The invention discloses a preparation method of high-purity
titanium dioxide, which is characterized by comprising the following steps: (1) preparing a
titanium solution: slowly adding a
titanium tetrachloride solution into deionized water to obtain the titanium solution; (2) heat-preservation
hydrolysis: adding an acidic dispersant into the titanium liquid obtained in the step (1), stirring and mixing uniformly at
room temperature, heating to 80-85 DEG C, preserving heat, and carrying out
hydrolysis reaction for 1-2 hours to obtain
hydrolysis slurry; (3) obtaining a precursor: cooling, aging, filtering, washing and
drying the hydrolyzed
slurry obtained in the step (2) to obtain a
metatitanic acid precursor; and (4) calcining: calcining the
metatitanic acid precursor obtained in the step (3) at 400 DEG C to obtain the high-purity
titanium dioxide. According to the preparation method of the high-purity
titanium dioxide, provided by the invention, the high-purity (greater than or equal to 99.9%)
titanium dioxide is prepared under mild
process conditions of low-temperature hydrolysis and low-temperature
calcination, the product yield reaches about 90%, and the obtained high-purity titanium dioxide is spherical titanium dioxide with a
rutile structure and has good
dispersity.