The present invention relates to a
monomer having a functional group, a heat-resistant
polymer having a rigid main chain using same, and a manufacturing method therefor. Particularly, the present invention relates to a
monomer having a pentafluorophenyl group of
chemical formula 1, a heat-resistant
polymer of chemical formulas 2 and 3 having the
monomer of the present invention, and a manufacturing method therefor. According to the present invention, a novel
polymer obtained by polymerizing a novel monomer of the present invention has a reactive group of reactive pentafluorophenyl, and thus may exhibit excellent reactivity and enable synthesis of polymers having an excellent
polymerization degree by using a polyhydroxyalkylation
polymerization method without a protective group. Due to such excellent reactivity, the polymer of the present invention can cause a
nucleophilic substitution reaction under mild conditions, and thus an
ion-exchange group, such as
sulfonic acid or phosphonic acid, can be introduced under mild conditions through such a reaction. In addition, the novel polymer of the present invention has
high heat resistance and
chemical resistance and good tensile strength, and thus can be used as an
engineering plastic. In addition, the novel polymer of the present invention can be imparted with
ionic conductivity or other functionalities by introducing a phosphonic
acid group or a
sulfonic acid group into any one of fluoro positions of pentafluorophenyl of the polymer, and accordingly, may be used as an
electrolyte membrane for a fuel
cell or water
electrolysis. [
Chemical formula 1] [
Chemical formula 2] [
Chemical formula 3]