850 results about "Thermal stability" patented technology

The invention provides an acetylacetone-based composite thermal stabilizer which is a mixture obtained by mixing zinc acetylacetonate, calcium acetylacetonate or magnesium acetylacetonate and hydrotalcite pro rata. The composite thermal stabilizer is suitable for chloride-containing high polymer, such as polyvinyl chloride, chlorinated polyethylene, chlorinated polyvinyl chloride, copolymer of vinyl chloride-ethylene or copolymer of vinyl chloride-vinyl acetate, has better thermal stability, prolongs the thermal aging time of the chloride-containing high polymer, and overcomes the shortcomings of poor long-term performance of single stabilizer of zinc acetylacetonate, poor transparency of stabilizer of calcium acetylacetonate, and poor initial colorability of stabilizer of hydrotalcite. The composite thermal stabilizer has low cost, good initial colorability, excellent long-term performance and good transparency, and is an efficient composite thermal stabilizer.

The invention provides a spindle constant-temperature AI closed-loop heat engine system, and relates to the technical field of numerical control machine tool control and heat management. The invention aims to solve the problems of response lag, uncontrollable thermal stress, single heating strategy and the like of the traditional spindle heat engine method. The system comprises a multi-dimensional thermal state sensing module used for constructing a multi-node discrete temperature field representing the overall thermal distribution of the main shaft; the real-time heat balance feedback module is used for judging the cold / hot starting state of the main shaft according to the initial temperature difference and executing a differentiated feedback control strategy; and an AI prediction forward compensation module that predicts a future cutting thermal load by pre-reading a machining instruction and generates a feedforward thermal compensation instruction. According to the method, the thermal stress is controlled by introducing the radial thermal gradient index as the safety constraint, negative precooling or positive preheating is achieved in combination with the AI predictive capacity, a feedback and feedforward composite control mode is formed, and the dynamic thermal stability and the machining precision of the main shaft under the complex working condition are improved.

The invention relates to the technical field of powder metallurgy materials, and discloses rare earth microalloyed ultrahigh-strength high-toughness hot work die steel and a preparation method thereof.The die steel is prepared from 4Cr5MoSiV1 pre-alloyed powder, rare earth hydride, boron carbide and porous amorphous carbon powder loaded with a nickel catalyst. The preparation method comprises the steps of material mixing, sheath packaging, graded dynamic reaction thermal devolatilization, hot isostatic pressing densification and heat treatment, in the graded dynamic reaction thermal devolatilization, active hydrogen generated by decomposition of rare earth hydride is used for reducing oxide on the surface of powder, and nickel catalyzed carbon powder is used for capturing water vapor at low temperature to generate CO to be discharged. An oxide film on the surface of the powder is thoroughly removed through in-situ chemical reaction, original particle boundaries are eliminated, meanwhile, a nano strengthening phase with high thermal stability is generated in situ, and the high-temperature strength, impact toughness and tissue compactness of the die steel are remarkably improved.

The invention provides a battery and an electric device. A positive plate comprises a positive active material, and the positive active material is doped and / or coated with a lanthanum element; the surface of the diaphragm is coated with a ceramic coating; the electrolyte comprises a first solvent, a second solvent, a first additive and a second additive; the first solvent comprises a cyclic carbonate compound, the second solvent comprises a chain fluorosulfonamide compound, the first additive comprises mannitol carbonate sulfate, and the second additive comprises succinonitrile; the lanthanum element is doped / coated on the positive active material, so that the release of lattice oxygen at high voltage or high temperature can be effectively inhibited, and the exothermic reaction activity at the thermal runaway initial temperature is reduced; the first additive and the second additive in the electrolyte respectively form a compact CEI film and an SEI film with high thermal stability on the surfaces of the positive electrode and the negative electrode; the diaphragm ceramic coating provides a physical barrier, the thermal shrinkage temperature of the diaphragm is increased, and internal short circuit is prevented.

The invention discloses a thermal insulation layer thickness determination method and system based on a phase change material. The method comprises the following steps: obtaining thermophysical parameters of a phase change material, and determining an applicable phase change material type in combination with temperature change characteristics of an application environment; after the phase-change material is applied, environment temperature data are collected, day and night temperature difference, seasonal change and sudden temperature fluctuation conditions are analyzed, and the heat adjusting requirements of the phase-change material in different time periods are calculated; and calculating the required thickness of the phase-change material according to the condition that the phase-change material is positioned on the outer layer or the inner layer of the thermal insulation layer on the basis of the calculated heat adjustment requirement, and performing optimization in combination with heat balance analysis. According to the invention, scientific calculation of the thickness of the phase change material is realized, so that the phase change material can provide effective heat storage and release under different environmental conditions, the problem of excessive use of the material or insufficient thermal insulation performance is avoided, and the thermal stability and energy-saving efficiency of the thermal insulation layer are improved.

The invention discloses a low-temperature curing photoresist applied to a flexible display panel and a preparation method of the low-temperature curing photoresist, and belongs to the technical field of energy conservation and environmental protection. The photoresist is prepared by compounding a reactive organic-inorganic mixed nano filler, a photosensitive resin matrix, a benzocyclobutenyl silicone oligomer (BSA resin) and an additive. The preparation method comprises the following steps: preparation and surface modification of the nanofiller; synthesizing a photosensitive resin matrix; compounding the oligomer with an additive; dispersing the slurry and adding a nano corrugated template; spin coating, ultraviolet pre-curing, low-temperature baking and heat post-curing are carried out. The curing temperature of the photoresist is lower than 120 DEG C, the resolution ratio is superior to 3 microns, and the bending tolerance frequency is gt; the adhesion strength is gt after 20000 times; 15 Kgf / cm < 2 >, and the water vapor permeability is lt; 10 <-6 >, heat resistance gt; the temperature is 150 DEG C, and the dielectric constant is lt; 3.5, VOC (Volatile Organic Compounds) emission lt; the organic light-emitting material has excellent flexibility, thermal stability and environmental protection performance, is suitable for a pixel definition layer of an OLED flexible display panel, and improves the light extraction efficiency and the anti-fatigue performance.

The invention belongs to the technical field of nano fluorescent powder, and particularly relates to Ca10 (PO4) 6 (OH) 2: RE < 3 + > nano fluorescent powder as well as a preparation method and application thereof. The preparation method comprises the following steps: mixing Ca (NO3) 2 and RE (NO3) 3 solutions in proportion to prepare a cation solution, dropwise adding a certain amount of H3PO4 to prepare a mixed solution, adjusting the pH value by using a charge compensation agent, uniformly stirring, performing ultrasonic dispersion, performing hydrothermal reaction on the obtained solution, and purifying to obtain the final product Ca10 (PO4) 6 (OH) 2: RE < 3 + > nano fluorescent powder. The charge compensation agent is at least one of KOH and LiOH. By utilizing the methods, the invention provides the Ca10 (PO4) 6 (OH) 2: RE3 + nano fluorescent powder taking K < + > / Li < + > as the charge compensation agent, and the Ca10 (PO4) 6 (OH) 2: RE3 + nano fluorescent powder has the advantages of thermal stability, color stability and high luminescence, and is suitable for temperature sensing, cheilogramma and anti-counterfeiting detection.

The invention provides a high-temperature-resistant shale inhibitor as well as a preparation method and application thereof, and belongs to the technical field of petroleum drilling. Natural polymer polyamino acid and carbon-rich solid matter biochar are used as raw materials to prepare the shale inhibitor, the biochar has the advantages of being high in thermal stability, porous, rich in surface oxygen-containing functional groups and the like, the biochar is combined with polyamino acid, and by means of the chemical effect of the polyamino acid and the physical blocking effect of the biochar, the shale inhibitor is prepared. The shale inhibitor can inhibit shale hydration expansion at high temperature and has good hydration dispersibility, and the prepared shale inhibitor is green and environment-friendly and has excellent high temperature resistance.

The invention belongs to the technical field of organic electroluminescence, and particularly provides an electroluminescent material and an organic electroluminescent device comprising the same, the electroluminescent material comprises a combination of a first organic compound and a second organic compound, the first organic compound has a structure as shown in a formula I, and the second organic compound has a structure as shown in a formula II; the second organic compound has a structure as shown in a formula II; through structural design of the first organic compound and the second organic compound, particularly introduction of a substituent group at a specific site, and synergistic compounding of the two organic compounds, the material has higher glass transition temperature Tg and excellent thermal stability while having excellent photoelectric properties and carrier transport properties. The electroluminescent material is used for the organic electroluminescent device, is especially suitable for a luminescent layer, and can effectively ensure the uniformity of a deposited film, so that the thermal stability of the device is excellent, and the high-temperature test life is remarkably prolonged.

The invention relates to the technical field of battery materials, in particular to a para-aramid lithium battery diaphragm and a preparation method thereof. The para-aramid lithium battery diaphragm comprises para-aramid slurry and a base membrane, the para-aramid slurry is coated on the two sides of the base membrane to form para-aramid coatings, and the para-aramid slurry comprises the following raw materials in parts by weight: 20-40 parts of modified para-aramid polymer liquid, 10-20 parts of nano ceramic composite material powder and 10-18 parts of a solvent; the nano ceramic composite material powder is prepared from the following raw materials in parts by weight: 50 to 100 parts of nano aluminum oxide, 8 to 12 parts of nano zirconium dioxide, 0.3 to 0.8 part of yttrium oxide, 1 to 5 parts of magnesium nitrate hexahydrate, 0.1 to 1 part of polyacrylic acid, 1 to 2 parts of ammonia water, 1 to 3 parts of coupling agent and 20 to 30 parts of silicon dioxide; the nano ceramic composite material powder is added into the para-aramid slurry, so that the para-aramid diaphragm has better thermal stability, and the phenomenon of thermal shrinkage of the diaphragm at high temperature is reduced.

The invention discloses a micro-fluidic technology-based double-shell microcapsule fire extinguishing agent and a preparation method thereof, and belongs to the technical field of fire extinguishing agents. A low-boiling-point liquid fire extinguishing agent serves as a capsule core, a polyurethane material prepared through the microfluidic technology serves as a first layer shell, flame-retardant materials such as melamine formaldehyde resin serve as a second layer shell, the capsule core is coated with the first layer shell, the first layer shell is coated with the second layer shell, and the double-shell microcapsule fire extinguishing agent based on the microfluidic technology is obtained. Microencapsulation of the low-boiling-point liquid fire extinguishing agent can be well achieved through the micro-fluidic technology, the obtained single-shell-layer microcapsule fire extinguishing agent is complete in structure, compact in shell layer, uniform in particle size and good in dispersity, the good flame retardant effect can be achieved through introduction of the second-layer shell resin type flame retardant material, and the heat stability of the microcapsule fire extinguishing agent is improved.

The invention discloses nano cellulose with high lignin content, a preparation method thereof and application of a barrier coating. The preparation method comprises the following steps: mixing a lignocellulose raw material with dilute sulphuric acid for acid pretreatment, and selectively depolymerizing hemicellulose to obtain lignin-rich residues of which the relative content of lignin is higher than that of the raw material; and carrying out mechanical nano fibrillation treatment to obtain the high-lignin-content nano cellulose with the lignin content of 29-60%. The prepared nano cellulose with high lignin content has excellent thermal stability, hydrophobicity and organic compatibility. The surface of paper is coated with the coating material, after hot pressing treatment, the Cobb value of the coated paper is as low as 3.3 g / m < 2 >, the water vapor permeability is only 12.1 g / (m < 2 >. D), grease permeation can be completely blocked, and the coating material has wide application prospects in the field of food packaging.

The invention discloses a positive current collector with high safety performance and a preparation method thereof, the positive current collector comprises an aluminum foil base material and a safety coating coated on at least one surface of the aluminum foil base material, and the safety coating comprises lithium-containing phosphate, oxide solid electrolyte, a conductive agent and a binder in a weight part ratio of (50-95): (1-20): (1-10): (1-5). According to the positive current collector disclosed by the invention, the surface of the aluminum foil base material is coated with the safety coating containing lithium phosphate as a main component, and the coating has excellent thermal stability and mechanical strength, so that the formation of an aluminum wedge under a needling condition can be effectively inhibited, the probability of short circuit between the positive current collector and a negative electrode is reduced, and the needling safety performance of the battery is remarkably improved. Meanwhile, the oxide solid electrolyte added in the safety coating increases a lithium ion transmission channel, improves the ion diffusion rate, and further enhances the safety performance and electrochemical performance of the positive electrode current collector.

The invention discloses a heat-resistant aluminum alloy material and a preparation method thereof, and relates to the technical field of metal material metallurgy, and the heat-resistant aluminum alloy material comprises the following components in parts by weight: 78-85 parts of pure aluminum ingot; 4-6 parts of electrolytic copper blocks; 1.5 to 2.5 parts of magnesium ingot; 0.8 to 1.5 parts of zinc particles; 2 to 3.5 parts of metal nickel powder; 0.1 to 0.3 part of titanium-aluminum alloy; 0.05 to 0.15 part of a zirconium-aluminum alloy; 0.08 to 0.2 part of scandium aluminum alloy; 0.05 to 0.12 part of a cerium rare earth metal block; according to the aluminum alloy material disclosed by the invention, the high-temperature performance of the aluminum alloy material is remarkably improved by optimizing the composition proportion of the alloy. Elements such as copper and nickel are added to form a stable strengthening phase, so that the high-temperature strength and the creep resistance are enhanced; due to introduction of rare earth elements cerium and scandium, crystal grains are refined, and the thermal stability of the material is improved; and through compound addition of zirconium and titanium, grain boundary migration at high temperature is further inhibited, the softening phenomenon is effectively delayed, and the material still keeps excellent mechanical properties and oxidation resistance in a long-term high-temperature environment.

The invention relates to the technical field of laser communication, and discloses a deflection-maintaining mirror, a coarse tracking pointing mechanism and laser communication terminal equipment, so that the deflection-maintaining mirror has high polarization-maintaining performance and high thermal stability. The deflection-maintaining oscillating mirror comprises a mirror frame and a reflecting mirror, a mounting hole is formed in the middle of the mirror frame, and the reflecting mirror is mounted in the mounting hole. The mirror surface of the reflecting mirror is provided with a polarization-maintaining reflecting film layer group, the polarization-maintaining reflecting film layer group comprises a first reflecting film layer and a multi-layer compensation dielectric film layer which are stacked, the first reflecting film layer is located between the multi-layer compensation dielectric film layer and the mirror surface of the reflecting mirror, the reflectivity of the first reflecting film layer to laser with the wave band of 800-1570 nm is larger than 99%, and the reflectivity of the second reflecting film layer to laser with the wave band of 800-1570 nm is larger than 99%. The overall reflectivity of the polarization-maintaining reflecting film layer set is larger than 99%, and the overall thickness of the polarization-maintaining reflecting film layer set is smaller than or equal to 600 nm.

The invention discloses a seasonal self-adjusting type frozen soil roadbed heat preservation method, belongs to the technical field of road engineering, and aims to solve the technical problems that the annual heat income and expenditure management is poor and the thermal stability of frozen soil is difficult to maintain for a long time due to the lack of seasonal self-adaptive adjusting capability in the conventional frozen soil roadbed heat preservation measure. According to the technical scheme, a heat preservation plate layer containing a closed air channel network is laid in the frozen soil roadbed, the two ends of the air channel network are connected with a first vertical ventilation pipe and a second vertical ventilation pipe respectively, and the opening and closing states of the air channel network are automatically regulated and controlled through temperature response mechanisms arranged on the pipes according to the environment temperature; the system can be adaptively switched among three modes of heat resistance and heat discharge in summer, cooling and cold storage in winter and transition buffering in spring and autumn. The method is mainly used for road roadbed construction and maintenance in permafrost and seasonal frozen soil regions, the thermal state of the roadbed can be effectively regulated and controlled, thaw collapse deformation is prevented, and long-term stability and safe operation of the road are guaranteed.

The invention belongs to the technical field of flexibility improvement and transformation of coal-fired power generation, and discloses a multi-parameter optimization method for optimizing equivalent electricity-electricity efficiency of an electric heating fused salt heat storage pure condensing power generation system, which comprises the following steps of: firstly, determining a fused salt heat storage medium temperature interval, a steam generator heat transfer structure and key parameters of a power generation subsystem; the main steam pressure, the reheating steam extraction pressure and the like are used as optimization variables; secondly, on the basis of thermodynamic feasibility and equipment safety, setting boundary conditions such as main steam pressure grading limitation, a deaerator operation boundary, a fused salt thermal stability threshold value and a heat exchanger heat transfer economical efficiency constraint; then, the heat exchange power of a steam generator is calculated through the reference working condition, the cold and hot salt design temperature and the heat exchange area are determined by combining the fused salt heat exchange temperature difference, and the fused salt mass, the heat storage tank volume and the electric heater power are calculated according to heat absorption and release balance; and finally, iteratively optimizing the key parameters by adopting a multi-parameter optimization algorithm until the equivalent electricity-electricity efficiency is optimal. The problems that in a traditional method, parameter collaboration is poor, constraint conditions are ignored, and global optimization is insufficient are solved, the operation efficiency and economical efficiency of the electric heating fused salt heat storage pure condensing power generation system are remarkably improved, and green and sustainable development of energy is facilitated.

The invention relates to a high-performance copper (I)-based glass scintillator material and a preparation method thereof, and particularly discloses a Cu (I)-based hybrid metal halide optimized based on halogen engineering (Cl, Br, I), and the X-ray absorption cross section and the light output performance are remarkably improved. The light yield of the material reaches 79, 770 photons MeV <-1 > and is improved by 180% compared with that before optimization. The transparent glass scintillation screen (optical transmittance gt; the material has excellent X-ray imaging resolution (20.5 lp mm <-1 >), and also shows good thermal stability (stable luminescence performance at a high temperature of 150 DEG C) and anti-radiation durability. The material has the advantages of high light yield, low detection limit, high spatial resolution and the like, provides a breakthrough solution for application of the zero-dimensional halogenated cuprous-based scintillator in the fields of X-ray detection and imaging, and is particularly suitable for the fields of medical diagnosis, industrial nondestructive testing, high-energy physical detection and the like.

The invention provides a mining polyurethane material for blocking spraying air leakage and a preparation method thereof, and belongs to the technical field of polyurethane. The preparation method comprises the following steps: carrying out surface treatment on a multi-walled carbon nanotube, mixing with porphyrin-Zn-MOF and polydopamine for modification to prepare a porphyrin-Zn-MOF polydopamine modified carbon nanotube, mixing with m-2DOPO-2NH2, reacting with KH560 modified nano silicon dioxide to prepare a modifier, mixing with polyether polyol and a catalyst, adding into water, adding a foaming agent and silicone oil, heating, stirring and mixing, transferring into a mold, carrying out heat preservation, and carrying out vacuum drying, so as to obtain a finished product. Adding diisocyanate, after foaming is completed and the temperature of the material is reduced to the room temperature, drying, heating and curing to prepare the mining polyurethane material for blocking spraying air leakage, adding the modifier into a polyurethane foaming system, so that the mechanical property and flame retardant property of the system are obviously improved, the antistatic property and the thermal stability are improved, the modifier can be uniformly dispersed in the system, and the flame retardant property and the antistatic property of the system are improved. And repeated spraying is avoided, the constructability is good, and wide application prospects are achieved.

The invention relates to the technical field of corrosion prevention of marine equipment, in particular to a sacrificial anode for a dry-wet alternating and high-temperature environment and a preparation method and application of the sacrificial anode. According to the sacrificial anode, the composite material composed of the carbon nanotubes and the metal elements is added into the aluminum-based alloy, the microstructure of the aluminum alloy is improved due to the addition of the carbon nanotubes, the thermal stability of the anode is improved, surface activation of the anode is promoted, the phenomenon that the surface of the anode is crusting and even passivated due to the influence of high temperature and a dry-wet alternating environment is prevented, and the service life of the anode is prolonged. Meanwhile, good conductivity is maintained; and by optimizing the ratio of the carbon nanotubes to the metal elements, the anti-corrosion protection efficiency on a metal structure in a high-temperature and dry-wet alternating environment is enhanced. Therefore, the method is expected to be applied to ocean environments such as ocean crude oil ship ballast tanks, FPSO (Floating Production Storage and Offloading) ballast tanks and mobile oil production platforms. The preparation method provided by the invention is simple and convenient, has a good industrial application prospect, and can improve the production efficiency and reduce the environmental pollution.

The invention provides a diaphragm, an electrochemical device and an electronic device, and relates to the technical field of electrochemical energy storage, the diaphragm is used for the electrochemical device, the diaphragm comprises a base membrane and a porous coating arranged on at least one side of the base membrane, and the porous coating comprises graphene oxide; the lamellar thickness of the graphene oxide is a nm, the volume particle size Dv50 of the graphene oxide is z [mu] m, and z / a is greater than or equal to 1000 and less than or equal to 6000. The diaphragm provided by the invention has good thermal stability and ion transmission effect, so that the risk of lithium precipitation is effectively reduced.

The application provides a flexible plugging agent for offshore oil and gas drilling fluid and a preparation method and application thereof, and belongs to the technical field of offshore oil and gas drilling and production. The plugging agent is prepared from the following raw materials: styrene, N-phenylmaleimide, 2-acrylamido-2-methylpropanesulfonic acid, sodium p-styrenesulfonate, 2-methacryloyloxyethylphosphorylcholine, a crosslinking agent, an initiator, a hydrophilic emulsifier, an oleophilic emulsifier and water. The plugging agent has excellent structural stability, heat resistance, salt resistance and hydration stability, has good adaptability to a low-density drilling fluid system, has a flexible deformation capacity, can effectively enter a complex leakage passage to achieve effective plugging, and can maintain the integrity and stability of a plugging layer under drilling fluid circulation shearing, temperature fluctuation and complex downhole conditions, thereby having applicability in a high-temperature and high-pressure drilling environment.

The application discloses a kind of water-based ceramic slurry adhesives for ceramic-coated polyolefin separators, and relates to the technical field of polyolefin separators.The adhesives prepared by the preparation method provided by the application can promote the uniform dispersion of inorganic ceramic particles in the ceramic slurry, and the excellent adhesion of the adhesives can firmly bond the inorganic ceramic particles to the separators, preventing the phenomenon of powder falling during production, transportation and use, thereby ensuring the improvement effect of the thermal stability of the inorganic ceramic particles on the separators.

The invention belongs to the technical field of magnetic material preparation, and particularly relates to a production process of high-performance rare earth permanent magnetic ferrite magnetic powder. The process comprises the following steps: preparing iron oxide red and auxiliary materials, wherein the auxiliary materials comprise calcium carbonate, strontium carbonate, lanthanum oxide and cobalt oxide; mixing the raw materials in proportion, and then carrying out dry ball-milling densification to obtain a mixed material; the obtained mixture is subjected to steam treatment, the water content of the mixture reaches 2%-5%, then curing is conducted, the curing time is at least 30 min, and the curing process is completed in the auger transfer process; pelletizing is performed; pre-sintering is performed; and coarsely crushing and sieving the pre-sintered material to obtain the rare earth permanent magnetic ferrite magnetic powder. Through steam pretreatment and curing, the strength and thermal stability of the ball material are remarkably improved, the ball material is kept complete and good in fluidity in the kiln, and the consistency and the qualified rate of products are improved.

This invention discloses a covalent organic framework material for selective solid-phase adsorption and separation, its preparation method, and its applications. The material is prepared by polycondensation reaction of electron-deficient triazine rings with short-chain linkers such as hydrazine hydrate, forming a layered structure with a high specific surface area of ​​602 m² / g and a concentrated pore size of 2.0 nm to 3.0 nm. This structure exhibits high adsorption capacity (up to 1.0 mg / g), rapid adsorption kinetics, and excellent selectivity for PAHs in organic solutions through strong π-π interactions and pore confinement effects. The preparation process is simple and the conditions are mild. The material has good thermal stability (>300℃), and its performance retention rate is higher than 92% after 5 cycles. When applied to the solid-phase adsorption of PAHs in petroleum products such as lubricating oil and white oil, it effectively eliminates matrix interference, allowing direct analysis without complex purification steps after adsorption. This overcomes the limitations of traditional materials such as silica gel and activated carbon, which have weak adsorption capacity and require cumbersome post-treatment, providing a new high-performance adsorption material solution for the efficient detection of trace PAHs in petroleum products.

The present invention provides a visual indicator film for the freshness of fresh-cut fruits, a preparation method, the use and a detection method. The preparation method comprises the following steps: preparing a Co-based MOF; washing and activating the Co-MOF; preparing a CMC-Na-based thin film; and preparing a CMC-Na-based thin film, and thereby obtaining an indicator film for phenol red (PR) or an indicator film for bromothymol blue (BTB). In the present invention, an irregular spherical Co-based metal organic framework (Co-MOF) loaded with PR or BTB is prepared, and the nanocomposites Co-MOF / PR and Co-MOF / BTB are obtained after dyes and the MOF are adsorbed by means of the hydrogen bond interaction. Then, the nanocomposites are embedded into a sodium carboxymethyl cellulose (CMC-Na) base material to prepare CO2-responsive packaging materials, namely, a CMC-Na / PR / Co-MOF and a CMC-Na / BTB / Co-MOF, which are used for monitoring the freshness of fruits in real time and in situ. The Co-MOF-based composite thin film has good water resistance, time-temperature stability and mechanical properties, and also exhibits enhanced ultraviolet-visible light barrier properties, dye migration resistance and thermal stability. The visual indicator film for the freshness of fresh-cut fruits can effectively reflect the concentration of CO2, and is suitable for real-time and in-situ monitoring of the freshness of fruits.

The application belongs to the technical field of magnetic material preparation, and particularly relates to a production process of high-performance rare earth permanent ferrite magnetic powder. The process comprises the following steps: preparing iron red and auxiliary materials, wherein the auxiliary materials comprise calcium carbonate, strontium carbonate, lanthanum oxide and cobalt oxide; mixing raw materials in proportion, then performing dry ball milling to obtain mixed materials; performing steam treatment on the obtained mixed materials to make the water content of the mixed materials reach 2-5%, then performing ripening, and the ripening time is at least 30 min, and the ripening process is completed in the screw conveyor; balling; pre-sintering; performing coarse crushing on the pre-sintered materials and sieving to obtain rare earth permanent ferrite magnetic powder. Through steam pretreatment and ripening, the strength and thermal stability of the ball materials are significantly improved, the ball materials remain complete in the kiln, the flowability is good, and the consistency and qualified rate of the product are improved.

The utility model discloses a die-casting aluminum straight barrel type waterproof heat dissipation controller which comprises a base, a surrounding plate is integrally formed around the top of the base, the top of the surrounding plate is fixedly connected with a surface cover, a plurality of heat dissipation ribs are arranged at the bottom of the base, heat dissipation steps are embedded in the tops of the heat dissipation ribs, and the heat dissipation steps are T-shaped. A socket hole and a binding post hole are respectively formed in the surface cover; according to the utility model, the base and the coaming are integrally formed and are matched with the surface cover for sealing, the socket hole and the binding post hole are matched with the sealing rubber ring and the annular waterproof gasket, the heat dissipation step is arranged in the base to facilitate the installation of the aluminum substrate, and the heat dissipation step is attached to the plurality of heat dissipation ribs, so that the heat conduction efficiency and the heat dissipation area are increased, and the heat dissipation efficiency is improved; the heat stability of the controller in the working process is guaranteed, the problems of poor heat dissipation and water inflow short circuit of a traditional controller are solved, and the controller is suitable for high-power and high-protection-requirement scenes such as electric vehicles and industrial motors.

The invention discloses a nanofluid mixed matrix membrane as well as a preparation method and application thereof, and belongs to the field of gas separation. The nanofluid mixed matrix membrane comprises a polymer matrix and a nanofluid filler, the nanofluid filler is of a three-dimensional layered structure, a core layer is a porous material layer, a secondary outer layer is a coupling agent connecting layer, and an outermost layer is an organic matter coronal layer containing a CO2-philic group. The coronal layer improves the compatibility of the porous material and the polymer matrix and increases the CO2 affinity of the mixed matrix membrane, not only increases the diffusivity of the mixed matrix membrane, but also increases the CO2 solubility, and due to the unique connection mode between the porous core and the coronal layer, the thermal stability of the porous core and the coronal layer is also enhanced. Therefore, the prepared novel efficient mixed matrix membrane has good gas separation performance and thermal stability and is especially suitable for CO2 separation, and CO2 / H2 of the product breaks through the Robeson upper limit in 2008.

The application discloses application of high-thermal-stability hydrofluoroether, and the high-thermal-stability hydrofluoroether has a structural formula of HCF2CF2CF2CF2CH2OCF2CF2H, and is used as a coolant for a cooler of a temperature control device in a semiconductor product processing process, and has the advantages that the high-thermal-stability hydrofluoroether with the specific molecular structure is used as the coolant for the cooler of the temperature control device in the semiconductor product processing process, the substance is compatible with most materials in a wide temperature range, has good thermal stability, chemical inertia and non-corrosiveness, is non-toxic in the use process, has good environmental and safety characteristics, has an ODP value of 0 and a very low GWP value, and the substance has excellent dielectric properties, low viscosity and high resistivity, and is especially suitable for a heat transfer fluid in a semiconductor wafer etching process.