1990 results about "Sintering" patented technology

The invention provides a performance optimization and regulation method for a high-temperature sintering furnace, and belongs to the technical field of intelligent regulation, and the performance optimization and regulation method comprises the following steps: arranging sensors in each heating area of the high-temperature sintering furnace, and monitoring the heating areas in real time; constructing a heating area operation state database, comparing the collected real-time data with a preset sintering process parameter range, and analyzing to obtain a performance analysis set of each heating area; establishing a three-dimensional heat conduction model, simulating heat flow distribution of each heating area under different heating powers and temperature settings, determining a thermal coupling effect of each heating area in different stages, and determining a heat transfer coefficient between adjacent heating areas; and an initial strategy of the high-temperature sintering furnace is determined, the initial strategy is optimized based on the auxiliary parameters of all the heating areas, and all the heating areas of the high-temperature sintering furnace are regulated and controlled according to the optimization strategy. The problems of inaccurate temperature control, single parameter analysis, insufficient thermal coupling effect processing and the like in the traditional regulation and control technology are effectively solved.

According to the mullite castable preparation method based on comprehensive utilization of the secondary aluminum ash nonferrous smelting slag, components are regulated and controlled by controlling the molar ratio of Al2O3 to SiO2, so that porous light mullite stably falls into a mullite phase region, and generation of excessive corundum phases is avoided. PMMA microspheres, corn flour, carbonized rice husks and SiO2 coated calcium carbonate composite pore-forming agent systems are adopted, and a layered slurry formula, gradient slip casting and segmented sintering processes are combined, so that the porosity and strength distribution are accurately regulated and controlled, and low-temperature sintering and amorphous phase change control are realized. By optimizing the grading of the porous light mullite aggregate and adding the homologous fine powder, the bonding strength and compressive strength of the castable are improved. And finally, the surface of the castable is coated with a compact mullite coating, so that the porosity is reduced, and the erosion resistance, corrosion resistance and stripping resistance are remarkably improved. The obtained castable has the advantages of light weight, high temperature resistance, high strength, low cost and excellent thermal stability and erosion resistance.

The invention discloses a production method of a high-performance sintered neodymium-iron-boron magnet. The production method comprises the steps of rapid quenching flaking, hydrogen decrepitation mixing, magnetic field forming, multi-stage treatment and composite coating. A nanocrystalline sheet is prepared through a rapid quenching technology, and uniform distribution of a grain boundary phase and rare earth elements is achieved through hydrogen decrepitation and material mixing; forming in a strong magnetic field and applying high pressure to improve the orientation degree; through high-temperature sintering, medium-temperature annealing and low-temperature aging treatment, magnet densification, grain boundary phase reconstruction and a magnetic domain structure are optimized; and finally, the corrosion resistance is improved by adopting a composite coating. The high-performance sintered neodymium-iron-boron magnet produced by the method comprises a main phase alloy, a grain boundary phase additive and a rare earth supplementary phase. Through low-oxygen nanocrystal preparation, grain boundary coordinated regulation and green process integration, compatibility of high performance, low cost and environmental protection is realized, and sustainable development of the rare earth permanent magnet material is promoted.

The invention discloses copper-containing slurry suitable for high-temperature sintering and a preparation method thereof, and the copper-containing slurry comprises the following components in percentage by mass: 10-80% of copper powder, 0-80% of silver powder, 0.2-1% of low-softening-point glass powder, 0-3% of high-softening-point glass, 15-20% of an organic carrier and 0.5-3% of an organic auxiliary agent, the low-softening-point glass powder is of a Pb-Te-Li system, the softening temperature ranges from 250 DEG C to 350 DEG C, and the softening temperature is lower than the decomposition temperature of the organic coating agent on the surface of the copper powder. The preparation method comprises the following steps: adding the components according to the ratio, stirring until the components are uniformly dispersed, grinding and sieving to obtain the copper-containing slurry suitable for high-temperature sintering. According to the prepared copper-containing slurry, the low-softening-point glass powder is adopted as a key component, a liquid-phase protection layer is formed in the high-temperature sintering process, oxidation and diffusion of copper are effectively inhibited, and the oxidation resistance and the conductive stability of the copper-containing slurry are improved. Meanwhile, the slurry has good flowability and printing performance, and can meet the requirements of the photovoltaic industry for efficient and low-cost conductive materials.

The invention discloses an integrated preparation method of a SiC-based composite material environment barrier coating in the technical field of aviation thermal structure materials, which comprises the following steps: cleaning a substrate, carrying out vacuum impregnation of phenolic resin and curing, coating Si slurry to form a bonding layer, coating rare earth silicate slurry to form a barrier layer, and drying to obtain the SiC-based composite material environment barrier coating. And finally carrying out high-temperature heat treatment in an inert atmosphere. According to the method, through an integrated slurry coating and gradient curing process, the performance of a base body is protected, and meanwhile efficient preparation of the coating is achieved; by adopting an integrated slurry coating and gradient curing technology and combining with an optimized medium-temperature sintering process, the matrix performance is effectively protected while the compactness of the coating is ensured, the bonding strength and interface stability of the coating are improved through the design of the phenolic resin transition layer and the silicon bonding layer in cooperation with the rare earth silicate barrier layer, and the bonding strength of the coating is improved. And the coating shows excellent protection performance in a high-temperature corrosion environment.

The invention relates to the technical field of high-performance structural ceramic materials and corrosion resistance optimization thereof, in particular to a preparation method of high-performance silicon nitride ceramic, which realizes performance improvement through dynamic optimization of a composite sintering aid, closed-loop regulation and control of air pressure sintering and multi-process data linkage. In the raw material pretreatment stage, a laser particle size analyzer is adopted for monitoring particle size distribution in real time, surface modification parameters are adjusted in a linkage mode, and a uniform monomolecular coating layer is formed; the proportion of rare earth oxide and aluminum oxide in the composite sintering aid is dynamically adjusted according to the fluctuation of the mixing torque, and agglomeration and segregation of the aid are inhibited. And in the air pressure sintering stage, the argon pressure and the heating rate are dynamically adjusted based on the slope of a shrinkage curve, and directional arrangement of beta-phase grains is promoted by combining low-temperature nitrogen protection and high-temperature argon densification. And multi-dimensional process control synergistically optimizes grain boundary components, structure and density, so that the corrosion resistance and the service life of the silicon nitride ceramic in a sulfur-containing environment are remarkably improved and the service life of the silicon nitride ceramic in the sulfur-containing environment is remarkably prolonged.

The invention relates to the technical field of sole processing, in particular to a sole composite processing method, which comprises the following steps: according to the rigidity requirement of an arch support area, preparing high-density slurry in which silicon nitride ceramic powder accounts for 30-40%, forming # imgabs0 # crystal phase through microwave-assisted sintering, and controlling the porosity to be 10-20%; according to the energy rebound requirement of the forefoot buffer area, graphene oxide / carboxymethyl cellulose aerogel powder is added into the slurry until the concentration is 25%, and the porosity is increased to 40-60% by combining the honeycomb porous network design; a nano silicon dioxide reinforcing agent is introduced into a wear-resistant area of the heel to 15%, a diamond-like carbon coating is formed through plasma surface treatment, and the porosity is limited to be 5-15%. According to the invention, silane is encapsulated by adopting polyurea microcapsules, and is released only when the material is damaged, so that dynamic self-repairing is realized, the shoe sole is endowed with dynamic repairing capability, and the service life is prolonged.

The invention provides a spacecraft quartz powder heat insulation tile which is prepared by adopting high-purity quartz powder (SiO2) as a main raw material and combining a high-temperature-resistant ceramic fiber reinforcement and a nano aerogel heat insulation layer through a high-temperature sintering process. The heat insulation tile has the following advantages: 1, the heat insulation tile has excellent high temperature resistance, and can tolerate 1600 DEG C high temperature for a long time and tolerate 1800 DEG C instantaneous thermal shock for a short time; 2, repeated use: the structure is stable, and high strength is still kept after multiple thermal cycles; light weight: the density is low (less than or equal to 0.5 g / cm < 3 >), and the load of a spacecraft is reduced; and 4, the thermal conductivity is low (less than or equal to 0.05 W / m.K), and heat transfer is effectively isolated. The method is suitable for thermal protection systems (TPS) of spacecrafts, such as thermal insulation of reentry capsules and rocket engine nozzles.

The invention relates to the technical field of inductors, in particular to an inorganic insulation integrally-formed power inductor and a preparation method thereof. The method comprises the following steps: S1, selecting a coil; s2, pre-stretching the coil; s3, pre-coating of inorganic powder is carried out; s4, pressing the magnetic powder; s5, sintering the ceramic layer at high temperature; and S6, integrally forming the inductor. By reasonably selecting the material and shape of the coil and the type of the magnetic powder and combining high-temperature sintering at the temperature of 250 DEG C or above, the magnetic conductivity and the bias resistance are improved, the diversified requirements of high frequency, high temperature, high power density and the like are met, and the performance of insulation, heat conduction and the like can be optimized; according to the integrated forming process, coil pre-packaging and magnetic core forming are completed in one step, production procedures are reduced, process integration and production efficiency are improved, production cost is reduced, the utilization rate of a magnetic core window reaches 100%, and the product size is reduced.

The invention relates to the technical field of intelligent sintering, and discloses a rare earth magnet intelligent sintering production line and a control system, and the system comprises a temperature data collection module, a temperature gradient evaluation module, a temperature change rate fitting module, a heating power adjustment module, a directional heat energy compensation module and an optimized heating instruction generation module. Temperature distribution information in the sintering furnace is obtained; evaluating real-time temperature gradients of different positions in the sintering furnace, and comparing the real-time temperature gradients with a preset gradient threshold value to identify a temperature abnormal region in the sintering furnace; fitting the temperature change rate of the temperature abnormal area; the material phase change critical parameters of the rare earth magnet in the current sintering stage are combined to adjust the heating power of the temperature abnormal area; performing directional heat energy compensation on the temperature abnormal region to obtain a power compensation amount; superposing the power compensation amount and the reference power of the sintering furnace to generate an optimized heating instruction; the intelligent sintering control efficiency of the rare earth magnet can be improved.

The invention discloses a silicon nitride ceramic based on a Yb2O3-MgSiN2 composite sintering aid and a preparation method of the silicon nitride ceramic, the silicon nitride ceramic comprises 93wt% of a Si3N4 matrix, 1-7wt% of Yb2O3 and the balance of MgSiN2, and the total mass of the Yb2O3 and the MgSiN2 as the composite sintering aid is 7wt%. The preparation method comprises the following steps: mixing the raw materials with absolute ethyl alcohol, then adding grinding balls, pouring the mixture into a polyethylene ball milling tank for ball milling, carrying out forced air drying treatment and grinding and sieving treatment on obtained slurry, and then putting sieved powder into a mold for SPS sintering. The problems that traditional silicon nitride ceramic is too high in sintering temperature, insufficient in grain boundary stability and the like are solved, and performance balance of low-temperature sintering, low oxygen content and high grain boundary stability of the silicon nitride ceramic is achieved under the industrial-grade production condition through the synergistic effect of material component innovation and process optimization; and a key material solution is provided for preparing the silicon nitride ceramic with good performance.

The invention discloses a preparation method and application of monolithic BiVO4 photocatalytic foamed ceramic. The method comprises the following steps: 1) preparing composite slurry containing BiVO4 powder, an organic additive and a reinforced phase; (2) uniformly attaching the composite slurry to the organic foam skeleton by adopting an impregnation method; 3) performing drying and heat treatment to remove organic components; and 4) performing high-temperature sintering to form the three-dimensional communicated porous structure. Through the structure-function integrated design, the problems that a traditional powder catalyst is difficult to recover, the activity of an immobilized catalyst is low and a supported catalyst is easy to fall off are solved. The obtained product is high in porosity, the compressive strength is larger than or equal to 0.1 MPa, the specific surface area is larger than or equal to 0.1 m < 2 > / g, visible light can be efficiently utilized for degrading emerging organic pollutants in water, and the degradation rate reaches 20-99%. The material has no nano-particle leakage risk, has excellent mechanical strength, chemical stability and engineering applicability, and provides a feasible scheme for large-scale application of a photocatalytic water treatment technology.

The invention relates to a bionic Al / SiC composite material with a three-dimensional network multilevel structure and a preparation method of the bionic Al / SiC composite material, and belongs to the technical field of new material preparation. According to the method, through the collaborative process of freeze casting and organic foam impregnation, the problem that in the prior art, the multilevel aperture and the complex network structure are difficult to cooperatively regulate and control is solved. The preparation method comprises the following specific steps: preparing tert-butyl alcohol-based ceramic slurry, impregnating the slurry with polyurethane foam, performing freeze casting molding, removing a solvent through freeze drying, performing high-temperature sintering to form SiC ceramic with a three-dimensional reticular hierarchical pore structure, and finally preparing the Al / SiC composite material through a vacuum pressure infiltration process. Wherein a sintering aid is added into the slurry, so that the sintering temperature is obviously reduced; the specification (40-60 ppi) of polyurethane foam, the solid phase content (20-30 vol.%) of slurry, the freezing speed (0-90 DEG C) and the content (5-20 wt.%) of a sintering aid are regulated and controlled. And the cross-scale collaborative design of micron-scale directional holes and millimeter-scale mesh holes is realized. The Al / SiC composite material prepared by the invention has the advantages that the compressive strength, fracture toughness and other properties are obviously higher than those of the traditional single-aperture porous ceramic, and the Al / SiC composite material is suitable for the fields of manufacturing and energy absorption of precise instruments, electronic packaging and optical devices.

The preparation method comprises the following steps: 1, dispersing an iron source, a phosphorus source, a lithium source, a carbon source, a dispersing agent, an element doping agent and a solvent in proportion, dividing the dispersed slurry into three parts of slurry A, B and C in proportion, respectively grinding the three parts of slurry, and respectively carrying out spray drying; 2, pre-sintering the three parts of spray materials at different temperatures, and crushing the pre-sintered materials; and step 3, mixing the crushed pre-sintered materials so as to realize multi-stage grain composition. Carrying out dry mixing on a carbon source and the pre-crushed material according to a certain mass ratio; and 4, carrying out secondary sintering, crushing and demagnetizing on the mixed material to obtain the multi-stage grading high-compaction lithium iron phosphate positive electrode material. According to the invention, primary sintering material grain grading and secondary carbon coating and sintering strengthening are realized through graded particle size design, and the compaction density and the specific capacity of the lithium iron phosphate positive electrode material are synergistically improved.

The invention discloses a rare earth antibacterial ceramic and a preparation method thereof, and belongs to the technical field of ceramic materials, the rare earth antibacterial ceramic comprises a base material, a rare earth antibacterial agent and an auxiliary additive, the base material is coated with a zirconium silicate coating layer; the matrix material is one of aluminum oxide or zirconium oxide, the rare earth antibacterial agent is a ternary composite oxide composed of at least three lanthanide elements, the lanthanide elements comprise Ce, Y, La and Nd, and the invention provides a preparation method of the composite material. Through collaborative innovation of ternary rare earth composite modification, zirconium silicate interface coating and a gradient sintering process, the core problems of single antibacterial spectrum, high-temperature failure and insufficient durability of traditional antibacterial ceramic are solved, and the antibacterial property, stability, biological safety and mechanical property are remarkably improved; and the method has clear technical progress and industrial application value.

A kind of preparation method of high compaction lithium iron phosphate of multistage gradation, including step one: iron source, phosphorus source, lithium source, carbon source, dispersing agent, element dopant and solvent are dispersed according to proportion, slurry after dispersion is divided into A, B, C three slurry according to proportion, three slurry are grinded respectively, and then are respectively carried out spray drying;Step two: three spray materials are respectively pre-sintered at different temperatures, and pre-sintered material is respectively crushed;Step three: the material after pre-sintering is mixed to realize multistage particle gradation.Certain mass ratio of carbon source and pre-crushed material are dry mixed;Step four: after secondary sintering, crushing and magnetic removal process, the multistage gradation high compaction lithium iron phosphate positive material is obtained.The present application realizes particle gradation of once sintered material, secondary carbon coating and sintering strengthening by grading particle size design, and realizes the collaborative improvement of compaction density and specific capacity of lithium iron phosphate positive material.

The invention relates to a preparation method of an MAX phase material. According to the specific technical scheme, precursor powder materials needed for preparing the MAX phase material are mixed to obtain mixed powder, the mixed powder is subjected to mechanical ball milling and cold press forming to form a blank, a to-be-sintered blank is obtained, the to-be-sintered blank is subjected to ultra-fast Joule hot sintering, and the MAX phase material is prepared. The MAX phase material is prepared by using an ultra-fast Joule thermal sintering method, the Joule thermal sintering method has the characteristics of high heating and cooling rate (104 DEG C / min) and high heating temperature (3000 DEG C), and according to the Arrhenius formula, the synthesis rate of the MAX phase material can be greatly improved due to the characteristics of high heating and cooling rate and high heating temperature, and rapid preparation of the MAX phase material is realized. According to the method, the preparation period of the MAX phase material can be greatly shortened, so that the aging can be improved, the energy consumption can be reduced, accurate and controllable preparation can be realized, and the method has important significance on low-cost and large-scale preparation of the MAX phase material.

The invention relates to the technical field of non-oxide ceramic-based composite materials, in particular to Fe-N-based high-entropy nitride ceramic as well as a preparation method and application thereof. The method comprises the following steps: by taking iron powder as a sintering aid, mixing (Hf < 0.2 > Zr < 0.2 > Ti < 0.2 > Nb < 0.2 > Ta < 0.2 >) N high-entropy powder with the iron powder, and carrying out ball milling treatment to obtain ball-milled powder; and under the oxygen-free condition, the ball-milled powder is subjected to sintering treatment, transformation from the loose ball-milled powder to compact and uniform solid solution ceramic is achieved in the sintering treatment process, and the Fe-N-based high-entropy nitride ceramic is obtained. According to the method, a nitride thermal reduction method sintering process is adopted, energy is provided for densification of the Fe-N-based high-entropy nitride ceramic by utilizing reaction heat release of the (Hf0. 2Zr0. 2Ti0. 2Nb0. 2Ta0. 2) N high-entropy powder and the iron powder, the sintering temperature is reduced, energy is saved, and the defect that densification needs to be carried out under a high-temperature condition in the prior art is overcome.

The invention relates to a method for improving early-stage performance of an all-solid-waste cementing material, and aims to improve the early-stage performance of the cementing material. At present, the early strength (1d strength) of an all-solid waste cementing material is generally low, but the characteristic is closely related to construction efficiency and is a key limit for large-scale application of the all-solid waste cementing material. Sintering is not included in the working procedures, and the product does not contain cement clinker. The method comprises the following steps: selecting industrial solid wastes such as steel slag, blast furnace water slag, iron alloy slag, silicomanganese slag, industrial byproduct gypsum, sintering fly ash, fly ash, calcined coal gangue and the like as raw materials; the industrial solid waste is subjected to independent or mixed grinding treatment; by optimizing the raw material ratio and introducing key component minerals, the specific surface area of the cementing material is increased, and active sites of the key minerals are dissociated and exposed. The mass of the introduced key components for optimizing the raw material ratio accounts for less than or equal to 15% of the total mass of the cementing material, the mass fraction of the key and active minerals is increased by less than or equal to 10%, and the early strength of the all-solid waste cementing material is increased by 30%.

The invention relates to the technical field of metal wire processing, and discloses a high-performance metal wire plastic coating process for aerospace engineering, which comprises the following steps: carrying out base material type selection on a metal wire, and carrying out surface treatment of precise cleaning, etching and depth gradient activation; a Ti-Cr alloy and graphene-copper composite transition layer is deposited through a magnetron sputtering technology, and a multi-layer coating structure is formed through electrostatic spraying of a base coating, a fluidized bed dipping function layer and high velocity oxy-fuel spraying of a nano composite coating in sequence; the molybdenum-gold composite sealing layer is prepared by adopting an electric arc spraying technology, and is subjected to vacuum ultraviolet curing enhancement, high-temperature gradient annealing, gradient sintering and vacuum curing treatment; and heat radiation on the surface of the coating is enhanced through laser-induced micro-nano structure regulation and silicon nitride film sputtering. Through collaborative optimization of base material treatment, coating construction, function strengthening and quality control, the interface bonding strength, the comprehensive performance and the environmental adaptability of the spaceflight metal wire coating are remarkably improved, and the service life of the spaceflight metal wire coating is remarkably prolonged.

The invention discloses a carbon nano tube reinforced tungsten carbide titanium metal ceramic material as well as a preparation method and application thereof, and belongs to the field of metal ceramic materials. According to the invention, a spark plasma coupling high-frequency induction sintering method is adopted, CNTs are uniformly dispersed in a material matrix through a method of dispersing CNTs through dry ball milling again, and the uniformly dispersed CNTs improve the discharge environment, reduce the sintering current and reduce the energy consumption under the spark plasma coupling high-frequency induction effect in the sintering process. The high-compactness, high-strength and high-wear-resistance (W, Ti) C-based metal ceramic material is prepared at the sintering temperature of 1350 DEG C by utilizing the ultrahigh conductive complementary effect of the (W, Ti) C metal ceramic material and the CNTs.

The invention provides a Joule heat ultrafast sintering preparation method of barium titanate ceramic with ultrahigh dielectric constant and low loss, which comprises the following steps: ball-milling and mixing barium titanate powder and copper oxide powder, drying, pressing into a cake-shaped sample, carrying out cold isostatic pressing to obtain a sample piece, and carrying out vacuum treatment on Joule heat ultrafast sintering equipment to obtain the barium titanate ceramic with ultrahigh dielectric constant and low loss. Putting the sample preparation sheet between two layers of graphite felts, and starting Joule heat ultrafast sintering equipment to enable the graphite felts to generate Joule heat, so as to realize short-time sintering of the barium titanate ceramic. According to the invention, a Joule heat ultrafast sintering technology is adopted, and Joule heat is generated by directly applying voltage and current to the graphite felt, so that the sintering time is greatly shortened, and environmental pollution is avoided; meanwhile, the dielectric constant of the barium titanate ceramic is greatly improved by adding copper oxide, and the energy consumption is remarkably reduced.

The invention provides a high-performance S < iC > composite material and a preparation method thereof, and the high-performance S < iC > composite material is prepared from the following components in parts by mass: 20-35 parts of industrial grade alpha-SiC powder, 10-14 parts of petroleum coke powder, 4-9 parts of short carbon fiber, 2-6 parts of T < iC > powder, 1-4 parts of sintering aid, 2-7 parts of PMMA microspheres, 4-11 parts of NaCl particles and 1-3 parts of polyvinyl alcohol. In the preparation process of the SiC composite material, full-chain innovation of one-step sintering and low-temperature precise post-treatment is adopted, perfect combination of low cost, high performance, high stability and green manufacturing is achieved, and the long-term bottlenecks of a traditional S-C composite material in the aspects of cost, performance, processing defects and the like are solved.

The invention relates to the technical field of ceramic material repairing, in particular to a one-time sintering repairing method for reactive sintering silicon carbide material defects. Comprising the following steps: measuring the defect size of reactive sintering silicon carbide, and cutting a silicon-based alloy block slightly larger than the defect size; carrying out ultrasonic cleaning on the defect part of the reactive sintering silicon carbide by adopting an organic solvent, wherein the ultrasonic time is 20-40 minutes; placing the silicon-aluminum alloy block above the defect of the reactive sintering silicon carbide, and uniformly paving silicon powder on the surface of the reactive sintering silicon carbide; the mass fraction of the silicon powder is 3-8% of that of the reactive sintering silicon carbide; setting a proper sintering temperature, heating according to a heating rate of 3-10 DEG C / min, and keeping the temperature for 1-3 hours after the sintering temperature is reached; the sintering temperature is higher than the melting point of the silicon-based alloy; and polishing the surface of the repaired reactive sintering silicon carbide to obtain the repaired reactive sintering silicon carbide. The method has the advantages that low-porosity and high-density repair of the crack area is guaranteed, and the optical performance of the reflector is not reduced.

The invention discloses a double-component reinforced 5Y-PSZ dental ceramic material and a preparation method thereof, and relates to the technical field of ceramic material preparation. The method comprises the following steps: mixing ZrCl4 and deionized water, and dropwise adding an ammonia water solution to prepare m-ZrO2 nano ceramic powder; zrOCl2. 8H2O, Y (NO3) 3.6 H2O and deionized water are mixed, the m-ZrO2 nano ceramic powder and polyethylene glycol 2000 are added, and the material is prepared through calcination, spray granulation, hot-pressing presintering and high-temperature sintering. According to the 5Y-PSZ dental ceramic material disclosed by the invention, the nano-scale m-phase ZrO2 is adopted as a reinforcing material and is dispersed and distributed inside the 5Y-PSZ, and through volume expansion generated by t-m phase change of the m-phase ZrO2, the anti-aging performance is guaranteed, and meanwhile, the reinforcement of the 5Y-PSZ dental ceramic material is realized. The invention solves the problem of insufficient strength of the 5Y-PSZ dental ceramic material in the prior art.

The invention discloses a conductive paste, a metallized substrate and a metallization process for manufacturing the metallized substrate, the conductive paste comprises metal particles, the particle size of the metal particles is 0.1-10 [mu] m, and the mass ratio of the metal particles is 80-98%; in the metallization process, a copper layer is arranged on the hole wall of a through hole or a blind hole of a substrate, then conductive slurry is filled in the hole with the copper layer, heating sintering treatment is carried out, and after heating sintering is carried out in an inert gas atmosphere at the temperature of less than or equal to 300 DEG C, metal particles can be fused to form a connection structure or a eutectic structure. A reinforcing layer can be formed between the nano metal particles and the copper layer, and the reinforcing layer is a metal bonding layer or an intermetallic compound layer. The metallization mode is suitable for a through hole or a blind hole of a glass / silicon / ceramic substrate with a high aspect ratio and a micro aperture, and the technical problems that complete filling is difficult to achieve and filling defects exist in an existing electroplating process, the electrical resistivity of conductive paste is high, and the interface bonding force is insufficient can be solved.

The invention provides a ceramic heating plate and a processing method of the ceramic heating plate. The machining method of the ceramic heating plate comprises the steps that the ceramic heating plate formed through normal-temperature isostatic pressing is prepared, the upper surface of the ceramic heating plate is made of aluminum nitride, at least an electrostatic adsorption metal wire mesh electrode is embedded in the ceramic heating plate, the process temperature of normal-temperature isostatic pressing forming is lower than 25 DEG C, and the process air pressure of normal-temperature isostatic pressing forming is lower than 200 Mpa; the process temperature of the high-temperature and high-pressure sintering is higher than 1500 DEG C, the process air pressure of the high-temperature and high-pressure sintering is higher than 100 Mpa, and the high-temperature and high-pressure sintering is used for avoiding the use of a binder or a ceramic layer spraying process, so that the heating temperature is increased, the sparking phenomenon of an equipment corrosive agent under high electrostatic adsorption voltage is avoided, and the service life of the equipment corrosive agent is prolonged. The service life of equipment is prolonged; and the safety performance of the process is improved.

The invention discloses medium-entropy MAB-phase ceramic powder and a preparation method thereof, and belongs to the technical field of ceramic material preparation. The chemical formula of the ceramic powder is (Cr1 / 3Mn1 / 3Fe1 / 3) 2AlB2, and the ceramic powder is structurally characterized in that three transition metal atoms of Cr, Mn and Fe are in random solid solution distribution at an M position. The preparation method of the material comprises the following steps: taking Cr powder, Mn powder, Fe powder, Al powder and B powder as raw materials, burdening according to a stoichiometric molar ratio in a chemical formula (Cr1 / 3Mn1 / 3Fe1 / 3) 2AlxB2 (wherein x is equal to 1.0-1.3), uniformly mixing, and sintering in a non-pressure tube furnace by adopting a two-stage heating sintering process. And crushing, drying and sieving the sintered product to obtain the ceramic powder. According to the invention, excessive aluminum powder is added to compensate high-temperature volatilization, and a two-stage sintering process is combined, so that the generation of an impurity phase is effectively inhibited, and a high-purity target product is successfully prepared. The synthesis method is simple in process, low in equipment requirement and suitable for large-scale production, and a material basis is provided for application of the medium-entropy MAB phase ceramic in the fields of electromagnetic functions, high-temperature environments and the like.