The invention provides an Al-Nb co-coated ternary positive
electrode material and a preparation method and application thereof, and belongs to the technical field of ternary
lithium ion battery
nickel cobalt lithium manganate positive
electrode materials, the Al-Nb co-coated ternary positive
electrode material comprises a ternary positive
electrode material and a
coating layer, the surface of the ternary positive
electrode material is coated with the
coating layer, the
chemical formula of the ternary positive
electrode material is LiNixCoyMn1-x-yO2, x is larger than or equal to 0.8 and smaller than 0.95, y is larger than 0, and y is larger than 0. 1-x-y is not equal to 0, the
coating layer comprises Al2O3 and LiNbO3, and the
mass ratio of Al2O3 to LiNbO3 is 1: (1-0.4). According to the invention, the Al2O3 coating layer can be used as a barrier, so that direct contact between the
nickel-
cobalt-
manganese ternary positive electrode material and an
electrolyte is effectively reduced, possible side reactions are inhibited, and
transition metal ions in the
nickel-
cobalt-
manganese ternary positive electrode material are prevented from being dispersed into the
electrolyte; liNbO3 has relatively high Li < + >
conductivity, and as a nickel-cobalt-
manganese ternary positive electrode material coating layer, the LiNbO3 can effectively improve the transmission efficiency of
lithium ions, improve the electrochemical performance of the positive electrode material, enhance the interface stability and improve the high
temperature resistance at the same time.