1522 results about "Acrylate polymer" patented technology

A hybrid film, comprising a first polymer film having a plasma-treated surface and a second polymer film having first and second surfaces, with the first surface of the second polymer film being disposed along the first plasma-treated surface of the first polymer film, has superior thermal and mechanical properties that improve performance in a number of applications, including food packaging, thin film metallized and foil capacitors, metal evaporated magnetic tapes, flexible electrical cables, and decorative and optically variable films. One or more metal layers may be deposited on either the plasma-treated surface of the substrate and/or the radiation-cured acrylate polymer. A ceramic layer may be deposited on the radiation-cured acrylate polymer to provide an oxygen and moisture barrier film. The hybrid film is produced using a high speed, vacuum polymer deposition process that is capable of forming thin, uniform, high temperature, cross-linked acrylate polymers on specific thermoplastic or thermoset films. Radiation curing is employed to cross-link the acrylate monomer. The hybrid film can be produced in-line with the metallization or ceramic coating process, in the same vacuum chamber and with minimal additional cost.

Embodiments of the invention provide analyte sensors having elements designed to modulate their chemical reactions as well as methods for making and using such sensors. In certain embodiments of the invention, the sensor includes an analyte modulating membrane that comprises a blended mixture of a linear polyurethane/polyurea polymer, and a branched acrylate polymer.

A composition and method for treating a wound with an inherently antimicrobial dressing. The dressing is a hydrogel containing from about 15 to 95 percent, and preferably from about 61 to 90 percent, by weight of a cationic quaternary amine acrylate polymer prepared by the polymerization of acryloyloxyethyl(or propyl)-trialkyl(or aryl)-substituted ammonium salts or acrylamidoethyl(or propyl)-trialkyl(or aryl)-substituted ammonium salts. The antimicrobial hydrogels are non-irritating to the wound, absorb wound exudate, and, due to the inherently antimicrobial properties, enhance the sterile environment around the wound. The hydrogels have sufficient adhesive properties that loose contact with the wound is assured but can also be removed without leaving any gel residue on the wound. The wound dressings are preferably formed on a substrate, such as a web or patch, for ease in application to and removal from the wound. If desired, additional antimicrobial or other pharmaceutically active agents can also be incorporated into the hydrogel structure.

Provided are a thermoplastic resin composition which is excellent in oil resistance, heat resistance, weatherability, impact resistance, transparency, and moldability, and which can be produced economically, an elastomer composition with low hardness and high tensile strength which is excellent in oil resistance and compression set, and a molded object produced by molding the thermoplastic resin composition or elastomer composition. The composition is produced by compounding a thermoplastic resin or an elastomer with a block copolymer having at least one methacrylic ester polymer block and at least one acrylic ester polymer block. Also provided are a process for producing a methacrylic ester-acrylic ester-methacrylic ester block copolymer which requires hardly any purification, which is excellent in heat resistance and weatherability, and in which the molecular weight and the molecular-weight distribution are controlled, and a methacrylic ester-acrylic ester-methacrylic ester block copolymer produced by the process.

The present invention relates to a method for preparing an acrylic ester polymer syrup by bulk polymerization, and more particularly, to a method for preparing an acrylic ester polymer syrup, which comprises the steps of: supplying a monomer solution and an initiator solution to a monomer solution reservoir and an initiator solution reservoir, respectively; supplying the monomer solution and the initiator solution to a complete-mixing type continuous reactor, while maintaining the dissolved oxygen in the monomer solution reservoir and the initiator solution reservoir at 0.0001 to 3 ppm, separately or after mixing prior to the supply; and performing bulk polymerization continuously while maintaining the solution mixture supplied to the continuous reactor at 70 to 150 ° C. and 1 to 10 atm, with a mean residence time of 30 to 240 minutes. In accordance with the present invention, an acrylic ester polymer syrup can be obtained with a degree of polymerization of 20 to 70% at a low polymerization temperature, even with a small amount of initiator. Productivity can be improved by reducing reaction time with the use of an initiator having a short half-life and polymerization can be performed very stably and continuously without gelation.

Medical devices having at least a portion thereof coated with a lubricious polymer are disclosed. The lubricious polymer can be, for instance, a hydrogel polymer, such as a quaternary amine acrylate polymer. To bond the lubricious polymer to the surface of the medical device, the medical device is first subjected to a solvent and a multi-functional monomer. The solvent causes the multi-functional monomer to become imbibed into the surface of the medical device. Thereafter, a polymer having lubricious properties is polymerized on the surface of the device. The multi-functional monomer reacts with the polymer coating securely affixing the polymer coating to the device.

Pressure-sensitive adhesives for optical films exhibit high cohesion, excellent re-workability, adhesion properties, heat resistance and durability without chemical crosslinking.

A pressure-sensitive adhesive contains an acrylic triblock copolymer (I) at not less than 60% by mass based on the total mass of all solids contained in the pressure-sensitive adhesive, the acrylic triblock copolymer being represented by the formula A1-B-A2 wherein: A1 and A2 are each independently an alkyl methacrylate polymer block having Tg of not less than 100° C. and B is an acryl acrylate polymer block having Tg of not more than −20° C.; the content of the polymer block B is 50 to 95% by mass; Mw is in the range of 50,000 to 300,000; and the molecular weight distribution is in the range of 1.0 to 1.5. In a preferred embodiment, the acrylic triblock copolymer (I) is a combination of an acrylic triblock copolymer (Ia) having Mw of 50,000 to less than 100,000 and an acrylic triblock copolymer (Ib) having Mw of 100,000 to 300,000, in a mass ratio (Ia):(Ib) of 45:55 to 75:25.

A composition and method for treating a wound with an inherently antimicrobial dressing. The dressing is a hydrogel containing from about 15 to 95 percent, and preferably from about 61 to 90 percent, by weight of a cationic quaternary amine acrylate polymer prepared by the polymerization of acryloyloxyethyl(or propyl)-trialkyl(or aryl)-substituted ammonium salts or acrylamidoethyl(or propyl)-trialkyl(or aryl)-substituted ammonium salts. The antimicrobial hydrogels are non-irritating to the wound, absorb wound exudate, and, due to the inherently antimicrobial properties, enhance the sterile environment around the wound. The hydrogels have sufficient adhesive properties that loose contact with the wound is assured but can also be removed without leaving any gel residue on the wound. The wound dressings are preferably formed on a substrate, such as a web or patch, for ease in application to and removal from the wound. If desired, additional antimicrobial or other pharmaceutically active agents can also be incorporated into the hydrogel structure.

The invention discloses a new method for preparing water-based polyacrylate modified polyurethane dispersion (PUD), which mainly comprises the following steps: (a) preparing an acrylate polymer or copolymer emulsion; (b) preparing a polyurethane prepolymer with carboxyl, and neutralizing the carboxyl; and (c) under the condition of high-speed stirring or other mechanical mixing, adding a polyacrylate emulsion into the polyurethane prepolymer for carrying out dispersion and chain extension. If unsaturated acetoacetate-based compounds are added when the polyacrylate emulsion is prepared, the prepared water-based polyacrylate modified PUD has self-crosslinking property.

Provided is a layered body including a substrate to be ground and a support, where the substrate may be ground to a very small (thin) thickness and can then be separated from the support without damaging the substrate. One embodiment is a layered body including a substrate to be ground, a joining layer having a curable acrylate polymer and a curable acrylate adhesion modifying agent in contact with the substrate to be ground, a photothermal conversion layer having a light absorbing agent and a heat decomposable resin, and a light transmitting support. After grinding the substrate surface which is opposite that in contact with the joining layer, the layered body is irradiated through the light transmitting layer and the photothermal conversion layer decomposes to separate the substrate and the light transmitting support.

Medical devices having at least a portion thereof coated with a lubricious polymer are disclosed. The lubricious polymer can be, for instance, a hydrogel polymer, such as a quaternary amine acrylate polymer. To bond the lubricious polymer to the surface of the medical device, the medical device is first subjected to a solvent and a multi-functional monomer. The solvent causes the multi-functional monomer to become imbibed into the surface of the medical device. Thereafter, a polymer having lubricious properties is polymerized on the surface of the device. The multi-functional monomer reacts with the polymer coating securely affixing the polymer coating to the device.

Moisture-curing binder comprising

• • a) a silane-modified polyurethane and
  • b) a silane-modified acrylate polymer,

with the binder being able to cure in the presence of moisture.

The invention discloses a double-layer coated essence microcapsule and a preparation method thereof. The essence microcapsule takes an oil soluble liquid essence as a capsule core, a gelatin modified amino resin composite material as a first-layer capsule wall and an acrylate polymer as a second-layer capsule wall, wherein a grafting transition area is formed by graft copolymerization of gelatin and acrylate between the first-layer capsule wall and the second-layer capsule wall. The preparation method comprises a step of prepolymer compounding, emulsification dispersion, microcapsule continuous double-layer coating and post-treatment. Compared with a single-layer coated microcaposule, the essence microcapsule has the advantages that the slow release performance, the heat resistance performance and the capsule wall material mechanical property are greatly improved, and the essence microcapsule can be used for most of microencapsulated essence products processed by heat extrusion molding of high molecular materials.

The invention provides a fluorin-containing POSS acrylate polymer. The fluorin-containing POSS acrylate segmented polymer resin has a structure shown by M'-M-M', wherein the M' is a fluorin-containing acrylate structure unit; and M is an irregular polymerization unit containing active group acrylate and POSS acrylate, and the fluorin-containing POSS is fluorin-containing polyhedral oligomeric silsesquioxane. The invention also provides a method for preparing the fluorin-containg POSS acrylate polymer and a paint containing the fluorin-containing POSS acrylate polymer. The preparation method adopts the POSS acrylate monomer with lower cost and fluorin-containing acrylate monomers to prepare the fluorin-containing POSS acrylate polymer with fluorin-containing acrylate structure units distributed on the two ends of the polymer by controlling the adding sequence of the fluorin-containing acrylate monomers, and has the advantages of simple process and low cost; and the prepared paint has low surface energy and high fouling resistance.

A personal safety protective device that includes a lens and a support structure onto which the lens is secured. The lens includes a substrate and a hard-coat layer located on the substrate of the lens. The hard-coat layer has a low surface energy outer surface that is derived from a) an additive that includes at least one of i) a perfluoropolyether urethane that includes hydrolysable silane groups, and ii) an acrylate polymer that includes at least one perfluoropolyether moiety and at least one hydrolysable silane group, and b) a silsesquioxane-based hard-coat composition. The provision of such a lens on a personal safety protective device enables the lens to be durable to abrasion and to be easily cleaned without use of solvents that could shorten the service life of the lens.

The invention describes acrylic and methacrylic acid ester-based polymeric materials containing as flexibilizing and brittleness reducing agents 1-60% of C₄-C₈ polyalkylene or polyalkyldiene compounds, preferably having a molecular weight of 300-2100, and the use of such materials in dentistry and medicine.

A plastisol formulation which can be used for coatings of metal sheets, the coatings having high abrasion resistance, contains a) a plasticizer or mixture of plasticizers; and b) a mixture of polymer particles containing at least two components A and B; c) at least one member selected from the group consisting of fillers, coupling agents, stabilizers, desiccants, rheological additives, hollow bodies and mixtures thereof; wherein the polymer particles containing at least two components A and B have one of the following structures ba) a 2-stage structure, a 3-stage structure or multi-stage structure, or bb) a gradient polymer structure.

Hardcoat formulations are described that cure into interpenetrating crosslinked acrylate polymers and crosslinked epoxy polymers. The epoxy polymers can comprise polysiloxane moieties and/or aliphatic moieties. The acrylate polymers can comprise aliphatic moieties and/or urethane moieties. UV initiator compounds can be used to initiate the curing process upon exposure to UV light. The resulting hardcoat materials are found to exhibit desirable properties. The hardcoat material can be placed over sparse metal transparent conductive layers to provide protection to the conductive layers.

PCT No. PCT/FR97/01621 Sec. 371 Date May 15, 1998 Sec. 102(e) Date May 15, 1998 PCT Filed Sep. 15, 1997 PCT Pub. No. WO98/10801 PCT Pub. Date Mar. 19, 1998The invention concerns a novel hydrophile adhesive mass to be used for medical purposes characterised in that said hydrophile adhesive mass comprises: (a) 10 to 35 parts by weight of sequenced poly(styrene/olefin/styrene) copolymer, in particular poly(styrene/isoprene/styrene), (b) 20 to 50 parts by weight of a tackifier resin, (c) 2 to 15 parts by weight of an acrylate polymer with a glass temperature less than -20 DEG C., (d) 2 to 25 parts by weight of a plasticizer, in particular a plasticizing oil, (e) 20 to 50 parts by weight of a hydrocolloid, (f) 0.1 to 2 parts by weight of at least one antioxidant. The invention also concerns the use of this adhesive mass for making protective bandages, in particular for treating blisters, skin-deep dermo-epidermic lesions, exudative wounds and burns.

There is a tin-free curable composition having (A) one or more organic polymers having a reactive-silicon-containing group, wherein at least one polymer has a main chain skeleton selected from the group consisting of polyoxyalkylene polymers, saturated hydrocarbon polymers, and (meth)acrylic acid ester polymers; (B) from 0.001 to 20 parts by weight for 100 parts by weight of the organic polymer(s) (A) of a silanol condensation catalyst consisting of one or more metal amidine complexes and one or more amine carboxylate salts, (C) a crosslinker or chain extender chosen from an alkoxysilane, an alkoxysiloxane, an oximosilane, an oximosiloxane, an epoxysilane, an epoxysiloxane, an aminosilane, a carboxysilane, a carboxysiloxane, an alkylamidosilane, an alkylamidosiloxane, an arylamidosilane, an arylamidosiloxane, an alkoxyaminosilane, an alkaryaminosiloxane, an alkoxycarbamatosilane, an alkoxycarbamatosiloxane, and combinations of two or more thereof; and (D) at least one adhesion promoter chosen from a silane or siloxane other than the compounds listed under (C). There is also a cured polymer formed from the tin-free curable composition.