3265 results about "Glass transition" patented technology

The invention relates to the technical field of batteries, in particular to a non-fluorine polymer, a preparation method thereof, a composite diaphragm and application of the composite diaphragm. The non-fluorine polymer has a core-shell structure, a core layer comprises a polymer A, a shell layer comprises a polymer B, the glass transition temperature Tg1 of the polymer A is 91-155 DEG C, and the glass transition temperature Tg2 of the polymer B is-30-10 DEG C. The core layer and the shell layer of the non-fluorine polymer have proper glass transition temperature and good physical and chemical properties, so that the comprehensive performance of the composite diaphragm is improved, and the cycling stability and the safety performance of the battery are improved.

The invention provides a diaphragm adhesive composition, a diaphragm and a lithium ion battery, the solid content of the diaphragm adhesive composition is 10-40wt%, and when the solid content of the diaphragm adhesive composition is diluted to 5wt%, the surface tension of a diluent is not less than 28mN / m; the diaphragm adhesive composition comprises polymer particles A and a polymer adhesive B, wherein the solid mass ratio of the polymer particles A to the polymer adhesive B is 100: (3-30); the particle size of the polymer particles A is 0.2-10 [mu] m, and the glass transition temperature of the polymer particles A is 30-90 DEG C; and the polymer adhesive B is a water-based emulsion type adhesive, the particle size of polymer particles contained in the polymer adhesive B is 0.1-1 mu m, and the glass transition temperature of the polymer adhesive B is-50-20 DEG C. The diaphragm adhesive composition disclosed by the invention is not easy to spread on a base material, can prevent an adhesive glue solution from being quickly diffused on the surface of a diaphragm, forms controllable, uniform-size and uniformly-distributed adhesive coating points on the surface of the base material, and has small influence on the air permeability of the diaphragm.

The invention relates to the technical field of high polymer material chemistry, and discloses a high and low temperature resistant anti-yellowing optical adhesive and a preparation process thereof, the high and low temperature resistant anti-yellowing optical adhesive comprises the following components by weight: 40-60% of modified organic silicon resin, 20-30% of urethane acrylate, 10-15% of alicyclic epoxy resin, 0.5-5% of a nano inorganic filler, 0.8-2.5% of an anti-yellowing composite reagent, and the balance of a solvent. The coating is prepared from the following components in percentage by weight: 0.5 to 1.5 percent of 2-hydroxy-2-methyl-1-phenyl-1-acetone, 0.1 to 0.3 percent of fluorine modified polyacrylate flatting agent and 0.3 to 1.0 percent of chloroplatinic acid-divinyl tetramethyl disiloxane complex catalyst. The preparation method comprises the following steps: mixing alpha, omega-dihydroxy polydimethylsiloxane and phenyltrimethoxysilane according to a mass ratio of 8: 2-7: 3, adding 0.3-1.0% of a chloroplatinic acid-divinyl tetramethyl disiloxane complex catalyst, and raising the temperature by stages under the protection of nitrogen, so that the glass transition temperature of the adhesive can reach 120 DEG C below zero and 125 DEG C, and the temperature of the adhesive can reach 120 DEG C below zero and 125 DEG C below zero. And the long-term service requirement of the optical device in an extreme temperature environment is met.

The invention discloses supercritical fluid foaming polyimide wave-absorbing foam and a preparation method thereof.The thermoplastic polyimide is prepared by the steps that aromatic dianhydride, aromatic diamine and aliphatic diamine serve as comonomers, polyimide acid is generated through solution polymerization, and then high-temperature cyclization is conducted; wherein the mole number of the aliphatic diamine accounts for 10-50% of the total mole number of the diamine, and the free volume and glass transition temperature of a molecular chain are effectively regulated and controlled by introduction of the aliphatic diamine; the wave-absorbing foam is prepared by taking polyimide as a matrix, doping 1-20wt% of wave-absorbing filler, and foaming for 1-3 hours in a supercritical carbon dioxide or nitrogen environment at the temperature of 180-220 DEG C and the pressure of 9-25MPa, through molecular structure design, the adsorption capacity and impact resistance of polyimide to carbon dioxide are remarkably improved, and the prepared foam has the advantages of light weight, high porosity, uniform foam structure and excellent heat resistance, can realize effective electromagnetic wave absorption in an X wave band, and is suitable for the fields of aerospace stealth and electromagnetic compatibility protection.

The invention relates to the field of polyester materials, and particularly discloses modified polyester with low yellowness value and high glass transition temperature characteristics and a preparation method thereof, and the modified polyester is prepared by taking terephthalic acid, diphenyldicarboxylic acid and fluorenyl aromatic dicarboxylic acid as carboxylic acid monomers, respectively esterifying with ethylene glycol, and carrying out co-polycondensation on corresponding esterification products. According to the present invention, the biphenyldicarboxylic acid with the conjugated aromatic ring structure and the fluorenyl aromatic dicarboxylic acid monomer are selectively introduced to modify the PET, such that the regularity of the polyester chain segment is broken so as to ensure the optical performance of the polyester; the movement of a polyester chain segment is limited so as to improve the Tg value of polyester; and by matching with a novel preparation method, the yellowness value of the polyester material is reduced.

The invention discloses a photoresist micro-lens array preparation method and system, and relates to the field of micro-nano optical device manufacturing. The preparation method of the photoresist micro-lens array comprises the following steps: carrying out chemical mechanical polishing treatment on a silicon wafer, spin-coating photoresist on a substrate to form a cylindrical array, and eliminating solvent gradient through pre-drying; forming a fluorocarbon nano film on the surface of the photoresist through plasma deposition so as to reduce the surface energy of the photoresist; realizing hot reflux of the photoresist based on gradient annealing, wherein the gradient annealing comprises a preheating section, a main reflux section and a stable section; on the basis of the preheating section, glass transition stress is avoided, fluorine-containing gas and inert gas are synchronously introduced into the main backflow section to act on a plasma sheath layer, so that the flowing direction of photoresist is regulated and controlled, and the edge coffee ring effect is inhibited; the stable section synchronously performs plasma assistance to lock the shape; and the precision and the consistency of the micro-lens array are improved through segmented temperature regulation and control and a plasma auxiliary technology.

The invention discloses a preparation method of a high-temperature-resistant high-strength polyimide composite material, and relates to the technical field of polyimide composites.The preparation method comprises the following preparation steps that S1, a customized silane coupling agent is prepared; s2, preparing a bionic dynamic interface modified reinforcing filler, wherein the modified reinforcing filler is synergistically modified through a bionic coating and a customized silane coupling agent; and S3, preparing a polyimide precursor solution containing the dynamic network. According to the preparation method of the high-temperature-resistant high-strength polyimide composite material, through the integrated design of'customized silane coupling agent + bionic dynamic interface modification + dynamic network-containing polyimide precursor + gradient hot-pressing curing ', the glass-transition temperature of the prepared composite material is greater than or equal to 335 DEG C, the tensile strength is greater than or equal to 208 MPa, and meanwhile, the thermal repair efficiency at 180-250 DEG C is greater than or equal to 87%; the technical bottleneck that high temperature resistance, mechanical strength and repairing performance of the material are difficult to consider at the same time in the prior art is solved.

The invention provides a compound containing a silicon group and an organic electroluminescent device thereof, and particularly relates to the technical field of organic electroluminescent materials. When the compound containing the silicon group is used as a covering layer material, the glass transition temperature is high, the thermal stability and the chemical stability are good, the light transmittance of a device can be improved, aging of the device is delayed, and therefore the service life of the device is effectively prolonged; and the compound has weak metal adsorption capacity, and can effectively inhibit the deposition of a metal electrode material on the surface of a nucleation inhibition layer when being applied to the nucleation inhibition layer, thereby improving the performance of the device. In conclusion, the silicon group-containing compound provided by the invention can be widely applied to the fields of panel display and the like, and has a good development prospect.

The invention provides a solvent-free UV dielectric insulation protective coating as well as a preparation method and application thereof. The high-surface-energy and high-glass-transition-temperature UV-curable coating is prepared by combining flexible modified polyurethane acrylate, flexible acrylate, rigid acrylate with high glass transition temperature, a high-functionality acrylate cross-linking agent, methyl methacrylate with high dilutability and high glass transition temperature as well as a plurality of photoinitiators, auxiliaries, pigment and filler powder and the like. The invention relates to a dielectric insulation protective coating with high adhesive force. The prepared coating is a solvent-free 100% solid single component, is complete in mixing and dissolving, convenient to construct, high in light curing energy utilization rate, high in production efficiency and suitable for large-scale automatic large-scale flow line production, and compared with PSA back glue used for a traditional PET blue film, the outer surface of the coating has higher surface energy, and the coating has the advantages of being high in light curing energy utilization rate and high in production efficiency. And the film has considerable dielectric insulation performance and good edge covering protection performance, and meets the development requirements of a higher charging voltage platform of a fast-charging electric vehicle in the future.

The present invention relates to an elastomeric laminate comprising at least two adjacent layers, wherein: the rubber composition constituting the first layer is based on 20 phr to 100 phr of at least one copolymer comprising ethylene units and 1,3-diene units of formula CH2=CR-CH=CH2, the ethylene units in the copolymer representing more than 50 mol% of the copolymer monomer units, and the symbol R represents a hydrocarbon chain having 3 to 20 carbon atoms, 0 phr to 80 phr of at least one diene elastomer having a diene unit weight concentration greater than 50%, 10 phr to 100 phr of a plasticizing system comprising at least one plasticizing resin having a glass transition temperature higher than 20°C and / or at least one plasticizer which is liquid at 23°C, and a reinforcing filler, and a crosslinking system; the rubber composition constituting the second layer is based on a diene elastomer having a diene unit weight concentration greater than 50% and a crosslinking system. The present invention also relates to a rubber article, in particular a pneumatic or non-pneumatic tire, comprising such a laminate.

Provided is an adhesive composition from which an adhesive layer having excellent heat-resistant durability can be formed. This adhesive composition comprises a (meth)acrylic resin, a crosslinking agent, a silane compound, and an ionic compound, wherein: the (meth)acrylic resin contains, as monomer units, an alkyl (meth)acrylate having a homopolymer glass transition temperature of lower than 0ºC, an alkyl (meth)acrylate having a homopolymer glass transition temperature of at least 0ºC, and a monomer having a polar group; and the ionic compound contains a cyano group-containing anion.

The invention provides a carbazole-containing heterocyclic compound and an organic electroluminescent device thereof, and relates to the technical field of organic electroluminescent materials. The carbazole-containing heterocyclic compound provided by the invention has relatively high polarizability, is beneficial to improving the refractive index, and can reduce the total reflection phenomenon during light emission of the device and effectively improve the light extraction efficiency of the device when being applied to a covering layer of the organic electroluminescent device; and meanwhile, the compound has relatively high glass transition temperature and good film-forming property, and can isolate moisture and oxygen, so that the luminous efficiency and the service life of the organic electroluminescent device are further improved and prolonged. The preparation method of the compound is simple, raw materials are easy to obtain, and the compound can be widely applied to the fields of organic thin film transistors, panel display and the like and has good application effects and industrialization prospects.

The invention relates to the field of high polymer materials, and discloses a preparation method and application of high-temperature-resistant transparent modified polyester. The preparation method comprises the following steps: 1) blending 9, 9-di-[(4-phenylphenoxy) dibenzoic acid] fluorene with diacid and dihydric alcohol, and carrying out esterification reaction; and 2) carrying out condensation polymerization on the esterification product to obtain the high-temperature-resistant transparent modified polyester with the glass transition temperature of more than 70 DEG C. According to the invention, 9, 9-di-[(4-phenylphenoxy) dibenzoic acid] fluorene is used as a modification monomer, and is copolymerized with other dibasic acids and dihydric alcohols to synthesize the modified polyester, and the modified polyester has high transparency and still has good mechanical properties and dimensional stability at high temperature. Therefore, the high-temperature-resistant transparent modified polyester is applicable to the application fields of optical films, optical lenses, reflective protective films, optical fibers or liquid crystal displays and the like.

To provide an aqueous filler composition that forms a ground coating film provided with cracking resistance, without causing adverse effect on finishing properties of subsequent top coat paint, excellent in coating work, and less in concealment unevenness, even when a wool roller is used.SOLUTION: An aqueous filler composition used to form a ground coating film using a wool roller prior to applying a top coat paint, comprises an aqueous resin (A) with a glass transition temperature of 30°C or lower, carbon black paste (B), pigment (C), urethane associative thickener (D), and water, where the pigment volume concentration is in the range of 30 to 65%. The content of the urethane associative thickener (D) is 0.1 to 2.5 pts.mass in an effective component amount based on 100 pts.mass of the resin solid content in the aqueous filler composition, and the brightness of the coating film formed by the aqueous filler composition is in the range of 70 to 92.SELECTED DRAWING: None

The invention discloses a highly permeable lawn and a preparation method thereof, the highly permeable lawn comprises artificial grass yarns, gum and a base layer, the artificial grass yarns are woven on the base layer, the gum is arranged on the bottom surface of the base layer, the artificial grass yarns and the base layer are fixed, the gum comprises latex, a calcium carbonate filler, a foaming agent and a cross-linking agent, the glass transition temperature Tg of the latex is 10-40 DEG C, the foaming agent is a foaming agent, and the cross-linking agent is a cross-linking agent. The latex comprises carboxylic butadiene-styrene latex and ethylene-vinyl acetate copolymer latex; the latex comprises the following components in parts by mass: 60-90 parts of carboxylic butadiene-styrene latex and 10-40 parts of ethylene-vinyl acetate copolymer latex. The base layer in the artificial turf is improved, the porous breathable gum is prepared, it is ensured that the mechanical property of the artificial turf meets the requirement, and the high water permeability of the artificial turf is achieved under the condition that drainage holes are not punched.

The invention provides a synthesis method of bio-based poly (ethylene 2, 5-furandicarboxylate) (poly (ethylene 2, 5-furandicarboxylate) for short) and performance application of the bio-based poly (ethylene 2, 5-furandicarboxylate). According to the method, 2, 5-furandicarboxylic acid (FDCA) derived from renewable resources and ethylene glycol (EG) are used as main raw materials, and the high-molecular-weight PEF is prepared through microwave-assisted esterification-polycondensation reaction under the action of a metal catalyst. The prepared PEF has excellent thermal mechanical property and gas barrier property, the glass transition temperature is about 58.6 DEG C, the melting temperature is about 187.4 DEG C, and the thermal decomposition 18% weight loss temperature exceeds 400 DEG C. The PEF material can be biologically degraded under the industrial composting condition, and the degradation speed is higher compared with that of traditional petroleum-based PET polyester. The PEF provided by the invention is suitable for the fields of food packaging films, beverage bottles and fiber materials, has the advantages of biodegradability, heat resistance stability and high barrier property, can partially replace polyethylene glycol terephthalate (PET) and other petrochemical plastics, and meets the requirements of sustainable development.

The invention relates to heavy anti-corrosion resin and a preparation method thereof, and belongs to the technical field of resin preparation. The formula of the heavy anti-corrosion resin comprises the following components in parts by weight: 80-100 parts of epoxy resin, 6-8 parts of liquid nitrile rubber, 3-5 parts of composite cerous phosphate, 1.5-2.5 parts of modified graphene oxide and 1-2 parts of polyethylene glycol. Wherein the cerous phosphate nanorods are large in specific surface area and high in length-diameter ratio, and are stably compounded with uniformly loaded nano zinc oxide to form double anti-corrosion barriers, and the dispersity and compatibility of the cerous phosphate nanorods can be improved by a dopamine coating; the modified graphene oxide is uniformly dispersed to form a labyrinth type shielding layer, and the modified graphene oxide and the composite cerous phosphate are mutually filled to form a multi-layer barrier; the liquid nitrile rubber and the epoxy resin form an interpenetrating network, so that the impact resistance and the adhesive force are enhanced; the polyethylene glycol improves the flexibility of the resin, adjusts the glass transition temperature and reduces the defects of the coating. The resin prepared according to the formula provided by the invention has an excellent anti-corrosion effect.

The invention discloses a preparation method of high-stability modified emulsified asphalt, and particularly relates to the technical field of asphalt materials, which comprises the following steps (by weight): S01, mixing 30-50 parts by weight of styrene-butadiene latex with the solid content of 45-60%, 10-25 parts by weight of acrylate copolymer emulsion with the glass transition temperature of-20-10 DEG C and 0.5-8 parts by weight of silane coupling agent to obtain a mixture A; a mixed emulsion is obtained; s02, adding 8-15 parts by weight of matrix asphalt, 2-8 parts by weight of a maleic anhydride grafted polypropylene compatilizer with the grafting rate of 1.0%-2.5% and a stabilizer into the mixed emulsion, and performing high-speed shearing at the rotating speed of 3000-5000 rpm for 20-40 min to obtain the modified polymer emulsion. According to the invention, the storage stability, the thermal stability and the interface bonding strength are improved.

The invention discloses a thermoplastic epoxy polymer with a micro-cross-linked structure and a preparation method thereof.The preparation method comprises the steps that in the step-by-step polymerization reaction process of thermoplastic epoxy resin, firstly, epoxy or amino or hydroxyl-terminated thermoplastic epoxy resin is obtained by controlling the group molar ratio and the reaction time of raw materials; when the molecular weight of a reaction product reaches a certain degree, polyfunctional epoxy compounds, amines, acid anhydrides, phenols and other compounds are introduced, and the thermoplastic epoxy resin with a micro-crosslinking structure is obtained through chain extension. The glass transition temperature of the thermoplastic epoxy polymer with the micro-crosslinking structure is obviously higher than that of a linear thermoplastic epoxy polymer of the same type. Compared with thermoplastic epoxy polymers of the same type, the thermoplastic epoxy polymer with the micro-crosslinking structure prepared by the invention still has the characteristics of thermoplasticity, capability of being melted by heating, capability of being dissolved by a solvent and the like.

The invention discloses a full bio-based copolymer based on a citric acid bicyclic monomer, a preparation method and an application, and belongs to the technical field of material synthesis, citric acid-derived bicyclic OPD diol and OPBMC diester are synthesized through oxidation reduction and transesterification, and then 1, 4-butanediol is partially replaced with OPD or 2, 4-butanediol is partially replaced with OPBMC through melt phase polycondensation reaction. Two series of random copolyester PBxOyF copolymer and PBOmFn copolymer of the PBF are prepared by adding 2, 5-dimethyl furandicarboxylate into the PBF, and then adding the PBxOyF copolymer and the PBOmFn copolymer into the PBF. According to the full-bio-based copolymer based on the citric acid bicyclic monomer, the preparation method and the application, the citric acid bicyclic monomer obviously improves the glass transition temperature and shows good mechanical properties; therefore, the bicyclic monomer based on citric acid has huge potential in the aspect of synthesizing novel bio-based copolyester with expected thermodynamic properties, and is expected to further expand the application range of the 2.5 furandicarboxylic acid-based polyester.

The invention relates to the technical field of electronic packaging materials, in particular to a phthalonitrile modified thermosetting resin composition containing a siloxane structure and application of the phthalonitrile modified thermosetting resin composition in the electronic packaging materials. The composition comprises multifunctional epoxy resin, XYLOK phenolic resin, a curing accelerator, a modifier and an inorganic filler, and the modifying agent is eugenol phthalonitrile trisiloxane. The modifier disclosed by the invention has good mechanical compatibility and dispersity in matrix resin; when the epoxy resin is applied to a thermosetting resin system, the processability can be improved, and the toughness of a cured product can be effectively improved while the glass-transition temperature is increased, so that the cured product has excellent bending property; the composition has excellent thermal stability, low bending modulus, good impact performance and humidity and heat resistance after being cured, the glass transition temperature of the composition is effectively improved, the comprehensive performance of resin is remarkably improved, and the composition is suitable for improving the packaging reliability and environmental stability of semiconductor devices.

The invention relates to the technical field of batteries, in particular to a battery diaphragm, a preparation method thereof and a secondary battery. The battery diaphragm comprises a base membrane and a coating arranged on at least one side surface of the base membrane, the coating comprises non-fluorine polymer particles and silane coupling agent modified inorganic filler particles, and the surface density of the coating is 1.5-2.5 g / m < 2 >; the mass ratio of the non-fluorine polymer particles in the coating is 10%-25%; the non-fluorine polymer particles are secondary agglomerated particles formed by agglomerating primary particles, and the D50 particle size of the primary particles is 0.4-0.6 mu m; the secondary agglomerated particles meet the condition that (D90-D10) / D50 is less than 1.3; the glass transition temperature Tg of the secondary agglomerated particles is-5 to 5 DEG C. The battery diaphragm disclosed by the invention has excellent heat resistance and adhesion with a pole piece, and the secondary battery adopting the battery diaphragm disclosed by the invention has more excellent cycle performance.

The invention relates to the field of optical thin films, in particular to a preparation method of an optical diffusion film. A preparation method of an optical diffusion film comprises the following steps: uniformly mixing a curing agent and polydimethylsiloxane, curing, and then carrying out oxygen plasma treatment and room temperature aging treatment to obtain a polydimethylsiloxane flat plate; dissolving PET particles and PMMA particles in a solvent to obtain a polymer solution; and placing a polydimethylsiloxane flat plate above the polymer solution, and standing to obtain the optical diffusion film. According to the application, PMMA is used as a high glass transition temperature component to be blended with PET, so that the overall glass transition temperature of a blending system is improved, and the practicability of the optical diffusion film in a high-temperature environment is improved; strong scattering is provided through the refractive index difference between air holes and a polymer phase, and a refractive index gradient is formed by using the refractive index difference between PET and PMMA, so that a secondary scattering interface is formed, and light absorption is reduced and high transmittance is maintained while high haze is ensured.

The present invention provides a polypropylene resin composition, a high-temperature resistant polymer film containing the same, and a preparation method and application thereof. By mass percentage, the polypropylene resin composition includes 79.7-98.9% of polypropylene resin, 1-20% of cycloolefin copolymer, and 0.1-0.3% of radiation crosslinking agent; the glass transition temperature of the cycloolefin copolymer is 120-160 °C; in the present invention, the film including the polypropylene resin composition has a high heat distortion temperature and a low thermal shrinkage rate, good high-temperature resistance, does not affect the dielectric properties of the film capacitor, has a small dielectric loss, can be biaxially stretched at a high draw ratio, and has a low cost.

The invention relates to the field of secondary batteries, and particularly discloses a wetting agent, positive electrode slurry, a preparation method and application. The wetting agent comprises an acrylate monomer, a cyano-containing monomer, a vinyl functional monomer, a surfactant and an initiator. The glass transition temperature of the wetting agent ranges from-50 DEG C to 30 DEG C, and after the wetting agent is soaked in electrolyte for 72 h, the mass swelling rate ranges from 500% to 3000%, and the volume swelling rate ranges from 50% to 1000%. A certain amount of the wetting agent is added into positive electrode slurry and is mixed and matched with a binder for use, so that the wettability of an electrolyte of a pole piece can be improved, a battery cell can quickly absorb the electrolyte, the electrolyte retention capacity of the battery is better, and the rate capability and the cycle performance of the battery are improved. And meanwhile, the wetting agent is of a linear structure and plays a long-range connection role in the pole piece, so that the adhesive force of the pole piece is improved, and the possibility that the pole piece falls off in the circulation process is reduced, thereby further improving the cycle performance of the battery.

The invention discloses a food baking processing program control system and method, and relates to the technical field of food processing intelligent control, and the method comprises the steps: collecting the dielectric characteristics of a material, capturing the change dynamic state of a dielectric loss angle tangent value, and recognizing the phase change stage of the material in real time through a time domain dielectric spectrum analysis method; constructing a dual-channel heat conduction model, and dynamically identifying the regional temperature gradient of the baking equipment according to the phase change stage of the material; and based on the regional temperature gradient of the baking equipment, through a multi-parameter coupling control algorithm, calculating the microwave power adjusting quantity and the wind speed ratio adjusting quantity of the baking equipment, and generating a composite control instruction set. According to the method, the phase change stage of the material is recognized in real time through a time domain dielectric spectrum analysis method, the relevance between relaxation time distribution and a phase change characteristic spectrum is accurately analyzed through inverse Laplace transformation and a dynamic time warping algorithm, and dynamic capture of key phase change nodes such as glass transition and starch gelatinization is achieved.

The invention provides a binder, a negative plate and a lithium ion battery. The binder comprises a C5-C10 alkyl acrylate structural unit, a polar structural unit and a hydroxyl-containing polyester structural unit, and the glass transition temperature of the binder is 73-93 DEG C. According to the binder, the binding power between an electrode material and a current collector and the dispersity of the carbon nanotubes in slurry can be remarkably improved, so that the rate capability and the cycling stability of the battery are effectively improved.

The invention relates to the technical field of preparation of high-moisture-absorption warm-keeping anti-wrinkle flexible cloth, in particular to high-moisture-absorption warm-keeping anti-wrinkle flexible cloth and a preparation process thereof.According to the designed moisture-absorption skin-friendly layer, alkali decrement treatment and silane coupling agent grafting treatment are combined, and the natural antibacterial property of coffee grounds is reserved; the shape memory polymer fibers of the anti-wrinkle layer deform when the temperature is larger than or equal to the glass transition temperature, the shape is fixed after cooling, a nanometer adhesive is melted in the hot pressing process to fill gaps of a framework, and the elastic recovery rate after repeated folding is far higher than 85%. The high porosity and low heat conductivity coefficient of aerogel fibers of the warm-keeping layer are combined with the heat storage and temperature regulation functions of phase change microcapsules, so that the air permeability of the warm-keeping layer is remarkably improved; all the layers are chemically bonded through plasmas to form covalent bond combination, so that the phenomenon of layering after multiple times of water washing or bending is effectively avoided.

The invention discloses a battery diaphragm and a preparation method thereof, a thermal composite battery cell and a secondary battery, and belongs to the field of secondary batteries, the battery diaphragm comprises a carrier layer and matrix type adhesive layers stacked on the surfaces of the two sides of the carrier layer, and the matrix type adhesive layers comprise a plurality of adhesive points which are distributed in a matrix and are arranged in a raised manner. The adhesive point is prepared from the following components in parts by mass: 8 to 16 parts of polymer, 2 to 7 parts of binder, 0.5 to 1.5 parts of dispersing agent, 3 to 9 parts of thickening agent and 0.1 to 0.4 part of wetting agent; the glass transition temperature of the polymer is-50 DEG C to 100 DEG C, and the particle size D50 of the polymer is 0.5 mu m to 50 mu m. By arranging the matrix type adhesive layer and improving the composition of the matrix type adhesive layer, the adhesion and liquid retention performance of the battery diaphragm can be enhanced, and the ventilation increment of the diaphragm is reduced.

The present invention provides a polymer with a polar group or a heterocyclic-bridged phthalazinone structure and a preparation method thereof, which relates to the technical field of synthesis of polymer materials. The polymer with a polar group or a heterocyclic-bridged phthalazinone structure mainly has more excellent heat resistance and good solubility by introducing a polar group or a heterocyclic-bridged phthalazinone structure. Its glass transition temperature can reach up to 405 °C and it can be dissolved in polar aprotic organic solvents such as N-methylpyrrolidone and 1,1,2,2-tetrachloroethane. In addition, the present invention can also regulate the heat resistance and solubility of such polymers by adjusting the structure and proportion of the structural unit with a polar group or a heterocyclic-bridged phthalazinone structure and other structural units, so that it can meet the needs of more different application scenarios. The present invention also provides a preparation method of the above polymer.