The invention belongs to the field of battery diaphragms, and particularly provides a preparation method of a
solid electrolyte composite material, which comprises the following steps: (S1) mixing a
polymer, a
plasticizer and a
lithium salt, adding into a second
solvent, dissolving and stirring to obtain an electrostatic
spinning precursor solution; (S2) depositing the electrostatic
spinning precursor solution on the surface of a
receiver through electrostatic
spinning to obtain a
fiber membrane, and separating the
fiber membrane from the
receiver; and (S3) soaking the
fiber membrane in a dispersion liquid, and performing dispersion treatment to obtain the
nanofiber composite material, specifically, a battery prepared from the
solid electrolyte composite material provided by the invention has excellent electrochemical performance, can still maintain a high capacity
retention ratio after multiple cycles, has excellent rate capability, and can be applied to the field of
lithium ion batteries, such as
lithium ion batteries, lithium
ion batteries, lithium ion batteries, lithium ion batteries, lithium ion batteries, lithium ion batteries, lithium ion batteries, lithium ion batteries, lithium ion batteries, lithium ion batteries, lithium ion batteries, lithium ion batteries, lithium ion batteries and lithium ion batteries. And the long-term stability and safety of the operation of the battery can be ensured.