1637 results about "Carboxylate" patented technology

The present invention relates to a composition comprising more than 25 weight % (based on the weight of the composition) of one or more ethylene polymers having an M_w of 20,000 g/mole or more and at least 0.1 weight % of a liquid hydrocarbon modifier where the modifier has: 1) a viscosity index of 120 or more, and 2) an kinematic viscosity of 3 to 3000 cSt at 100° C., and 3) a pour point of −10° C. or less, and 4) a flash point of 200° C. or more; and wherein the modifier contains less than 5 weight % of functional groups selected from hydroxide, aryls, substituted aryls, halogens, alkoxys, carboxylates, esters, acrylates, oxygen, nitrogen, and carboxyl, based upon the weight of the modifier.

A process for forming a thermoplastic vulcanizate compromising the steps of dynamically vulcanizing a rubber within a blend that comprises the rubber and a thermoplastic polymer, where said step of vulcanizing is carried out by using a phenolic resin in the presence of a catalyst system formed by combining a metal halide and a metal carboxylate. Also, a thermoplastic vulcanizate having low moisture pick-up with a technologically useful cure.

There is provided an alcohol composition obtained by dimerizing an olefin feed comprising C6-C10 linear olefins to obtain C12-C20 olefins, followed by conversion to alcohols, such as by hydroformylation. The composition has an average number of branches ranging from 0.9 to 2.0 per molecule. The linear olefin feed preferably comprises at least 85% of C6-C8-olefins. The primary alcohol compositions are then converted to anionic or nonionic surfactants, preferably sulfated or oxyalkylated or both. The sulfated compositions are biodegradable and possess good cold water detergency. The process for making the dimerized primary alcohol comprises dimerizing, in the presence of a homogeneous dimerization catalyst under dimerization conditions, an olefin feed comprising C6-C10 olefins and preferably at least 85 weight % of linear olefins based on the weight of the olefin feed, to obtain a C12-C20; optionally double bond isomerizing said C12-C20 olefins; and converting the C12-C20 olefins to alcohols, preferably through hydroformylation. The process is preferably a one-step dimerization. The homogenous catalyst comprises a mixture of a nickel carboxylate or a nickel chelate, with an alkyl aluminum halide or an alkyl aluminum alkoxide.

Liquid feed flame spray pyrolysis of solutions of a metal oxide precursor which is an alkoxide or C_1-6 carboxylate and at least one second metal oxide precursor and/or second metal compound dissolved in oxygenated solvent by combustion with oxygen lead to the formation of sub-micron mixed-metal oxide powders not accessible by other processes or by the pyrolysis of metal chlorides or nitrates. The powders have numerous uses in advanced materials applications including particulate solid state lasers, advanced ceramic materials, and as catalysts in organic synthesis and automobile exhaust systems.

This invention provides a catalys conponent and catalyst. Said catalyst comprises titanium, magnesium and at least three electron donor compounds a, b and c, in which is selected from mono-aliphatic-carboxylate or mono-aromatic-carboxylate compounds, b is selected from a special diatomic alkoxide compound, and c is selected from binary binary-aliphatic-carboxylate or binary-aromatic-carboxylate or b is ether compound. Advantages: high polymerization activity and stereospecificity when used for olefin polymerization, in particular for propylene polymerization, wide molecular weight distribution of obtained polymer and good shape of polymer granulars.

An acid gas absorbent comprising a metal sulfonate, phosphonate or carboxylate of a hindered amine and a process for the selective removal Of H2S as well as other acidic components such as carbon disulfide, carbonyl sulfide and oxygen and sulfur derivatives of C1 to C4 hydrocarbons from mixtures containing such acidic components and CO2 using said absorbent.

A fast hardening clear coating composition for repairing a clearcoat/colorcoat finish of a vehicle, which composition is capable of being wet sanded, buffed or polished to a high gloss finish on the same day of application, comprising a film forming binder and an organic liquid carrier, where the binder contains a hydroxyl component comprising a hydroxyl-containing acrylic polymer and a hydroxyl-terminated polyester oligomer, and an organic polyisocyanate crosslinking component, at least portion of which comprises a trimer of isophorone diisocyanate, where the composition further contains, as a combined curing catalyst, at least one dialkyl tin aliphatic carboxylate, at least one tertiary aliphatic mono or diamine, and at least one aliphatic carboxylic acid, in an effective amount such that the clear coating composition on curing at ambient temperatures is in a water spot free and sufficiently hard state for sanding or buffing within about 4 hours after application or on cool down when baked under normal conditions.

The present invention generally provides taxane prodrugs comprising at least one taxane joined by hydrolyzable bond(s) to one or more polyethylene glycol oligomer(s) selected from the group consisting of a straight or branched polyethylene glycol oligomer having from 1 to 25 polyethylene glycol units and optionally comprising a salt-forming moiety. The polyethylene glycol oligomer preferably comprises a salt-forming moiety, which is preferably selected from the group consisting of ammonium and carboxylate.

Provided are partially or fully neutralized mixtures of carboxylate functionalized ethylene high copolymers or terpolymers (Mw between 80,000 and 500,000 Da) with carboxylate functionalized ethylene low copolymers (Mw between 2,000 and 30,000 Da). The compositions are used in films, multilayer structures and other articles of manufacture. The compositions are preferably used on a surface of the articles.

The present invention provides a curable composition including: an organic polymer (A) which has on average 1.1 to 50 groups per one molecule thereof each represented by the general formula (1) and has one or more silicon-containing functional groups capable of cross-linking by forming siloxane bonds:

—NR¹—C(═O)—  (1)

wherein R¹ is a hydrogen atom, or a substituted or unsubstituted monovalent organic group; and a metal carboxylate and/or a carboxylic acid (B), the curable composition giving a cured article excellent in curability and also excellent in heat resistance although a non-organotin catalyst is used.

The present invention is a polymeric resin composition having improved toughness, suitable for use in transparent glazing, comprising an at least partially neutralized ethylene acid copolymer metal carboxylate resin, wherein the metal carboxylate consists essentially of zinc metal counter-ions.

An overbased magnesium composition deposit control additive for residual fuel oils and turbine fuels is an overbased magnesium sulfonate, carboxylate or phenate or mixtures thereof containing at least 14% and upwards to about 18% by weight of magnesium and containing a succinic anhydride and lower carboxylic acid co-promoter reaction product. The additive when added to fuel oils, such as residual fuel oils containing high asphaltenes, reduces, if not eliminates, magnesium/asphaltene deposits or sediment and the consequential plugging of filters. The additive also reduces, if not eliminates, vanadium caused corrosion in the turbine. The invention is also the process for preparing the overbased composition or deposit control additive, wherein the overbasing reaction incorporates the combination of a lower carboxylic acid, preferably acetic acid and a succinic anhydride, preferably dodecenyl succinic anhydride (DDSA), as the co-promoter.

The invention relates to a fatty alcohol polyoxypropylene polyoxyethylene ether carboxylate, a preparation thereof and an application thereof. The structural general formula of the fatty alcohol polyoxypropylene polyoxyethylene ether carboxylate is RO(PO)n(EO)mCH2COOX, wherein R is an aliphatic alkyl group or an alkylphenyl group; (PO)n is polyoxypropylene; n is between 6 and 12; (EO)m is polyoxyethylene; m is between 1 and 4; X is an alkali metal, the fatty alcohol and the polyoxypropylene at the left terminal of the structural general formula are lipophilic groups; and polyoxyethylene and the carboxyl group at the right terminal of the structural general formula are hydrophilic groups. Polyoxypropylene is added to increase the lipophilicity of fatty alcohol carboxylate surfactants to adapt to the application of tertiary oil recovery, and a small amount of polyoxyethylene is added to adjust the hydrophilicity and simultaneously carboxylate fatty alcohol polyoxypropylene esters on condition that the current fatty alcohol raw material is unchanged.

A thickened oil emulsifying viscosity reducer consists of anion surface activator, non-ionic-anion surface activator, demulsifier and water in proportion by 1:0.1-50:0.01-20 and water content is 0.2-5000 times of the sum of a, b and c. Anion surface activator comprises sodium salt and calcium salt of petroleum sulfoacid salt methyl condensate and sulfonated lignin; non-ionic-anion surface activator is chosen organic phosphate salt, sulfuric ester salt , carboxylate and sulfosalt of alkylphenol or fatty alcohol-polyoxyethylene ether; demulsifier is copolymer of alkyl ammonium halide cation demulsifier, polyethylene glycol polyoxytrimethylene polylol ether non-ionic demulsifier or polyethylene glycol polyoxytrimethylene polyethylene polyamines block. It has strong emulsifying ability and low thickened oil viscosity,

A method of solvating metal ions in an aromatic organic liquid. The method includes adding an ammonium salt having an organic acid reagent to the aromatic organic liquid. The organic acid reagent comprises a carboxylate having eight (8) or less carbon atoms. Thereafter, an aqueous solution comprising a metal salt is added to the aromatic organic liquid comprising the ammonium salt and the organic acid reagent. As a result, at least 10% by weight of metal ions is solvated in the aromatic organic liquid.

A new class of releasable corrosion inhibiting materials for protective coatings, methods of making the same, methods of using the same, and coatings containing the same are provided. The materials comprise one or more corrosion inhibitors that are chemically anchored to the surface of a particle having an aluminum oxyhydroxide surface through a carboxylate bond. The carboxylate/aluminum-oxyhydroxide-surface bond breaks under corrosion-causing conditions (for example the presence of high levels of hydroxide ions generated by the cathodic oxygen reduction reaction on metals such as iron and aluminum) thereby allowing the corrosion inhibitors to detach from the particle surface when corrosion is present.

The present invention relates to aqueous polyurethane dispersions that are free from N-methylpyrrolidone and other solvents and wherein the polyurethanes are the reaction products of A) a mixture of 25% to 90% by weight of 1-isocyanate-3,3,5,-trimethyl-5-isocyanatomethylcyclohexane (IPDI) and 10% to 75% by weight of 4,4′-diisocyanatodicyclohexylmethane, wherein the preceding percentages are based on the weight of component A), with B) one or more polyols having average molarcular weights (Mn) of 500 to 6000, C) one or more compounds which have at least one OH— or NH-functional group and contain a carboxyl and/or carboxylate group, wherein at least 50 mol % of the acid groups, based on the total moles of acid incorporated into the polyurethane, are incorporated by dimethylolpropionic acid, D) one or more polyols and/or polyamines having average molecular weights (Mn) of below 500, and E) optionally one or more monoalcohols and/or monoamines. The present invention also relates to a process for preparing the aqueous polyurethane dispersions and to the use of the polyurethane dispersions for preparing coatings or adhesives.

There is a tin-free curable composition having (A) one or more organic polymers having a reactive-silicon-containing group, wherein at least one polymer has a main chain skeleton selected from the group consisting of polyoxyalkylene polymers, saturated hydrocarbon polymers, and (meth)acrylic acid ester polymers; (B) from 0.001 to 20 parts by weight for 100 parts by weight of the organic polymer(s) (A) of a silanol condensation catalyst consisting of one or more metal amidine complexes and one or more amine carboxylate salts, (C) a crosslinker or chain extender chosen from an alkoxysilane, an alkoxysiloxane, an oximosilane, an oximosiloxane, an epoxysilane, an epoxysiloxane, an aminosilane, a carboxysilane, a carboxysiloxane, an alkylamidosilane, an alkylamidosiloxane, an arylamidosilane, an arylamidosiloxane, an alkoxyaminosilane, an alkaryaminosiloxane, an alkoxycarbamatosilane, an alkoxycarbamatosiloxane, and combinations of two or more thereof; and (D) at least one adhesion promoter chosen from a silane or siloxane other than the compounds listed under (C). There is also a cured polymer formed from the tin-free curable composition.

Lubricant oil and grease composition containing an additive package comprising wear-resistant additives in the form of nanoparticles, wherein the additives are a carbonate selected from the group consisting of a carbonate of a Group 1a alkali metal and a carbonate of a Group 2a alkaline earth metal, a sulfate of a Group 1a alkali metal or a Group 2a alkaline earth metal, a phosphate of a Group 1a alkali metal or Group 2a alkaline earth metal, a carboxylate of a Group 1a alkali metal and a carbonate of a Group 2a alkaline earth metal, or a combination thereof.

The present invention provides corrosion inhibition formulations and compositions for inhibiting mineral scale and the corrosion of metals particularly the cavitation corrosion of aluminum in the presence of aqueous liquids. The combination of a mixture of polymeric polycarboxylates, azoles, nitrate salts, phosphates, stabilized silicates and transition metal compounds provide a synergistic protective effect against the cavitation corrosion of aluminum in aqueous liquids reducing the corrosion rate and is effective at relatively low concentrations and varying pH ranges. The addition of selected polymeric polycarboxylates not only significantly reduces glycol based coolant cavitation erosion-corrosion, heat rejecting aluminum corrosion, and hard water precipitates and scale, it has been discovered that polymeric polycarboxylates in combination with siloxane stabilized silicates enhance secondary silicate stabilization leading to improvement in aluminum corrosion protection and coolant life when utilized with selected amounts of the above-identified additives. The formulations are particularly suitable for automotive applications.

A process for synthesizing a metal telluride is provided that includes the dissolution of a metal precursor in a solvent containing a ligand to form a metal-ligand complex soluble in the solvent. The metal-ligand complex is then reacted with a telluride-containing reagent to form metal telluride domains having a mean linear dimension of from 2 to 40 nanometers. NaHTe represents a well-suited telluride reagent. A composition is provided that includes a plurality of metal telluride crystalline domains

(PbTe)_1-x-y(SnTe)_x(Bi₂Te₃)_y   (I)

having a mean linear dimension of from 2 to 40 nanometers inclusive where x is between 0 and 1 inclusive and y is between 0 and 1 inclusive with the proviso that x+y is less than or equal to 1. Each of the metal telluride crystalline domains has a surface passivated with a saccharide moiety or a polydentate carboxylate. A densified mass having a density of greater than 95% of the theoretical density includes a plurality of lead telluride, tin telluride, bismuth telluride, or a combination thereof of domains having a mean linear dimension of from 2 to 40 nanometers inclusive that have been subjected to hot isotactic pressing.

The invention relates to polyurethane elastomers, a process for the preparation of these polyurethane elastomers and a the preparation of elastomeric molded parts comprising these polyurethane elastomers. These elastomers comprise the reaction product of a polyol component, chain extenders and/or crosslinking agents, one or more amine catalysts, a catalyst mixture which contains at least one organic titanium compound and at least one organic zinc compound, and optionally an organic lithium carboxylate and/or an organic bismuth carboxylate; with a polyisocyanate component.

A highly reactive polyurethane powder coating composition, which contains uretdione groups that are hardenable at low temperatures, contains A) at least one uretdione-containing powder coating hardener based on aliphatic, (cyclo)aliphatic or cycloaliphatic polyisocyanates and hydroxyl-containing compounds, the hardener having a melting point of from 40 to 130° C., a free NCO content of less than 5% by weight, and a uretdione content of 6-18% by weight; B) at least one hydroxyl-containing polymer having a melting point of from 40 to 130° C., and an OH number of between 20 and 200 mg KOH/g; C) 0.001-3% by weight of at least one tetraalkyl ammonium carboxylate catalyst, based on a total amount of components A) and B). Components A) and B) are present in a ratio so that for each hydroxyl group of component B) there is from 0.3 to 1 uretdione group of component A).

An improved process is described for manufacturing zirconia-treated titanium dioxide pigments, wherein the zirconia treatment is accomplished in the process of fluidizing a titanium dioxide filter or press cake and then drying the same, through the addition to the filter or press cake of one or more alkaline water-soluble zirconium reagents selected from ammonium zirconyl carbonate, the water-soluble ammonium zirconyl carboxylates and mixtures of these. Aqueous solutions of such zirconium reagents, in addition to being effective for imparting a zirconia surface treatment to the titanium dioxide materials, also prove to be effective fluidizing agents for forming high solids dispersions of the zirconia-treated titanium dioxide pigment materials which can be spray dried without substantial dilution and excessive energy requirements.

The invention relates to a surfactant composition for intensified oil production and a preparation method thereof, mainly for solving the problems that the existing surfactant has poor oil displacement efficiency in tertiary oil recovery, inorganic base contained in a displacement of reservoir oil system damages the stratum and oil wells, corrodes equipment and pipelines, and results in difficult emulsion breaking. The surfactant composition for intensified oil production comprises a cationic surfactant and an anion-nonionic surfactant, wherein the cationic surfactant is any one of quaternary ammonium salt and quaternary amine alkali, the anion-nonionic surfactant is any one of fatty alcohol polyoxyethylene/polypropylene ether carboxylate and fatty alcohol polyoxyethylene ether/polypropylene ether sulfonate, and the molar ratio of the cationic surfactant to the anion-nonionic surfactant is 1:0.01-1:100. Due to adoption of the surfactant composition and the preparation method, the above problems can be well solved. The techcnial scheme can be used in the oil field intensified oil production process.

An oil material comprising a dimerdiol ester with a monocarboxylic acid having 4 to 34 carbon atoms or with a dimerdiol ester with a dicarboxylic acid; and a cosmetic and an external agent excellent in safety, stability, gloss, feeling and the like comprising the dimerdiol carboxylate.

The invention is an adhesive composition comprising

• • a) i) a trialkoxysilane functional polyether or polyurethane wherein the polyether or polyurethane has a weight average molecular weight of 6000 or greater and a dialkyltin carboxylate or dialkyltin alcoholate; or
    • ii) a dialkoxysilane functional polyether or polyurethane and a dialkyltin alcoholate; and
  • b) a primary or secondary amino straight chain alkyl trialkoxysilane;
  • wherein the dialkyltin carboxylate or dialkyltin alcoholate is present in an effective amount to facilitate bonding of the adhesive to a substrate of from about 0.1 to about 1.0 percent by weight based on the weight of the adhesive and the primary or secondary amino straight chained alkyl trialkoxysilane is present in an amount which is effective to facilitate bonding of the adhesive to a substrate wherein the amount is from about 0.5 to about 1.2 percent by weight. In another embodiment, the invention is a method of bonding a window in a vehicle. The process comprises applying to a window or a window frame of a structure an adhesive according to the invention; contacting the window with the window frame of a substrate wherein the adhesive is located between the window and the substrate; and allowing the adhesive to cure. This process is especially useful when the substrate is unprimed metal, plastic, fiberglass or a composite, optionally coated with a coating. In another embodiment it is useful when the window is unprimed.

The present invention relates to a process for producing an ether carboxylate which includes the steps of (1) reacting an aliphatic monohydric alcohol with an alkylene oxide in the presence of an alkali catalyst; (2) neutralizing a reaction solution obtained in the step (1) with an acid such as hydroxycarboxylic acids to obtain an ether alcohol; and (3-1) reacting the obtained ether alcohol with a monohalogenofatty acid or a salt thereof and an alkali metal hydroxide, or (3-2) subjecting the obtained ether alcohol to catalytic oxidation reaction in the presence of a catalyst. The obtained ether carboxylate has a less odor and a high quality and is therefore suitably used in the applications such as cosmetics and toiletries.

A thermoplastic composition comprises a polycarbonate that is not aryl carboxylate end-capped, and an aryl carboxylate end-capped polycarbonate of formula:

Ar¹-C(O)—O-(-L-)_m-O—C(O)-A¹

wherein each Ar¹ is independently an aryl group, -(-L-)_m- is a polycarbonate linking group with m units of linking unit L, and m is at least one; wherein the aryl carboxylate end-capped polycarbonate has aryl carboxylate end groups present in the thermoplastic composition in an amount of 0.01 to 500 mmol/Kg based on the combined weights of the polycarbonate that is not aryl carboxylate end-capped, and the aryl carboxylate end-capped polycarbonate, and wherein a molded article having a thickness of 3.2±0.12 millimeters and consisting of the aryl carboxylate end-capped polycarbonate, the polycarbonate, and less than or equal to 1.0 percent total weight of aliphatic diol, a mold-release agent, and an antioxidant has, after exposure to a total gamma radiation dose of 81 kGy and when measured according to ASTM D1925-70, an increase in yellowness index (dYI) of less than or equal to 24.5, when compared to the unexposed molded article. A method for preparing the aryl carboxylate end-capped polycarbonate that is not aryl carboxylate end-capped, and thermoplastic composition, an article prepared from the thermoplastic composition, are also disclosed.

The present invention encompasses compounds of Formula I: as well as the pharmaceutically acceptable salts and hydrates thereof. The compounds are useful for treating immune mediated diseases and conditions, such as bone marrow, organ and tissue transplant rejection. Pharmaceutical compositions and methods of use are included.