2322 results about "Silicate" patented technology

The invention discloses a matte glaze and a preparation method thereof. The matte glaze comprises the following components by weight: 1-5 parts of zinc oxide, 5-15 parts of barium carbonate, 0-15 parts of zirconium silicate, 10-25 parts of potassium feldspar, 10-20 parts of kaolin, 5-15 parts of calcite, 5-15 parts of calcined talcum powder, 20-35 parts of a matte frit and 0.5-1 part of an additive. Specifically, the matte frit comprises the following components by weight: 30-50 parts of SiO2, 15-20 parts of Al2O3, 0.01-0.5 part of Fe2O3, 3-10 parts of CaO, 0.5-5 parts of MgO, 1-5 parts of K2O, 3-10 parts of Na2O, 3-10 parts of ZnO, 0.1-1 part of B2O3 and 10-25 parts of BaO. By introducing the matte frit, the melting temperature of the formula is lowered, the firing range of the formula isbroadened, and the glaze texture achieves a fine matte effect.

The invention relates to the technical field of filling materials, and particularly discloses an ardealite-based high-strength anti-seepage filling material and a preparation process thereof, the ardealite-based high-strength anti-seepage filling material comprises 50%-65% of pretreated ardealite, 15%-25% of Portland cement, 5%-15% of superfine slag powder, 5%-10% of electrolytic manganese residues, 5%-8% of silica fume, 3%-6% of metakaolin, 2%-4% of a composite alkali activator and 0.5%-1.2% of a polycarboxylic acid water reducer, 0.3%-0.8% of an organic silicon water repellent and 0.05%-0.1% of cellulose ether; according to the invention, through chemical reaction of Mn < 2 + > in the electrolytic manganese residue and SO4 < 2-> in the phosphogypsum, micron-sized manganite crystals (MnAl2 (SO4) 4. 22H2O) are generated to actively fill internal micro-cracks of the material, so that a filling body is endowed with a self-repairing function and the impermeability is improved, and a composite alkali activator composed of NaOH and water glass is used for synergistically activating potential gelling activity of the superfine slag powder and the silica fume, so that the self-repairing filling material is prepared. And the formation of hydration products is accelerated, and 0.3-0.5 T of pulsed magnetic field is applied in the stirring process, so that the manganite crystals are guided to orderly grow along the expected stress direction of the filling body, and the compressive strength is improved.

The invention relates to the technical field of cement-based soil curing agents, and particularly discloses a roadbed soil cement cementing material curing agent and a use method thereof. The curing agent comprises Portland cement, coal gangue particles, fly ash, silica fume, an anti-permeability reinforcing agent, a water reducing agent and fibers. The anti-permeability reinforcing agent is prepared by the following steps: (1) dispersing polyaluminum sulfate powder into absolute ethyl alcohol, then adding a silane coupling agent and a water repellent agent, and heating and preserving heat under a stirring condition; and then separating out solids to obtain the modified polyaluminum sulfate. And (2) adding the modified polyaluminum sulfate into water, heating and preserving heat under a stirring condition, drying by distillation to remove water, and grinding the obtained solid product. The curing agent provided by the invention not only reduces the adverse effect of acid soil on the stability of a formed soil consolidated body, but also improves the impermeability and the durability of the soil consolidated body.

The invention discloses a mine water recharge reservoir scaling trend prediction, scale removal and permeation enhancement method, and the trend prediction method comprises the steps: carrying out the conventional physicochemical index analysis of the water quality of mine water and a monitoring well according to the hydrogeological information of a recharge reservoir, and calculating the scaling trend of the mine water recharge reservoir based on a Retino index method and the relative saturation R.S. The scaling conditions of carbonate, sulfate and silicate are rapidly judged respectively; when scaling occurs, the ion concentration change on a path is revealed through a Transport module and an Equilibrium Phases module in the PHREEQC software, and verification is carried out through a measured value of a monitoring well; and then according to the mineral dissolution precipitation reaction and the percentage of the reservoir rock sample composition, calculating the reaction dose and the void ratio so as to formulate a mine water recharge reservoir permeation enhancement optimization scheme. According to the method, the scaling trend of the mine water recharge reservoir can be effectively predicted, the recharge process is monitored, and continuous operation of deep well recharge sealing work of mine water is facilitated.

The invention discloses a fluoride salt-free nitrate-free cast iron enamel semitransparent glaze as well as a preparation method and application thereof, and belongs to the technical field of enamel. The semitransparent glaze is prepared from quartz, anhydrous borax, sodium carbonate, potassium carbonate, calcium carbonate, potassium feldspar, zinc oxide, lithium carbonate, zirconium silicate, titanium dioxide, aluminum oxide, trisodium phosphate, antimony oxide, magnesium carbonate and barium carbonate according to a specific mass ratio. The preparation method comprises the steps of raw material mixing, high-temperature melting under a pure oxygen condition, wiredrawing detection, quenching and the like. The semitransparent glaze is completely free of fluoride salt and nitrate, the problems of fluoride emission and environmental protection equipment blockage are avoided from the source, the fluorine content of the product is not detected through detection, the product meets the requirements of European Union REACH regulations, meanwhile, the product has good porcelain surface, luster and low-temperature firing adaptability, and is suitable for cast iron matrixes, the firing temperature is 740-760 DEG C, and the firing time is 2-3 hours. The method can be used for producing green and environment-friendly enamel products.

The invention belongs to the technical field of new building materials, and provides a low-alkalinity and early-strength ardealite filling and curing material and a preparation method thereof.The low-alkalinity and early-strength ardealite filling and curing material is prepared from ardealite, a curing agent and water, the curing agent comprises silica fume, limestone powder, superfine granulated blast furnace slag powder, metakaolin, calcium aluminate powder, Portland cement clinker powder, a suspension stabilizer and hydroxypropyl methyl cellulose ether. The problems of delayed coagulation, low early strength and high alkalinity of a common cement-based ardealite filling material can be solved, and the technical requirements of ardealite cemented filling are met.

The invention belongs to the field of grouting materials, and discloses a composite grouting material as well as a preparation method, a construction method and application thereof. The composite grouting material comprises the following components: sulphoaluminate cement clinker powder, Portland cement clinker powder, a reinforcing agent, a coagulant and a modifier, the reinforcing agent comprises superfine mineral powder, superfine fly ash, silica fume and calcium sulfate whiskers; the coagulant comprises alumina clinker powder, calcium hydroxide, lithium carbonate and aluminum hydroxide; the modifier comprises a shrinkage reducing agent, a thickening agent, a water reducing agent and a retarder. The composite grouting material has the advantages of being good in pumpability, short in gelation time, free of plastic shrinkage, high in early strength, good in volume stability, high in durability, appropriate in price, environmentally friendly, free of toxicity and the like, and the requirement for rapid grouting maintenance is met in the subway operation window period.

The invention relates to the technical field of cement mortar compositions, and particularly discloses a double-component anti-freezing early-strength slurry and a preparation method and application thereof. The double-component anti-freezing early-strength slurry provided by the invention is composed of a component A and a component B in a weight ratio of 25: (4-10), the component A is prepared from the following components in parts by weight: 250 to 280 parts of Portland cement, 90 to 100 parts of admixture, 145 to 165 parts of sand and 6.4 to 8.4 parts of water reducing agent; and the component B comprises the following components in parts by weight: 8-10 parts of a sodium nitrite antifreeze agent, 50-58 parts of a reinforcing aid, 32-40 parts of anhydrite, 240-270 parts of an admixture, 155-175 parts of sand and 4.1-6.1 parts of a water reducing agent. By utilizing the technical scheme, the prepared double-component anti-freezing early-strength slurry has the advantages of rapid development of early compressive strength and stable growth of later compressive strength under different ultralow temperature conditions.

The invention discloses a high-ground-temperature-resistant ultrahigh-flow nano-modified polymer grouting material as well as a preparation method and application of the high-ground-temperature-resistant ultrahigh-flow nano-modified polymer grouting material, and belongs to the technical field of geotechnical engineering. According to the present invention, the nanometer modified cementation particles are combined with the calcium hydroxide, the sodium carbonate, the cellulose nanofiber and the tannic acid to regulate and control the hydration process, the fluidity and the mechanical strength, the nanometer modified cementation particles are injected into the deep surrounding rock, the high fluidity can be maintained in the high ground temperature environment for a long time, the grouting diffusion range is effectively expanded, and the accurate regulation and control of the grouting material gelling time can be achieved. Meanwhile, high-mass-fraction fly ash and silica fume are excited to generate calcium aluminosilicate hydration products, and the problems that an existing conventional calcium silicate grouting cementing material is poor in reinforcing and anti-seepage effect in a high-ground-temperature environment, slurry is prone to cracking and the like are solved.

The invention belongs to the field of coal gangue resource utilization, and particularly discloses a method for separating and recovering silicon and aluminum elements from coal gangue. The coal gangue is used as a raw material, and efficient resource utilization of the coal gangue is realized through crushing and ball milling, high-temperature roasting activation and acid-base combined treatment. The coal gangue is subjected to high-temperature fluorination roasting by adopting an activating auxiliary agent fluorinating agent to form soluble fluosilicate (H2SiF6) and a fluorine-aluminum compound (AlF3), so that the subsequent silicon-aluminum separation is obviously promoted. The method comprises the following steps: desiliconizing through alkali treatment, leaching and converting silicon in the coal gangue into sodium silicate, and carrying out solid-liquid separation to obtain sodium silicate filtrate and aluminum-rich leaching residues; and then acid treatment is conducted on the aluminum-rich leaching residues, aluminum salt or aluminum hydroxide is prepared, and finally efficient separation of silicon and aluminum is achieved. According to the method, through high-temperature activation roasting, the normal-pressure alkaline leaching desiliconization effect is improved, the acid extraction aluminum efficiency is remarkably improved, the advantages of an acid method and an alkaline method are effectively combined, and the problems that coal gangue resources are difficult to utilize and the resource recovery rate is low are solved.

The invention provides a hydraulic concrete freeze-thaw damage microstructure segmentation method, electronic equipment and a medium. The method comprises the following steps: acquiring concrete two-dimensional CT images of different freeze-thaw cycle times; and taking the concrete two-dimensional CT image as the input of the U-Net network model, and training the U-Net network model to obtain a concrete microstructure segmentation model. According to the method, the problem that high-density groups of hydrated silicate, calcium hydroxide, unhydrated clinker and the like belonging to a mortar phase are misclassified into coarse aggregates is effectively avoided, and the problems that a traditional threshold method is not obvious in dividing boundary and unstable in dividing result are solved. The method provides an effective means for quantifying the influence of freeze-thaw damage on a multi-scale pore structure in the concrete and establishing damage evolution of the concrete under the action of freeze-thaw cycle.

The invention relates to the technical field of expansive soil treatment, and particularly discloses an expansive soil rapid hardening material as well as a preparation method and application thereof. The invention discloses an expansive type rapid hardening material for soil. The expansive type rapid hardening material is prepared from the following components: high belite sulphoaluminate cement clinker, ordinary Portland cement, gypsum, solid waste high-activity superfine powder, a nano crystal nucleus induction activating agent, a nano modified complexing agent and a modified early strength agent, the nano crystal nucleus induction activating agent is prepared from nano Al2O3, sodium dodecyl benzene sulfonate, NaOH and Na2SiO3; the nano modified complexing agent is prepared from nano SiO2, lauryl sodium sulfate and silane; the modified early strength agent is prepared from modified graphene oxide, Na2SiO3 and water. According to the technical scheme, the solid waste can be recycled, the expansive soil treated by the hardening material can achieve the effects of high hour strength and good water stability, and the curing speed and the production efficiency are greatly improved.

The present invention provides a method for manufacturing a non-fired brick whereby reductions in corrosion resistance and creep resistance due to the generation of low melting point substances can be suppressed, and sufficient strength can be exhibited. In the present invention, water is added to and mixed with a refractory raw material formulation containing 0.2-15 mass% of magnesia having a particle diameter of less than 75 μm and 0.3-10 mass% of silica having a particle diameter of less than 44 μm, with the remainder being mainly one or more of an alumina raw material, an alumina silica raw material, a silica raw material, and a spinel raw material, and the total content ratio of alkali metal phosphates and alkali metal silicates being less than 1 mass% (including 0). Thereafter, the mixture is press molded and then left standing at room temperature or heat treated at a temperature of 1000°C or less.

The invention provides a thermal response self-ceramization fireproof coating and a preparation method thereof. The thermal response self-ceramization fireproof coating is prepared from the following raw materials in parts by mass: 3 to 10 parts of acrylic monomer, 3 to 10 parts of organic sulfonate, 1 to 4 parts of silane coupling agent, 0.5 to 3 parts of silicate ester, 4 to 6 parts of ceramic precursor, 3 to 6 parts of fluxing agent and 0.05 to 0.4 part of initiator. The fluxing agent comprises a component A and a component B, the component A is one of boric oxide, zinc borate or low-melting-point glass powder, and the component B is one of phosphorus pentoxide and ammonium polyphosphate. The silane coupling agent can be copolymerized with an acrylic monomer to construct a C-C main chain, the C-C main chain and silicate ester are subjected to hydrolytic condensation to form a Si-O-Si three-dimensional network, a chemical cross-linked skeleton is formed, and the chemical cross-linked skeleton can generate silicon dioxide at high temperature to participate in a ceramization reaction; the ceramic precursor and silicate ester can form a strong physical cross-linking effect, so that the fireproof coating with a chemical and physical double-cross-linked network can be formed, and the fireproof coating has excellent mechanical property and machinability at normal temperature.

A free-flowing solid activator for a geopolymer mortar or concrete comprises or consists of an alkali(ne) metal carbonate surface treated with a sub-stoichiometric amount of alkali(ne) metal hydroxide. In one embodiment a method for producing an activated fly ash comprises: a) spraying an aqueous alkali(ne) metal silicate onto the surface of a solid particulate fly ash; b) drying the spray-treated product of step a); c) optionally grinding the dried product of step b); and optionally, repeating the spray treatment process for the product of step b) or step c) by returning the product of step b) or step c) to step a).

The present invention discloses a 3D three-dimensional glaze, which comprises the following components in percentage by weight: 45% - 60% of silicon dioxide, 17% - 25% of aluminum oxide, 1% - 2% of calcium oxide, 0.06% - 1.2% of magnesium oxide, 0.4% - 0.6% of sodium oxide, 1% - 3% of potassium oxide, 10% - 20% of zirconium oxide, 0.2% - 0.6% of zinc oxide, and 1% - 3% of boron oxide; the loss on ignition of the 3D three-dimensional glaze is 1.8% - 3.6%. The preparation method of the 3D three-dimensional glaze is to quantitatively weigh powders such as zirconium silicate, quartz powder, calcined alumina, potassium feldspar, ceramic frit powder, sodium carboxymethyl cellulose, and industrial tripolyphosphate, and then sequentially add the powders and emulsifying wax into water and stir to obtain a glaze slurry. After adjusting the viscosity of the glaze slurry, the 3D three-dimensional glaze is obtained by passing through an 80-mesh sieve. The present invention improves the adhesion of the 3D three-dimensional glaze on the surface of the green body, and when fired directly or in combination with other glazes, the three-dimensional glaze lines will not collapse, crack, have bubbles or breakpoints.

The application discloses a kind of ship super-long anticorrosion special nano powder coating, preparation method and application, belong to ship heavy anticorrosion material technical field.The preparation method of the ship super-long anticorrosion special nano powder coating is as follows: epoxy resin, graphene modified epoxy resin, core-shell structure ZnO@SiO2, modified 2,5-dimercapto-1,3,4-thiadiazole, borosilicate glass powder, flaky boron nitride, silane coupling agent modified silica, phenolic amine curing agent, 2-ethyl-4-methylimidazole, fumed silica, defoaming agent, ultraviolet absorber, high-temperature pigment are put into stirrer and stirred for 20-30min, then melt extrusion is carried out through double screw extruder, the extrusion temperature is 90-110 DEG C, grinds and sieves, and the ship super-long anticorrosion special nano powder coating is obtained.The coating prepared by the application has good anticorrosion performance and can be applied in the field of ship metal surface corrosion protection.

The invention relates to a curing agent for an iron tailing engineering backfill material and a use method of the curing agent. The curing agent is composed of Portland cement, calcium hydroxide, fly ash, modified superfine slag powder, alkaline residues and a sodium phosphate buffer system. And by adding the curing agent, the backfill material has excellent compressive strength, durability and permeability resistance. Due to the filling and interface enhancing effects of the modified superfine slag powder, the compactness of the material is remarkably improved, and the porosity and the permeability coefficient are reduced; the alkaline residues accelerate the curing reaction, and the freeze-thaw resistance of the material is improved. The method is suitable for various complex geological and environmental conditions, and the stability and safety of the backfill material in an extreme environment are ensured.

The invention relates to the technical field of coating preparation, and discloses a high-adhesion quick-drying inorganic zinc silicate shop primer and a preparation method thereof.The high-adhesion quick-drying inorganic zinc silicate shop primer is prepared from modified zinc powder, modified graphite powder, a sodium silicate solution, alpha-phase nanometer AlO, a quick-drying agent, an adhesion promoter, heat-resistant filler, a dispersing agent, a defoaming agent and a diluting solvent; the quick-drying agent is prepared by compounding zinc naphthenate, EDTA and titanium isopropylate according to the mass ratio of 1: (0.2-0.3): (0.4-0.6), the quick-drying agent accelerates the reaction by catalyzing hydrolysis of silicate through zinc salt, chelating of EDTA and metal ions, titanium isopropylate provides titanium ions to synergistically form a film and improve the quick-drying efficiency, the adhesion promoter is prepared by compounding KH-560 and E-44 epoxy resin according to the mass ratio of 3: 1, and the adhesion promoter is prepared by compounding epoxy resin and epoxy resin. The adhesion promoter enhances interface mechanical occlusion and adhesion through silane bonding base materials and epoxy resin, other raw materials are matched with the adhesion promoter to accelerate the drying speed of the primer, and a coating coated with the primer is not prone to stripping and peeling. The application has the effects of improving the adhesive force and drying speed of the inorganic zinc silicate shop primer.

The invention belongs to the field of magnetic materials, and particularly discloses europium-based silicate as well as a preparation method and application thereof. The general chemical formula of the europium-based silicate is Eu2SiO4, and the europium-based silicate is subjected to secondary magnetic phase change from a paramagnetic state to a ferromagnetic state at the magnetic phase change temperature of 5.8 K; and at the temperature of 5.5 K, when the magnetic field change is 0-2T, the maximum magnetic entropy change is greater than 10J. Kg <-1 >. K <-1 >. The europium-based silicate disclosed by the invention generates paramagnetic to ferromagnetic phase change near the liquid helium temperature, is accompanied by a low-magnetic-field giant magnetothermal effect near the magnetic phase change temperature, shows large magnetic entropy change and refrigerating capacity near the liquid helium temperature, and has a wide application prospect in the field of magnetic refrigeration in a liquid helium temperature region.

The present disclosure provides a new wet atomic layer etch (ALE) process for etching silicon dioxide (SiO2) materials. More specifically, the present disclosure provides various embodiments of methods that utilize new etch chemistries for etching a SiO2 layer in a cyclic wet ALE process. The new etch chemistries disclosed herein use an anhydrous basic surface modification solution to create self-limiting reactions on exposed surfaces of the SiO2 layer and form a silicate passivation layer, which is insoluble in the surface modification solution, but readily soluble in a dissolution solution.

The invention discloses a composite heavy metal adsorbent synthesized through mineral conversion and a preparation method of the composite heavy metal adsorbent, and belongs to the technical field of deep processing of natural nonmetallic minerals and preparation of heavy metal adsorption functional materials, and the main preparation method comprises the following steps: S1, crushing and crushing natural clay minerals, and sieving with a 80-mesh sieve to obtain mineral powder; s2, mixing the obtained mineral powder with a calcium compound, and carrying out ball milling; s3, adding a boron compound, and continuing ball milling; s4, adding water into a solid material obtained by ball milling according to a solid-to-liquid ratio of (1: 5)-(1: 20), putting into a microwave hydrothermal reaction kettle, adding an organic auxiliary agent, carrying out gradient heating to 100-200 DEG C, reacting for 30-120 minutes, then naturally cooling to room temperature, separating, drying and crushing; according to the invention, natural clay raw ore is taken as a raw material, and the borate-silicate composite adsorption material is prepared in a preparation mode of combining solid-phase reaction and microwave hydrothermal treatment, so that high-concentration and low-concentration heavy metal ions are efficiently removed.

The invention discloses an alkali-free accelerator and a preparation method and application thereof in the technical field of concrete additives, and the alkali-free accelerator provided by the invention comprises the following components in percentage by mass: 40%-50% of aluminum sulfate, 10%-15% of magnesium sulfate, 0.2%-0.6% of diethanol amine, 0.5%-1% of catechol-4-ammonium sulfonate, 5%-10% of a stabilizer and the balance of water. The stabilizer comprises silicate dispersion liquid and silica sol. The alkali-free accelerator provided by the invention can be used for spraying concrete, the mixing amount of the alkali-free accelerator is generally 4-6% of the mass of cement, the alkali-free accelerator is good in rapid setting effect and has excellent early and later compressive strength, and meanwhile, the alkali-free accelerator has relatively excellent stability.

The invention provides a preparation method and application of a nano calcium silicate nucleating agent, and relates to the technical field of nano material preparation, the preparation method comprises the following steps: conveying a calcium salt solution, a silicate solution and a dispersant solution into a microfluidic reactor for reaction to obtain the nano calcium silicate nucleating agent; wherein the retention time of the reaction in a microchannel of the microfluidic reactor is 1 to 10 minutes; and the inner diameter of the microchannel is 20-500 [mu] m. The invention solves the technical problems of slow mass and heat transfer, long reaction time and need of exploration and amplification of the process in the traditional kettle type or magnetic stirring process for preparing nano calcium silicate, and achieves the technical effects of fast mass and heat transfer, high production efficiency, easy industrialization amplification and shortening of the industrialization research and development period. The obtained nano calcium silicate nucleating agent is beneficial to improving the early strength performance of cement, and has no influence on the later strength of the cement.

The invention relates to the technical field of water treatment, and discloses an aluminum-based composite silicon removal agent and application thereof. The aluminum-based composite silicon removal agent comprises a component A and a component B, the component A is sodium metaaluminate; the component B comprises one or more of crystalline aluminum chloride, polyaluminum chloride and polyaluminum sulfate. The two components in the aluminum-based composite silicon removal agent can form multi-stage aluminum form distribution of'multi-core-mononuclear-colloid 'in wastewater, so that a complete silicon removal path of'pH regulation and control, charge neutralization, adsorption complexing, bridging flocculation and chemical precipitation' is constructed, and efficient removal of silicate radicals can be realized. The composite silicon removal agent does not need to accurately adjust the pH value of the system, the requirement for operation precision is low, operation is easy, and the dosage of the agent is small.

The invention discloses a preparation method for forming a micro-nano hydrophobic coating by dip-coating on the surface of a fabric, and relates to the technical field of hydrophobic modification of natural fiber fabrics. According to the first part of the product, the selected fabric is formed by weaving natural materials through pulping, spinning and other processes, the fabric hydrophobic coating is composed of two parts, the first part is that a hydrophobic solution and the fabric are selected to construct a microcosmic basic structure, the second part is that a hydrophobic layer is secondarily covered with a mixed solvent, and micro-nano solid particles are added; by utilizing the properties of a silane coupling agent and polydimethylsiloxane, the silane coupling agent and the polydimethylsiloxane are mixed according to a proportion, and the mixture is smeared on the surface of the fabric to construct a rough coating. The preparation method has the advantages that the hydrophobicity is good, and a modified product can still have a good hydrophobic effect after being soaked in water for a long time; the environment is protected, when landfill treatment is needed, the product can be degraded in the natural environment for two years, and when combustion treatment is needed, only carbon dioxide, water and other environment-friendly gases can be generated; water and soil loss is prevented, the hydrophobic effect can be kept in the soil for two years, and afforestation and desert greening are facilitated; the soil is fertile, and the product is rich in sodium ions after being soaked in sodium methyl silicate, so that the nutrient of the soil is increased, and the soil is kept in a fertile state.

The invention discloses modified cement-water glass slurry and a preparation method thereof, and belongs to the technical field of building material preparation. The preparation method comprises the following steps: weighing the following raw materials in parts by weight: 50-70 parts of Portland cement, 20-35 parts of a water glass solution, silica fume, modified nano-silica, an early strength agent and the like, carrying out dry mixing on solid powder, stirring with part of deionized water to form base slurry, adding the water glass solution and the rest deionized water, and carrying out high-speed dispersion to obtain a slurry; and finally, carrying out ultrasonic treatment for 10-15 minutes at the frequency of 20-40 kHz and the power of 300-500 W. Wherein the early strength agent is compounded by triethanolamine and sodium sulfate according to the ratio of 1: 2-1: 3. According to the method, through raw material compounding and process optimization, the dispersity, the early strength and the crack resistance of the slurry are improved, and the method is mainly used for grouting operation in the field of construction engineering such as foundation reinforcement and water prevention and leakage stoppage.

The invention provides a gradient self-repairing sealing coating and a preparation method thereof, and relates to a high-temperature protection material. The gradient self-repairing sealing coating comprises a bonding layer, a gradient middle layer, a transition layer and an abradable surface layer which are sequentially arranged from a base body to the surface. A bonding layer in the gradient self-repairing sealing coating contains silicate, so that the bonding strength and the heat-resistant stability of a matrix are improved; rare earth silicate and Ir elements are introduced into the gradient intermediate layer, so that high-temperature corrosion resistance is enhanced, and thermal stress is relieved; the transition layer contains zirconium oxide and graphene and has the functions of thermal isolation and stress regulation; the abradable surface layer is formed by combining rare earth silicate and graphite, low friction and preferential abrasion are achieved, and effective sacrifice protection is provided. The overall structure can have multiple properties of heat, corrosion resistance and abrasion resistance, and is suitable for the surface protection requirement under the complex hot end working condition.

The invention discloses a fluoride-salt-free and nitrate-free cast iron enamel zirconium white glaze as well as a preparation method and application thereof, and belongs to the technical field of enamel. The zirconium white glaze is prepared from quartz, borax pentahydrate, magnesium carbonate, potassium carbonate, potassium feldspar, zinc oxide, aluminum hydroxide, calcium carbonate, zirconium silicate, sodium tripolyphosphate and lithium carbonate according to a specific mass ratio. The preparation method comprises the steps of raw material mixing, high-temperature melting under a pure oxygen condition, wiredrawing detection, quenching and the like. The zirconium white glaze is completely free of fluoride salt and nitrate, the problems of fluoride emission and environmental protection equipment blockage are avoided from the source, the fluorine content of the product is not detected through detection, the product meets the requirements of European Union REACH regulations, and meanwhile, the zirconium white glaze has good porcelain surface, luster and firing adaptability, is suitable for cast iron matrixes, has the firing temperature of 740-760 DEG C and the firing time of 87-87 hours, and can be widely applied to cast iron substrates. The method can be used for producing green and environment-friendly enamel products.

The invention discloses a sulfate and chloride ion erosion resistant offshore wind power tower high-strength grouting material and a preparation method thereof. The grouting material comprises Portland cement, fine aggregate, ricinoleic acid modified nano zinc oxide, an anion erosion resistant agent, an expansion component, composite fibers and an additive. Wherein the anti-anion erosion agent comprises mineral powder, barium salt, lithium silicate, a calcium formate early strength agent and silica fume; the preparation method comprises the following steps: firstly, mixing and stirring the cement, the expansion component and the fine aggregate to obtain powder A; mixing and stirring ricinoleic acid modified nano zinc oxide, an anti-anion erosion agent and an additive to obtain powder B; mixing and stirring the powder A and the powder B, adjusting the water-cement ratio, adding the composite fiber, and stirring. The grouting material is good in fluidity, high in strength and excellent in fatigue resistance, can effectively prevent permeation of sulfate and chloride ions, and has high durability.