1138 results about "Barium titanate" patented technology

The invention discloses a high-temperature-resistant, high-voltage-resistant and anti-breakdown capacitor base film and a preparation method thereof. The high-temperature-resistant, high-voltage-resistant and anti-breakdown capacitor base film is prepared from the following raw materials in parts by weight: 100 parts of polypropylene; 17 to 36 parts of polyvinylidene fluoride; 3-12 parts of enhanced and improved talcum powder; 1-6.5 parts of modified barium titanate; 1-6 parts of a cross-linking agent; 2-10 parts of a compatilizer; and 0.05-2 parts of an initiator. The capacitor base film is high in mechanical strength, and has excellent high temperature resistance, thermo-oxidative aging resistance, high voltage resistance and anti-breakdown performance; the enhanced and improved talcum powder is constructed by taking expanded layer modified talc as a carrier and titanium dioxide-carbon dot composite particles as a loading component and grafting and coating the organic matter, so that the defects of the talcum powder can be overcome, and the improvement effect of the talcum powder on heat resistance, high-voltage resistance and breakdown resistance can be fully exerted; meanwhile, the system can be endowed with excellent thermo-oxidative aging resistance.

The invention discloses a preparation method of high-polarization bismuth ferrite-lead titanate-barium zirconate titanate-based ferroelectric ceramic, which comprises the following steps: preparing oxide raw materials according to the chemical formula of the bismuth ferrite-barium titanate ceramic-based ferroelectric ceramic, mixing to obtain mixed powder, pre-sintering the mixed powder to obtain pre-sintered powder, granulating the pre-sintered powder to obtain granules, and sintering the granules to obtain the high-polarization bismuth ferrite-lead titanate-barium zirconate titanate-based ferroelectric ceramic. Performing compression molding on the granules to obtain a green body, performing degumming sintering on the green body to obtain sintered ceramic, and performing annealing treatment on the sintered ceramic to obtain the bismuth ferrite-lead titanate-barium zirconate titanate based ferroelectric ceramic. According to the invention, annealing treatment is carried out on sintered ceramic, after annealing treatment, defect dipoles generated by volatilization of Pb and Bi in the ceramic are rearranged under the action of a temperature field, relaxor ferroelectric-ferroelectric phase change occurs in a ceramic phase, a ferroelectric hysteresis loop reflects that the girdling of the loop is opened, and the rectangularity is increased; a bipolar strain curve is converted into a typical butterfly shape of ferroelectric from a bud shape, and the ferroelectricity of the ceramic is further greatly improved.

The invention discloses a method for preparing nano barium titanate based on sol-gel synergistic hydrothermal reaction, which comprises the following steps: (1) dissolving barium acetate in an acetic acid aqueous solution to obtain a barium source solution; weighing tetrabutyl titanate according to the molar ratio of barium to titanium being greater than 1.25, and dissolving the tetrabutyl titanate in alcohol to obtain a titanium source solution; (2) uniformly mixing the barium source solution and the titanium source solution, preserving heat at 20-80 DEG C to obtain gel, drying and grinding to obtain white powder of the barium titanate precursor: (3) preparing a 2-4mol / L inorganic strong alkali aqueous solution, adding the white powder and a dispersing agent into the inorganic strong alkali aqueous solution, and fully stirring to obtain a barium titanate precursor suspension; and (4) transferring the barium titanate precursor suspension into a reaction kettle for hydrothermal reaction, and after the reaction is completed, washing, drying and grinding to obtain the nano barium titanate powder. The preparation method is low in cost, and the prepared nano barium titanate powder is uniform in distribution, spherical or sphere-like in morphology, small in particle size, 80-150nm in average particle size and good in particle crystallinity.

The invention relates to a temperature characteristic controllable multilayer ceramic dielectric capacitor and a preparation method thereof, the multilayer ceramic dielectric capacitor is formed by a dielectric layer A and a dielectric layer B through mutual staggered superposition and firing, the dielectric layer A is composed of barium titanate, magnesium oxide, manganous-manganic oxide, vanadyl acetylacetonate, rare earth oxide A, rare earth oxide B, silicon dioxide, calcium carbonate and zirconium oxide, and the dielectric layer B is composed of barium titanate, magnesium oxide, manganous-manganic oxide, vanadyl acetylacetonate, rare earth oxide A, rare earth oxide B, silicon dioxide, calcium carbonate and zirconium oxide; the dielectric layer B is composed of barium titanate, magnesium oxide, manganous-manganic oxide, vanadyl acetylacetonate, rare earth oxide C, rare earth oxide D, silicon dioxide, calcium carbonate, zirconium oxide and nickel oxide; the multilayer ceramic dielectric capacitor is formed by the dielectric layers A and the dielectric layers B in a staggered and stacked mode through firing, the combination of the double dielectric layers is different from a traditional single dielectric layer, and the capacitor has the advantages of being high in dielectric constant and high in temperature stability at the same time.

The invention relates to the field of shielding materials, and provides lead-free rubber with ionizing radiation shielding performance and a preparation method thereof, and the lead-free rubber is mainly prepared from barium titanate / boron nitride composite filler, barium tungstate / boron carbide composite filler, tungsten powder, bismuth powder, a rubber matrix and an auxiliary agent according to a proportion. The barium titanate particles are uniformly loaded on the surface of the flaky boron nitride, so that the gamma ray and X ray shielding performance is improved, and meanwhile, the boron nitride provides excellent neutron shielding capability; barium tungstate particles are loaded on the surfaces of the boron carbide nanowires to form a multi-scale shielding network, and the shielding effect of neutrons and ionizing radiation is remarkably enhanced. The rubber matrix endows the material with excellent flexibility and mechanical properties. By scientifically optimizing the component proportion and the preparation process, the problems that a traditional high-density shielding material is prone to agglomeration, poor in flexibility and the like are solved, and the material shows excellent performance in the fields of gamma ray, X ray and neutron shielding and is suitable for the fields of nuclear energy, medical protection, industrial radiation protection and the like.

The invention discloses a high-refractive-index nano-composite optical adhesive and a preparation method thereof, and belongs to the technical field of optical transparent adhesives. The optical adhesive is prepared by taking a polyurethane acrylate oligomer with a specific structure as matrix resin, introducing surface-modified barium titanate and zirconium oxide core-shell nanoparticles as a functional filler, and matching with an active diluent, a photoinitiator and a silane coupling agent in a specific proportion. Through the design of the core-shell structure, the core problems that the high-refractive-index nanoparticles are easy to agglomerate in an organic resin matrix, the dispersion stability is poor and the bonding force with a matrix interface is weak are effectively solved. The prepared optical adhesive has a refractive index of more than 1.65, a light transmittance of more than 99% and a haze of less than 0.3% after being cured, has excellent bonding strength, weather resistance and long-term use stability, and is especially suitable for precise lamination of high-end display devices (such as OLEDs (Organic Light Emitting Diodes) and micro-lens arrays).

The invention relates to a self-generating interbody fusion cage and a preparation method thereof, the interbody fusion cage comprises a porous tantalum support and bioactive piezoelectric ceramic arranged on the porous tantalum support, and the bioactive piezoelectric ceramic comprises hydroxyapatite and barium titanate; the preparation method comprises the following steps that the porous tantalum support is obtained through 3D printing, assembling positions of the bioactive piezoelectric ceramics are reserved on the upper surface and the lower surface of the porous tantalum support, the bioactive piezoelectric ceramics are embedded into the assembling positions of the upper surface and the lower surface of the porous tantalum support, and the weight ratio of barium titanate to hydroxyapatite is (92-98): (2-8). Compared with the prior art, the vertebral fusion cage has the advantages of promoting vertebral fusion by utilizing mechanical force in a human body to generate electricity, matching mechanical properties of a contact surface of the fusion cage, providing osteogenesis related ions, being relatively good in interface combination and the like.

The invention relates to the technical field of dielectric materials, and discloses a composite dielectric material and a preparation method and application thereof.The composite dielectric material comprises filler and a base material, the filler is modified barium titanate, and the base material is cyanoethyl cellulose; the modified barium titanate comprises a barium titanate core and a shell, the shell comprises a polymer containing an epoxy group, the core and the shell are connected through a covalent bond, and an infrared spectrum test shows that in an infrared spectrogram of the modified barium titanate, characteristic peaks of the epoxy group and carbonyl respectively exist at 910 + / -10 cm <-1 > and 1720 + / -10 cm <-1 >. Epoxy groups in the modified barium titanate filler can react with hydroxyl groups in a cyanoethyl cellulose matrix material to form covalent linkage, compatibility of the filler and a matrix is improved, meanwhile, a potential well is formed, migration of carriers can be limited, and the composite material has good dielectric performance and energy storage performance.

A dielectric ceramic composition includes a first crystal grain that has a perovskite structure expressed by a general formula of BaTiO3, and has a core portion and a shell portion surrounding the core portion and including dysprosium, and a second crystal grain in which an elemental ratio of barium to titanium is 0.70 or less and a main component is barium titanate composite oxide. An elemental ratio of barium to titanium of the dielectric ceramic composition is 0.90 or more and 0.98 or less.

The invention provides a Joule heat ultrafast sintering preparation method of barium titanate ceramic with ultrahigh dielectric constant and low loss, which comprises the following steps: ball-milling and mixing barium titanate powder and copper oxide powder, drying, pressing into a cake-shaped sample, carrying out cold isostatic pressing to obtain a sample piece, and carrying out vacuum treatment on Joule heat ultrafast sintering equipment to obtain the barium titanate ceramic with ultrahigh dielectric constant and low loss. Putting the sample preparation sheet between two layers of graphite felts, and starting Joule heat ultrafast sintering equipment to enable the graphite felts to generate Joule heat, so as to realize short-time sintering of the barium titanate ceramic. According to the invention, a Joule heat ultrafast sintering technology is adopted, and Joule heat is generated by directly applying voltage and current to the graphite felt, so that the sintering time is greatly shortened, and environmental pollution is avoided; meanwhile, the dielectric constant of the barium titanate ceramic is greatly improved by adding copper oxide, and the energy consumption is remarkably reduced.

The invention relates to the technical field of polymer composite materials, and discloses a nano-ceramic-based composite insulating coating and a preparation method thereof, and the coating is prepared from a composite resin matrix, a composite functional ceramic filler, a double-reactivity organosilicon linker and an initiator. Wherein the composite resin matrix is composed of vinyl-terminated polydimethylsiloxane and a vinyl ether functionalized fluorocarbon copolymer, and a soft and rigid interpenetrating network structure is formed. The composite functional ceramic filler is prepared from needle-shaped silicon nitride, flaky hexagonal boron nitride, nano silicon dioxide, nano cerium oxide and nano barium titanate. According to the invention, a chemical bonding interface is constructed between the inorganic filler and the organic resin, and the synergistic effect of the composite matrix and the multifunctional filler is optimized, so that the coating has excellent adhesive force, flexibility and thermal shock resistance, obtains high volume resistivity and breakdown strength, and meets the insulation protection requirements under harsh working conditions.

The invention belongs to the technical field of metal powder materials, and particularly relates to a method for coating nickel powder with barium titanate, which comprises the following steps: preparing an inner shell of nickel oxide and / or sulfide; dispersing the nickel powder with the inner shell in the dispersion liquid; sequentially adding a barium compound and a titanium compound into the dispersion liquid; the nickel powder with the inner shell and the barium compound and the titanium compound adsorbed on the surface is dried, and the barium compound and the titanium compound on the surface react to form a barium titanate coated outer shell; and dispersing the dried coated powder to form the barium titanate coated nickel powder with the double-shell structure. According to the nickel powder with the double-shell structure prepared by the technical scheme, the co-firing property of the nickel powder and a dielectric material is improved through the barium titanate shell of the outer shell, the combination degree of nickel and the dielectric material can be better improved through the nickel oxide and / or the nickel sulfide of the inner shell, and the dielectric property of the dielectric material is improved. Therefore, the yield of the nickel powder and the dielectric material in the process of preparing the electronic component is improved, and the electrical property of the electronic component is improved.

The invention provides a high-dielectric low-loss X7P type dielectric ceramic material and a preparation method and application thereof, and relates to the technical field of functional ceramic materials, the dielectric ceramic material is composed of a perovskite type compound as a main component and an auxiliary component; wherein the perovskite type compound contains a Ba element and a Ti element, and the auxiliary components comprise a first auxiliary component containing an Mg element, a second auxiliary component containing SiO2, a third auxiliary component containing an Mn element and a fourth auxiliary component containing a rare earth element R. According to the invention, barium titanate is doped and modified, so that the excellent performance of combining different compounds is realized, the dielectric constant and temperature stability of the dielectric ceramic material are improved, and the dielectric loss is reduced.

The invention provides a high-voltage low-loss dielectric material and a preparation method thereof, and relates to the technical field of high-voltage ceramic capacitors, and the high-voltage low-loss dielectric material comprises the following raw materials in parts by mass: 35-38 parts of barium titanate, 20-29.5 parts of strontium titanate, 15-17.5 parts of titanium dioxide, 9-12 parts of bismuth oxide, 3-4 parts of zirconium oxide, 0.8-1.0 part of X, 1.2-1.4 parts of antimony oxide, 1-1.2 parts of calcium carbonate and the like. The preparation method of the dielectric material comprises the following steps: 1, preparing the dielectric material; melting calcium carbonate, magnesium oxide, zinc oxide and the like, performing water quenching, and performing ball-milling granulation to obtain zinc borosilicate glass powder; uniformly mixing the zinc borosilicate glass powder with barium titanate, strontium titanate, titanium dioxide and the like, and granulating to obtain oxide powder; and tabletting and sintering the oxide powder to obtain the high-pressure low-loss dielectric material. The high-voltage low-loss dielectric material is high in dielectric constant, small in dielectric loss, high in compression strength and good in high-temperature stability, and the preparation method is simple.

The invention belongs to the technical field of ceramic materials, and particularly relates to a ceramic dielectric material and a preparation method and application thereof. The ceramic dielectric material provided by the invention is prepared from the following raw materials: barium titanate, calcium zirconate, a sintering aid and a modifier, the sintering aid is a Li-Zn-B-Si glass material; and the modifier comprises one or more of Nb2O5, MnCO3, MgO and RE2O3 (rare earth oxide). The ceramic dielectric material has the advantages of high-temperature stability, high dielectric constant, low loss and high insulating property.

The invention discloses a composite current collector containing a PTC material and a preparation method thereof, and relates to the technical field of current collectors, and the composite current collector comprises a polymer base film and copper metal layers located on the upper and lower surfaces of the polymer base film. The polymer base film is prepared from the following raw materials in parts by weight: 100 to 110 parts of modified polypropylene, 20 to 25 parts of modified PTC (Positive Temperature Coefficient) material, 1.2 to 1.4 parts of lubricant, 0.3 to 0.5 part of initiator and 14 to 18 parts of filler. According to the synthesized modified polypropylene, benzotriazole and an epoxy group are grafted into a polypropylene molecular chain, so that the binding power of a polymer base film and a copper metal layer and the corrosion resistance of the composite current collector are improved. The synthesized modified PTC material is obtained by loading a thiophene ring and DOPO on nano barium titanate, so that the composite current collector has relatively high ultraviolet resistance, flame retardance and thermal runaway resistance. The composite current collector containing the PTC material is high in use safety in a battery and worthy of popularization and application.

The invention belongs to the crossing field of biomedical engineering and additive manufacturing, and particularly relates to a 3D printing metamaterial piezoelectric bone defect repair scaffold, and the pore structure of the scaffold is formed by compounding three extremely small curved surface units, namely Gyandroid, SchwarzP and Diamond, which are defined by mathematical expressions; the porosity of the stent is 30%-70%, and the pore diameter range is 0.1-1 mm; the stent is made of a piezoelectric composite material composed of polyvinylidene fluoride (PVDF), polylactic acid and barium titanate, the piezoelectric composite material comprises the following components in percentage by mass: 30%-55% of polyvinylidene fluoride (PVDF), 20%-45% of polylactic acid (PLA) and 10%-25% of barium titanate (BaTiO3), and the sum of the mass percentages of all the components is 100%. Precise regulation and control of a macrostructure and a microstructure are achieved through a multi-material 3D printing technology, and the system has the mechanical adaptability, degradation controllability and the function of actively promoting bone regeneration and is suitable for large-section bone defect repair scenes such as craniomaxillofacial and long bones of four limbs.

The invention relates to the technical field of composite materials, in particular to a high-conductivity thermosetting resin-based composite material and a preparation method thereof.The high-conductivity thermosetting resin-based composite material is prepared from, by weight, 50-80 parts of epoxy resin, 10-30 parts of conductive carbon nanotubes, 20-40 parts of nano-silver particles, 10-20 parts of functionalized polyurethane prepolymer, 5-15 parts of polyamine curing agent and 2-8 parts of organosilane coupling agent. 5-15 parts of graphene nanosheets, 5-15 parts of aluminum borate whiskers and 5-15 parts of barium titanate nanoparticles; 2-10 parts of conductive polymer microspheres; 1 to 5 parts of nano zinc oxide; wherein the conductive polymer microsphere comprises a core formed by polyaniline or polypyrrole, and a polyurethane polymer or a polyacrylate polymer wrapping the outer layer of the core; the surface of the core is modified by adopting nano silver particles and gamma-aminopropyltriethoxysilane; the conductive polymer microspheres are used for providing a long-range conductive path, the nano-silver particles are used for providing short-range conductive connection, and the conductive polymer microspheres and the nano-silver particles form a multi-layer conductive network.

The invention discloses a self-cleaning composite piezoelectric ceramic membrane as well as a preparation method and application thereof, and belongs to the field of composite ceramic membranes. The technical problem that an existing ceramic membrane separation technology is poor in biomembrane pollution resisting effect is solved. According to the preparation method, the barium titanate ceramic membrane is firstly prepared to serve as the base membrane, then the copper oxide one-dimensional nanostructure is loaded on the piezoelectric ceramic substrate, and the base membrane has a large membrane surface area and can be combined with more catalysts, so that more active sites are provided for catalytic reaction; according to the composite membrane, the hydrophilicity, the anti-pollution performance and the piezoelectric catalysis self-cleaning performance of the membrane are remarkably improved, and pollutants in water can be quickly and effectively separated, so that the flux and the anti-pollution performance of the membrane are improved.

The present invention relates to the technical field of dielectric ceramic powder preparation processes, and in particular, to tetragonal-phase nano barium titanate powder, a preparation method therefor, and a use thereof. The preparation method comprises the following steps: (S.1) preparing a crystalline phase-controllable mesoporous titanium dioxide precursor, adding the mesoporous titanium dioxide precursor into a barium salt solution according to a barium-titanium molar ratio of 2-4, and then adding ethanol and ammonia water to obtain a barium titanate precursor suspension, wherein the volume ratio of ethanol in the barium titanate precursor suspension is 40%-60%; (S.2) carrying out hydrothermal reaction on the barium titanate precursor suspension to obtain a barium titanate suspension; and (S.3) carrying out centrifugal washing, drying and grinding on the barium titanate suspension to obtain tetragonal-phase nano barium titanate powder. In the present application, the barium-titanium molar ratio between an anatase mesoporous titanium dioxide precursor and a barium salt in the hydrothermal reaction process and the proportion of ethanol in a hydrothermal medium in the hydrothermal reaction process are controlled at the same time, such that barium titanate powder having a higher c / a value and particle size uniformity can be obtained.

The invention discloses an A and B site doped BaTiO3-based dielectric ceramic, which is characterized in that the chemical formula of the A and B site doped BaTiO3-based dielectric ceramic is (Bax1Cax2Sr1-x1-x2) (Ti0. 4La0. 2Ce0. 2Ta. 2) O3, 0 < = x1 < = 1, 0 < = x2 < = 1, and x1 + x2 < = 1. The invention also discloses a preparation method of the composition. Other elements are simultaneously introduced into A and B of the barium titanate ceramic dielectric material, so that the high-temperature stability of the barium titanate ceramic dielectric material is improved, the energy storage performance of the barium titanate ceramic dielectric material is also improved, and the defects that an existing barium titanate ceramic dielectric material is poor in dielectric property temperature stability and low in energy storage efficiency are overcome.

The invention relates to the technical field of flexible electronics and sensing, in particular to a capacitive flexible pressure sensor based on a barium titanate composite dielectric layer, which sequentially comprises a lower electrode layer, an upper electrode layer, a lower electrode layer and an upper electrode layer from bottom to top, the composite dielectric layer is arranged on the lower electrode layer and is formed by compounding an elastic polymer matrix and a high-dielectric-constant barium titanate (BaTiO3) filler; the upper electrode layer is made of a flexible conductive material and is arranged on the composite dielectric layer; the lower electrode layer and the upper electrode layer are connected with an external capacitance measuring circuit through wires. According to the sensor disclosed by the invention, the comprehensive performance of high sensitivity, wide detection range, low hysteresis and excellent cycle stability is realized by optimizing the shape of the barium titanate filler, surface modification and composite structure design.

The invention relates to a thin film electro-optical crystal-silicon nitride heterogeneous integrated N * N high-speed optical switch array and a preparation method thereof. The thin film electro-optical crystal-silicon nitride heterogeneous integrated N * N high-speed optical switch array is formed by connecting 1 * 2 or 2 * 2 Mach-Zehnder high-speed optical switch units according to a certain topological structure. Wherein the high-speed optical switch unit is composed of a silicon nitride passive waveguide and a thin-film electro-optical crystal / silicon nitride heterogeneous integrated phase shift region. Comprising but not limited to thin-film lithium niobate, thin-film lithium tantalate, barium titanate and lead zirconate titanate is integrated above the silicon nitride phase shifting arm through a micro transfer printing method to form a heterogeneous integrated phase shifting region. The large-scale high-speed optical switch array with excellent performance is realized by combining the characteristics of ultra-low loss, CMOS compatibility, thermal stability and the like of a silicon nitride material, the characteristics of low power consumption, low loss, high-speed modulation and the like of a thin film electro-optical crystal and the advantages of high flexibility, parallel integration, low cost, low loss and the like of a micro transfer printing method.

A dielectric ceramic composition includes a first crystal grain that has a perovskite structure expressed by a general formula of BaCaTiO3, and has a core portion and a shell portion surrounding the core portion and including a rare earth element and manganese, and a second crystal grain in which an elemental ratio of total of barium and calcium to titanium is 0.70 or less and a main component is barium calcium titanate.

The invention discloses a dielectric and magnetic loss coupling type multi-frequency high-absorption composite wave-absorbing material. The chemical formula of the composite wave-absorbing material is (FeCoNiCraMn) x. (BaTiO3) y, the invention also discloses a preparation method of the composite wave-absorbing material, which comprises the following steps: step 1, mixing iron, cobalt, nickel, chromium and manganese, and carrying out suspension smelting, vacuum gas atomization and sieving to obtain high-entropy alloy spherical powder; secondly, the flaky high-entropy alloy is obtained after ball milling; thirdly, the flaky high-entropy alloy is naturally cooled and then dried; and fourthly, the dried flaky high-entropy alloy is mixed with barium titanate powder, and ball milling is carried out. According to the composite wave-absorbing material, the FeCoNiCrMn series high-entropy alloy provides magnetic loss capacity, barium titanate provides dielectric loss capacity, the synergistic effect of multiple loss mechanisms is achieved, and the composite wave-absorbing material is suitable for the technical field of wave-absorbing materials.

The invention discloses a chip multilayer ceramic capacitor and a preparation method and application thereof. The chip multilayer ceramic capacitor comprises a ceramic sintered body. The ceramic sintered body comprises an inner electrode layer and a dielectric layer which are alternately stacked, and the dielectric layer contains double-shell-layer coated barium titanate-based ceramic crystal grains; the double-shell-layer coated barium titanate-based ceramic crystal grain sequentially comprises an inner core, an inner shell layer and an outer shell layer from inside to outside, the ratio of the area of the inner shell layer to the area of the inner core is 0.1-0.4; the ratio of the area of the shell layer to the area of the inner core is 0.3-0.7; the double-shell coated barium titanate-based ceramic crystal grains contain BaTiO3, R2O3, MgO, M1, M2 and (Ca (1-x-y) BaxSry) ZrO3. The chip multilayer ceramic capacitor provided by the invention has the excellent performances of high capacity, high voltage resistance, high dielectric temperature characteristic and the like.

The invention belongs to the technical field of lithium ion solid-state batteries, and relates to a composite polymer electrolyte membrane as well as a preparation method and application thereof. The preparation method of the composite polymer electrolyte membrane comprises the following steps: generating a precursor salt containing Ba and Ti on the surface of an inorganic solid electrolyte through a wet chemical method, and forming a compact barium titanate coating layer on the surface of the electrolyte in a high-temperature calcination process to obtain the barium titanate surface modified inorganic solid electrolyte; uniformly dissolving a high-molecular polymer material, the barium titanate surface modified inorganic solid electrolyte and a lithium salt in a solvent, heating and stirring to prepare a uniform solution; and drying to form a membrane to obtain the polymer composite electrolyte membrane. Barium titanate has a special piezoelectric property and can be spontaneously polarized in a crystal structure to generate a polarization field, and the polarization field can sensitively sense the nonuniformity of lithium ion transmission dynamics and interact with the nonuniformity to balance the transmission process of lithium ions in the solid electrolyte, so that the bottleneck problem of ion migration in the traditional electrolyte is solved.

The invention discloses an acoustic response light-emitting composite nanomaterial as well as a preparation method and application thereof, and belongs to the technical field of light-emitting composite nanomaterials. The acoustic response luminescent composite nano material provided by the invention comprises hollow mesoporous silica nano particles and europium-doped barium titanate nano particles loaded on the surfaces of the hollow mesoporous silica nano particles and in mesopores; the chemical formula of the europium-doped barium titanate nanoparticles is BaTiO3: Eu < 3 + >; the mass ratio of the hollow mesoporous silica nanoparticles to the europium-doped barium titanate nanoparticles is 1: (0.8-1.5). The sound response luminescent composite nano material provided by the invention can realize detection of sound intensity, and has good temperature stability, and meanwhile, the preparation method is simple and low in cost.

The invention relates to the field of ceramic materials, provides a high-voltage-resistant PTC (Positive Temperature Coefficient) thermal sensitive ceramic material as well as a preparation method and application thereof, and aims to improve the voltage resistance and PTC effect stability of thermal sensitive ceramic. The material is composed of aluminum oxide-coated manganese-doped barium titanate nanorods, hollow-core silicon dioxide microspheres and a glass phase sintering aid, and the electric heating performance and the microstructure stability are optimized by constructing a core-shell structure and a three-dimensional composite system. A hydrothermal method and a sol-gel method are adopted to precisely control a raw material structure, and alcohol dispersion, tape casting and weak oxidizing atmosphere sintering are combined, so that the compactness and consistency of the ceramic are ensured. The material is suitable for high-voltage temperature control elements and over-current protection devices, and is widely applied to the fields of new energy automobile battery pack over-temperature protection, high-voltage power equipment current limiting elements, industrial automatic temperature control switches and the like.

A multilayer ceramic capacitor includes: a capacitor body comprising a dielectric layer and an internal electrode layer; and an external electrode disposed on an outside surface of the capacitor body, wherein the capacitor body includes an active portion where the dielectric layer and the internal electrode layer are alternately disposed, side margin portions disposed at both side end portions of the active portion facing each other, and bonding portions disposed between the active portion and the side margin portions, and at least one of the active portion or the side margin portions includes a barium titanate-based main ingredient including barium (Ba) and titanium (Ti), and gallium (Ga).