3534 results about "Phenol" patented technology

The present invention discloses a method for detecting and applying C1-C2-alkyl-substituted phenol isomers, which relates to the technical field of environmental detection and includes: selecting a corresponding sample pretreatment process to prepare a test sample according to the petroleum content range in the sample; under a mobile phase of methanol-5.0-6.5 mmol / L ammonia water, using LC-MS to detect the test sample to obtain the concentration of the first component and the standardized concentrations of co-eluted 3,5-dimethylphenol and 2,6-dimethylphenol; under a mobile phase of acetonitrile-4.0-10.0 mmol / L ammonia water, using LC-MS to detect the test sample to obtain the concentration of 3,5-dimethylphenol, or the standardized concentrations of co-eluted 3,5-methylphenol and 3-ethylphenol, or the standardized concentrations of co-eluted 2,6-dimethylphenol and 2,4-dimethylphenol; under a mobile phase of methanol-5.0-6.5 mmol / L ammonia water or acetonitrile-4.0-10.0 mmol / L ammonia water, using LC-MS to separately detect the calibration samples of the co-eluted components, and calculate the conversion factor of the co-eluted components and the concentration of the other component. The present invention realizes the accurate quantification of phenol and 12 C1-C2-alkyl-substituted phenol isomers.

The present invention discloses a characterization method and application of C0-C2-alkyl-substituted phenols, relating to the technical field of environmental detection. The method includes: selecting a corresponding sample pretreatment process to prepare a test sample according to the petroleum content range in the sample; detecting the test sample by LC-MS under a mobile phase system of methanol-5.0-6.5 mmol / L ammonia water to obtain the concentration of the first component and the normalized concentrations of co-eluted 3,5-dimethylphenol and 2,6-dimethylphenol; detecting the test sample by LC-MS under a mobile phase system of methanol-7.0-11.5 mmol / L ammonia water to obtain the concentration of 3,5-dimethylphenol; detecting calibration samples of 3,5-dimethylphenol and 2,6-dimethylphenol respectively by LC-MS under a mobile phase system of methanol-5.0-6.5 mmol / L ammonia water, calculating a conversion factor, and obtaining the concentration of 2,6-dimethylphenol; and obtaining the contents of 13 single components of C0-C2-alkyl-substituted phenols based on the concentrations of the first component, 3,5-dimethylphenol and 2,6-dimethylphenol. The present invention realizes the quantitative characterization of 13 single components of C0-C2-alkyl-substituted phenols.

The invention relates to the technical field of organic chemical synthesis, in particular to a preparation method of 3, 4 '-diaminodiphenyl ether.The preparation method comprises the steps that S1, under inert gas and in a first solvent, m-dinitrobenzene and p-acetamidophenol are subjected to a heating reaction under the condition of a weak base catalyst, and 3-nitro-4-acetamido diphenyl ether is prepared; s2, in a second solvent, the 3-nitro-4-acetamido diphenyl ether is subjected to a hydrogenation reduction reaction, and 3-amino-4-acetamido diphenyl ether is prepared; and S3, dissolving the 3-amino-4-acetaminodiphenyl ether in an alcohol solvent system, adding an aqueous solution of alkali, controlling the reaction temperature, carrying out a hydrolysis reaction, and after the reaction is finished, carrying out post-treatment to obtain the 3, 4 '-diaminodiphenyl ether. The preparation method provided by the invention has the advantages of easily available raw materials, low price, good selectivity and high product yield, and is more suitable for industrial production by comprehensively considering economical efficiency and safety.

The preparation method comprises the following steps: by taking 2, 2 '-[4-(4-aminophenylazo) phenylimine] diethanol and phenol as raw materials, preparing a bisazobenzene compound according to a molar ratio of 1: 1, carrying out nucleophilic substitution on the compound and alkyl bromide according to a molar ratio of 1: 1 to prepare a bisazobenzene monomer, and carrying out side-chain type photoresponse bisazobenzene polyurethane on the bisazobenzene monomer to prepare the side-chain type photoresponse bisazobenzene polyurethane. And carrying out a reaction on the bisazobenzene monomer and diisocyanate urethane to obtain the side chain type photoresponse bisazobenzene polyurethane. The bis-azobenzene polyurethane has obvious trans-cis configuration change along with the increase of ultraviolet irradiation time in a tetrahydrofuran solution, and gradually recovers the trans configuration under the irradiation of visible light. Besides, the bisazobenzene polyurethane and polyurethane are subjected to melt blending to prepare a composite material film, and the composite material film has an obvious light-induced bending phenomenon under ultraviolet irradiation.

The invention provides an anti-aging flame-retardant epoxy resin coating and a preparation process thereof, and belongs to the technical field of coating preparation. The preparation process comprises the following steps: preparing the flame-retardant additive; preparing a coated modified black phosphorus nanosheet; preparing modified hollow glass beads; preparing the epoxy resin coating. The preparation method comprises the following steps: dissolving 3, 4-dihydroxy benzaldehyde and 2-amino-4-methylphenol in absolute ethyl alcohol, carrying out a heating reflux reaction, carrying out dehydration condensation on an aldehyde group in the 3, 4-dihydroxy benzaldehyde and an amino group in the 2-amino-4-methylphenol to generate an imine bond-containing intermediate, respectively dissolving the intermediate and phosphonitrilic chloride trimer, and carrying out a reaction to obtain the phosphonitrilic chloride trimer. The preparation method comprises the following steps: firstly, adding phosphonitrilic chloride into an intermediate, then mixing for reaction, enabling phenolic hydroxyl groups in the intermediate and phosphonitrilic chloride trimer to be subjected to nucleophilic substitution reaction to generate the flame-retardant additive containing phosphorus and a Schiff base structure, and the flame-retardant additive has relatively good compatibility with an epoxy resin matrix, is not easy to separate out and can effectively improve the flame-retardant property of the epoxy resin coating.

The invention discloses a method for catalytically oxidizing lignin to depolymerize into an aviation oil intermediate by using a cellulose carbon aerogel supported copper nano-catalyst. Comprising the following steps: (1) dissolving cellulose powder into a mixed alkali solution of NaOH and urea, and stirring at low temperature to obtain a clear and transparent cellulose solution; and washing to be neutral to obtain well dispersed cellulose suspension. And (2) carrying out suction filtration molding, and freeze-drying for a period of time to obtain the cellulose aerogel. And (3) immersing in an ethanol solution of copper nitrate for ultrasonic treatment, and drying in a vacuum drying oven. And (4) carrying out high-temperature calcination in an N2 atmosphere to obtain a catalyst which is marked as Cu / CA. And (5) the catalyst can efficiently catalyze a Fenton-like reaction to oxidize a dimer model compound of lignin in acidic, neutral and alkaline environments to obtain products including benzoic acid, acetophenone, benzyl alcohol, phenol and the like, the required hydrogen peroxide concentration is low, and the catalyst has the advantages of simple process, high catalytic activity, low cost and the like, can be used for effectively degrading lignin to prepare aviation oil intermediates, and has wide application prospects. And repeated cyclic utilization is realized.

The invention discloses a high-strength nano composite stiffening filling master batch and a preparation method thereof, and relates to the technical field of high polymer materials, the raw materials comprise a nano filler, a matrix material and a functional additive; the nano filler comprises nano diamond, nano silicon carbide and bio-based nano cellulose, the base material comprises polyimide, polyether-ether-ketone and bio-based polylactic acid, and the functional additive comprises a hindered phenol antioxidant, a nano aluminum hydroxide flame retardant, a nano silicon dioxide reinforcing agent, an ultraviolet light absorber, a carbon nano tube and nano silver particles. Nano-diamond, nano-silicon carbide and bio-based nano-cellulose are adopted as nano-fillers, polyimide, polyether-ether-ketone and bio-based polylactic acid are combined as base materials, and a plurality of functional additives are added, so that the preparation of the high-strength nano-composite stiffening filling master batch is realized; and the problems of poor dispersibility, mechanical property damage, insufficient hardness and poor interface bonding of the traditional filler master batch can be solved.

The invention relates to a composition comprising at least one oxidation coupler chosen from 6-hydroxybenzomorpholine of formula (I), one of its addition salts, its solvates and / or the solvates of its salts, at least one oxidation coupler chosen from 2-amino-5-ethylphenol of formula (II), one of its addition salts, its solvates and / or the solvates of its salts, and at least one compound chosen from N, N-dicarboxymethyl glutamic acid, one of its salts, and mixtures thereof. The invention also relates to a process for dyeing keratin fibres, preferably the hair, comprising the application of the composition to said keratin fibres.

The invention discloses a method for increasing the phenol yield through catalytic pyrolysis of a decommissioned fan blade, and relates to the technical field of waste composite material resourceful treatment.The method comprises the steps that decommissioned fan blade fragment materials obtained after crushing and magnetic separation are subjected to multispectral imaging, multispectral data are obtained, and pretreatment is conducted; performing spectral feature extraction on the preprocessed multispectral data by using a convolutional neural network; identifying and separating the fragment materials based on spectral characteristics and automatic separation equipment; carrying out activation and carbonization treatment on the separated balsa wood fragments to prepare a carbon-based catalyst; carrying out catalytic pyrolysis on the separated fragment material by utilizing an automatic adjusting reactor and a carbon-based catalyst; collecting a product generated by catalytic pyrolysis, and carrying out qualitative and quantitative analysis on phenols to obtain a qualitative analysis result and a quantitative analysis result. According to the method, through a mode of combining multispectral imaging and the convolutional neural network, different types of composite materials are accurately identified and classified.

The invention discloses a flame-retardant insulating powder coating for a new energy automobile and a preparation method of the flame-retardant insulating powder coating, and belongs to the technical field of coatings. The flame-retardant insulating powder coating for the new energy automobile is prepared from the following raw material components in parts by mass: 380 to 384 parts of epoxy resin, 56 to 58 parts of a toughening agent, 5 to 10 parts of modified flame-retardant filler, 100 to 101 parts of a composite curing agent, 5 parts of a flatting agent, 1 part of benzoin and 0.7 part of an accelerant, the toughening agent is obtained by carrying out a reaction on an isophorone diisocyanate tripolymer, 4-bromophenol and N-p-coumaroyl tyramine; the modified flame-retardant filler is obtained by firstly wrapping hexagonal boron nitride with polydopamine and then modifying with a silane coupling agent; the silane coupling agent is obtained by combining 4-benzonitrile oxygen butyl trimethoxy silane and a sulfydryl silane coupling agent; and the composite curing agent is obtained by combining 4, 4-diaminodiphenylmethane and amino-sulfydryl functional organic polysiloxane.

The invention relates to the technical field of industrial wastewater deep purification, and discloses an industrial wastewater deep purification system based on nano catalytic membrane separation, which comprises a pretreatment module, a catalytic degradation module, a membrane separation module, an intelligent control module and a regeneration maintenance module which are sequentially connected according to a treatment flow, the pretreatment module adjusts the water quality of inlet water to a range suitable for subsequent treatment through pH adjustment and suspended matter interception, that is, the pH is 2-11, and the turbidity is less than or equal to 50NTU; the catalytic degradation module is used for decomposing organic pollutants and mineralizing refractory substances under the excitation of ultraviolet / visible light by utilizing the photocatalytic characteristic of a nano catalytic membrane. The TiO2 / WO3 heterojunction nano catalytic membrane is adopted, so that deep oxidation of refractory pollutants such as phenol and sulfonamide antibiotics is realized, finally, the COD removal rate of 98.7% is achieved, and compared with a traditional photocatalytic process, the energy consumption is reduced by 54%.

The invention relates to the field of cables, and discloses a modified polyvinyl chloride composite material for cables and a preparation method thereof.The composite material comprises low-density polyethylene, polyvinyl chloride, ethylene-vinyl acetate copolymer, nitrile rubber, modified graphene oxide, modified nano calcium carbonate and auxiliaries; the modified graphene oxide is prepared by reacting acylating chlorination of graphene oxide with an anti-aging derivative, the anti-aging derivative is prepared by reducing a benzoxazole-containing intermediate generated by a reaction of 2-amino-4-bromophenol and 4-cyanobenzaldehyde to obtain an aminated benzoxazole-containing intermediate, then the aminated benzoxazole-containing intermediate reacts with p-phenylenediamine, and then the product reacts with 3-(3, 4-dichlorophenyl)-1, 2, 3-triazole-3-one to obtain the anti-aging graphene oxide. 2, 5-di-tert-butyl-4-hydroxyphenyl) propionyl chloride is subjected to a reaction to prepare the product. And the modified nano calcium carbonate is prepared by reacting phosphonitrilic chloride trimer with an amino silane coupling agent and 2-amino benzoxazole-5-borate and then grafting on the surface of the nano calcium carbonate. The composite material prepared by the invention has excellent flame retardance, heat resistance and long-acting oxidation resistance.

The invention relates to a two-component composition as well as a preparation method and application thereof, and belongs to the technical field of woodware seal primers. The double-component composition provided by the invention comprises a component A and a component B, the component A comprises epoxy resin (1a) containing an aromatic ring structure and more than two epoxy groups and silane (1b) containing one epoxy group; in the component A, the weight of the silane (1b) accounts for 18-60 wt% of the total weight of the epoxy resin (1a) and the silane (1b); the component B comprises silane (1c) containing one amino group and substituted phenol (1d) with a specific structure; and in the component B, the weight of the substituted phenol (1d) accounts for 0.3-10 wt% of the total weight of the silane (1c) and the substituted phenol (1d). The double-component composition disclosed by the invention can realize dual curing, is high in crosslinking density, has the advantages of excellent surface effect, sanding property, flexibility, sealing property and wood warming effect, does not contain a solvent or only has low solvent content, and is particularly suitable for woodware seal primer.

The invention belongs to the technical field of sewage treatment, and particularly relates to a coking phenol-cyanogen sewage treatment system, which comprises a pretreatment stage, a biochemical treatment stage and an advanced treatment stage, a mixing cavity, a flotation cavity, a separation cavity, a scum cavity and a clear water cavity are sequentially formed in the air flotation tank; the scraping plate is movably connected to the upper part of the separation cavity and is used for scraping dross; the recovery valve pipe is arranged below the clear water cavity, and a concentration sensor is arranged in the recovery valve pipe and used for detecting the impurity concentration in the clear water; according to the coking phenol-cyanogen sewage treatment system, the scraping depth of the scraping plate is correspondingly adjusted according to the concentration value of the impurities at the clear water, and the larger the amount of scum in the separation cavity is, the larger the downward moving speed of the corresponding scraping plate is, so that the scum in the separation cavity can be thoroughly and effectively scraped and recycled by the scraping plate.

The invention provides a flame-retardant polyolefin composition as well as a preparation method and application thereof, and the flame-retardant polyolefin composition comprises the following components in parts by weight: 13-22 parts of an ethylene-vinyl acetate copolymer, 1.5-8.5 parts of linear low density polyethylene, 8-17 parts of a polyolefin elastomer, 35-55 parts of a flame retardant and 0.5-2.5 parts of an antioxidant. The antioxidant comprises a main antioxidant and an auxiliary antioxidant; the main antioxidant comprises a hindered phenol antioxidant and an amine antioxidant; and the auxiliary antioxidant comprises a thioester antioxidant and / or a phosphite ester antioxidant. According to the flame-retardant polyolefin composition disclosed by the invention, the ethylene-vinyl acetate copolymer, the linear low-density polyethylene and the polyolefin elastomer are compounded according to a specific content, and meanwhile, the antioxidant with specific composition is matched, so that the flame-retardant polyolefin composition is good in heat resistance, aging resistance and precipitation resistance; meanwhile, the mechanical property is good.

The invention belongs to the technical field of enzyme engineering, and particularly relates to a P450 peroxygenase mutant and application of the P450 peroxygenase mutant in degradation of phenol environmental pollutants. The mutant is formed by mutating phenylalanine into alanine from the 46th amino acid of P450 peroxygenase with an amino acid sequence as shown in a sequence table SEQ ID NO.1, and the amino acid sequence of the P450 peroxygenase is as shown in a sequence table SEQ ID NO.2. The P450 peroxygenase mutant provided by the invention has the advantages of high catalytic efficiency, high protein expression quantity, low industrial cost and the like. The operation process for degrading the phenol environmental pollutants is simple, the process is mature, the cost is low, harmful impurities are not contained, and the method is non-toxic and environment-friendly.

The present disclosure relates to an improved, efficient, scalable process to prepare intermediate compounds, such as 2,2′,2″-(1,3,5,2,4,6-trioxatriborinane-2,4,6-triyl)tris(3-fluorophenol), useful for the synthesis of compounds, such as Compound 9, for the treatment of KRAS G12C mutated cancers.

The invention discloses a synthesis method of bromo-triazine, which belongs to the technical field of organic synthesis, and comprises the following steps: preparing an alumina-loaded N, N-dimethylaminopyridine catalyst, filling the alumina-loaded N, N-dimethylaminopyridine catalyst in a fixed bed reactor, introducing tribromophenol and metal oxide mixed slurry and cyanuric chloride slurry, carrying out a reaction for 2-4 hours, and carrying out a reaction for 2-4 hours to obtain the bromo-triazine. Raising the temperature for reaction to obtain a crude product solution; and performing post-treatment to obtain a bromo-triazine product. According to the invention, the aluminum oxide loaded N, N-dimethylaminopyridine catalyst is synthesized, and the N, N-dimethylaminopyridine enables the reaction speed to be higher and the yield to be higher; nano aluminum oxide is adopted for loading, so that on one hand, dealkalization synthesis of bromotriazine is realized, and on the other hand, the reaction efficiency is accelerated; the continuous process realizes non-aqueous medium and low-temperature short-time reaction, so that hydrolysis is further avoided; the aluminum oxide loaded N, N-dimethylaminopyridine catalyst is high in activity and stability, the synthesis method is simplified, and the aluminum oxide loaded N, N-dimethylaminopyridine catalyst is suitable for industrial large-scale production.

The invention discloses a method for preparing calcium hydroxide slurry with high specific surface area and high pore volume, which comprises the following steps: S1, adding an alcohol reagent into water to obtain a solution A; s2, adding an inorganic salt solution into the solution A, and uniformly mixing to obtain a solution B; s3, a reagent X is added into the solution B, ultrasonic mixing is performed to obtain a solution C, and the reagent X is a mixture of phenol or triethanolamine, ethidene diamine and ethylamine; and S4, adding calcium oxide powder into the solution C, continuously stirring, and reacting to obtain calcium hydroxide slurry. The invention provides a method for preparing calcium hydroxide slurry with high specific surface area and high pore volume, the calcium hydroxide slurry prepared by the method can form calcium hydroxide with high specific surface area and high pore volume when in use, and the method aims to solve the problems of low specific surface area and low pore volume of the existing calcium hydroxide. Therefore, the problem of desulfurization performance inactivation caused by blockage of calcium hydroxide (desulfurizer) pores by generated CaSO3 and CaSO4 in the desulfurization process is avoided.

The invention provides an insulating material, a preparation method, application and a cable. The insulating material is prepared from the following raw materials: polyethylene, a reactive antioxidant, an initiator, a cross-linking agent and an assistant cross-linking agent. The reactive antioxidant comprises one or more of a hindered phenol group, an allyl group, an acrylic acid group, an acrylate group, a carboxylic acid group, an anhydride group and an anhydride derivative group; the number of impurity particles with the particle size of 50-70 microns contained in the polyethylene is less than 3. The reactive antioxidant can be grafted to a polyethylene molecular chain through melting, and the grafted reactive antioxidant is not easy to migrate in the use process and shows excellent long-term thermal oxidation stability and space charge inhibition capability, so that the electrical performance and thermo-oxidative aging resistance of the insulating material are improved.

The invention belongs to the field of preparation of medical intermediates, and particularly relates to a preparation method of an On-DNA sulfinic acid structure compound. The method for preparing the On-DNA sulfinic acid structure compound comprises a step of oxidizing On-DNA thiol (phenol) into the On-DNA sulfinic acid structure compound under alkaline and heating or illumination conditions, a solvent used in the reaction step is a mixed solution of water, dimethyl sulfoxide, N, N-dimethylformamide, acetonitrile, ethanol or tetrahydrofuran, the reaction temperature is not more than 80 DEG C, and the reaction time is not more than 2 hours. And the illumination wavelength ranges from 365 nanometers to 535 nanometers. The On-DNA sulfinic acid structure compound obtained in the invention can be directly used for constructing a structure compound with a sulfonyl group, the reaction condition is mild and convenient, a new method and a new idea are provided for construction of a DNA coding compound library, and the On-DNA sulfinic acid structure compound has a very good application prospect in lead drug development.

The invention discloses a melt blending preparation process of a semiconductive shielding material for an ultrahigh-pressure crosslinked polyethylene cable, which comprises the following steps: S1, premixing low-density polyethylene and an ethylene-vinyl alcohol copolymer in proportion, the vinyl alcohol chain segment content of the ethylene-vinyl alcohol copolymer being 25%-45%; s2, performing plasma surface treatment on carbon black, and compounding the carbon black with carbon nanotubes to form a conductive filler system; s3, under the protection of inert gas, adding the matrix resin in the step S1 and the conductive filler in the step S2 into a double-screw extruder in stages, and synchronously adding a hindered phenol and phosphite compound antioxidant; and S4, carrying out segmented mixing under the temperature gradient of 160-210 DEG C. Through synergistic compounding of the plasma surface modified carbon black and the carbon nanotubes and in combination with a staged feeding process, directional dispersion of the conductive filler is realized, a three-dimensional interpenetrating conductive network is formed, and the local electric field homogenization capability of the ultrahigh-voltage cable is remarkably improved.

The invention discloses a catalyst for hydrogen production through tar steam reforming and a preparation method and application thereof. The catalyst comprises a cobalt-magnesium-aluminum composite spinel carrier and an active component loaded on the cobalt-magnesium-aluminum composite spinel carrier, the active component comprises nickel and at least one metal additive selected from iron, zirconium and ruthenium. The preparation method mainly comprises the following steps: preparing the carrier by adopting a coprecipitation method, loading the active component by adopting an impregnation method, and drying and reducing to obtain the final catalyst. The catalyst is used for tar component steam reforming hydrogen production reaction, especially for treating raw materials containing phenol and water vapor at 600-700 DEG C, tar conversion can be efficiently catalyzed, product gas rich in hydrogen can be generated, hydrogen selectivity is high, and almost no methane is generated. The catalyst has the advantages of high activity, good stability, strong carbon deposition resistance and the like, and is suitable for purification and high-value utilization of biomass pyrolysis tar.

The invention discloses an ammonia nitrogen detection system and an application method thereof, and ammonia nitrogen detection test paper, the ammonia nitrogen detection system is prepared by the following steps: step SA1) preparing a dipping mixed solution, the dipping mixed solution comprises: a potassium sodium tartrate solution with a concentration of 3-60 g / L; a sodium salicylate solution with a concentration of 20-320 g / L; the concentration of the sodium nitroprusside solution is 0.1 to 0.8 g / L; and deionized water. On the basis of the principle of salicylic acid-pypocholoride spectrophotometry, the impregnated test paper, the reagent tube and the standard colorimetric card are combined, and the rapid ammonia nitrogen detection system special for medium-concentration sewage detection is successfully developed. The toxicity problem of mercury iodide in a Nessler reagent method and the toxicity problem of phenol in a phenol-pypocholoride spectrophotometric method are avoided, main reagents are non-toxic and harmless to a human body, interference of metal ions in a water sample can be effectively eliminated by adopting sodium potassium tartrate tetrahydrate as a chelating agent, and the detection stability and accuracy are improved.

The present invention belongs to the field of water treatment technology, and relates to a fluorinated ZIF-67 / graphene composite catalyst for coal chemical wastewater treatment and a preparation method thereof. The catalyst uses porous graphene as a carrier to load fluorinated ZIF-67. First, 2-trifluoromethylimidazole is introduced into ZIF-67 to prepare fluorinated ZIF-67, and an in-situ preparation method is used to make it grow evenly on the surface of a porous graphene carrier to obtain a fluorinated ZIF-67 / graphene composite catalyst. 2-trifluoromethylimidazole modification can improve the hydrophobicity of the catalyst, making it less susceptible to erosion during water treatment; The porous structure of graphene provides a larger specific surface area, increases the number of active sites of the catalyst, prevents nanoparticles from agglomerating, and improves its mechanical strength. The catalyst has the ability to highly degrade organic pollutants, is suitable for treating pollutants such as phenols and greases that are difficult to biodegrade in coal chemical wastewater, and has broad market prospects.

The present disclosure relates to stick compositions including 2,4-bis-{[4-(2-ethyl hexyloxy)-2-hydroxy]-phenyl}-6-(4-methoxyphenyl)-1,3,5-triazine, at least one solvent for solubilizing the bemotrizinol, and at least one lipophilic gelling agent, as well as to methods of making and using such compositions.

The present disclosure relates to compositions including 2,4-bis-{[4-(2-ethyl hexyloxy)-2-hydroxy]-phenyl}-6-(4-methoxyphenyl)-1,3,5-triazine, avobenzone, and additional organic UV filter(s), as well as to methods of making and using such compositions.

The invention provides a binder, negative electrode slurry, a negative electrode plate and a battery. The adhesive comprises a polymer, the polymer comprises an acrylic acid structural unit, a structural unit containing quaternary ammonium salt, a phenolic ether structural unit and a flexible structural unit, and the mass ratio of the acrylic acid structural unit to the structural unit containing quaternary ammonium salt to the phenolic ether structural unit to the flexible structural unit is (30-70): (1-10): (0.5-5): (5-20); the phenolic ether structural unit comprises at least one of an aromatic phenol structural unit and an aromatic ether structural unit. The binder provided by the invention synergistically provides a triple dispersion mechanism of electrostatic stability, surface adsorption and hydrophobic anchoring through the acrylic acid structural unit, the structural unit containing quaternary ammonium salt and the phenolic ether structural unit, so that the negative electrode slurry can form a long-term stable aqueous slurry system without depending on an additional dispersant. The binder forms a bactericidal and bacteriostatic barrier in the slurry, has a stable anticorrosion structure network, and is stable in electrochemical performance.

The invention discloses a comprehensive prevention and control method for tobacco root knot nematode disease containing a biological agent. The method comprises the steps of crop rotation of tobacco and buckwheat / quinoa, host resistance induction of the microbial agent in the seedling raising period, tobacco planting soil quality improvement in the transplanting period and the like. The agronomic characters of tobacco seedlings are effectively improved, and the physical characters of soil are improved; the chemical properties of soil pH, alkali-hydrolyzable nitrogen, available phosphorus, quick-acting potassium, exchangeable calcium, exchangeable magnesium and the like are improved; the activity of soil urease, sucrase, acid phosphatase, catalase and peroxidase is improved; the content of water-soluble phenols, compound phenols and total phenols in soil is reduced; the disease index of the tobacco root knot nematode disease can be remarkably reduced, the survival rate of tobacco is increased, the application amount of chemical agents is reduced, and the healthy and sustainable development of the tobacco industry is promoted.

The present disclosure relates to compositions including 2,4-bis-{[4-(2-ethyl hexyloxy)-2-hydroxy]-phenyl}-6-(4-methoxyphenyl)-1,3,5-triazine and an antioxidant system, as well as to methods of making and using such compositions.