84 results about "Titanium diboride" patented technology

The invention provides a preparation method of prismatic titanium diboride powder, and belongs to the technical field of titanium diboride powder. The preparation method comprises the steps of titanium source preparation, boron source preparation, material mixing, cold isostatic pressing and carbon thermal reduction reaction. The step of preparing the titanium source comprises the following steps: heating TiO2 powder body liquid, raising the temperature to 52-55 DEG C, adding a tetrabutyl titanate solution, uniformly stirring, adding an ammonia water solution to adjust the pH value to 7.0, and carrying out heat preservation stirring for 2.7-3.2 hours to obtain the titanium source; the step of preparing the boron source comprises the following steps: adding B4C powder into absolute ethyl alcohol, carrying out ultrasonic dispersion, then adding a mixed solution, controlling the adding rate of the mixed solution to be 0.8-1.2 g / min, heating to 34-37 DEG C, and carrying out heat preservation and stirring for 3.8-4.2 hours to obtain the boron source; the titanium diboride powder obtained through the method is in a prism shape and is uniform in particle, high in density and purity and poor in high-temperature oxidation resistance.

The present invention provides a titanium diboride particle-reinforced heat-resistant aluminum alloy powder for electron beam additive manufacturing. The chemical composition of the aluminum alloy powder includes, by mass percentage, Cu: 1.8-2.7%, Ni: 0.8-1.4%, Mg: 0-1.8%, Fe: 0.1-1.4%, TiB2 particles 0.1-10%, and the balance is aluminum. The main steps of its preparation method are: melting of the particle-reinforced aluminum alloy preform ingot and gas atomization forming of the particle-reinforced aluminum alloy powder. The block formed by electron beam additive manufacturing using the titanium diboride particle-reinforced heat-resistant aluminum alloy powder of the present invention has no cracks, and the microstructure is uniform and the grains are fine. After heat treatment, the obtained tensile strength is 320 MPa, and the elongation is greater than 10%, which is better than the average level of the mechanical properties of electron beam additive manufacturing aluminum alloys.

The invention relates to the technical field of aluminum alloy pipes, in particular to a corrosion-resistant aluminum alloy pipe which comprises an aluminum alloy pipe and a corrosion-resistant layer coated on the surface of the aluminum alloy pipe, the aluminum alloy pipe comprises the following raw materials: 0.1-0.3% of Mg, 0.06-0.2% of Si, 0.1-0.5% of Fe, 0.005% of Cu, 0.2-0.5% of Mn, less than 0.1% of Cr, 0.1-0.4% of Zn, 0.05-0.2% of Ti, 0.01-0.05% of V and the balance of Al; the corrosion-resistant layer comprises the following components in parts by weight: 100 parts of epoxy resin emulsion, 15-25 parts of composite modified titanium diboride, 3-5 parts of an amino curing agent, 1-3 parts of carbon fibers, 20-30 parts of deionized water, 2-3 parts of a dispersing agent and 0.3-0.5 part of a defoaming agent. According to the technical scheme, the overall corrosion resistance and impact resistance of the aluminum alloy pipe are remarkably improved.

The invention provides a PCBN composite material and a preparation method thereof.The preparation method comprises the steps that two or more of zirconium oxide, titanium nitride, silicon nitride, titanium diboride, silicon carbide, titanium carbide, titanium carbonitride, aluminum oxide and aluminum nitride are mixed, and ceramic composite powder is prepared; the CBN micro powder and a metal binding agent are subjected to ball milling and mixing, and CBN pre-composite micro powder is prepared; mixing the CBN pre-composite micro powder with the ceramic composite powder to obtain a premix, placing the premix in a mold for pre-pressing to obtain a blank piece, and then assembling the blank piece for sintering to obtain a PCBN composite material; the mass percentage content of the ceramic composite powder is 5%-40%, the mass percentage content of the metal binding agent is 15%-30%, and the mass percentage content of the CBN micro powder is 45%-65%. According to the method, the toughness and the stability of the PCBN cutter can be improved on the premise of low content of CBN (Cubic Boron Nitride).

The invention belongs to the technical field of aero-engine materials, and particularly relates to a high-temperature-resistant aero-engine blade and a preparation method thereof.According to the blade, titanium-aluminum alloy is adopted as a base body, and two novel materials including a core-shell structure self-healing reinforcement phase and a rare earth niobate ferroelastic protection compound are introduced, so that the high-temperature-resistant aero-engine blade is obtained; and the comprehensive performance of the blade in a high-temperature environment is remarkably improved. The core-shell reinforcement phase takes titanium diboride as a core and boron nitride as a shell, and can realize a self-healing function at a high temperature; the rare earth niobate compound has ferroelastic behavior and ultralow thermal conductivity through doping modification of tantalum and rhenium. The preparation process comprises the following steps: mixing the titanium-aluminum alloy powder, the reinforcing phase, the silicon carbide short fibers and the binder, carrying out spark plasma sintering molding, carrying out machining, applying the protective coating through plasma spraying, and finally carrying out heat treatment. According to the method, the process is simplified, and the prepared blade has excellent high-temperature resistance, oxidation resistance and mechanical property and is suitable for aero-engine hot end components.

The invention relates to the field of laser cladding powder, in particular to wear-resistant and corrosion-resistant laser cladding powder and a preparation method thereof. The laser cladding powder is used for solving the problem that a cladding layer formed by existing laser cladding powder is poor in abrasion resistance and corrosion resistance. According to the laser cladding powder, the carbon nano tube loaded lanthanum-yttrium oxide powder and the copolymer coated titanium diboride powder are added, and the carbon nano tube and the lanthanum-yttrium oxide have a synergistic effect to refine grains, so that the corrosion resistance of a cladding layer is improved, and the carbon nano tube has good wear resistance; after the surface of the titanium diboride powder is coated with the copolymer, the dispersity of the titanium diboride is improved, a product decomposed by the copolymer reacts with the titanium diboride under the action of laser to generate titanium carbide, and the wear resistance of a cladding layer is enhanced; the laser cladding powder is suitable for prolonging the service cycle of a mold, can be used for surface strengthening of mine equipment parts, enhances the wear resistance and corrosion resistance of the mine equipment parts, reduces the maintenance frequency of the equipment, and can provide an effective solution for surface strengthening of parts in various industrial fields.

The invention provides high-purity superfine titanium diboride and a preparation method thereof, and relates to the field of titanium diboride preparation. The method comprises the following steps: mixing boron oxide, titanium hydride, a carbon source, nano rare earth oxide and an organic solvent, and drying to obtain a mixture; in a vacuum environment, performing first roasting on the mixture to obtain a first roasted material; and in an oxygen-containing atmosphere, carrying out second roasting on the first roasting material to obtain the high-purity superfine titanium diboride. In the first roasting process, boron oxide, titanium hydride and a carbon source are completely melted and fully contacted, then further, the carbon source forms a carbon skeleton, the contact area between the melted boron oxide and titanium hydride and the carbon skeleton is further enlarged, liquid-liquid mixing and the increase of the contact area can reduce the reaction kinetic conditions, the reaction temperature is greatly reduced, and the reaction time is greatly shortened. The particle size of the generated titanium diboride is reduced, and the molten boron oxide and titanium hydride react on the porous carbon skeleton in a liquid-liquid form to generate the high-purity superfine titanium diboride.

The invention relates to the technical field of material surface engineering and metallurgical equipment, in particular to a composite coating for prolonging the service life of a crystallizer copper plate and a plasma spraying preparation method thereof.The composite coating comprises, by mass, 35%-55% of chromium, 20%-55% of nickel, 5%-10% of titanium diboride, 0.1%-0.3% of niobium and the balance chromium carbide and inevitable trace impurity elements. According to the invention, titanium diboride and chromium carbide are used as main hard reinforcing phases, so that the coating shows excellent wear resistance at normal temperature and high temperature; a hollow graphite electrode is adopted in the spraying process, plasma arc is generated, and meanwhile an ablation product (carbon) provides a carbon source for formation of chromium carbide; the titanium powder and the boron powder are subjected to an in-situ reaction in a plasma arc to generate titanium diboride, and the in-situ synthesis technology enables hard phase particles to be fine and uniformly distributed, and forms a firm interface with a metal binding phase, so that the problems of interface pollution and weak combination caused by the addition of the hard phase are avoided.

This invention discloses a coating for sand casting of aluminum-lithium alloys and its preparation method. The coating comprises a surface layer in contact with the sand mold and a top layer in contact with the melt. The surface layer material is an alcohol-based zirconium oxide coating containing graphene, and the top layer coating is an alcohol-based boride coating containing titanium diboride and zirconium diboride. This invention effectively improves the coating density and heat transfer rate by doping graphene with metal boride nanoparticles. Using graphene, ceramic materials, and metal borides as aggregates and dopants effectively suppresses the burn-off of light elements such as Li, reducing subcutaneous pinholes and porosity defects in the casting. Using zirconium oxide powder as aggregate increases nucleation sites, effectively improving the quality of non-ferrous metal castings.

The invention provides a prismatic titanium diboride reinforced boron nitride-based conductive ceramic evaporation boat and a preparation method thereof, and belongs to the technical field of ceramic evaporation boats. The step of preparing the boron nitride matrix comprises the following steps: adding boron nitride powder into a nitric acid solution to obtain pretreated boron nitride powder; adding the pretreated boron nitride powder into absolute ethyl alcohol, adding tetrabutyl titanate and deionized water, adjusting the pH value to 4.0-4.3, stirring for 1.2-1.5 hours at the temperature of 30-32 DEG C, drying and calcining to obtain a boron nitride matrix; the prepared conductive ceramic evaporation boat is low in resistivity, high in strength, excellent in corrosion resistance and good in comprehensive performance.

The invention discloses a four-phase composite ceramic heating element and a preparation method thereof, and relates to the technical field of ceramic heating materials, the composite ceramic heating element comprises the following components: 30%-40% of titanium diboride, 30%-40% of titanium carbide, 10%-28% of silicon carbide, 1%-12% of hexagonal boron nitride, 0.5%-3% of nano zirconium dioxide and 1%-4% of silicon nitride. A four-phase composite system of TiB2 (titanium diboride), TiC (titanium carbide), SiC (silicon carbide) and hBN (hexagonal boron nitride) is constructed, basic expansion reduction is achieved through the low expansion characteristic of SiC, thermal expansion mismatching stress between different phases is dispersed in combination with the interface regulation and control effect of an h-BN layered structure, compared with an existing ternary system, the minimum thermal expansion coefficient is reduced to 5.8 * 10 <-6 > K <-1 >, and the thermal expansion coefficient is reduced to 5.8 * 10 <-6 > K <-1 >. And the interfacial compatibility is remarkably improved, and thermal stress is prevented from being gathered at the interface.

The invention relates to the field of refractory materials, in particular to a high-strength refractory material and a preparation method thereof, which are used for solving the problem that the existing traditional refractory material is low in strength and difficult to meet the high-standard requirement of modern industry on equipment. The high-strength refractory material comprises the following components: silicon carbide, tabular corundum, silicon powder, yttrium oxide, magnesium oxide, titanium diboride and a phosphorus-containing phenyl multi-epoxy-group binding agent, according to the preparation method, silicon carbide, tabular corundum, silicon powder, yttrium oxide, magnesium oxide and titanium diboride are taken as main raw materials, the main raw materials are endowed with excellent mechanical properties, and after a phosphorus-containing phenyl polyepoxy binding agent is added, the mechanical properties of the main raw materials can be further remarkably improved, so that the prepared refractory material has the characteristics of high strength, high temperature resistance and the like. The composite material shows high durability and reliability in a high-temperature environment, and is suitable for thermal protection in the high-temperature environment and internal construction of high-temperature equipment.

The application belongs to the technical field of refractory materials, and particularly relates to high-strength anti-stripping industrial kiln castable and a preparation method thereof. The industrial kiln castable provided by the application comprises white corundum, modified corundum, petalite, composite micropowder, modified micropowder, a binder and sodium hexametaphosphate. The white corundum, the modified corundum and the petalite are used as aggregates of the kiln castable, the composite micropowder and the nano micropowder are added to fill the aggregate gaps, and the porosity of the castable is reduced. The titanium dioxide is used to dope the corundum to form a solid solution, and a silica ceramic layer is coated on the surface of the nano titanium diboride by using a sol-gel method, so that the interface bonding force between the nano titanium diboride and the matrix is strengthened, the rigid reinforcing points are increased, and the high-temperature compressive strength is improved.

The invention relates to the technical field of metal-based composite materials, in particular to a preparation method of a titanium-based composite material with a bimodal non-uniform net structure. The invention provides a preparation method of a titanium-based composite material with a bimodal non-uniform net structure, which comprises the following steps: mixing titanium alloy metal powder as a base material with nano titanium diboride, lanthanum hexaboride and a silicon powder reinforcement material through high-energy ball milling to obtain composite powder; a field-assisted sintering technology (FHP) is utilized, and a non-continuous reinforced titanium-based composite material (DRTiMCs) sintered blank is obtained; and carrying out heat preservation in a vacuum heat treatment furnace, and then carrying out a hot rolling experiment to obtain the DRTiMCs with the bimodal non-uniform network structure. The bimodal non-uniform net structure is composed of micron TiBw, nano TiBw, nano La2O3 and nano silicide, DRTiMCs of the bimodal non-uniform net structure have excellent strength and ductility, the tensile strength reaches 1544 MPa and 1560 MPa, and the percentage elongation after fracture is 7.7% and 10.2%. The DRTiMCs provide a good working idea for further development and engineering application of the composite material in the fields of aviation and aerospace.

The application relates to a preparation method of a titanium diboride reinforced Ni60AA alloy coating on the surface of a continuous casting crystallizer copper plate, and belongs to the technical field of laser cladding. The method comprises the following steps: S1, pretreatment of the surface of a substrate; S2, preheating of the substrate; S3, preparation of a nickel-based cladding layer on the surface of the copper plate as a transition layer; S4, preparation of a reinforced deposition layer on the surface of the nickel-based transition layer; and S5, machining of the cladded workpiece to the required precision and size under working conditions. According to the application requirements of the application of the crystallizer copper plate under the challenges of high temperature, high wear and thermal cracking resistance, a functional gradient coating of titanium diboride reinforced Ni60AA composite material is designed. The coating realizes the gradual enhancement of the material performance from the substrate to the surface layer by regulating the laser directional energy deposition of the titanium diboride and nickel-based composite powder on the surface of the copper plate, so that the hardness, wear resistance and thermal cracking resistance of the deposition layer are significantly improved.

The present invention belongs to the technical field of coatings, and particularly relates to a one-coat material for engine bottom and its preparation method. The coating material uses polyaspartate resin, introduces a rigid polysulfone chain segment to restrict the excessive movement of the flexible chain segment of the resin and improve the crosslinking density of the polymer, thereby enhancing the intermolecular force, improving the efficiency of molecular chain transfer and dissipation of energy, and further improving the impact resistance of the material; introduces a hydrophobic polymethacrylate chain segment to endow the coating with good water resistance; fills with nano titanium diboride to improve the wear resistance and corrosion resistance of the coating. The coating prepared by the present invention is a low-VOC one-coat material, which not only has good adhesion of the primer and can firmly adhere to the surface of the substrate, but also has the properties such as water resistance and corrosion resistance of the topcoat; at the same time, it reduces the emission of VOCs, helps to reduce air pollution, and meets the requirements of environmental protection policies.

This invention relates to the fields of materials surface engineering and metallurgical equipment technology. Specifically, it relates to a composite coating for improving the lifespan of copper plates in crystallizers and its plasma spraying preparation method. The chemical composition, by mass percentage, includes: 35%-55% chromium, 20%-55% nickel, 5%-10% titanium diboride, 0.1%-0.3% niobium, with the balance being chromium carbide and unavoidable trace impurities. In this invention, titanium diboride and chromium carbide are used as the main hard reinforcing phases, enabling the coating to exhibit excellent wear resistance at both room temperature and high temperature. During the spraying process, a hollow graphite electrode is used, generating a plasma arc. Simultaneously, the ablation products (carbon) provide a carbon source for the formation of chromium carbide. Titanium powder and boron powder undergo an in-situ reaction in the plasma arc to generate titanium diboride. This in-situ synthesis technology results in fine and uniformly distributed hard phase particles, forming a strong interface with the metal binder phase, avoiding the problems of interface contamination and weak bonding caused by externally added hard phases.

The invention provides a positive electrode material and a preparation method thereof, an electrochemical device and electronic equipment, and particularly relates to the technical field of battery materials. The positive electrode material comprises a substrate and a coating layer, the substrate is a nickel-based layered oxide, and in the nickel-based layered oxide, the molar content of nickel is not less than 80% on the basis of the total amount of metal except lithium; the surface of the base body is coated with the coating layer, and the coating layer is a titanium diboride layer. The nickel-based layered oxide material is subjected to surface coating through titanium diboride, so that direct contact between an active material and an electrolyte can be reduced, generation of an interface side reaction is inhibited, and the cycle life of the battery is effectively prolonged; extraction of extra lithium elements from the interior of the matrix material can be avoided, the problem of low capacity caused by unbalance of stoichiometric ratio of lithium in the material is prevented, and the performance of the subsequent ternary positive electrode material is ensured to be fully exerted.

The application discloses a kind of powder preparation devices of titanium diboride for lithium battery preparation, including preparation container, controller, gas pressure gauge and servo motor, the output end of the servo motor passes through preparation container and is fixedly connected with ball screw nut pair, kettle wall contact component is arranged outside the ball screw nut pair, specifically relates to titanium diboride powder preparation technical field, the dispersion component rotation is realized when screw shaft axial rotation and is driven to realize the dispersion stirring operation of kettle body bottom material, the preparation rate of material can be promoted by dispersion component rotation and drives material stirring, and the purpose of kettle body wall scanning and dispersion component dispersion material can be completed under the premise that only one servo motor works, so that the purpose of promoting material preparation rate and reducing material loss can be simultaneously realized in energy-saving environment, effectively realize the purpose of reducing cost and improving yield and product quality.

This invention relates to the field of sliding materials for seismic isolation bearings, specifically disclosing a high-temperature resistant and wear-resistant composite material for building seismic isolation bearings and its preparation method. The high-temperature resistant and wear-resistant composite material for building seismic isolation bearings comprises the following raw material components in parts by weight: aliphatic polyketone, high-styrene resin-modified methyl vinyl silicone rubber, silicone resin, fluorosilicone rubber, polytetrafluoroethylene, high-temperature resistant filler, lubricant, compatibilizer, and coupling agent; the high-temperature resistant filler comprises the following raw material components: chopped basalt fiber, titanium diboride, silicon nitride, and ceramic powder. The high-temperature resistant and wear-resistant composite material for building seismic isolation bearings prepared by this invention synergistically improves the material's wear performance, thermal stability, and compressive modulus through mechanisms such as hard embedding of filler, elastic energy absorption of rubber and plastic, and self-lubricating interface construction, thus overcoming the shortcomings of existing technologies.

The invention belongs to the technical field of refractory materials, and particularly relates to a high-strength anti-stripping industrial kiln castable and a preparation method thereof. The industrial kiln castable provided by the invention is prepared from white corundum, modified corundum, petalite, composite micro powder, modified micro powder, a binding agent and sodium hexametaphosphate. White corundum, modified corundum and petalite are adopted as aggregates of the kiln castable, and composite micro powder and nano micro powder are added to fill gaps of the aggregates, so that the porosity of the castable is reduced; the corundum is doped with titanium dioxide to form a solid solution, and the surface of the nano titanium diboride is coated with a silicon oxide ceramic layer by a sol-gel method, so that the interface bonding force between the nano titanium diboride and a matrix is enhanced, rigid reinforcing points are increased, and the high-temperature compressive strength is improved.

The invention provides a preparation method of large-size titanium diboride powder, and belongs to the technical field of titanium diboride powder. The preparation method comprises the following steps: pretreating modified titanium dioxide and carbon black, and mixing and sintering. The step of modifying titanium dioxide comprises the following steps: adding boric acid and lithium carbonate into an ethanol solution, then adding titanium dioxide, and carrying out ultrasonic dispersion to obtain coated titanium dioxide; adding the coated titanium dioxide into a niobium nitrate solution, stirring for 20-30 minutes at room temperature, drying, and roasting for 110-120 minutes at the temperature of 580-600 DEG C to obtain modified titanium dioxide; the titanium diboride powder prepared by the method is uniform in size distribution, high in purity and good in stability.

The present invention discloses a TiB2-modified Mo-Si-B composite coating, its preparation method, and application, relating to the technical field of high-temperature alloy oxidation protection. The prepared composite coating comprises an inner layer, an intermediate layer, and an outer layer stacked in sequence; the inner layer is disposed on a substrate; and the titanium diboride (TiB2) in the outer layer can be uniformly distributed, regionally distributed, or gradiently distributed as needed. The present invention controls the coating structure and the distribution of modified elements by regulating the content, size, slurry composition, and coating method of the TiB2 introduced into the slurry, thereby obtaining a structurally matched composite coating.

The utility model discloses a glass cover plate, a display module and electronic equipment, and the glass cover plate comprises a base material layer; the titanium diboride layer is arranged on the upper surface of the base material layer; and the scandium oxide layer is arranged on one side, back to the base material layer, of the titanium diboride layer. The mechanical property and the wear resistance of the product are improved, and the optical property is also considered.

The invention discloses a multiphase ceramic material connector for a fuel cell, the multiphase ceramic material connector is divided into an upper surface layer, a middle matrix layer and a lower surface layer in the height direction, and the upper surface layer and the lower surface layer are both formed by compounding lanthanum hexaboride and hexagonal boron nitride. And the middle matrix layer is formed by compounding titanium diboride and hexagonal boron nitride. According to the invention, the composite ceramic material connector has excellent conductivity, can realize full-temperature-range conductivity from room temperature to high temperature, and has better mechanical properties and machinability.

The invention relates to the technical field of high-strength fittings, in particular to a preparation method of a high-strength fitting with a high-temperature-resistant coating. The preparation method comprises the following steps that S1, pretreatment is conducted, specifically, surface pretreatment is conducted on the fitting, and a base body is obtained; s2, preparing a plasma spraying coating, wherein the plasma spraying coating comprises the following raw materials: 304 stainless steel powder, chromium carbide, titanium carbide, titanium diboride, low-density polyethylene, aluminum, titanium nitride and yttrium oxide. According to the method, the surface of the base body can be coated with the paraffin, particle materials in the plasma spraying material serve as hard supports and are evenly dispersed in the 304 stainless steel powder material, particles are molten and embedded into the metal base body under the high-temperature effect of plasma spraying, and at the moment, the paraffin covering the surface of the base body can play a role in delaying combination; therefore, the plasma spraying material and the substrate are effectively combined in a stable high-temperature state, the stability of the coating is improved, and the wear resistance and high-temperature stability of the hardware fitting are effectively improved.

The present invention relates to a high-speed rail brake pad backplate structure and a pulse current welding method thereof. A unidirectional pulse current ignites a gradient-distributed high-entropy powder between the brake material and the backplate, forming a fluctuating weld surface. The unidirectional pulse current has a pulse frequency of 1250Hz-25000Hz. The high-entropy powder is composed, by mass percentage, of the following components: 7% titanium powder, 10% carbon powder, 10% titanium diboride powder, 40% copper powder, and 33% iron powder. Advantages include a simple welding method, strong adaptability, a wide parameter adjustment range, a secure connection between the brake material and the backplate after welding, excellent impact resistance, and the ability to adapt to varying connection performance requirements and product quality standards by varying the transition powder composition.

The invention discloses a medium-low temperature aluminum nitride ceramic heater and a preparation method thereof. The medium-low temperature aluminum nitride ceramic heater comprises an aluminum nitride ceramic substrate and a metal water-cooling base or a ceramic connecting support body which are sequentially arranged from top to bottom, wherein the metal water-cooling base or the ceramic connecting support body is used for supporting the aluminum nitride ceramic substrate; the aluminum nitride ceramic matrix is prepared from the following raw materials in percentage by mass: 85-95% of aluminum nitride, 3-5% of yttrium oxide, 0-10% of titanium nitride, 0-10% of titanium diboride, 0-5% of silicon carbide, 0-5% of tungsten carbide and 0-5% of titanium dioxide. According to the aluminum nitride ceramic heater, the formula of the aluminum nitride ceramic matrix of the aluminum nitride ceramic heater is optimized, other materials such as yttrium oxide, titanium nitride, titanium diboride, silicon carbide, tungsten carbide and titanium dioxide are introduced, and the content of each component is changed through formula blending, so that the purpose of performance optimization is achieved; the volume resistivity of the aluminum nitride ceramic heater in the medium and low temperature environment is effectively reduced, the adsorption force in the machining process is guaranteed to meet the requirement, the preparation technology is simple, operation is easy to control, and industrial production is facilitated.

The application belongs to the technical field of aero-engine materials, and particularly relates to a high-temperature-resistant aero-engine blade and a preparation method thereof. The blade adopts titanium-aluminum alloy as a matrix, introduces two new types of materials of a core-shell structure self-healing reinforcing phase and a rare earth niobate iron elastic protective compound, and significantly improves the comprehensive performance of the blade in a high-temperature environment. The core-shell reinforcing phase takes titanium diboride as a core and boron nitride as a shell, and can realize self-healing function at high temperature. The rare earth niobate compound is modified by doping tantalum and rhenium, and has ferroelastic behavior and ultralow thermal conductivity. The preparation process comprises the following steps: mixing titanium-aluminum alloy powder, the reinforcing phase, silicon carbide short fibers and a binder, and then performing discharge plasma sintering to form; after mechanical processing, a protective coating is applied by plasma spraying; and finally, heat treatment is performed. The method simplifies the process, the prepared blade has excellent high-temperature resistance, oxidation resistance and mechanical properties, and is suitable for aero-engine hot end components.

This invention relates to the field of electronic materials technology, specifically disclosing a titanium diboride ceramic electrode slurry, its preparation method, and a ceramic electrode. The titanium diboride ceramic electrode slurry is characterized by being prepared from the following components by mass percentage: 40%–89% titanium diboride powder, 10%–50% organic system, 1%–5% solid binder phase, and 0–5% additives. This invention uses titanium diboride powder as the functional phase. The physicochemical properties of titanium diboride are similar to those of the ceramic substrate. By bonding it to the ceramic substrate through high-temperature sintering, the sintering shrinkage behavior is more compatible, effectively reducing stress and defects during co-firing, and improving bonding strength and process stability.