the square root of √σ0 of the Casson yield stress of σ0 is 10 Pa1 / 2 or less.
Owner:MATERIAL CONCEPT

High-washability hot-melt polyester as well as preparation method and application thereof

The invention discloses a hot-melt polyester with high washing resistance, which is prepared from the following raw materials: a binary acid composition, a dihydric alcohol composition, an antioxidant and a catalyst, and the molar ratio of the binary acid composition to the dihydric alcohol composition is 1: (1.8-2.2). According to the invention, the hydrophobicity and structural stability of polyester can be obviously improved, so that the reflective layer is not easy to peel off in the washing process, and good bonding strength and retroreflection coefficient are maintained after washing. The retroreflection coefficient is 180-300 cd.lx <-1 >. M <-2 > and the bonding strength is 1.2-1.8 MPa after the reflective material is washed for 50 times by an ISO 15797-part4 method, so that the reflective material meets the requirements of keeping high washing resistance and high brightness from a common mark to a high-end protective reflective material, and has a wide application prospect.
Owner:HANGZHOU CHINASTARS REFLECTIVE MATERIAL

Polyester material, preparation method thereof and antibacterial product

The invention relates to a polyester material, a preparation method thereof and an antibacterial product. The polyester material comprises a polyester main chain and antibacterial peptide; the polyester main chain is prepared from the following raw materials: dibasic acid and / or dibasic ester and dihydric alcohol; the dibasic acid comprises terephthalic acid, and the dibasic ester comprises terephthalic acid ester; the antibacterial peptide is prepared through a ring-opening polymerization reaction of amino-acid ester-N-carboxy anhydride. According to the polyester material, the heat resistance and the optical performance are further improved while good antibacterial performance is achieved.
Owner:WANHUA CHEM GRP CO LTD

Diol compound, resin, polycarbonate resin, and optical molded article

To provide a diol compound capable of enhancing the refractive index of a resin, and a resin, a polycarbonate resin, and an optical molded article having an enhanced refractive index.SOLUTION: The present invention provides a diol compound represented by the following formula (1). In formula (1), H bonded to C may be substituted with a C1-C10 alkyl group or a C1-C10 heteroatom-containing alkyl group; W represents a group selected from the following formula (W-1) and the like (where * represents a bonding site, and n independently represents an integer of 1 to 4); and Ar1 and Ar2 independently represent a substituted or unsubstituted aromatic group or heteroaromatic group.SELECTED DRAWING: None
Owner:MITSUI CHEMICALS INC

Alkaline composition, its use and a process for cleaning substrates comprising cobalt and copper

The presently claimed invention relates to an alkaline composition for cleaning a substrate comprising i) copper or copper alloy and ii) cobalt or cobalt alloy, the composition comprising: a) at least one pH adjustor selected from diglycolamine, 4,4-diethoxy-N,N-dimethyl-1-butanamine, 3-dimethylaminopropan-1-ol, dimethylaminoethoxyethanol, N,N-dimethylisopropanolamine, ethylethanolamine, N-methyldiethanolamine, 2-(2-(methylamino)ethoxy)ethanol, 3-(methylamino)propane-1,2-diol, 2-[2-[2-(2-methoxy- ethoxy)ethoxy]ethoxy]ethylamine, 2-[2-(2-aminoethoxy)-ethoxy]-ethanol, N-butyldiethanolamine, diisopropanolamine, N-methyldiisopropanolamine, monoethanolamine, 3-dimethylamino-1,2-propandiol, 2- amino-1-butanol, 2-(2-(2-(2-aminoethoxy)ethoxy)ethoxy)ethanol, prolinol, 1-methyl-2-pyrrolidinemethanol, 1-methyl-2-pyrrolidinemethanol, 1-methyl-3-pyrrolidinol, 2-amino-2-methyl-1-propanol, N,N-dimethylethanolamine, butylethanolamine, diethylethanolamine, 3-methoxypropylamine, 4-(2-hydroxyethyl)morpholine, 4-(dimethylamino)cyclohexanol, 2-amino-2-methyl-1, 3-propanediol, or diisopropylamine; b) at least one complexing agent selected from C2 to C12 hydrocarbon having at least two sulfonic acid or carboxylic acid groups; c) at least one polymeric dispersing agent having a weight average molecular weight ≥ 1000 g / mol; and d) a solvent comprising water.
Owner:BASF SE

Resin composition and cured product thereof

PendingJP2026103975APolymer scienceCarboxylic acid
The object of the present invention is to provide a resin composition that is heat-curable or photocurable, alkali-soluble, has a low dielectric constant and dielectric loss tangent of the cured product, and exhibits high adhesion and glass transition temperature, as well as excellent insulation reliability. [Solution] A resin composition is used that contains a compound represented by the following formula (1) and a compound containing one or more epoxy groups in one molecule. TIFF2026103975000012.tif29170 (In formula (1), each X independently represents a residue of an aromatic or aliphatic tetracarboxylic anhydride with the carboxyl group removed. Y represents a divalent residue of a diol with the hydroxyl group removed. Each Z independently represents a residue of a functional group containing a radically polymerizable double bond. n is the average number of repeating units and is a real number between 0.1 and 20.)
Owner:NIPPON KAYAKU CO LTD

Polyester resin composition and method for producing same

Provided is a polyester resin composition which has a high degree of crystallinity and which crystallizes to the same degree as the surface even in the interior. A polyester resin composition comprising a dicarboxylic acid component mainly composed of furandicarboxylic acid and a diol component mainly composed of ethylene glycol, the polyester resin composition having a crystallinity of 5% or more, and the heights (I1-I4) of absorbance peaks in an infrared absorption spectrum satisfying the following formula. I1 / I2-I3 / I4 < = 0.20 (In the formula, I1 represents the height of the absorbance peak near 1340 cm <-1 > on the surface of the polyester resin composition, I2 represents the height of the absorbance peak near 1580 cm <-1 > on the surface of the polyester resin composition, I3 represents the height of the absorbance peak near 1340 cm <-1 > at a depth of 1 mm from the surface of the polyester resin composition, and I4 represents the height of the absorbance peak near 1580 cm <-1 > at a depth of 1 mm from the surface of the polyester resin composition. I4 represents the height of absorbance peak near 1580 cm-1 at a position at a depth of 1 mm from the surface of the polyester resin composition)
Owner:TOYOBO CO LTD

Methods for preparing diol

Provided is a method for preparing a diol. In the method, a saccharide and hydrogen as raw materials are contacted with a catalyst in water to prepare the diol. The employed catalyst is a composite catalyst comprised of a main catalyst and a cocatalyst, wherein the main catalyst is a water-insoluble acid-resistant alloy; and the cocatalyst is a soluble tungstate and / or soluble tungsten compound. The method uses an acid-resistant, inexpensive and stable alloy needless of a support as a main catalyst, and can guarantee a high yield of the diol in the case where the production cost is relatively low.
Owner:CHANGCHUN MEIHE SCI & TECH DEV CO LTD +1

Resin composition

Provided is a thermoplastic resin composition having excellent optical characteristics, which does not impair the characteristics of an optical resin composition, has high flowability and good moldability, and has a composition capable of preventing gelation (increase in molecular weight). The polycarbonate resin contains a structural unit (A) derived from a diol represented by formula (1), and a structural unit (B) represented by formula (2) and / or a structural unit (C) represented by formula (3). # imgabs0 #
Owner:MITSUBISHI GAS CHEM CO INC

A method for preparing (1'S, 2'S)-eugenolylglycerol 3'-O-β-D-glucopyranoside

PendingCN122628109ASide chainDouble bond
The application belongs to the technical field of compound preparation, and discloses a preparation method of (1'S, 2'S)-eugenol glycerol 3'-O-beta-D-glucopyranoside. The method is characterized in that: a phenolic hydroxyl group allyl compound protected by a benzyl group is subjected to O-glycosylation reaction with a D-glucopyranosyl donor protected by an acetyl group, so as to obtain an olefin type protected glycoside intermediate which retains a side chain carbon-carbon double bond; then, asymmetric dihydroxylation reaction is performed on the intermediate, so as to construct a target vicinal diol chiral structure; finally, the acetyl protecting group of the sugar hydroxyl group and the benzyl protecting group of the phenolic hydroxyl group are sequentially removed, so as to obtain the target compound. The preparation method of (1'S, 2'S)-eugenol glycerol 3'-O-beta-D-glucopyranoside is characterized in that: the glycoside bond is constructed before dihydroxylation, which is beneficial to reducing the competition reaction of multiple hydroxyl groups and realizing the preparation of the target compound.
Owner:TIANJIN UNIV

Residual acid analysis method for alcohol compounds

The invention discloses a residual acid analysis method for alcohol compounds. The method comprises the following steps: providing an organic solvent, and putting the organic solvent into a distiller to distill the organic solvent and obtain a purified organic solvent in a distillation middle section; mixing a basic inorganic compound with the purified organic solvent to produce a titration liquid; mixing a diol compound with the purified organic solvent to generate a sample to be detected; and carrying out acid-base titration on the to-be-detected sample by using the titration liquid so as to analyze the acid residual quantity of the diol compound. Wherein the equivalent concentration of the alkaline inorganic compound in the titration liquid is not more than 0.005 N. Therefore, the detection accuracy of the residual acid analysis of the alcohol compounds can reach the concentration grade which is low enough, and the detection limit is improved.
Owner:NANYA PLASTICS CORP

Method for producing bio-based dihydric alcohol

The invention discloses a method for producing bio-based dihydric alcohol. According to the method, bio-based methyl 2-tetrahydrofuroate, tetrahydrofurfuryl propionate and methyl 2-(tetrahydrofuran-2-yl) acetate are used as precursors for dihydric alcohol synthesis, Cu-Ga-Mn / SiO2 or Cu-Ga-Mn / SiO2-Al2O3 is used as a hydrogenation catalyst, cyclic ether ester structures are synchronously activated in a fixed bed reactor, ester group hydrogenation and tetrahydrofuran ring opening are synergistically carried out, and the high-purity tetrahydrofuran is obtained. The reaction path is shortened. The hydrogenation catalyst is prepared by combining a sol-gel method and hydrothermal synthesis through roasting and reduction, active components are uniformly distributed, and the hydrogenation catalyst has excellent hydrogenation activity and structural stability.
Owner:HENAN NON-GRAIN BIO-BASED MATERIALS TECHNOLOGY INNOVATION CENTER CO LTD

A glycol ether microtubular reactor

The utility model relates to dihydric alcohol ether micro -tube type reactor technical field, and disclose a dihydric alcohol ether micro -tube type reactor, including the tubular reactor body, the both sides of tubular reactor body surface all are connected with the connecting port for feeding, the inner chamber of tubular reactor body is provided with the auxiliary block of reinforcement fluid chaos mixing effect, the utility model discloses in the routine use of tubular reactor body, can be under the action of liquid heat exchanger body, pressurizing pump, heat exchange pipe and liquid delivery pipe, the heat of tubular reactor body inner chamber is heat exchanged, reaches the effect of temperature control to reduce the possibility of by -product production in the reaction due to local overheating, and can be under the action of pressurizing pump, can make the pressure change of pressurizing chamber inner chamber, thereby make the vibration piece pressure vibrate, and then reach the effect of vibration and drop viscous material, reduce the probability of tubular reactor body block, improve the practicality of this device.
Owner:QINGDAO HIGHLY CHEM NEW MATERIALS CO LTD

Production method of 4-10B-boric acid-L-phenylalanine with high boron atom utilization rate

The invention provides a production method of 4-10B-boric acid-L-phenylalanine with high boron atom utilization rate, which comprises the following steps: A, adding strong base and a Turbo Grignard reagent into a 4-halogenated-phenylalanine derivative for reaction, and then adding glycol ester borane for continuous reaction to obtain a 4-boryl-phenylalanine derivative; and B, carrying out acidic hydrolysis on the 4-boryl-phenylalanine derivative, so as to obtain the 4-10B-boric acid-L-phenylalanine. The boron element is introduced into phenylalanine molecules through halogen-metal exchange and electrophilic substitution reaction, wherein the reagent combination of the Turbo Grignard reagent and the glycol ester borane ensures the efficient proceeding of the boronylation process. The production method disclosed by the invention is mild in reaction condition and simple to operate, has high-level comprehensive yield and 10B boron atom utilization rate, and provides a new way for realizing low-cost commercial production of 10B-BPA.
Owner:SHANGHAI JIAOTONG UNIV

Polyester resin, resin composition for cosmetic container, molded article, and cosmetic container

Provided is a polyester resin containing diol structural units and dicarboxylic acid structural units, in which 1-25 mol% of all the diol structural units are diol structural units (alpha) having a cyclic acetal skeleton, and 15-40 mol% of all the dicarboxylic acid structural units are dicarboxylic acid structural units (beta) derived from isophthalic acid.
Owner:MITSUBISHI GAS CHEM CO INC

Catalyst Containing Coke and Method for Producing Dienes

ActiveCN114286722BCatalystsHydrocarbon preparation catalystsDiffuse reflectance infrared fourier transformPtru catalyst
The present invention relates to a catalyst comprising coke, characterized in that the coke has at least two peaks at wavelengths between 1450 cm-1 and 1700 cm-1 when analyzed by diffuse reflectance infrared spectroscopy (“diffuse reflectance infrared Fourier transform spectroscopy” - DRIFTS). The aforementioned catalyst comprising coke can be advantageously used in a process for producing dienes, preferably conjugated dienes, more preferably 1,3-butadiene, said process comprising dehydrating at least one enol having at least 4 carbon atoms. Preferably, the enol having at least 4 carbon atoms can be obtained directly from a biosynthetic process or by a catalytic dehydration process of at least one diol. When the enol is butenol, the diol is preferably butanediol, more preferably 1,3-butanediol, even more preferably bio-1,3-butanediol, i.e., 1,3-butanediol derived from a biosynthetic process. When the diol is 1,3-butanediol or bio-1,3-butanediol, the dienes obtained according to the process of the present invention are 1,3-butadiene or bio-1,3-butadiene, respectively.
Owner:VERSALIS SPA +1

Non-aqueous inkjet ink composition and recording method

Provided is a non-aqueous inkjet ink composition and recording method that can achieve both good gloss and good unevenness reduction. A non-aqueous inkjet ink composition according to an embodiment of the present invention contains a luster pigment, and diol monoethers A and B represented by the following formula (1) that differ in flash point, the flash point of the diol monoether A being 85°C or lower, the flash point of the diol monoether B being 95°C or higher, the total content of the diol monoether A and the diol monoether B being 20 to 60% by mass relative to the total amount of the ink composition, and the content of the diol monoether A being greater than the content of the diol monoether B.R1‑(O‑R2) n ‑OH … Formula (1)In formula (1), R1 is an alkyl group having 1 to 8 carbon atoms or a phenyl group, R2 is an alkylene group having 1 to 5 carbon atoms, and n is an integer of 1 to 4.
Owner:SEIKO EPSON CORP

condom

The present invention provides a condom comprising a copolymer X obtainable by polymerisation of monomers A, B, C, and D;wherein monomer A is one or more compound of the formula:in which R1 and R2 are independently selected from H and C1-C20 alkyl optionally substituted by a hydroxyl, primary amine or secondary amine group, provided that one of R1 and R2 bears a hydroxyl, primary amine or secondary amine group;monomer B is one or more diisocyanate compound of the formula OCN—R3—NCO, in which R3=C4-C20 alkylene, which may optionally be cyclic or branched;monomer C is one or more telechelic hydroxy terminated polyalkylene glycol compound having a number average molecular weight of 1000 to 10,000 and is preferably linear;monomer D is one or more diol of the formula HO—R4—OH, in which R4 is C2-C20 alkylene which may be interrupted by 1-5 heteroatoms selected from the group consisting of O, N and S, preferably 1 O atom and / or preferably wherein R4 is linear;wherein, the molar ratio of monomers D to C is in the range 0.1:1 to 10:1.
Owner:RECKITT BENCKISER HEALTH LTD