8488results about "Flat articles" patented technology

The invention relates to the technical field of folding screen supporting films, and particularly discloses a double-layer buffering supporting film for a flexible folding display screen and a preparation method of the double-layer buffering supporting film. The double-layer buffer supporting film for the flexible folding display screen sequentially comprises a release film layer, a first adhesive layer, a first stainless steel layer, a second adhesive layer, a second stainless steel layer and a protective film layer from top to bottom, the first adhesive layer and the second adhesive layer are prepared by curing the same pressure-sensitive adhesive composition; the pressure-sensitive adhesive composition is prepared from the following raw materials: acrylate copolymer, hydrogenated rosin glyceride, hyperbranched polyesteramide-dopamine conjugate, acylhydrazone bond modified siloxane, a curing agent and a silane coupling agent; the protective film layer comprises the following raw materials: PET particles, nano silicon dioxide, an ethylene-vinyl acetate copolymer and an antioxidant. The double-layer buffer supporting film has the advantages of being high in supporting rigidity and interlayer peel strength, and serious folds caused by long-term repeated folding of the folding screen can be relieved.

The invention discloses an intelligent thickness control system for calendering a high-brightness edge sealing sheet, and relates to the technical field of intelligent manufacturing and industrial process control. The method sequentially comprises six steps of multi-modal online acquisition, multi-source fusion drift compensation, digital twinning real-time synchronization, model prediction closed-loop control, high-speed execution fault self-diagnosis and reinforcement learning adaptive optimization. Thickness data are synchronously obtained through laser, terahertz, ultrasound and environment quantity, trusted thickness flow is output through a drift model and a confidence matrix, future thickness is predicted through digital twinning rolling to give uncertainty, first-step control quantity is generated through quadratic programming, millisecond-level execution is conducted through a distributed clock, and self-healing is conducted under shadow driving hot standby and cloud diagnosis. And reinforcement learning agent online iteration improves the energy-saving and stable performance, and full-life-cycle closed-loop control with accurate thickness, low energy consumption and long service life of equipment under complex working conditions is realized.

A process or method for manufacturing a fire-retardant treated wood composite board or panel, such as oriented-strand board, with a low melting point fire retardant (FR) material, such as boric acid, while the press is operating at typical press temperatures above the FR material melting point. An intervening overlay is applied to the top surface of the mat on the forming line, after the use or application of any FR material within or on the mat, prior to entry into the press. The intervening overlay covers the top surface so as to prevent the melting fire retardant material from contacting the press platen(s). After pressing, the intervening overlay may be removed from the top surface by sanding, buffing, or other methods. The intervening overlay also may be sized so as to extend over one or more edges of the underlying panel, for ease of removal post-process.

The invention relates to the technical field of high polymer material processing, in particular to an insulation board extrusion molding control method and system.The method comprises the steps that 1, multi-dimensional parameters are collected in real time, at least three detection sections are arranged on an outlet section of a die head of an extruding machine in the material flowing direction, and each section synchronously collects the following data; 2, evaluating the rheological state of the melt in real time; 3, dynamically reconstructing a temperature field, dividing the die cavity into an axial independent temperature control section and a circumferential heating unit, and dynamically adjusting the power of the heating unit according to a state judgment result in the step 2; 4, pressure-rotating speed cooperative compensation is carried out; and 5, closed-loop verification is carried out, the density uniformity of the formed plate is detected after the adjustment instruction is executed, and if the density range exceeds the limit, the step 2 is executed again. By accurately controlling the temperature and the concentration of the foaming agent, the feasibility of high-proportion mixing of the reclaimed material is optimized, the quality fluctuation caused by temperature and viscosity fluctuation is reduced, and green manufacturing, energy conservation and consumption reduction are promoted.

The invention is suitable for the field of film manufacturing, and provides a PO film tape casting process which comprises the following steps: S1, raw material pretreatment; s2, mixing the materials; s3, melt extrusion; s4, carrying out tape casting; s5, cooling and shaping; s6, thickness detection and adjustment; s7, carrying out post-treatment; and S8, rolling is conducted. According to the invention, the three-stage gradient cooling process significantly reduces the internal stress of the film, improves the dimensional stability, and reduces the warping shrinkage of subsequent processing; the thickness deviation of the thin film is controlled within + / -0.01 mm through an online thickness detection and automatic adjustment system, so that the product precision is improved; the surface tension of the film is stably improved by the corona post-treatment process, and the application scene is widened; through strict raw material pretreatment, the bubble defect of the film is effectively avoided, and the appearance quality of the product is improved; and a combined process of high-speed mixing and double-screw extrusion is adopted, so that uniform dispersion and full plasticization of the materials are ensured, and the problems of crystal points, stripes and the like are reduced.

The invention discloses a high-bonding-strength flame-retardant composite current collector base film and a preparation method thereof. The high-bonding-strength flame-retardant composite current collector base film is prepared from the following raw materials in parts by weight: 100 parts of PP resin, 1.5 parts of a lubricant, 0.8 part of an antioxidant and 16 parts of reinforced flame-retardant composite particles, the reinforced flame-retardant composite particles are prepared by the following steps: S1, preparing amidated porous carbon microspheres; s2, compounding the amidated porous carbon microspheres with mica powder to prepare a composite carrier; s3, loading a flame retardant to prepare a flame-retardant compound; s4, in-situ grafting of maleic anhydride grafted polypropylene is carried out, and the reinforced flame-retardant composite particles are obtained. By adding the reinforced flame-retardant composite particles into the PP resin, the flame retardance and mechanical strength of the PP-based composite current collector base film and the interface bonding force between the PP base film and the metal conductive layer can be comprehensively improved.

The invention relates to the technical field of film material preparation, and discloses a polylactic acid antibacterial packaging film and a preparation method thereof, the polylactic acid antibacterial packaging film comprises the following raw material components by weight: 60-80 parts of polylactic acid, 10-20 parts of polyvinyl alcohol, 10-20 parts of nano zinc oxide, 0.5-1.5 parts of nano cellulose, 1-3 parts of an antibacterial agent, and 10-15 parts of corn starch; the antibacterial agent is prepared from the following components in parts by weight: 5-10 parts of carboxymethylated chitosan and 0.5-2 parts of a dynamic disulfide bond cross-linking agent, the substitution degree of the carboxymethylated chitosan is greater than or equal to 80%, the antibacterial agent is prepared from tea tree essential oil and eugenol, and the dynamic disulfide bond cross-linking agent is bis (3-aminopropyl) disulfide. By adopting a composite system of carboxymethylated chitosan and a dynamic disulfide bond cross-linking agent, the technical effects of humidity-triggered self-repairing and mechanical property synergistic improvement are achieved, and compared with a packaging film with a single polymer base material in the prior art, the problem of antibacterial failure caused by mechanical damage is solved.

The invention discloses a microporous diaphragm for a low-electrical-impedance lithium battery and a preparation method of the microporous diaphragm. The diaphragm comprises: a base film layer, wherein the base film layer is of a microporous structure formed by biaxially stretching polypropylene and / or polyethylene; the surface of the base film layer is coated with the functional coating, and the functional coating contains mixed slurry of inorganic nanoparticles and a binder; the surface modification layer is formed by introducing a hydrophilic electrolyte group on the surface of the functional coating through plasma treatment or chemical grafting. The base membrane layer forms a uniform micropore structure through a two-way stretching process, the functional coating is formed by compounding nano silicon dioxide or aluminum oxide and polyvinylidene fluoride according to a specific proportion, a porous layer with gradient pore diameter is formed, the pore size of the porous layer is smaller than that of the base membrane layer, and efficient permeation of electrolyte is ensured. Electrolyte-philic groups such as sulfonic groups are introduced into the surface modification layer, so that the wettability of the diaphragm to an electrolyte is remarkably improved. During preparation, the base membrane is formed through melt blending, two-way stretching and pore-forming agent extraction, and then the functional layer is constructed through slurry coating and a low-temperature plasma treatment or sulfonation process. The diaphragm combines gradient aperture design, inorganic filler enhancement and surface chemical modification, and realizes low impedance, high thermal stability and excellent mechanical strength.

The invention relates to the field of electromagnetic functional composite materials, and particularly discloses a multi-layer composite structure flexible frequency selective surface material and a preparation method thereof. The ultra-high molecular weight polymer fiber-reinforced polymer-based composite material thin-film mechanical enhanced band-pass frequency selection array sequentially comprises an acrylic acid polyvinylidene fluoride organic polymer coating environment-resistant layer, a metal oxide organic film isolation layer, an ultra-high molecular weight polymer fiber-reinforced polymer-based composite material thin-film mechanical enhanced layer, a band-pass frequency selection layer and a packaging protection layer from top to bottom, and the band-pass frequency selection layer is a hexagonal / circular ring nested band-pass frequency selection pattern array. The packaging protection layer is formed by printing a conductive coating composed of conductive filler / polymer resin matrix, and the packaging protection layer is an ink coating. The flexible frequency selective surface material has the characteristics of light weight, high strength, salt fog / rain / ultraviolet and other severe environments, frequency selective wave transmission and multiple functions, has good gas barrier property, is beneficial to maintaining the shape of an inflatable hangar made of a skin and ensuring normal operation of radar equipment, and has good practical engineering application value.

The invention discloses a multi-layer composite barrier film and a production process thereof, and belongs to the field of polymer composite materials. Aiming at the problems of obvious performance attenuation, poor interlayer binding force and low step-by-step compounding process efficiency of a barrier film in a humid and hot environment in the prior art, the invention provides a five-layer asymmetric structure design: an outer layer, a bonding layer, a barrier layer, a bonding layer and an inner layer. Wherein the barrier layer is formed by blending EVOH and MAH-PA6 and cooperating with nano montmorillonite to form a multi-barrier network, so that the oxygen permeability is smaller than or equal to 0.3 cm / (m.24h. 0.1 MPa), and the water vapor permeability is smaller than or equal to 1.5 g / (m.24h). The production process innovation comprises five-layer co-extrusion melt flow rate ratio control, three-roller gradient cooling and a bidirectional plasma processing technology, the continuous production speed is larger than or equal to 120 m / min, and the interlayer peeling strength is larger than or equal to 8 N / 15 mm. The barrier property stability is remarkably improved.

The invention relates to the technical field of capacitor films. The invention discloses a preparation process of a multilayer polypropylene capacitance film, which comprises the following steps: S1, raw material preparation: preparing basic resin, a nano ceramic filler, a nucleating agent and an antioxidant into multilayer raw materials respectively; s2, fusing multiple layers of raw materials by an independent screw extruder, and compounding by a co-extrusion die head to form a film blank; and S3, carrying out air ring gradient cooling on the film blank. And S4, longitudinally and transversely stretching the film blank. And S5, performing heat setting in a segmented heating furnace, and performing corona treatment to improve surface energy. And S6, segmentally curing the moisture-proof coating by using an infrared oven. The multilayer heterostructure is adopted, the comprehensive performance of the capacitor film is improved through material matching, the dielectric constant, the breakdown strength and the moisture resistance are enhanced, and the problem of considering the dielectric property and the mechanical property is solved. The innovative process guarantees stable performance, is compatible with an existing production line, can realize large-scale production, meets the requirements of fields such as new energy and the like, and provides a feasible scheme for localization of high-performance capacitor films.

The invention relates to the technical field of high-barrier environment-friendly packaging films, and discloses a high-barrier environment-friendly packaging film with an antibacterial function, the high-barrier environment-friendly packaging film comprises a base layer, a nano composite barrier layer, a bio-based functional layer and an outer protective layer from bottom to top in sequence, and the layers are tightly attached through a coated starch-based adhesive. According to the high-barrier environment-friendly packaging film with the antibacterial function, good biodegradability of polyhydroxyalkanoate adopted in the base layer film, polycaprolactone which is adopted in the nano-composite barrier layer film and has a biodegradable function and konjac glucomannan in the biological functional layer film are utilized; the composite packaging film can be decomposed into carbon dioxide and water by microorganisms in various environments, has excellent flexibility and processability, can adapt to different packaging requirements, provides basic flexibility, structural support and green and environment-friendly effects for the whole packaging film, and has a wide application prospect. The procyanidine arranged in the outer protective layer film provides stronger antibacterial property and water solubility for the whole packaging film.

The invention belongs to the field of functional textile materials, and provides a directional moisture-conducting, dry, comfortable, breathable and quick-dry fabric and a preparation method thereof. A three-layer composite structure design is adopted, the outer layer is a gradient wetting structure formed by attaching a thermoplastic polyurethane film subjected to single-face thermal orientation treatment and knitted fabric, the middle layer is a hydrophilic non-woven fabric, the inner layer is a knitted fabric subjected to hydrophilic finishing, and the two layers are compounded through a hot melt adhesive dot-shaped net. Hydrophilic blocks of the thermoplastic polyurethane film are directionally enriched through single-face contact heating, gradient distribution with one hydrophilic side and one hydrophobic side is formed, and the hydrophobic surface is coated with a low-surface-energy coating. The fabric has excellent one-way moisture conduction performance, moisture can be rapidly transmitted from the inner layer to the outer layer and rapidly volatilized, dryness and comfort of the close-fitting fabric are kept, meanwhile, the fabric has good air permeability and quick-drying performance, the moisture conduction rate is increased by 30% or above compared with that of traditional fabric, and the fabric is suitable for being popularized and applied. The fabric has wide application value in the fields of sportswear, outdoor equipment, leakage-proof underpants and the like.

The invention relates to the technical field of research and development of BIB liquid packaging materials, and discloses a PE-PA-based composite film, a manufacturing process and an application in BIB liquid packaging, and specifically comprises the following steps: synthesizing a PE-PA compatilizer; the preparation method comprises the following steps: carrying out ring-opening reaction on an epoxy functional group of a PE-PA compatilizer and an amino functional group or a carboxyl functional group at a PA resin molecular chain end to prepare PE-PA compatilizer grafted nylon resin, and carrying out physical anchoring action on a long-chain alkane structure on the PE-PA compatilizer grafted nylon resin and a PE resin molecular chain to prepare the PE-PA alloy master batch; low-density polyethylene resin is used as a raw material of a supporting layer, PE-PA alloy master batch is used as a raw material of a functional layer, metallocene polyethylene resin is used as a raw material of a heat sealing layer, a three-layer co-extrusion blow molding film forming technology is adopted, the PE-PA composite film is prepared, and the film product is excellent in comprehensive performance and can be used for manufacturing a BIB bag body.

The invention relates to a preparation method of a hydrophobic and oleophobic PTFE membrane, and belongs to the technical field of PTFE membrane preparation. Aiming at the problems that an existing PTFE membrane is difficult to construct a micro-nano multi-stage coarse structure and has a synergistic effect with low chemical surface energy, the hydrophobic and oleophobic properties are insufficient and the structural stability is poor, the key points of the technical scheme provided by the invention are as follows: firstly, carrying out ethanol ultrasonic cleaning on a PTFE base membrane of 20-30 microns, and carrying out vacuum plasma treatment to form a nano coarse structure and oxygen-containing polar group active sites; then, under the protection of nitrogen, immersing into an ethanol solution containing perfluorodecyltriethoxysilane, dibutyltin dilaurate and nano cellulose whiskers, carrying out hot-pressing compounding with PET non-woven fabric, carrying out heat treatment, and finally, coating with a fluorine-containing polymer nano fiber layer through an electrostatic spinning process; the composite hydrophobic layer with the synergistic effect of a micro-nano multistage coarse structure and chemical low surface energy is formed, the water contact angle is larger than or equal to 155 degrees, and the oil contact angle is larger than or equal to 130 degrees. The PTFE film prepared by the preparation method can be used in the fields of waterproof breathable materials, self-cleaning surfaces, oil-resistant packaging and the like.

The invention discloses a multilayer co-extrusion heat-shrinkable film and a preparation method thereof, the film comprises an outer wear-resistant layer, a middle support layer and an inner functional layer, the thickness ratio of each layer is 1: 3: 1-1: 5: 1, the total thickness is 50-150 [mu] m, and the raw materials are prepared according to respective formulas. The preparation method comprises the steps of raw material preparation, melt mixing, die head extrusion, two-way stretching, water-cooling shaping, electronic crosslinking, aging treatment, heating softening and cold and hot shaping. The carbon nanotubes (CNT) and the h-BN nanosheets synergistically hinder crack propagation in the middle layer, so that the crack propagation resistance of the film is remarkably improved, the tensile strength, the thermal shrinkage rate and other properties are also optimized, compared with a traditional film, the comprehensive properties of wear resistance, high strength and high thermal shrinkage rate are achieved through interface collaborative design, meanwhile, the production cost is reduced by 20-30%, and the application prospect is wide. The method is suitable for food packaging, electronic device protection and other fields.

The invention relates to the technical field of BOPP (biaxially-oriented polypropylene) films, in particular to a scratch-resistant adhesive-free matt film and a preparation method thereof, and the scratch-resistant adhesive-free matt film comprises a matt layer, a core layer and a thermal composite layer which are sequentially arranged, the matt layer comprises co-polypropylene, high-density polyethylene, 2.0-2.5 wt% of linear alkyl silicone (the weight-average molecular weight is 12-150 thousands, and the surface tension is 42-45 mN / m) taking maleic anhydride modified aziridine as a terminal group, and 2000-4000 ppm of spherical polymethyl methacrylate (the particle size D50 is 4.0-5.0 microns); the core layer comprises homo-polypropylene; and the thermal composite layer comprises an ethylene-vinyl acetate copolymer and 2000 to 4000 ppm of a spherical anti-blocking agent. According to the scratch-resistant adhesive-free matt film, through collaborative design of the components of the matt layer and the thermal composite layer, balance of scratch resistance, high surface tension (printing applicability) and winding and unwinding smoothness of the surface of the matt layer is achieved, and a solution for the scratch-resistant generality problem of the matt surface of the high-end BOPP matt film is provided.

The invention discloses a synchronous temperature control method for co-extrusion molding of a multilayer polymer film, and relates to the technical field of high polymer material processing, and the method comprises the following steps: setting a target temperature interval of each polymer layer of the multilayer polymer film, and according to the melting characteristics, heat sensitivity and interface bonding requirements of each layer of material, setting a target temperature interval of each polymer layer of the multilayer polymer film; respectively determining an extrusion temperature set value and an allowable fluctuation range; through layered independent temperature control and preheating matching, thermal behavior synchronization of multiple polymer melts is achieved, and the interface bonding stability is improved; through a die head heat insulation and buffer structure, interlayer heat interference is effectively shielded, and the integrity of a functional layer is guaranteed; through the intelligent closed-loop temperature control system, the state of each temperature control area is predicted and adjusted in real time, and self-adaptive optimization of thermal control is achieved. And the co-extrusion quality, the consistency and the production intelligent level of the multi-layer film are integrally improved.

The invention relates to the technical field of biomedical materials, and discloses an electret electrostatic therapy membrane and a preparation process thereof.The electret electrostatic therapy membrane is prepared from, by mass, 15%-20% of fluorinated polyether ester, 10%-20% of a composite nano-fiber material, 10%-20% of a composite nano-fiber material, 10%-20% of a composite nano-fiber material and the balance water. 1%-2% of carboxymethyl chitosan; 2-5% of nano cerium oxide particles with the particle size of 50-100 nm; 0.5-1.0% of graphene quantum dots, the particle size of which is 5-10 nm; 1%-2% of sodium hyaluronate; the components are prepared into a film through an electrostatic spinning method, electret performance is given to the film through a charge injection process, finally, the film body is attached to a flexible silica gel adhesion layer, and the flexible silica gel adhesion layer is externally coated with a peelable protective film so that the structural integrity can be kept before the flexible silica gel adhesion layer is used. The composite membrane body disclosed by the invention shows excellent adhesion, charge activation capability and thermal response performance in applications of electrostatic therapy, dielectric assisted stimulation and the like, and has good multi-scene adaptability and clinical application potential.

The invention relates to the field of cellular board pressing machines, in particular to a pressing device for a non-adhesive cellular board. The conveying rollers are symmetrically arranged on the inner side of the mounting frame, and the outer sides of the conveying rollers on the two sides are sleeved with a conveying belt; a limiting pressing unit; an auxiliary maintenance unit; wherein the limiting press-fit unit comprises a supporting assembly, a pressing assembly, a knocking assembly and an automatic limiting assembly, the supporting assembly is arranged on the outer side of the conveying belt, connected with the mounting frame and connected with the auxiliary maintaining unit, and the pressing assembly is arranged between the supporting assembly and the conveying belt; an automatic limiting assembly connected with the supporting assembly is further arranged on the outer side of the pressing assembly, a knocking assembly is further arranged on the pressing assembly, the limiting press-fit unit is arranged and matched with the auxiliary maintaining unit, the stability of the non-adhesive cellular board in the pressing process can be guaranteed, bubbles at the connecting position can be discharged in the pressing process, and the pressing efficiency is improved. And therefore, the stress of the non-adhesive cellular board is more uniform, and the strength of the non-adhesive cellular board after compression molding is ensured.

The invention belongs to the technical field of PCTFE film preparation, and particularly relates to a preparation process of a PCTFE film with low water vapor permeability, high strength and yellowing resistance. The preparation process comprises the following steps: (1) preparing modified polytrifluorochloroethylene resin; (2) preparing a mixture of fluorosilane modified alpha-zirconium phosphate and vermiculite nanosheets; (3) preparing a KH-550 silane coupling agent modified aluminum borate crystal whisker; and (4) preparing the PCTFE film with low water vapor permeability, high strength and yellowing resistance. According to the preparation technology of the PCTFE film, segmented temperature control is matched with the shearing speed in the twin-screw extrusion process, agglomeration of a mixture of fluorosilane modified alpha-zirconium phosphate and vermiculite nanosheets is avoided, performance complementation of all the components is ensured, the strength of the prepared PCTFE film is enhanced through aluminum borate whiskers, and the tensile strength of the PCTFE film is improved. The antioxidant and the ultraviolet light absorber solve the oxidation problem in high-temperature processing, and synchronous improvement of barrier, strength and weather resistance is achieved.

The high-performance insulation blanket comprises a surface layer, an EVA adhesive layer and a surface layer which are sequentially arranged, and the surface layer and the EVA adhesive layer are attached in a calendering mode; the surface layer is prepared from the following raw materials in parts by weight: 45 to 55 parts of ethylene-vinyl acetate copolymer, 10 to 20 parts of natural rubber, 8 to 18 parts of PA6 short fiber, 7 to 10 parts of dopamine modified mica powder, 6 to 10 parts of MAH-g-EVA, 10 to 15 parts of flame retardant, 0.2 to 0.4 part of antioxidant, 0.8 to 1.2 parts of lubricant and 2 to 4 parts of coloring agent. In the surface layer formula system, under the synergistic effect of the natural rubber, the PA6 short fiber and the dopamine modified mica powder, the tear resistance and puncture resistance of the material are greatly improved, and meanwhile, the material has excellent comprehensive properties such as high temperature resistance, insulation, flame retardance and aging resistance, and is suitable for the field of high-requirement insulation protection.

The invention relates to the technical field of preparation of medical supplies, in particular to a surgical membrane and a preparation process. During specific use, firstly, a polyurethane base membrane is selected and subjected to plasma treatment; spraying a nano SiO2 dispersion liquid containing a photoinitiator on the surface of the treated polyurethane base film, and then performing ultraviolet patterning irradiation to form a micro-bulge structure to obtain a base material layer; projecting the colloidal fluid to a temperature gradient mask through a digital micromirror device, so that the colloidal fluid is subjected to regional thermal polymerization on the substrate layer to form an intelligent adhesive layer with viscosity gradient; by adopting an aerosol jet printing technology, super absorbent fibers and polyvinyl alcohol-borax dynamic crosslinking hydrogel are co-deposited to form a drainage layer, so that the technical problems that a surgical membrane prepared by a surgical membrane preparation mode in the prior art is inflexible in adhesion and poor in surface structure performance, and a preparation process is difficult to accurately control are solved.

The application relates to the technical field of waterproof coiled materials, in particular to a preparation method of an anti-aging modified asphalt waterproof coiled material, which comprises a polyethylene film, a base layer and a modified asphalt base body, wherein the modified asphalt base body comprises the following raw materials in parts by weight: 45-60 parts of asphalt, 10-15 parts of SBS elastomer, 8-12 parts of a softening agent, 3-5 parts of a waterproof functional agent, 4-6 parts of an anti-aging agent, 5-9 parts of SBR, 5-10 parts of a composite filler and 0.03-0.05 parts of an initiator; the anti-aging modified asphalt waterproof coiled material prepared by the method has excellent waterproof performance, heat aging resistance and ultraviolet aging resistance, and the anti-aging modified asphalt waterproof coiled material also has a complex network structure, which endows the base body with excellent mechanical properties.

The invention relates to the field of biodegradation, and discloses a full-biodegradable composite film as well as a preparation method and application thereof. The composite film comprises a barrier layer, a protective layer and a bonding layer, the protective layer is arranged on the surface layer of the composite film, and the barrier layer and the protective layer are bonded through the bonding layer; matrix resin B of the bonding layer is selected from degradable resin grafted polar monomers and / or degradable resin grafted monomers containing groups capable of reacting with hydroxyl; the matrix resin C of the barrier layer at least contains polyglycolic acid with multimodal molecular weight distribution. The composite film provided by the invention has excellent barrier property and biodegradability, and also has good interlayer peel strength and heat sealing strength.

The invention discloses a preparation method of an environment-friendly degradable single-sided perspective sticker, and belongs to the technical field of modified nano materials. The method comprises the following steps: (1) preparation of a multi-layer composite structure: mixing polylactic acid and poly (butylene succinate), adding nano-montmorillonite and a surface modifier, and carrying out melt blending to form a first-layer melt; stirring poly (butylene adipate-co-terephthalate) and fluorescent carbon nanodots to form a second layer of melt; the first layer, the pressure-sensitive adhesive layer and the second layer are co-extruded and compounded to form a film blank. And (2) construction of the nano-film: biaxially stretching the film blank, imprinting a micropore array, dipping in the silver nanoparticle suspension, and drying to obtain the nano-film. And (3) coating functionalization treatment: immersing into a fluorine-containing nano coating solution, and curing. And (4) post-treatment: carrying out secondary curing. The obtained single-sided perspective sticker is suitable for the fields of buildings, vehicle privacy films and the like, and solves the problems of serious pollution and slow degradation of a traditional sticker.

The invention discloses a composite film based on light-biological synergistic gradient degradation and a preparation method thereof, the composite film sequentially comprises a light response layer, a transition layer and a biological response layer from outside to inside, and the light response layer comprises a polycaprolactone matrix, a tetraphenylporphyrin iron photosensitizer and anatase type TiO2 nanorods; the transition layer is a gradient blend of polylactic acid and modified starch; the biological response layer comprises polyhydroxyalkanoate and bacterial cellulose nanofibers; through the design of the three-layer gradient structure and the construction of the bionic microchannel, the synergistic effect of light degradation, hydrolysis and biodegradation is realized; the composite membrane has excellent mechanical properties and environmental adaptability, the degradation period can be accurately regulated and controlled within 30-180 days, and the soil degradation rate within 60 days reaches 91% or above; the preparation method comprises the processes of electrostatic spinning, gradient co-extrusion and bacterial cellulose in-situ culture. The material can be widely applied to the fields of agricultural mulching films, food packaging and the like, and the problems that a traditional degradable film is poor in mechanical property and uncontrollable in degradation are solved.

The invention relates to the technical field of glass fiber felts, in particular to a high-strength fire-resistant glass fiber felt and a preparation method thereof. The high-strength fire-resistant glass fiber felt is characterized by comprising a fire-resistant glass fiber felt base material prepared by mixing glass fibers and chopped basalt fibers, and the mass ratio of the glass fibers to the chopped basalt fibers is (4-5): 1; the glass fibers and the chopped basalt fibers are subjected to oxygen plasma treatment. The glass fiber and the short-cut basalt fiber are compounded according to a specific proportion, and the performance advantages of the glass fiber and the short-cut basalt fiber are combined. The glass fibers provide high modulus and corrosion resistance, and the basalt fibers enhance high temperature stability and impact resistance. Active groups are introduced to the fiber surface through oxygen plasma treatment, and chemical bonding with resin is enhanced. The optimized fiber mixing ratio remarkably improves the tensile strength and high temperature resistance of the base material, meanwhile, the binding force of the fibers and the resin is enhanced through oxygen plasma treatment, internal pores of the material are reduced, and the material is more compact and durable.