2129 results about "Thermal stability" patented technology

The invention provides an acetylacetone-based composite thermal stabilizer which is a mixture obtained by mixing zinc acetylacetonate, calcium acetylacetonate or magnesium acetylacetonate and hydrotalcite pro rata. The composite thermal stabilizer is suitable for chloride-containing high polymer, such as polyvinyl chloride, chlorinated polyethylene, chlorinated polyvinyl chloride, copolymer of vinyl chloride-ethylene or copolymer of vinyl chloride-vinyl acetate, has better thermal stability, prolongs the thermal aging time of the chloride-containing high polymer, and overcomes the shortcomings of poor long-term performance of single stabilizer of zinc acetylacetonate, poor transparency of stabilizer of calcium acetylacetonate, and poor initial colorability of stabilizer of hydrotalcite. The composite thermal stabilizer has low cost, good initial colorability, excellent long-term performance and good transparency, and is an efficient composite thermal stabilizer.

The invention belongs to the technical field of polymer plastic materials, and particularly relates to a high-temperature-resistant anti-corrosion polytetrafluoroethylene material and a preparation method thereof. The polytetrafluoroethylene is prepared from the following raw materials in parts by weight: 50 to 60 parts of polytetrafluoroethylene, 5 to 10 parts of fluorinated modified graphene oxide, 3 to 5 parts of aluminum powder, 5 to 8 parts of modified silicon carbide fiber, 3 to 5 parts of silane modified nano silicon dioxide, 2 to 3 parts of polyphenylene sulfide, 2 to 3 parts of polyimide, 0.5 to 0.8 part of dispersing agent and 0.5 to 1 part of antioxidant. The heat conduction performance and the interface bonding force are improved through the fluorinated modified graphene oxide, the impact resistance and the wear resistance are enhanced through the silicon carbide fibers, and the corrosion resistance and the wear resistance are improved through the aluminum powder; silane modified silicon dioxide enhances the mechanical property of the composite material by improving the dispersity of the filler, and PPS and PI interact with the surface of the filler through polar groups in molecular chains, so that the interface strength is improved, and the toughness and the thermal stability are improved.

The invention discloses a high-temperature-resistant epoxy resin composite material and a preparation method thereof, and relates to the technical field of composite materials. The high-temperature-resistant epoxy resin composite material is prepared from the following raw materials in parts by weight: 70 to 80 parts of modified epoxy resin, 8 to 15 parts of high-temperature-resistant modifier, 15 to 30 parts of curing agent, 3 to 8 parts of nano reinforcing filler, 1 to 3 parts of coupling agent, 3 to 6 parts of carbon fiber, 2 to 5 parts of nano titanium dioxide, 5 to 10 parts of organic silicon rubber, 1 to 3 parts of conductive agent, 3 to 7 parts of flame retardant and 2 to 4 parts of zinc borate. The high-temperature-resistant epoxy resin composite material has outstanding advantages and strong thermal stability, and can bear high temperature; mechanical performance is excellent, and firmness and durability are achieved; the self-repairing capability is achieved, and the service cycle can be prolonged; the anti-permeability is good, and gas and liquid can be effectively blocked; the surface is smooth, the friction coefficient is low and the application prospect is wide.

The invention belongs to the technical field of intelligent control, and particularly relates to an intelligent regulation and control method for an operating environment in an SF6 ring main unit. The method comprises the following steps: firstly, acquiring temperature, gas pressure and humidity data of a plurality of sampling points in the ring main unit, and constructing a time sequence environment data set through time synchronization and missing interpolation processing; analyzing the temperature data, extracting fluctuation characteristics, determining an environment disturbance factor in combination with an electric arc trigger intensity index, and obtaining a cabinet body temperature control safety factor in combination with a dynamically adjusted temperature rise threshold and a gas insulation state; then constructing an environment equivalent thermal inertia model and a hot-pressure covariant model based on historical data, and calculating a thermal stability index of the cabinet body; and finally, whether adjustment is triggered or not is judged according to the thermal stability index and the temperature control safety factor, if yes, a temperature abnormal area is positioned through a convolutional neural network and a clustering method, the temperature control response level is calculated, a temperature control strategy library is called to be matched with adjustment parameters, and accurate control is achieved.

The invention discloses an acylhydrazone bond-linked three-component covalent organic framework material and application thereof in photocatalytic full-decomposition of water. The three-component COFs expands the designability of the structure and function of the porous organic material by generating ordered anisotropic tiling and ordered pores with abnormal shapes. In addition, COFs connected through acylhydrazone bonds have good thermal stability and chemical stability, and nitrogen atoms on the acylhydrazone bonds can provide a large number of sites for load metal. According to the invention, two electron-deficient and electron-rich nodes are introduced into a COFs framework to form a donor-pi-acceptor structure motif, and Pt metal nanoparticles are loaded onto a three-component covalent organic framework material by using a NaBH4 reduction method. The material has great potential in the aspect of producing H2 and H2O2 through photocatalytic full decomposition of water by taking water as a reactant while solar energy is utilized and a sacrificial agent is not added.

The invention relates to the technical field of ceramics, in particular to a preparation method of a heat-resistant ceramic marmite. The heat-resistant ceramic marmite is composed of a green body and a glaze surface, and the green body is prepared from, by weight, 30-35 parts of fused quartz, 8-10 parts of petalite, 9-11 parts of kaolin, 19-21 parts of washed illite clay, 5-7 parts of sepiolite, 5-6 parts of andalusite, 7-9 parts of coal gangue, 0.2-0.7 part of zinc spinel and 2-3 parts of talc; the glaze surface is prepared from the following raw materials in parts by weight: 18 to 20 parts of fused quartz, 14 to 16 parts of petalite, 12 to 14 parts of kaolin, 5 to 6 parts of calcium oxide, 1.5 to 2 parts of zinc oxide, 1 to 1.5 parts of strontium oxide, 8 to 10 parts of spodumene, 0.6 to 0.8 part of lanthanum oxide, 8 to 10 parts of ZrSiO4 coated Al2O3 and 1.2 to 1.8 parts of pigment. The prepared ceramic marmite has the advantages of matt appearance, higher thermal stability, low water absorption rate and excellent comprehensive performance, and is not easy to crack and wear.

The invention discloses a method for preparing a modified PHA composite material by using a twin-screw extruder and application of the modified PHA composite material. The method comprises the following steps: carrying out in-situ melt blending on polyhydroxyalkanoate (PHA), poly (butylene adipate terephthalate)-poly (butylene adipate terephthalate) (PBAT), polyvinyl alcohol (PVOH) and chain extenders in a twin-screw extruder, so that the chain extenders such as polyfunctional group epoxy or isocyanate react with molecular terminal groups of the PHA, the PBAT and the PVOH to form a partially crosslinked or grafted structure; therefore, the compatibility is enhanced, the thermal stability is improved, and the barrier property is remarkably improved. Experiments prove that the obtained modified PHA composite material has the characteristics of high strength, high elongation, excellent water and oxygen resistance and biodegradability, and meets the strict requirements of multiple fields such as food packaging, agricultural plastic mulching films, medical consumables and the like on mechanical properties and barrier properties. The preparation method is simple, convenient and efficient, and large-scale continuous production can be achieved on existing double-screw extrusion equipment.

The invention relates to a preparation method and application of high-compaction-density composite sodium ferric phosphate. The preparation method comprises the following steps: weighing a sodium source, an iron source and a phosphorus source according to a stoichiometric ratio of [xNa + (a-x) A]: [yFe + (b-y) B]: P = a: b: (c + 2), mixing and dispersing the iron source, the sodium source, the phosphorus source and a chelating agent into pure water, reacting for a period of time at a certain temperature, transferring into a sand mill for grinding, adding a dispersing agent, cane sugar, the dopants A and B, and obtaining slurry F after grinding; and carrying out spray drying on the slurry F to obtain powder K. The powder K is transferred to a tubular furnace, and the oxygen content is 1t under the N2 protective atmosphere; and calcining at the temperature of 450-600 DEG C under the pressure of 50 ppm, and then carrying out air jet pulverization to obtain sodium ferric pyrophosphate positive electrode material powder with high compaction density and a molecular formula of (NaxAa-x) (FeyBb-y) (PO4) cP2O7. When the product is used, the compaction density is high, the dynamic performance of the material is enhanced, the thermal stability and chemical stability of the material are improved, and the electrochemical performance is good.

The invention relates to the technical field of temperature control, in particular to a temperature control management method and system for an electrolytic water tank and a medium. The method comprises the following steps: performing micro-channel structure processing on a main body shell of the electrolytic water tank, and embedding a modular micro-channel cooling plate to obtain geometric parameters of a cooling channel; identifying a key thermosensitive area of the electrolytic water tank; deploying a flexible micro temperature sensor array in the key thermosensitive area, and constructing a multi-point temperature monitoring network; collecting data in real time based on a multi-point temperature monitoring network to obtain real-time temperature data; and designing a micro-channel cooling liquid flow path based on cooling channel geometric parameter topological optimization to obtain a cooling liquid flow field structure. By integrating the micro-channel cooling structure and the high-density temperature monitoring network, efficient heat exchange and dynamic intelligent regulation and control of the electrolytic water tank cooling system are achieved, and the heat stability, safety and energy utilization efficiency are remarkably improved.

The invention belongs to the technical field of ship bearings, and particularly relates to a ship bearing radial loading test bench and method for simulating ice load and water immersion working conditions, and the method comprises the steps: installing a to-be-tested intermediate bearing on a test platform, enabling the intermediate bearing to sleeve a test shaft, starting a cooling water circulation system to control the flow, cooling water enters a cooling water coil pipe to establish oil pool cooling circulation; a driving motor is started; a test shaft stably operates through equipment such as a reduction gearbox and the like; a dynamic pressure lubrication state is established, a radial dynamic load or a stable constant load is applied through a hydraulic loading system to simulate an icebreaking load working condition, and a simulated water body is injected into a water tank; the test conditions of the intermediate bearing in a ship immersion environment are constructed through water pressure adjustment, the temperatures of lubricating oil, a bearing bush and cooling water are monitored in real time, the loading force is adjusted through feedback data, and the performance of the intermediate bearing is judged after the test is finished. The problems that ice excitation and soaking environment simulation are insufficient and a loading structure is eccentric in the prior art are solved, and high-precision cooling and thermal stability evaluation are achieved.

According to the mullite castable preparation method based on comprehensive utilization of the secondary aluminum ash nonferrous smelting slag, components are regulated and controlled by controlling the molar ratio of Al2O3 to SiO2, so that porous light mullite stably falls into a mullite phase region, and generation of excessive corundum phases is avoided. PMMA microspheres, corn flour, carbonized rice husks and SiO2 coated calcium carbonate composite pore-forming agent systems are adopted, and a layered slurry formula, gradient slip casting and segmented sintering processes are combined, so that the porosity and strength distribution are accurately regulated and controlled, and low-temperature sintering and amorphous phase change control are realized. By optimizing the grading of the porous light mullite aggregate and adding the homologous fine powder, the bonding strength and compressive strength of the castable are improved. And finally, the surface of the castable is coated with a compact mullite coating, so that the porosity is reduced, and the erosion resistance, corrosion resistance and stripping resistance are remarkably improved. The obtained castable has the advantages of light weight, high temperature resistance, high strength, low cost and excellent thermal stability and erosion resistance.

The invention discloses a transparent composition photoresist with low shrinkage and low vacuum deflation. Comprising the following raw materials in percentage by mass: 1-5% of modified polyhedral oligomeric silsesquioxane (POSS), 1-5% of an expanding monomer, 1-5% of modified acrylic resin, 1-5% of epoxy resin, 1-5% of a thiol cross-linking agent, 1-5% of an initiator, 0.1-3% of a curing accelerator, 0.2-0.5% of a flatting agent, 0.1-5% of a silane coupling agent, 0.01-0.2% of an antioxidant and 80-90% of an electronic-grade organic solvent. The invention also provides a preparation method of a cured coating prepared from the transparent composition photoresist with low shrinkage and low vacuum deflation. The product provided by the invention not only can maintain the properties of high hardness, high thermal stability, high planarization ability, high barrier property, low hygroscopicity, low dielectric constant and the like of the transparent composition photoresist coating, but also can enable the transparent composition photoresist coating to have excellent low shrinkage and low outgassing, thereby achieving the purposes of saving energy, reducing emission, reducing cost and improving efficiency; the low shrinkage of the transparent composition photoresist coating also widens the development of the material in the fields of other panel production processes such as OLED (Organic Light Emitting Diode) and the like.

The invention provides a power system economic dispatching method considering dynamic capacity increase of a line and a related device. The method comprises the following steps: establishing a target function taking the minimum unit operation cost of a power system as a target; determining constraint conditions of the target function according to the parameters of the power system, wherein the constraint conditions comprise unit constraint, network variable constraint, linearized alternating current power flow constraint and linearized line thermal stability constraint; the economic dispatching model of the power system is solved, an economic dispatching scheme of the power system is obtained, and the economic dispatching model of the power system comprises a target function and constraint conditions. According to the method, the temperature change of the line is tracked by using the linearized line thermal stability constraint, so that the transmission capacity of the line can be improved on the basis of meeting the thermal stability constraint, an economic dispatching strategy is optimized, and the economic dispatching efficiency is improved by linearizing the alternating current power flow constraint and the line thermal stability constraint. The power system economic dispatching model is constructed into a mixed integer linear programming model, so that the solving speed and efficiency of the model can be improved.

The invention discloses a phthalonitrile modified phenolic aerogel and a preparation method and application thereof. Linear phenolic aldehyde, 4-nitrophthalonitrile and a basic catalyst are dissolved in an organic solvent, a water bath reaction is conducted, powder is prepared, and phthalonitrile etherified phenolic resin is obtained; preparing a mixed solvent, and dissolving linear phenolic aldehyde and phthalonitrile etherified phenolic resin in the mixed solvent to obtain a mixed solution; adding a cross-linking agent into the mixed solution, carrying out sol-gel reaction to obtain wet gel, and aging, segmentally curing and drying the wet gel to obtain the phthalonitrile modified phenolic aerogel. The pyrolytic property of the phenolic aerogel is improved, the phthalonitrile modified phenolic aerogel with high carbon residue and high thermal stability is obtained under the condition of low-temperature heating, and the method is suitable for being applied to the field of thermal insulation ablation of a thermal protection system of aerospace equipment.

The invention discloses a phase change microcapsule modification method which comprises the following steps: S1, selecting a paraffin phase change material or a hydrated salt phase change material, and adding 0.5-1.5 wt% of a chemical stabilizer to modify the thermal stability of the phase change material; s2, compounding a microcapsule wall material by using polyurethane (PU) and nano silicon dioxide (SiO2), and adding 1wt% of carbon nanotubes (CNT) and 0.5-2wt% of nano silicon dioxide (SiO2); s3, the microcapsule wall material is subjected to surface hydrophobic coating treatment, polymethyl methacrylate (PMMA) is sprayed to form a waterproof isolation layer, the modified microcapsule phase change material is obtained, and in the step S1, 0.5-1.5 wt% of graphene oxide (GO) is added for modification when the paraffin phase change material is selected. The preparation method is reasonable in design, energy storage, heat preservation and mechanical properties of PCM-UHPC are remarkably improved through multi-layer composite modification of the PCM microcapsules and the nano-enhancement technology of the UHPC matrix, and the preparation method is suitable for the fields of energy-saving buildings, temperature control infrastructures and the like and has wide application prospects.

The invention discloses a phosphate composite flame retardant and a preparation method thereof, and relates to the technical field of flame retardants. The phosphate ester composite flame retardant is prepared from phosphorus-nitrogen grafted and coated network-shaped silicon dioxide powder, a Co-MOF composite graphene oxide catalytic carrier and pentaerythritol phosphate ester, the phosphorus-nitrogen grafted coated network-shaped silicon dioxide powder is prepared from a network-shaped dispersion modifier, silicon dioxide, dopamine hydrochloride, phosphorus oxychloride and 4, 4-diaminodiphenyl methane, a Co-MOF composite graphene oxide catalytic carrier is filled with phosphorus-nitrogen grafted and coated network-shaped silicon dioxide powder and pentaerythritol phosphate, migration of components is effectively reduced, the thermal stability of a flame-retardant system is enhanced, meanwhile, the compatibility and dispersity in an epoxy resin matrix are improved, the phosphorus-nitrogen grafted and coated network-shaped silicon dioxide powder, the pentaerythritol phosphate and the phosphorus-nitrogen grafted and coated network-shaped silicon dioxide powder have a synergistic effect, and the flame-retardant effect is improved. A carbon residue layer after combustion is more compact and continuous, isolation and protection effects can be better played, and the flame retardant property is remarkably improved.

The invention discloses a biochar / carbon nanotube / myristic acid composite phase change material as well as a preparation method and application thereof, and belongs to the technical field of heat storage. The meat biochar / carbon nanotube / myristic acid composite phase change material is prepared by adopting a vacuum impregnation method. The original biochar is modified by KOH, so that the specific surface area and pore volume of a sample are increased, the specific surface area of the modified KBC3 reaches 813.56 m < 2 > / g, and the loading capacity of the KOH modified biochar on MA is increased to 63%. The result shows that the MA sample is successfully loaded into the porous material, and the structure is kept intact. In order to further improve the loading rate and the leakage resistance of the phase change material, carbon nanotubes are doped in the KBC / MA phase change material, and when the loading rate of MA is improved to 75%, KBC1.5 / MA severely leaks in a shape stability performance experiment, and the mass loss rate reaches 8.5%. And KBC1.5 / CNT1 / MA only has little leakage in the thermal stability test process, so that the leakage resistance of the composite phase change material is greatly enhanced. Through BC modification and CNTs introduction, the heat conduction capability and the photothermal conversion capability of the composite PCMs are greatly improved.

The invention belongs to the technical field of building materials, and particularly relates to a preparation method of a high-strength sintered tile. The preparation method of the high-strength sintered tile comprises the following steps: (1) crushing green body raw materials, sieving, adding water, carrying out ball milling, and carrying out spray drying to obtain powder; (2) performing compression molding on the powder obtained in the step (1) to obtain a green body; drying the green body to obtain a tile blank; (3) coating the tile blank obtained in the step (2) with glaze, and drying to obtain a glazed tile blank; and sintering the glazed tile blank, and then cooling to room temperature to obtain the ceramic tile. The high-strength sintered tile obtained by the preparation method is high in bending strength, high in thermal stability, low in water absorption and good in freezing resistance, and has a wide application prospect.

The invention relates to the technical field of fan shell materials, in particular to an antibacterial PP (polypropylene) fan shell material and a preparation method thereof. The polypropylene composite material is prepared from the following components in parts by weight: 80 to 90 parts of polypropylene composite material, 1 to 3 parts of polyethylene glycol grafted maleic anhydride, 1 to 5 parts of modified lignin, 8 to 15 parts of nano modified montmorillonite, 1 to 4 parts of silver nitrate, 1 to 3 parts of coupling agent KH550, 0.1 to 0.5 part of calcium stearate and 0.3 to 0.6 part of antioxidant, through double modification of lignin and three-step modification of montmorillonite, the dispersity and interface bonding strength of the filler are remarkably improved, the tensile strength of the material is improved by 37% or above, and meanwhile good toughness is kept; a multi-component synergistic system realizes the persistence of the antibacterial performance, and the antibacterial efficiency of 95% or above is still kept after 7 days. Thirdly, through the synergistic effect of the modified lignin and the nano-montmorillonite, the thermal stability of the material is remarkably improved, and the initial degradation temperature is increased by 20-35 DEG C.

The invention discloses a multilayer polyimide film as well as a preparation method and application thereof, belongs to the technical field of high-performance polyimide, and solves the problem that the thermal stability is not ideal when a PI film is applied to a flexible PI plate in the prior art. The method comprises the following steps: mixing ODA, GAPD and DMAc in an ice bath, mixing BPDA and TAHQ, and adding the mixture in batches to obtain a solution B; adding SiO2 aerogel into absolute ethyl alcohol, and carrying out ultrasonic treatment at room temperature to obtain a solution C; coating the solution B into a film shape, drying, coating the solution C on the film, drying, coating the solution B on the film again, and drying to obtain the polyimide film. The multilayer low-dielectric polyimide film prepared by the invention has the advantages of low dielectric, high temperature resistance, high interface compatibility and low water absorption.

The invention relates to a glass bead, in particular to a high-refractive-index large-particle-size glass bead for road marking and a spheroidizing forming preparation method of the high-refractive-index large-particle-size glass bead. The material comprises the following components in parts by weight: 30 to 40 parts of titanium dioxide, 30 to 40 parts of silicon dioxide, 10 to 15 parts of barium nitrate, 10 to 15 parts of zirconium nitrate, 5 to 7 parts of zinc oxide, 3 to 5 parts of boric acid, 3 to 5 parts of calcium fluoride, 5 to 110 parts of Nb2O5 and 5 to 15 parts of a La2O3-ZrO2 compound. According to the invention, calcination is carried out at 900 DEG C for 12 hours, which is helpful for improving the thermal stability and mechanical strength of the glass beads, so that the glass beads can be used for a long time in a severe outdoor environment and are not easy to damage. And at the high temperature of 1300 DEG C and the spraying speed of 75 m / s, through precise intersection of the two nozzles in the combustion chamber, precise control over the melting and forming process of the glass beads is ensured, and therefore the high-quality high-refractive-index glass beads are obtained. The Nb2O5 and La2O3-ZrO2 compound is added, so that the refractive index of the glass beads is improved, and a relatively high yield is maintained.

The invention discloses a preparation method of a POK and EVOH blending modified high-barrier material, which comprises the following steps: pre-drying, uniformly mixing, cooling and curing, air injection for water removal, pelletizing, secondary drying and the like to obtain the POK and EVOH modified high-barrier material, compounding the POK, EVOH and EAA according to a certain proportion to form a three-phase mixed system, and playing a synergistic effect to obtain the POK and EVOH blending modified high-barrier material. The oxygen barrier effect is improved; through the special compatilizer for POK, the compatibility of POK and the EVOH material is improved, and the mechanical property of the material is improved; the oxygen barrier effect of POK at high temperature and high humidity is basically not reduced, and the oxygen barrier effect of the whole system at high temperature and high humidity is improved; the antioxidant system improves the thermal stability of the EVOH material and the POK material during processing, and solves the problems that the materials are easy to decompose during processing and easy to yellow after being used for a long time.

The invention provides a binder for a ceramic coating diaphragm, a preparation method of the binder, the ceramic coating diaphragm and a battery in order to solve the problems that a water-based binder used by an existing ceramic coating diaphragm is poor in thermal stability and the diaphragm is curled in a low-humidity environment. The binder comprises latex particles, the latex particles comprise a core-layer polymer and a shell-layer polymer, the shell-layer polymer is arranged on the outer surface of the core-layer polymer, the raw material of the core-layer polymer comprises a first polymeric monomer, and the raw material of the shell-layer polymer comprises a second polymeric monomer and a third polymeric monomer, the second polymeric monomer includes a polymerizable monomer containing an oxazoline group. The adhesive provided by the invention is mixed with a ceramic material to prepare ceramic slurry, the ceramic slurry is coated on the surface of a base membrane to obtain a ceramic coated diaphragm, the ceramic diaphragm can resist thermal shrinkage of 150 DEG C, the transverse thermal shrinkage and the longitudinal thermal shrinkage of the ceramic diaphragm are controlled within 3%, and the diaphragm is high in peel strength, low in humidity and free of curling.

The invention discloses nano ettringite particle reinforced aramid nanofiber aerogel as well as a preparation method and application thereof, and belongs to the technical field of aerogel. The preparation method provided by the invention comprises the following steps: dissolving a calcium source, an aluminum source and sulfate in water, adding a first surfactant, adjusting the pH value to 9-12, stirring for reaction, and after the reaction is finished, washing a solid product to be neutral to obtain nano ettringite particles; uniformly stirring and mixing the nano ettringite particles, para-aramid nanofibers, a second surfactant and a cross-linking agent in water to obtain an ettringite / aramid nanofiber dispersion liquid; the ettringite / aramid nanofiber dispersion liquid is sequentially subjected to concentration, directional freezing and freeze drying, and the ettringite / aramid nanofiber composite material is obtained. The preparation method disclosed by the invention is simple, the raw materials are easy to obtain, and the obtained nano ettringite particle reinforced aramid nanofiber aerogel has relatively high mechanical strength and thermal stability.

The invention discloses a preparation method of two-component microcapsule self-repairing insulation paper based on epoxy resin and polymercaptan. The preparation method comprises the following steps: (1) preparing a repairing agent microcapsule and a curing agent microcapsule by an emulsion polymerization method; (2) mixing the prepared repairing agent microcapsule and curing agent capsule to obtain a bi-component microcapsule solution, and adding the bi-component microcapsule solution into the treated paper pulp; and (3) performing papermaking, drying and calendaring on the paper pulp added with the bi-component microcapsule solution to obtain the insulation paper. According to the invention, diglycerol ether type bisphenol F epoxy resin (DGEBF) stabilized by an emulsifier is adopted as a core of a repairing agent, polythiol (PETMP) stabilized by the emulsifier is adopted as a core of a curing agent, and the emulsifier is cellulose nanofiber, so that the insulating paper with self-repairing performance is prepared. The dielectric constant, the breakdown field strength, the tensile strength, the elongation at break and the thermal stability of the insulation paper are superior to those of traditional cellulose insulation paper, and the overall performance and the service life of the insulation paper can be effectively improved.

The invention provides a high-conductivity high-temperature anti-oxidation life-prolonging coating for an electrolytic aluminum anode, which is prepared from the following raw materials in parts by weight: 34-50 parts of refined bauxite; 20 to 25 parts of water; 20 to 30 parts of silicon carbide; 1.5 to 3 parts of graphene; 4-6 parts of a glaze forming agent; 2.1 to 2.2 parts of a film forming agent; 0.3 to 0.4 part of a modifier; the glaze forming agent is composed of albite, talc and lanthanide oxide. The invention also provides a preparation method of the coating. The coating prepared by the invention is coated on the surfaces of a carbon block and an anode steel claw, the mechanical property and the conductivity of the coating can be improved by adding silicon carbide and graphite, cracks between the coating and the carbon block as well as between the coating and the steel claw can be made up by adding the glazing agent, and the adhesiveness, the thermal stability and the fracture toughness are improved. The coating provided by the invention can reduce the anode loss, improve the conductivity and reduce the production energy consumption and cost of electrolytic aluminum to a certain extent, and has popularization and application prospects.

The invention discloses a pure silicon Beta molecular sieve packaging metal catalyst and a preparation method and application thereof, and the preparation method comprises the following steps: dissolving a silicon source, a template agent, a ligand, a metal salt and a mineralizer in water, carrying out a crystallization reaction at 120-200 DEG C, and carrying out calcination treatment and reduction treatment on the crystallized solid to obtain the pure silicon Beta molecular sieve packaging metal catalyst. The pure silicon Beta molecular sieve packaged metal catalyst is obtained. The pure silicon twelve-membered ring macroporous Beta molecular sieve encapsulated metal catalyst is prepared through a ligand protection in-situ hydrothermal synthesis strategy, so that the size of a metal nanocluster can be reduced, the high-temperature thermal stability of the metal nanocluster is improved, the adsorption and diffusion processes of guest molecules can be regulated and controlled, and the stability of the metal nanocluster is improved. Furthermore, the catalyst shows excellent catalytic performance when being used for catalyzing a propane dehydrogenation reaction and a methyl cyclohexane dehydrogenation reaction, and efficient and stable propane and methyl cyclohexane dehydrogenation performance is achieved.

The invention relates to the field of artificial leather, and discloses a high-dispersion halogen-free flame retardant polyether polyol composite material and a preparation method thereof, and the high-dispersion halogen-free flame retardant polyether polyol composite material comprises the following components by mass: 60-75 parts of a polyether polyol matrix; 20 to 30 parts of a core-shell synergistic flame retardant; 3 to 5 parts of a hyperbranched polysiloxane dispersant; 2-5 parts of a nano zinc borate synergist; 0.5 to 1 part of an anti-dripping agent; the preparation method comprises the following steps: preparing a phosphorus-nitrogen core-shell flame retardant; premixing with polyether polyol, and performing dynamic condensation to form a bonding interface; carrying out ultrasonic-shearing synergistic dispersion on the nano material; and finally, carrying out underwater pelletizing to obtain the high-dispersion halogen-free composite material. According to the invention, through cooperation of core-shell flame-retardant structure design and a dynamic process, and combination of hyperbranched dispersant multi-point anchoring and ultrasonic-shear energy field dispersion technologies, efficient dispersion of a flame retardant and a nano material is realized; the interfacial condensation reaction is accurately controlled through a low-oxygen environment, and the flame retardant efficiency and thermal stability of the material are improved.

The invention relates to the field of ZIF-8 nanocrystals, in particular to a thermostable ZIF-8 nanocrystal and a one-pot synthesis method thereof. The thermostable ZIF-8 nanocrystal is prepared from the following substances in parts by weight: 10 to 15 parts of 2-methylimidazole; 4-8 parts of zinc nitrate hexahydrate; and 75-80 parts of an organic cosolvent. According to the invention, the ratio of the raw materials, especially the ratio of 2-methylimidazole to zinc nitrate hexahydrate, is optimized, so that the formation conditions of ZIF-8 are optimized, and the thermal stability of ZIF-8 is improved. The structural integrity of the material can be maintained under high temperature and harsh conditions, and the material is suitable for application occasions requiring high-temperature treatment. Besides, the polarity and dissolving capacity of the solvent can be effectively improved through selection of the organic cosolvent, crystal growth of ZIF-8 is promoted, then the crystal morphology and performance of ZIF-8 are affected, and the final product has better physical and chemical properties.

The invention relates to the field of lithium ion batteries, and discloses a high-heat-resistance and low-water-absorption lithium battery diaphragm and a preparation method thereof, and the high-heat-resistance and low-water-absorption lithium battery diaphragm is prepared from the following components by mass: 40-60 parts of alumina; 25 to 42 parts by mass of sodium perfluorooctanoate; 65 to 85 parts by mass of ultrapure water; 0.5-1.2 parts by mass of a dispersant; 1.3 to 2.9 parts by mass of a pore forming agent; 2.6 to 3.8 parts by mass of an adhesive; the base film is a polypropylene base film or a polyethylene base film, and the thickness of the base film is 7 to 9 [mu] m. Through aluminum oxide surface modification, base membrane treatment and optimized coating and drying processes, the water absorption of the diaphragm is remarkably reduced, the binding force of the coating and the base membrane is improved, the uniformity and microporous structure of the coating are improved, and excellent heat resistance, air permeability and electrochemical performance of the diaphragm are realized; the problems of poor thermal stability, high water absorption and insufficient coating adhesion in the prior art are solved.