3127results about "Macromolecular adhesive additives" patented technology

The invention discloses a pure bio-based polyhydroxyalkanoate adhesive as well as preparation and application thereof, and belongs to the technical field of degradable adhesives. According to the adhesive, polyhydroxybutyrate valerate or polyhydroxybutyrate hexanoate is used as a matrix, and the acid value reaches 2-15 mg KOH / g through molten end group activation; a reactive emulsifier with a hydrophilic-lipophilic balance value of 9-12 is introduced into a water phase, and the stable aqueous dispersion is prepared through phase inversion high-shear emulsification. The Z-average particle size of the dispersion is 0.12-0.30 [mu] m, and the content of the free surfactant is not higher than 30wt%. After the tackifying resin, the plasticizer and the vegetable wax are compounded, the bio-based carbon content of the obtained adhesive is not lower than 95%, and the volatile organic compound content is not higher than 100 mg / kg. The paper / paper heat sealing strength of the adhesive is not lower than 7.0 N / 15mm, the 180-degree peel strength is not lower than 7.5 N / 25mm, and the adhesive can pass repulping evaluation.

The invention relates to the technical field of folding screen supporting films, and particularly discloses a double-layer buffering supporting film for a flexible folding display screen and a preparation method of the double-layer buffering supporting film. The double-layer buffer supporting film for the flexible folding display screen sequentially comprises a release film layer, a first adhesive layer, a first stainless steel layer, a second adhesive layer, a second stainless steel layer and a protective film layer from top to bottom, the first adhesive layer and the second adhesive layer are prepared by curing the same pressure-sensitive adhesive composition; the pressure-sensitive adhesive composition is prepared from the following raw materials: acrylate copolymer, hydrogenated rosin glyceride, hyperbranched polyesteramide-dopamine conjugate, acylhydrazone bond modified siloxane, a curing agent and a silane coupling agent; the protective film layer comprises the following raw materials: PET particles, nano silicon dioxide, an ethylene-vinyl acetate copolymer and an antioxidant. The double-layer buffer supporting film has the advantages of being high in supporting rigidity and interlayer peel strength, and serious folds caused by long-term repeated folding of the folding screen can be relieved.

The invention relates to the field of adhesives, in particular to a structural adhesive epoxy composition and a preparation method thereof. The structural adhesive epoxy composition is prepared from the following raw materials: epoxy resin, a toughening agent, a reinforcing agent, filler, a latent curing agent, a latent accelerant, a chemical foaming agent, a physical foaming agent and the like. Finally, the epoxy composition prepared by the invention can be used as a structural adhesive raw material, has ultrahigh expansion rate, low-temperature rapid curing capacity and structural adhesive property, and also has good mechanical properties and excellent comprehensive application effect, so that the complex requirements of the application field of the prior art on the structural adhesive raw material are met.

The invention provides a self-repairing EVA adhesive film and a preparation method thereof, and relates to the technical field of solar photovoltaic module packaging. According to the self-repairable EVA adhesive film disclosed by the invention, through Diels-Alder reactive group grafting and silane coupling agent microencapsulation technologies, a dual self-repairing mechanism of a photovoltaic module packaging adhesive film is realized, and the dual self-repairing mechanism comprises physical rearrangement repairing and chemical bonding repairing; while high light transmittance (more than or equal to 90%) and bonding strength (more than or equal to 96 N / cm) are maintained, the aging resistance (delta YI is less than or equal to 3) of the EVA adhesive film is remarkably improved, the service life of the EVA adhesive film is remarkably prolonged, and the problems that a traditional EVA adhesive film is easy to age in an extreme environment and is easy to suffer from micro damage caused by mechanical stress are solved; the preparation process disclosed by the invention is compatible with the existing production line, and has a relatively high industrial application value.

The invention relates to the technical field of conductive glue, in particular to polyurethane modified silicone rubber, sprayable conductive glue and a preparation method thereof. The polyurethane modified silicone rubber is prepared from the following components in parts by weight: 50 to 150 parts of vinyl silicone oil, 20 to 50 parts of polyurethane powder and 5 to 15 parts of compatilizer, the sprayable conductive glue comprises the following components in parts by weight: 20-40 parts of conductive particles, 5-15 parts of hydrogen-containing silicone oil, 50-150 parts of polyurethane modified silicone rubber, 1-10 parts of a coupling agent, 1-5 parts of a catalyst, 1-2 parts of an inhibitor, 40-90 parts of a diluent and 1-2 parts of a defoaming agent, compared with traditional silicone rubber, the polyurethane modified silicone rubber provided by the invention is high in mechanical strength and not easy to tear, when the polyurethane modified silicone rubber provided by the invention is used for preparing sprayable conductive glue, a conductive layer formed by the conductive glue is excellent in conductivity, and meanwhile, the mechanical property is also remarkably improved.

The invention belongs to the technical field of conductive adhesives, and particularly relates to a salt-fog-resistant waterborne conductive adhesive and a preparation method thereof.The salt-fog-resistant waterborne conductive adhesive is mainly prepared from, by weight, 5-10 parts of salt-fog-resistant waterborne polyurethane; 5 to 10 parts of water-based tackifying resin; 30 to 50 parts of conductive silver powder; 10 to 20 parts of ethanol; 2-10 parts of an anti-hydrolysis agent; and 10-30 parts of deionized water. According to the salt-fog-resistant aqueous conductive adhesive, polyurethane resin with polytetrahydrofuran alcohol and polycaprolactone polyol as main structures is used as matrix resin, a system is endowed with excellent water resistance and salt-fog resistance, the salt-fog-resistant aqueous conductive adhesive shows outstanding hydrolysis-resistant stability after being cured, and the salt-fog-resistant aqueous conductive adhesive and the conductive silver powder have a synergistic effect, so that the anti-settling performance is effectively improved.

The invention discloses a high-toughness conductive and thermal-conductive epoxy adhesive, a preparation method thereof and a conductive film, and belongs to the technical field of conductive materials. Comprising the following raw material components in parts by weight: 100 parts of epoxy resin, 4-25 parts of a latent curing agent, 0.5-5 parts of an accelerant, 200-600 parts of conductive filler, 5-15 parts of an epoxy-terminated polyurethane flexibilizer, 5-20 parts of a core-shell flexibilizer, 5-10 parts of a nitrile rubber flexibilizer, 2-10 parts of a reactive diluent, 0.5-2 parts of a coupling agent and 20-50 parts of a solvent. Through compounding of the over-end epoxy type polyurethane flexibilizer, the core-shell flexibilizer and the nitrile rubber flexibilizer, the prepared conductive adhesive has excellent toughness and bonding characteristics, and meanwhile, the shrinkage stress and thermal stress in the curing process can be reduced.

The application belongs to the technical field of conductive glue, and particularly relates to a conductive glue, a preparation method and application thereof, wherein the conductive glue is made of the following raw materials in parts by weight: 40-60 parts of synthetic acrylic resin, 5-15 parts of epoxy resin, 25-45 parts of conductive filler, 5-15 parts of latent curing aid, 80-120 parts of diluent and 5-8 parts of auxiliary agent. By adding the latent curing aid, the application can reduce the potential possibility of the reaction of the acrylic resin and the epoxy resin at room temperature, thereby improving the storage effect of the conductive glue, improving the overall performance of the electronic product and meeting different application scenarios with different requirements. The preparation method directly mixes the raw materials such as the acrylic resin, the epoxy resin, the conductive filler, the auxiliary agent, the diluent and the latent curing aid uniformly in the preparation process without the need of separation and storage, thereby reducing the production cost, simplifying the use process of the user, improving the production efficiency of the conductive glue and the product quality.

The invention discloses a high-temperature-resistant tough epoxy resin adhesive and a preparation method thereof, and relates to the technical field of epoxy resin, the high-temperature-resistant tough epoxy resin adhesive comprises the following components by mass: 30-60 parts of epoxy resin, 15-40 parts of a modified curing agent, 5-20 parts of a flexibilizer, 8-35 parts of an inorganic filler, 1-5 parts of a coupling agent, and 0.5-3 parts of an antioxidant; the epoxy resin is formed by compounding bisphenol A epoxy resin and novolac epoxy resin according to the mass ratio of (1-3): 1; the modified curing agent is prepared by modifying an imidazole curing agent with a silane coupling agent. The problem that high temperature resistance and toughness of an epoxy resin adhesive are difficult to consider at the same time can be solved.

The invention discloses an electrolytic adhesive, an electrolytic cotton adhesive tape and a preparation method of the electrolytic adhesive. The electrolytic cotton adhesive tape comprises the following components in parts by weight: 5-10 parts of 1, 1 '-ferrocene diformyl chloride, 10-15 parts of acrylic acid beta-cyclodextrin ester, 3-8 parts of polyethylene glycol diglycidyl ether, 10-20 parts of ionic liquid, 1.5-3 parts of a cross-linking agent, 10-15 parts of tackifying resin and 0.5-1.5 parts of an initiator, and a polymer matrix comprises an acrylic acid-hydroxypropyl acrylate copolymer and acrylic acid-2-ethylhexyl ester. Comprising an adhesive layer and an adhesive tape base layer, the adhesive layer is prepared from the electrolytic adhesive, and the adhesive tape base layer is prepared from acrylic foam; the obtained electrolytic cotton adhesive tape has high initial adhesion and viscosity strength after power-on and power-off re-adhesion.

The invention provides an environment-friendly water-based acrylic emulsion adhesive without containing an organic solvent. The environment-friendly water-based acrylic emulsion adhesive is prepared from the following raw materials: 55-60 wt% of eleostearic acid hydroxyethyl acrylate (TMA), 15-25 wt% of butyl acrylate (BA), 3-10 wt% of acrylic acid (AA), 2-5 wt% of a cross-linking agent, 3-8 wt% of modified soil and 0.5-1 wt% of an initiator as a solid phase; the liquid phase is deionized water, and the environment-friendly water-based acrylic emulsion adhesive is prepared through semi-continuous emulsion polymerization. The prepared environment-friendly water-based acrylic emulsion adhesive is high in biodegradability and low in VOC content, has the mechanical property matched with that of a traditional acrylic emulsion adhesive and also has the self-repairing capacity, waste materials can be treated by changing the temperature or pH condition, the environment-friendly water-based acrylic emulsion adhesive can be recycled for multiple times, and the recycling cost is reduced.

The invention discloses a polyurethane modified epoxy resin adhesive as well as a preparation method and application thereof, and the polyurethane modified epoxy resin adhesive is prepared from the following components in parts by mass: 7-10 parts of E51 type bisphenol A diglycidyl ether, 3.5 parts of a phenolic aldehyde amine T31 curing agent and 1-3 parts of synthetic polyurethane, the synthetic polyurethane is prepared from polyether triol, polyether amine, isophorone diisocyanate and glycerol carbonate, and a blending system of the synthetic polyurethane and bisphenol A diglycidyl ether is adopted to be subjected to covalent crosslinking with phenolic aldehyde amine T31, so that the adhesive has high toughness and strength guarantee; the synthetic polyurethane prepared by the method is obtained through simple, green and efficient solvent-free synthesis, and the synthesized product has certain fluidity at room temperature, so that the subsequent stirring preparation process of an adhesive is facilitated. And a solvent-free synthesis method is adopted, so that the use of a toxic organic solvent in the traditional polyurethane synthesis process is avoided, and the synthesis process is greener.

The present invention relates to the technical field of tackified adhesive films and specifically to a tackified adhesive film. The tackified adhesive film comprises a substrate layer and a UV-tackified adhesive layer applied onto the substrate layer. The UV-tackified adhesive layer is prepared by using a modified polyester resin, which is obtained by the graft polymerization of a hydroxyl-terminated polyester resin, butyl methacrylate, and isocyanatoethyl methacrylate, as a main resin and mixing the main resin with a tackifying resin, a photo-curing agent and the like. The UV-tackified adhesive layer has relatively high cohesive strength and relatively good adhesion to a PET substrate. Before a UV-induced tackification reaction, an initial peel force is not significantly increased with the extension of standing time, so that an adhesive tape can be easily removed without causing damage and contamination such as residual adhesive to an adherend . After the UV-induced tackification reaction, the modified polyester resin can improve the bonding strength between the adhesive tape and the adherend.

A substrate-conveying support tape includes: a support film; a primer layer provided on the support film; and a temporary fixing material layer provided on the primer layer, in which the support film is a polyimide film, the temporary fixing material layer contains a thermoplastic resin, and the primer layer contains at least one selected from the group consisting of a silane coupling agent having an epoxy group or a ureido group, an epoxy resin, a polyurethane rubber, and an acrylic rubber having an acid value of 5 mgKOH / g or more.

The invention discloses a high-performance conductive adhesive doped with conductive nanoparticles, and belongs to the technical field of conductive adhesives. The high-performance conductive adhesive provided by the invention is prepared from the following raw materials in parts by weight: 50 to 100 parts of vinyl liquid silicone rubber, 100 to 400 parts of modified silver coated copper powder, 1 to 10 parts of nano silver powder I, 1 to 10 parts of epoxy silane modified prepolymer, 3 to 30 parts of hydrogen-containing silicone oil, 0.1 to 5 parts of platinum catalyst and 0.05 to 1 part of inhibitor. The silver-coated copper powder and the epoxy silane are modified, so that the conductivity and the binding power of the conductive adhesive are greatly improved, and the epoxy silane modified prepolymer can form strong covalent bond combination with the surface of an adhered object through a high-density epoxy group of the epoxy silane modified prepolymer; the nano-silver bulges on the surface of the modified silver coated copper powder increase the effective contact area and the number of contact points among the conductive filler particles, so that the conductive adhesive has the characteristics of high conductivity, low resistance, high adhesive strength and strong toughness.

The invention discloses a high-temperature-stripping-resistant epoxy structural adhesive as well as a preparation method and application thereof, and belongs to the technical field of high-performance composite materials. The epoxy structural adhesive comprises bisphenol A type epoxy resin, novolac epoxy resin, polysiloxane-polyurethane modified epoxy resin, core-shell modified epoxy resin, PEEK ultrafine powder and other components, and through mutual cooperation of all the components, the problems that in a high-temperature service environment, the adhesive layer modulus of traditional adhesive is rapidly attenuated, and a bonding interface is prone to failure are solved; the epoxy structural adhesive provided by the invention has both rapid curing and heat resistance, is stable in interface bonding, has the highest modulus of 1.28 GPa at 80 DEG C, the highest peel strength of 7.8 N / mm at 80 DEG C, and a damage mode of cohesion or high-proportion mixed damage, and is especially suitable for structural bonding requirements of harsh scenes such as peripheral structures of automobile engines, high-temperature areas of electronic equipment and the like.

The invention relates to the technical field of fire extinguishing microcapsules, in particular to a high-airtightness perfluorohexanone fire extinguishing microcapsule and a preparation method and application thereof.The perfluorohexanone fire extinguishing microcapsule comprises a composite shell layer and a fire extinguishing core, and the composite shell layer is made of ethylene-vinyl alcohol copolymer resin and silicon dioxide nanoparticles; the fire extinguishing core is a perfluorohexanone fire extinguishing agent and is applied to preparation of indoor fire extinguishing pastes, fireproof coatings and polyurethane adhesive materials. According to the perfluorohexanone fire extinguishing microcapsule disclosed by the invention, the diffusion of low-polarity perfluorohexanone is effectively prevented by utilizing the strong hydrogen-bond interaction between hydroxyl groups in the ethylene-vinyl alcohol copolymer resin, and especially under the condition of relatively high temperature, the perfluorohexanone fire extinguishing microcapsule has a good fire extinguishing effect. The problem that an existing perfluorohexanone fire extinguishing microcapsule is poor in long-term air tightness under the condition of high encapsulation efficiency is effectively solved, and meanwhile harmful substances such as formaldehyde cannot be generated.

The invention relates to a counter hot melt adhesive material with high viscosity, and belongs to the technical field of hot melt adhesives. The counter hot melt adhesive material with high viscosity provided by the invention is prepared from the following raw materials in parts by weight: 41.5 to 42.5 parts of TPU, 55.5 to 56.5 parts of EVA and 1 to 3 parts of functional aids, and the functional aids comprise POE-g-MAH, a tackifying system, nano boron nitride with the surface grafted with a silane coupling agent, an antioxidant 1076, dibenzoyl peroxide, epoxy-terminated silicone oil and white mineral oil. According to the counter hot melt adhesive material provided by the invention, all the components cooperate with one another, so that the counter hot melt adhesive material can still keep relatively high viscosity in a humid and hot environment, and the requirements of practical application are met.

The present invention relates to an adhesive composition for a polyester tire cord, a method for preparing a polyester tire cord, and a tire cord comprising the same, according to the present invention, when the polyester tire cord is prepared, the adhesive composition can be used for manufacturing a polyester tire cord, according to the present invention, the binding force between polyester fibers and a first treatment liquid can be increased by treating with the first treatment liquid containing a salt containing an anionic functional group, and then the crosslinking density can be increased by treating with a second treatment liquid containing an isoprene rubber latex, thereby not only having excellent high-temperature adhesive force, but also having excellent water resistance. And no harmful substances are used, so that the environment-friendly property is realized. In addition, uniform adhesion of the processing liquid is achieved by minimizing the influence caused by the external environment, thereby reducing the manufacturing manufacturability and the production cost. The polyester tire cord prepared as above can exhibit high heat-resistant adhesive force, rubber coverage, and excellent heat resistance characteristics.

The invention discloses a wear-resistant environment-friendly PET base material adhesive tape and a preparation method thereof, and belongs to the technical field of adhesive tapes, raw materials comprise a PET adhesive tape film and an EB curing modified adhesive, the surface of the modified PET adhesive tape film subjected to corona treatment is coated with the EB curing modified adhesive, then electron beam radiation curing is carried out, the absorbed dose of electron beams is 38-42 kGy, and the EB curing modified adhesive is prepared. And then cooling, rolling and curing to obtain the wear-resistant environment-friendly PET base material adhesive tape. The modified PET adhesive tape film is prepared from the following raw materials: PET resin and modified polyolefin elastomer master batch; the EB curing modified adhesive is prepared from the following raw materials: butyl acrylate, 2-ethylhexyl acrylate, tripropylene glycol diacrylate, acrylate resin, urethane acrylate and starch modified core-shell microsphere powder. According to the mode, a modification process is added in the preparation process of the PET adhesive tape film and the adhesive, and finally the environment-friendly PET base material adhesive tape with excellent comprehensive performance is prepared.

The invention discloses a single-component high-heat-resistance type epoxy adhesive and a preparation method of the single-component high-heat-resistance type epoxy adhesive. The adhesive is prepared from the following components in parts by weight: 30 to 40 parts of N, N-4, 4 '-diphenylmethane bismaleimide; 50 parts of bisphenol F epoxy resin; 36.47 parts of 4, 4 '-diaminodiphenyl sulfone; 20 to 40 phr of phenyl glycidyl ether; 1 to 2 phr of two terminal type epoxy silicone oil; 4 to 6 phr of hydroxyl-terminated polyether sulfone; 10 to 20 phr of boron nitride, the surface of which is modified by gamma-glycidyl ether oxypropyl trimethoxy silane; and 1 to 3 phr of an adhesion promoter. According to the adhesive disclosed by the invention, the heat resistance, the mechanical property, the dimensional stability, the process adaptability and the like are synergistically improved, the use requirements of an aviation structural part on long-term service at 150-180 DEG C and an electronic packaging device on the condition of short-time reflow soldering at about 200 DEG C can be met, and the reliability of the adhesive in a high-temperature environment is remarkably improved.

The invention provides a composite photo-initiation system electronic adhesive as well as a preparation method and application thereof, and relates to the technical field of anisotropic conductive adhesive films. The adhesive comprises a thermoplastic resin solution, an acrylate monomer, epoxy resin, a polyfunctional oligomer solution containing a carbon-carbon double bond and an epoxy group, an insulating inorganic filler, conductive particles and a composite photoinitiator solution, wherein the composite photoinitiator is composed of a free radical photoinitiator and a cationic photoinitiator, and acrylate free radical chain polymerization and epoxy resin cationic ring opening polymerization are synchronously triggered through ultraviolet light; and the polyfunctional oligomer is used as a molecular bridge to bond the two-phase curing network to form an interpenetrating cross-linked structure. The electronic adhesive provided by the invention realizes low-temperature rapid curing for 1-15 seconds, the curing shrinkage rate is reduced to below 1%, the reliability defect caused by oxygen inhibition, high shrinkage rate and phase separation of a traditional single system is solved, and the electronic adhesive is suitable for low-temperature efficient packaging of high-precision electronic components.

The invention discloses a recyclable lawn and a preparation method thereof, and belongs to the technical field of artificial turfs. The lawn sequentially comprises artificial grass yarns, a base cloth layer and a back glue layer from top to bottom, the artificial grass yarns and the base cloth layer are made of polyolefin; the back adhesive layer is prepared from the following components in parts by weight: 4 to 8 parts of polyolefin elastomer, 10 to 20 parts of olefin block copolymer, 20 to 30 parts of hydrogenated styrene-butadiene copolymer, 8 to 12 parts of styrene-isoprene copolymer, 10 to 12 parts of butadiene-styrene rubber, 2 to 6 parts of ethylene-acrylic acid copolymer, 15 to 30 parts of plasticizer, 0.1 to 0.4 part of antioxidant, 3 to 6 parts of compatilizer and 2 to 4 parts of modified filler; according to the lawn, the artificial grass yarns, the base cloth layer and the gum layer are similar in component, so that the lawn can be conveniently and integrally recycled subsequently, the utilization rate of the lawn gum is increased, and resource waste is reduced.

The invention relates to the field of pouring sealants, and discloses a modified epoxy resin pouring sealant and a preparation method thereof, the pouring sealant comprises epoxy resin, a modified inorganic filler, a modified additive and an auxiliary agent; the modified inorganic filler is prepared by grafting a quaternized s-triazine derivative and an inorganic filler; the quaternized s-triazine derivative is prepared through the steps that 3, 5-diaminophenylboronic acid, cyanuric chloride, 3-chloropropyltrimethoxysilane and 1, 4-butanediamine are sequentially subjected to substitution to prepare a s-triazine derivative, then the s-triazine derivative reacts with N, N-dimethyl-1, 3-diaminopropane, and bromoethane is used for quaternization treatment. The modified additive is prepared from a modified bismaleimide monomer prepared from maleic anhydride and 5 (6)-amino-1-(4-aminophenyl)-1, 3, 3-trimethylindane and 1-methyl-4-isopropyl cyclohexene through a self-stabilization precipitation polymerization method, the prepared pouring sealant is high in tensile strength, good in impact resistance and good in mechanical property, and the prepared pouring sealant has the advantages of being good in mechanical property, good in mechanical property and good in mechanical property. Meanwhile, good heat resistance, flame retardance, dielectricity and antibacterial activity are achieved.

The invention relates to the technical field of binders, in particular to a lithium ion battery negative electrode binder and a preparation method thereof, the lithium ion battery negative electrode binder comprises the following raw materials by weight: 15-45 parts of a temperature resistant material, 10-20 parts of a toughening material, 6-10 parts of an anticorrosive filler, 50-150 parts of bisphenol epoxy resin and 1-5 parts of a reducing agent. According to the preparation method, side reactions existing in the preparation process of the lithium ion negative electrode battery are inhibited, the electrochemical stability, interface compatibility and processing performance of the lithium ion battery are improved, the binding force of the negative electrode binding interface of the lithium ion battery can be enhanced, a rigid-flexible interpenetrating network is formed, the fracture toughness of the binding agent is improved, and the service life of the binding agent is prolonged. Through the synergistic effect of fluorination modification and a rigid framework, the three-in-one performance of high adhesion, electrolyte resistance and high temperature resistance is achieved, cerium oxide nanoparticles can be subjected to oxidation reduction, free radicals are eliminated, electrolyte oxygenolysis is inhibited, and the problems that an adhesive is weak in adhesion force and poor in electrolyte corrosion resistance stability are solved.

The invention provides an organic silicon pouring sealant for a new energy automobile heater and a preparation method thereof, the organic silicon pouring sealant comprises a component A and a component B, the mass ratio of the component A to the component B is 1: 0.9-1.1; the component A comprises the following components in percentage by mass: 35%-45% of double-end vinyl silicone oil; 3-5% of modified silicone oil; 10%-20% of spherical silica powder; 35-45% of aluminum hydroxide; 0.1%-0.3% of fumed silica; 1%-2% of a molecular sieve; 0.3%-0.5% of a platinum catalyst; 0.1%-0.3% of carbon black; wherein the modified silicone oil is vinyl alkoxy terminated silicone oil. According to the technical scheme provided by the invention, hydroxyl silicone oil is subjected to alkoxy and vinyl end-capping modification, so that the organic silicon pouring sealant can form good bonding sealing with an aluminum alloy matrix and an electronic component when being cured at normal temperature, does not have obvious smell, and is convenient to use.

The invention relates to an organic silicon temporary bonding material as well as a preparation method and application thereof. The organic silicon temporary bonding material is prepared from the following components in parts by weight: 5 to 20 parts of hydrogen-containing polysiloxane, 5 to 10 parts of vinyl polysiloxane, 0.01 to 10 parts of dispersion promoting filler, 0.01 to 10 parts of adhesion promoting filler, 0.01 to 1 part of inhibitor, 0.001 to 1 part of catalyst and 30 to 58 parts of solvent. The organic silicon temporary bonding material provided by the invention is high in initial adhesion, good in heat resistance and chemical resistance, low in wafer warpage after bonding, small in total thickness deviation of gluing, and good in stripping property and cleaning removability.

The invention relates to the technical field of photovoltaic packaging materials, and discloses a butyl sealant for a self-repairing photovoltaic module and a preparation method of the butyl sealant. The butyl sealant is prepared from the following substances in parts by weight: 40 to 60 parts of modified butyl rubber, 20 to 35 parts of inorganic filler, 5 to 15 parts of tackifying resin, 2 to 8 parts of plasticizer, 0.5 to 2 parts of anti-aging agent, 0.3 to 1.0 part of bifunctional crosslinking monomer, 0.08 to 0.25 part of composite catalyst, 2 to 5 parts of microcapsule type repairing agent and 3 to 10 parts of drying agent. According to the invention, through the dual-mechanism design of a'sulfydryl-amino-silicon oxygen bond 'dynamic network and the microcapsule type repairing agent, the self-repairing performance and the aging resistance are synchronously and remarkably improved, and the contradiction that'the self-repairing performance and the aging resistance of a traditional material are difficult to consider at the same time' is solved. Tests show that the 12h repair rate of the sealant for 3mm scratches at 50 DEG C is greater than or equal to 98%, the tensile strength retention rate is greater than or equal to 92% after the sealant is subjected to damp-heat aging at 85 DEG C / 85% RH for 1000 h, and the sealant is superior to existing similar products.

The invention belongs to the technical field of photovoltaic packaging adhesive films, and provides an EVA photovoltaic packaging adhesive film and a preparation method and application thereof. The EVA photovoltaic packaging adhesive film is prepared from 85 to 100 parts of ethylene-vinyl acetate copolymer, 1 to 15 parts of PID (Potential Induced Degradation)-resistant master batch, 0.6 to 1.8 parts of cross-linking agent and 0.2 to 2 parts of auxiliary agent, wherein the anti-PID master batch is prepared from 50 to 100 parts of ethylene-octylene copolymer, 1 to 20 parts of modified MOFs (Metal-Organic Frameworks), 1 to 15 parts of compatibilizer and 1 to 15 parts of beta-cyclodextrin. According to the EVA photovoltaic packaging adhesive film, the aging resistance, the mechanical strength, the water resistance, the PID resistance and the like of the EVA photovoltaic packaging adhesive film can be improved when the EVA photovoltaic packaging adhesive film is applied to a photovoltaic module end, the power attenuation phenomenon caused by existing EVA photovoltaic adhesive films PID-p and PID-s is obviously reduced, the PID power attenuation phenomenon of the photovoltaic module is effectively reduced, the service life of a battery piece is prolonged, and the photoelectric conversion efficiency of the battery piece is improved.

The invention provides a negative electrode binder composition, a negative electrode plate and a secondary battery, aiming at the problem that an existing negative electrode binder cannot effectively inhibit volume expansion of a silicon negative electrode. The negative electrode binder composition comprises a polysaccharide compound, a compound containing a linear rigid chain and metal cations complexed with the polysaccharide compound, and the mass ratio of the polysaccharide compound to the compound containing the linear rigid chain to the metal cations is (0.5-10): (10-40): (0.02-0.5); the polysaccharide compound and the compound containing the linear rigid chain both contain carboxyl groups, the pH value of the negative electrode binder composition is 5-8, the carboxyl groups in the polysaccharide compound and the carboxyl groups in the compound containing the linear rigid chain are at least partially complexed with metal cations, and the polysaccharide compound complexed with the metal cations forms a double helix structure. According to the negative electrode binder composition disclosed by the invention, the polysaccharide compound and the compound containing the linear rigid chain form a self-recovery network structure, so that crushing of negative electrode material particles is effectively prevented, and a material interface is stabilized.