610 results about "Titanium diboride" patented technology

The present invention relates to dry refractory compositions having excellent thermal insulation values. The dry refractory composition also has excellent resistance to molten metal and slag. The composition comprises a lightweight filler material selected from the group consisting of perlite, vermiculite, expanded shale, expanded fire clay, expanded silica-alumina hollow spheres, vesicular alumina, sintered porous alumina, alumina spinel Stone insulating aggregate, ettringite insulating aggregate, expanded mullite, cordierite and anorthite, and a matrix material selected from the group consisting of calcined alumina, fused alumina, sintered magnesia, fused magnesia, Silicon fume, fused silica, corundum, boron carbide, titanium diboride, zirconium boride, boron nitride, aluminum nitride, silicon nitride, sialonite, titanium dioxide, barium sulfate, zircon, sillimanite Group of minerals, pyrophyllite, fire clay, carbon and calcium fluoride. The composition may also contain dense refractory aggregates selected from the group consisting of calcined clay, calcined clinker, minerals of the sillimanite group, calcined bauxite, pyrophyllite, silica, zircon, baddeleyite, cordierite , corundum, sintered alumina, fused alumina, fused quartz, sintered mullite, fused mullite, fused zirconia, sintered zirconia mullite, fused zirconia mullite, sintered magnesia, Fused magnesia, sintered spinel and fused spinel refractory clinker. The composition also contains a heat activated binder and a dust suppressant.

A press plate for producing decorative laminate from resin impregnated paper, with alumina particles on its pressing surface, is coated with diborides selected from the group consisting of hafnium diboride, molybdenum diboride, tantalum diboride, titanium diboride, tungsten diboride, vanadium diboride, or zirconium diboride or mixtures thereof for making the press plate resistant to scratching. The preferred diborides are titanium and zirconium. The most preferred diboride is titanium. The color, gloss and surface appearance of laminate pressed with a titanium diboride coated press plate is substantially the same as laminate pressed with the press plate before coating.

A part made of a porous material containing carbon, in particular a C/C composite material, is protected against oxidation by being impregnated with a composition in an aqueous medium containing at least a phosphorous compound, elemental titanium, and boron or a boron compound other than titanium diboride, to form in the presence of oxygen and at least one alkali or alkaline-earth element M that catalyses oxidation of carbon, at least one P—O—Ti-M type association bonded by boron oxide B₂O₃ and trapping the element M.

The invention particularly relates to a WCoB ternary boride cermet material and a preparation method thereof. The adopted technical scheme is as follows: taking 5-30wt% of titanium diboride powder, 20-70wt% of tungsten carbide powder and 10-60wt% of cobalt powder as a mixing material; adding grinding ball and the mixing material into a ball mill, wherein, the mass ratio of the grinding ball to the mixing material is 4-10:1; then adding a grinding ball medium, and the liquid level of the grinding ball medium is 5-30mm higher than the layer of grinding ball and the mixing material; wetly milling for 10-100h by the ball mill; adding forming agent which accounts for 2-15wt% of the mixing material; mixing for 1-30h in the ball mill; granulating to obtain required powder; pressing the powder and sintering for 1-10h at the temperature of 1250-1500 DEG C to obtain the WCoB ternary boride cermet material. The WCoB ternary boride cermet material prepared by the method in the invention has low cost, simple process, higher abrasive resistance and high temperature resistant performance, and can satisfy higher service conditions.

The preparation method of high-purity TiB2 ceramic micropowder uses active metal reducing agent and cleap oxide raw material, and adopts the following steps: uniformly mixing TiO2, B2O3 and metal Mg powder, die-pressing and forming, placing the above-mentioned obtained material in a self-spreading high-temp. synthesis equipment with argon protection at normal temp. and normal pressure, lighting to make combustion, breaking combustion product, pickling so as to obtain the invented high-purity TiB2 ceramic micropowder. As compared with traditional carbon thermal reduced TiB2 ceramic powder saidinvention possesses the advantages of high purity, fine crystal grain, simple process and low energy consumption and time consumption, and as compared with SHS simple substance synthetic TiB2 ceramicpowder it is low in production cost.

The invention provides a high-plasticity aluminum-based composite material containing TiB2 particles and a preparation method thereof, and relates to an aluminum-based composite material and a preparation method thereof. The invention solves the problems of the prior art, such as poor plasticity and toughness and difficulty in secondary processing. The composite material contains (by volume) titanium diboride reinforcement particles 10-25 percent, aluminum particles 25-35 percent, and aluminum alloy matrix in balance. The preparation method comprises: (1) weighing titanium diboride reinforcement particles, aluminum particles and aluminum alloy matrix; (2) mixing by mechanical dry method to obtain a reinforcement powder; (3) placing the reinforcement powder in a die and compression-molding; (4) heating the die; (5) melting aluminum alloy and casting in the die; (6) applying a pressure on the die with molten aluminum and maintaining the pressure for a period of time and cooling; (7) demoulding and taking the cast ingot, that is reinforced aluminum-based composite material. The inventive aluminum-based composite material has high plasticity and good wear resistance and is adapted to secondary processing and machining.

The invention relate to a method for manufacturing a TiB<2> ceramic-reinforced wear-resistant surfacing flux-cored welding wire. The method aims to overcome shortcomings of existing flux-cored welding wires for wear-resistant surfacing. The method includes mixing metal powder with nonmetal powder; manufacturing a steel strip of the welding wire; adding the powder into the steel strip; and winding the steel strip to form a reel and packaging the reel to obtain the titanium diboride ceramic-reinforced wear-resistant surfacing flux-cored welding wire. The metal powder includes high-carbon ferrochrome powder, medium-carbon ferromanganese powder, ferromolybdenum powder, ferrosilicon powder and aluminum magnesium alloy powder, the nonmetal powder includes titanium diboride powder and graphite powder. The method has the advantages that the proportion of chemical compositions of a powder core of the flux-cored welding wire is reasonable and advanced, data are accurate, the TiB<2> ceramic-reinforced wear-resistant surfacing flux-cored welding wire is good in welding effect and high in quality, a welded joint is high in strength and good in wear-resistant performance, the hardness of a welded layer reaches HRC68.4, the wear-resistant performance is improved by 20%, and the titanium diboride ceramic-reinforced wear-resistant surfacing flux-cored welding wire is perfect.

The invention discloses a boracic titanium carbonitride based cermet tool bit material and the preparing method thereof. The tool bit material is based on carbonitride as the parent metal, characterized in the tool bit is composed of 0.005% to 0.25% by mass of boron, 6% to 11% by mass of C, 2% to 7% by mass of N, 35% to 70% by mass of Ti, 5% to 20% by mass of W, 0 to 12% by mass of Mo, 0 to 9% by mass of Ta, 1% to 7% by mass of Nb and 6% to 25% by mass of Co and Ni, wherein boron is prepared by adding one or more selected from single substance boron, titanium diboride, molybdenum boride, boron carbide and boric oxide which are in raw material power form. The tool bit material is prepared mainly by mixing the raw material, ball-milling dispersing, press forming, pre-sintering and high-temperature sintering, its high-temperature hardness, high-temperature strength, red hardness and inoxidability are obviously improved, the cutting speed is greatly increased, and the service life is notably entended.

A set of three low cost processes for removing boron, phosphorus, carbon and other metal and nonmetal impurities during the process of converting metallurgical grade silicon to electronic grade silicon. One process removes boron by using one or more high temperature solids removal devices to remove solid titanium diboride from a halosilane reactor effluent stream where the high temperature is preferably greater than 200 C., more preferably greater than 300 C. and most preferably greater than 400 C. A second process removes carbon as methane and phosphorus as phosphine by means of a membrane separator which processes all or part of a hydrogen recycle stream to recover hydrogen while rejecting methane and phosphine. A third process separates a high boiling halosilane stream into a large low impurity stream and one or more small high impurity streams some of which can be sent for halogen recovery.

The invention relates to a boron nitride-titanium diboride ceramic composite material and a preparation method thereof. The invention solves the problems that preparation of the traditional boron nitride-based ceramic composite material has high cost, long production period and difficulty in manufacturing products with large size. The boron nitride-titanium diboride ceramic composite material is prepared from carbonized boron powder, titanium powder and diluent powder. The boron nitride-titanium diboride ceramic composite material is prepared by the following steps of raw material drying, ball milling and mixing, blank production and self-propagating synthesis of the blank. The method has short production period and low cost ad can realize the production of products with large size.

The invention relates to a high-temperature high-pressure preparation method for titanium diboride and belongs to the technical field of preparation for ultra-hard ceramic material. The method comprises the following steps of: taking titanium powder and boron powder as raw materials or titanium powder and carbon tetraborate powder as raw materials; preparing titanium diboride material by performing the processes of mixing materials, pressing into blocks, assembling, high-temperature high-pressure synthesis, cooling and releasing pressure; performing on a high-pressure device, after keeping temperature at 1300-2000K and pressure at 1.0-6.0GPa for 1-3 hours, cooling and releasing pressure, thereby obtaining TiB2 bulk sintered body. The method provided by the invention is simple and easily implemented; no fluxing agent is adopted; the pure-phase TiB2 material is prepared by changing the proportion of the raw materials and the compounding condition; a result of X-ray detection shows that the product is pure TiB2 phase and no other impure phase is introduced; and according to the TiB2 material prepared by taking B4C as the raw material, the residual C element is capable of enhancing the toughness of TiB2 or the C element is simply separated from TiB2.

The invention relates to a method for preparing nano titanium diboride polycrystalline powder, which comprises the following steps of: mixing raw materials B2O3, TiO2, Mg and KBH4 uniformly, directly performing self-propagating reaction or performing self-propagating reaction after briquetting on the obtained mixed raw materials, and separating and purifying the self-propagating reaction product to obtain the nano titanium diboride polycrystalline powder. The method has the advantages that: (1) the method controls the heat effect of the reaction system, can save energy, reduce the self-propagating reaction temperature and inhibit side reaction and byproduct impurities, and greatly improves the purity of the product; (2) a large amount of gas formed in the reaction process inhibits product grain growth and sintering agglomeration and realizes grain size control of the nano TiB2; and (3) the method has simple reaction process and technique, is easy to control and suitable for industrial production, reduces the preparation cost for preparing the nano titanium diboride polycrystalline powder, and has great utility value.

The invention relates to copper-based powder dispersion ceramic as well as a preparation method and application thereof, and relates to the field of ceramic materials. The copper-based powder dispersion ceramic is prepared from an anti-abrasion constituent element as one of the raw materials, wherein the anti-abrasion constituent element comprises the following components by mass percent of all the raw materials: 1-5 percent of diamond powder and 1-5 percent of titanium diboride powder. The copper-based powder dispersion ceramic is high in impact pressure resistance, high in mechanical intensity, high in friction and abrasion resistance, long in service life, high in heat dissipation property and heat recovery property, high in high-temperature and low-temperature resistance, high in acid, alkaline, oil, water and the like corrosion resistance and the like.

The invention relates to macro aggregate ball shape metal ceramic nm compounding spray coating powder that contains titanium diboride 50-70wt%, cobalt 10-24wt%, chromium powder 6-13wt%, tungsten boride 5-11%, and the other is rare earth powder. Mixing the powder according to the ratio, wet method ball milling, centrifuging, pressure spraying graining, vacuum heat treatment technology and grain classifying process, the 20-45um and 45-75um granularity of powder would be gained. It has good abrasion resistant, high temperature resistant and corrosion resistance capability.

The invention provides a pelleting method of titanium diboride powder, which is suitable for preparing high-content high-strength large TiB2 particles for the wettable cathode of an aluminium electrolysis cell and is especially suitable for preparing the high-content high-strength large TiB2 particles for the wettable cathode of a deflector-type aluminium electrolysis cell. The method is characterized in that the high-content high-strength TiB2 particles are prepared by carrying out processes of kneading, shaping, roasting, crushing, sieving and the like on the titanium diboride powder as the main aggregate by adopting an organic binder or inorganic binder or a compound binder of the organic binder or the inorganic binder. The method has simple preparation process, controllable granularity and convenient application. The TiB2 particles prepared by the invention has the TiB2 content of 70-95 percent, the strength of 30-60MPa, and the resistivity of 0.5-40 muomega.m, and moreover, the TiB2 particles have small deformation and strong high temperature melt penetration resistance, can be completely wetted with aluminium liquid, realizes aluminium electrolysis production energy saving, prolongs the service life of the cathode of the aluminium electrolysis cell and reduces the aluminium electrolysis production cost.

The invention discloses a nano-ceramic composite spraying powder and a preparation method for the same. The nano-ceramic composite spraying powder comprises MCrAlTaY with definite components, nano-aluminium oxide and/or nano-yttrium oxide, and nano-titanium diboride, wherein in MCrAlTaY, M is Ni, Co or Ni-Co alloy; the MCrAlTaY and the nano-aluminium oxide and/or nano-yttrium oxide form an alloy oxide ceramic composite powder; and nano-titanium diboride is nano-metal ceramic powder. The preparation method comprises the following steps of: conveying the composite powder in a ball mill; adding a ball-milling medium and an organic adhesive; starting the ball mill and uniformly mixing; adding the ceramic powder; and starting the ball mill again until all the ceramic powder is uniformly wrapped on the particle surface of the composite powder, taking out the wet material and drying, and then obtaining the nano-ceramic composite spraying powder. The spraying powder is good in resistance to high-temperature oxidation and resistance to thermal corrosion, thus enhancing the toughness and the resistance to thermal fatigue strength of a coating; and the prepared powder is uniform and complete in coating shape and good in flowability, thus reducing spraying difficulty.

An aluminum-boron-carbon (ABC) ceramic-metal composite bonded to a metal or metal-ceramic composite other than ABC composite is made by forming a porous body comprised of particulates being comprised of a boron-carbon compound that has a particulate layer of titanium diboride powder on the surface of the porous body. The porous body is infiltrated with aluminum or alloy thereof resulting in the simultaneous infiltration of the TiB₂ layer, where the layer has an aluminum metal content that is at least about 10 percentage points greater by volume than the (ABC) composite. The ABC composite is then fused to a metal or metal-ceramic body through the infiltrated layer of titanium diboride, wherein the metal-ceramic body is a composite other than an aluminum-boron-carbon composite.

The invention relates to a wear-resistant and antifriction composite coating for aluminum alloy component surfaces. The coating is composed of, by weight, 13-15% of tungsten carbide powder, 18-20% of titanium diboride powder, 2.0-4.0% of cerium oxide powder, 3.0-5.0% of nickel-coated molybdenum disulfide powder and the balance nickel-base alloy powder, wherein the components are blended through adhesives and then are arranged on the aluminum alloy component surfaces in a laser cladding mode for forming the coating; in the nickel-coated molybdenum disulfide powder, the coating ratio of nickel is 71-73%; nickel-base alloy is composed of, by weight, 0.75-0.85% of C, 15-16% of Cr, 3.5-4.5% of Si, 3.0-4.0% of B, 14.5-15.5% of Fe and the balance Ni. The coating is high in wear resistance and low in friction coefficient and solves the friction and wear problems of aluminum alloy used for friction members of mechanical equipment at high loads or impact loads, the service life is prolonged, and the friction energy consumption is lowered.

A part made of a composite material containing carbon, having an open internal residual porosity is protected against oxidation by performing at least one stage in which an impregnating composition is applied, said impregnating composition containing at least one metal phosphate and titanium diboride. Efficient protection against oxidation is thus obtained at temperatures of more than 1000° C., also in the presence of a carbon oxidation catalyst and in a damp medium.

The present invention relates to CBN briquetting which contains CBN and matrix phase, the matrix phase combines with a second horniness phase and maximum titanium diboride, thereinto, the second horniness phase is selected from TiCN, TiC, TiN or its mixture and solid solution, the XRD peak height of thetitanium diboride peak (101)(after back ground emendation) is below 12 percent of the CBN peak (111) height.

An aluminum alloy and a method of casting. At least one of zirconium, scandium, a nucleating agent selected from the group consisting of metal carbides, aluminides and borides, and rare earth elements are added to the alloy while in the molten state such that upon solidification, the cast alloy exhibits improved hot tear resistance. In a particular form, the nucleating agent may be titanium diboride for grain refining. Other agents that can be used for grain refining include scandium, zirconium, silicon, silver and one or more rare earth elements. In the case of rare earth elements, mischmetal may be used as a precursor. Combinations of titanium diboride and at least one other agent are especially effective in reducing the incidence of hot tearing in products cast from the modified aluminum alloy.

The invention discloses a high-dispersive-distribution nano-TiB2 particle reinforced aluminum matrix composite material and a preparation method thereof. Firstly, a uniform-structure Al-TiB2 intermediate alloy is prepared through an ultrasound assisted mixed salt reaction (K2TiF6/KBF4-Al), wherein the average particle diameter of in-situ endogenous TiB2 particles is smaller than 100nm; the Al-TiB2 intermediate alloy and Al are used as raw materials, or Al-TiB2 intermediate alloy, Al and alloy elements are used as raw materials, the nano-TiB2 particles are introduced into an aluminum (alloy) matrix through an intermediate alloy dilution method, ultrasound agitation treatment is used as assistance, then pouring into a mold is performed, and ultrasound is applied during solidification (introduction through a bottom introduction method); and thus the high-dispersive-distribution nano-TiB2 particle reinforced aluminum matrix composite material is obtained.