The invention discloses a growth method of
calcium-
magnesium-
zirconium doped
gadolinium-
gallium garnet, and relates to the field of
crystal material preparation, and the method comprises the following steps: (1)
raw material preparation and pretreatment: selecting Gd2O3, Ga2O3, CaCO3, MgO and ZrO2
powder with the purity greater than or equal to 99.99%, dividing the
powder into a core layer, a
transition layer and a
surface layer according to a stoichiometric ratio to prepare a gradient doped precast block, and
roasting the gradient doped precast block at 800 DEG C for 4 hours for later use; (2) equipment transformation and debugging: transforming the Czochralski growth furnace into an upper and lower independent double-temperature-zone structure, equipping a PID intelligent
temperature control system, and debugging to form a stable temperature field with an axial
temperature difference of less than 5 DEG C / cm and a radial
temperature difference of 2 DEG C; through a gradient synergistic
doping technology,
crystal lattices of the inch SGGG
crystal are effectively improved, the mismatching rate of the inch SGGG crystal and a high-
bismuth iron garnet epitaxial layer is reduced, the problem of interface defects caused by lattice mismatching of a traditional GGG crystal is solved, the quality of the epitaxial layer is remarkably improved, and growth and preparation of the large-size, low-defect and high-uniformity SGGG crystal are achieved.