604 results about "Deoxidization" patented technology

The invention provides a preparation method of graphene, and particularly relates to a method for preparing biomass graphene employing cellulose as a raw material. The specific preparation method comprises the following steps: 1, preparing a catalyst solution; 2, carrying out ionic coordination and high-temperature deoxidization on cellulose and a catalyst, so as to obtain a precursor; 3, carrying out thermal treatment; 4, carrying out acid treatment, and drying to obtain the graphene, wherein the prepared graphene is uniform in morphology, has a single-layer or multi-layer two-dimensional layered structure; the dimension is 0.5-2 microns; and the electrical conductivity is 25,000-45,000S/m. The preparation method is simple in preparation technology, low in cost, high in yield, high in production safety, and controllable in product dimension and physical property; industrialized production can be realized; the graphene prepared by the method can be applied to electrode materials of super capacitors and lithium ion batteries, and can also be added to resin and rubber as an additive; and the physical property of the material can be improved.

The invention relates to a liquid hydrocarbon mercaptan removal technique capable of deeply removing total sulfur, in particular to a sweetening technique for liquefied gas in an oil refinery. The oil refining liquid hydrocarbon refers to components of liquefied gas and light gasoline, wherein the liquefied gas is a raw material for producing MTBE, and the light gasoline is a component for producing high-cleanness gasoline. In order to solve the problem of high total sulfur in the oil refining MTBE and the light gasoline, according to the shape and the distribution rule of sulfocompounds in the liquid hydrocarbon, processes such as functional reinforcement of a recycle solvent, three-phase mixed reinforced regeneration, regenerated catalyst and extractant separation and recycle solvent deoxidization and the like are adopted in the conventional process of liquid hydrocarbon extraction, oxidization and mercaptan removal, so the technical effects of reinforcing the mercaptan removal depth, improving carbonyl sulfide removal rate, and avoiding forming disulphide in the extracting, saving energy and reducing emission and the like are achieved. Thus, the liquid hydrocarbon can be deeply desulfurated, the problem of high total sulfur in the oil refining MTBE and the light gasoline is solved and the slag discharging quantity in the conventional process is greatly reduced.

The invention relates to a heavy oil and biomass hydrogenation coliquefaction treatment process in which one or two of heavy oil and biomasses are used as raw materials in vacuum gas oil with the distillation range of 360-540 DEG C and FCC (Fluid Catalytic Cracking) oil slurry. In the process, an oil-soluble transition metal organic compound with hydrogenation activity is used as a catalyst, dimethyl sulfide is used as a vulcanizing agent, a full-back-mixing type empty barrel reactor is used as a slurry column hydrogenation reactor, the reaction temperature is uniform, and the structure is simple. By using the process, the conversion rate of the biomasses can be up to over 90wt% at lower hydrogen pressure of 4-8MPa and the temperature of 370-430 DEGC, and the yield of oil phases is up to over 70wt%. A dispersive hydrogenation catalyst adopted in the process can be used for greatly reducing the quantity of green cokes and taking a better deoxidization effect on the biomasses.

The invention discloses ramie cotton fabric inorganic nanometer antibacterial finishing agent and a preparation method thereof. Silver nitrate and micro-molecular organic or inorganic reducing agent, such as ascorbic acid, tannic acid, tartaric acid and the like, are added into polyethyleneglycol and the mixture engages in deoxidization under 5-100 DEG C, producing nanometer silver with good dispersivity and stability. The polyethyleneglycol accounts for 50-90%of the weight and the ratio of silver salt to micro-molecular reducing agent is 1:1-4:1. The prepared nanomemter silver is dispersed in aqueous medium so as to get nanometer silver finishing agent and the weight percentage of nanometer silver is 0.25%-0.5%. The ramie cotton fabric can be made into composite material with excellent antibacterial effect after being soaked in the finishing agent. The fabric made from the antibacterial finishing agent has the characteristics of quick, efficient, broad-spectrum and lasting antibacterial effect. The preparation method and the finishing process are simple in technique and low in cost and have no pollution and are easy to industrialize.

The invention relates to a process for smelting ultra-low-carbon steel, which comprises melted iron pretreatment desulfuration, converter smelt, LF furnace refining, RH vacuum process and continuous casting procedure in turn. Converter smelt tapping adopts non deoxidization tapping, steel which is tapped off is refined by LF ladle furnace before carried out melt iron vacuum decarburization processing, wherein refining is mainly used to proceed modifying property processing and further desulfuration and heating for top slag of melted iron, and the melted iron is reinforced with positive oxygen blowing decarburization after shifted into a RH vacuum container. The process can control carbon, nitrogen and sulfur in steel to preset objects which are required, and has excellent castability when a casting machine casted, thereby realizing casting by several furnaces.

The invention relates to a preparation method for a polyimide/oxidized graphene nanocomposite film, and belongs to the technical field of preparation of functional polymer materials. The preparation method comprises the following steps: performing ultrasonic even dispersion on the oxidized graphene in an organic solvent to obtain an oxidized graphene sheet suspension, wherein per ml of the oxidized graphene sheet suspension contains 1.3*10<-5>-1.3*10<-4>g oxidized graphene sheets; introducing nitrogen for carrying out deoxidization protection, adding diamine monomers into the suspension, mechanically stirring until full dissolution is achieved, adding dianhydride monomers, the moles of which are equal to that of the diamine monomers, in batches, and mixing for one to six hours under the ice bath conditions, so as to obtain polyamide acid/oxidized graphene composite solution; pouring the polyamide acid/oxidized graphene composite solution onto a die, removing the organic solvent, performing gradient temperature rise within 100-300DEG C, and carrying out thermal imidization to obtain the polyimide/oxidized graphene nanocomposite film.

The invention discloses a smelting process of high-carbon bearing steel. High-alkalinity refining slag with the alkalinity value of 6-9 is obtained through adding conditioned slag and a deoxidizing agent, so that relatively good desulfuration and deoxidization effects are achieved, the content of S can be reduced to about 0.002%, and the content of O can be reduced to be less than 7ppm. Meanwhile, in order to avoid brittle impurity generation caused by overhigh alkalinity of refining slag, the content Al of the molten steel is strictly controlled in a smelting process, enough aluminum blocks for deoxidizing are added at one step in a tapping process, and no aluminum is replenished in the subsequent process, so that a deoxidized product is prevented from being floated; the content of Al in the refining slag is controlled at about 0.010%, so that secondary oxidation caused in a pouring process is reduced. On the other hand, the value of CaO/Al2O3 in the refining slag is controlled at about 1.7, so that the melting point of slag is relatively low, the flowability of the slag is relatively good, the steel slag is easy to separate, and the slag rolling and reduction reaction of molten steel in a vacuumizing process are reduced. Therefore, D-type inclusions in the bearing steel are effectively prevented from being increased, and the rating standards of inclusions in the bearing steel are reached.

The invention discloses a method for smelting high-grade non-oriented silicon steel with excellent magnetism. The method comprises the following steps of: 1) smelting, namely smelting the following chemical components: less than or equal to 0.005 weight percent of C, 2.6 to 3.4 weight percent of Si, 0.2 to 0.5 weight percent of Mn, less than or equal to 0.2 weight percent of P, less than or equal to 0.005 weight percent of S, 0.3 to 1.6 weight percent of Al, less than or equal to 0.005 weight percent of N, less than or equal to 0.005 weight percent of O, less than or equal to 0.0015 weight percent of Ti, and the balance of Fe and inevitable inclusions, and modifying ladle top slag in the tapping process of a converter so as to ensure that the ladle top slag comprises 30 to 37 weight percent of CaO, 7 to 20 weight percent of SiO2, 35 to 45 weight percent of Al2O3, 5 to 9 weight percent of MgO, and 0.6 to 2.6 weight percent of T.Fe+MnO when the Ruhrstahl-Heraeus (RH) refining treatment begins; 2) performing RH refining, namely deoxidizing by using ferrosilicon when the decarburization of the RH refining is finished, wherein the adding speed of the ferrosilicon is less than or equal to 12.5kg/ton/min; and 3) adding 0.5 to 2.0 kg of calcium alloy into each ton of molten steel for the denaturation control of inclusions after the deoxidization and alloying are performed through the RH refining.

The invention belongs to the gas-solid fluidized bed reactor field and relates to a dual-distributing plate coal-based serial fluidized bed chemical-chain combustion apparatus suitable for the chemical-chain combustion of burning coal and other solid fuels; the bottom of a bubbling fluidized bed is provided with a gas inlet and a feed port; the inside of the bubbling fluidized bed is divided into three regions by two distributing plates; the bottom of a low gas velocity region and the bottom of a high gas velocity region are respectively provided with a distributing plate; the middle between two regions is provided with a transition region with a reduce section to realize different gas flow velocities in the low gas velocity gasification region and the high gas velocity deoxidization region; the upper part of a bubbling fluidized bed is in tubular communication with the upper part of a cyclone separating device; the top of the cyclone separating device is provided with an exhaust port which is communicated with a gas inlet of the bubbling fluidized bed; the lower part of the cyclone separating device is pumped to the low gas velocity gasification region by a feed leg; the bottom of the high gas velocity deoxidization region is communicated with a circulating fluidized bed by a feed returning device; the bottom of the circulating fluidized bed is provided with an air inlet; the upper part of the circulating fluidized bed is communicated with the cyclone separating device. The dual-distributing plate coal-based serial fluidized bed chemical-chain combustion apparatus has the advantages of low cost, flexible operation, high thermal efficiency, wide application range, etc.

The invention discloses a method for preparing an antibacterial composite material with nano-silver particles evenly dispersed in a polymeric matrix, which belongs to technique for preparing antibacterial nano composite materials and comprises the following steps: preparing styrene/methyl methacrylate hybrid monomers, a sodium dodecyl sulfate hybrid monomer solution, a silver nitrate aqueous solution and a trisodium citrate aqueous solution; mixing the silver nitrate aqueous solution and the trisodium citrate aqueous solution with the sodium dodecyl sulfate hybrid monomer solution according to a volume ratio to obtain a micro-emulsion containing silver nitrate and a micro-emulsion containing trisodium citrate; stirring and mixing the two micro-emulsions to obtain a stable micro-emulsion having hybrid monomers of continuous phases and containing the nano-silver particles; and then dispersing the emulsions in distilled water to prepare a common emulsion, introducing nitrogen for deoxidization, adding an initiator to perform emulsion polymerization reaction, using sodium chloride to perform emulsion-breaking and separation on the product, fully washing the product with deionized water, and soaking the product in ethanol, and drying the product to constant weight so as to obtain the antimicrobial nano-silver/poly(styrene-methyl methacrylate) composite material. The method has simple preparation processes and can make the nano-silver particles evenly dispersed in the polymer matrix, and the prepared composite material has broad-spectrum bactericidal property, and has high fatality rate to Escherichia coli, bacillus subtilis, staphylococcus aureus and pseudomonas aeruginosa in 24 hours.

The present invention relates to material technology, and is low temperature plasma reduction process for preparing nanometer metal. The production process includes: filling metal salt into vacuum chamber of plasma discharger, vacuumizing the vacuum chamber, introducing plasma discharge gas to pressure of 30-200 Pa, and applying DC or AC voltage of 200-5,000 V with a high voltage power source to discharge the gas and to form plasma reducing the metal salt for 5-120min, so as to prepare nanometer metal particle. The production process has simple equipment, easy operation, low power consumption, great metal treating amount and environment friendship; and the prepared nanometer metal particle has high purity, small size, narrow size distribution, high dispersivity, excellent performance and unique compounding performance with other material, and may find wide application foreground in molecular device, chemical/biological sensor and other fields.

The invention relates to a thermal treatment method of tantalum powder. The method comprises the following stages: (1) a vacuum thermal treatment stage: placing the raw tantalum powder with the porosity of 80-98% into a crucible in such a manner that the thickness of the tantalum powder in the crucible is less than 60 mm; heating the crucible in a heating furnace in vacuum at 900-1,400 DEG C; andthen cooling the crucible to the room temperature and passivating the tantalum powder to obtain the condensed tantalum powder; and (2) a deoxidization thermal treatment stage: uniformly mixing the condensed tantalum powder obtained in the stage (1) with a reducing agent to obtain the mixed powder; placing the mixed powder in the crucible in such a manner that the thickness of the mixed powder in the crucible is less than 60 mm; heating the crucible in a heating furnace in vacuum or inert atmosphere at 700-1,100 DEG C; then cooling the crucible to the room temperature and passivating the obtained tantalum powder; performing pickling to remove the residual reducing agent; and drying and screening to obtain the tantalum powder suitable for an electrolytic capacitor. The tantalum powder prepared by the method provided by the invention has low oxygen content and good electrical performance.

The invention discloses a method for smelting tire cord steel and a method for continuously casting tire cord steel; the methods comprise the following steps of: (1), carrying out primary smelting on molten iron or semi-steel by converter top-bottom blowing, and tapping into a steel ladle without deoxidization; (2), carrying out recarburization and pre-alloying on the molten steel in the tapping process, so on the basis of the total weight of the molten steel, the activity oxygen content in the molten steel is 0.004-0.008wt%, the C content is 0.64-0.68wt% and the Al content is less than 0.4wt%; (3), blowing argon to the molten steel in the steel ladle after tapping, and carrying out vacuum refining and alloy fine adjustment; and (4), carrying out ladle furnace refining on the molten steel which is subjected to the vacuum refining by using the manner of bottom blowing argon, adding refining slags batch by batch and adding deoxidizing agents batch by batch, so the total content of FeO and MnO in the steel ladle top slag is less than or equal to 10wt%. In the methods, the tire cord steel is produced by using the technological process consisting of converter primary smelting, vacuum refining and steel ladle furnace refining and cogged ingot continuous casting pouring, and thus the clean production of tire cord steels is achieved.

The invention discloses a method for preparing high-titanium iron by step-by-step metal thermal reduction, which comprises an aluminum thermal reduction smelting step and a reinforced reduction refining step, wherein the raw materials include rutile or high-titanium slag, aluminum powder, iron ore concentrate, slag forming agent and KClO3 in a mass ratio of 1.0: 0.37-0.50: 0.05-0.10: 0.15-0.25: 0.20-0.25, and the smelting temperature is 1,900 to 2,200 DEG C; the reinforced reduction refining time in the second step is 10 to 30 minutes, and after the refining is finished, a high-titanium iron alloy is obtained by cooling, ingot formation and impurity removal; and the composite reducing agent is calcium-magnesium alloy. The method has the advantages of wide raw material source and low production cost; the step-by-step reduction operations are adopted in the method, the reduction smelting of the first step is performed under the condition that the aluminum is insufficient, and the calcium-magnesium alloy composite reducing agent is adopted in the deoxidization refining of the second step, so the Al residue in the high-titanium iron alloy is remarkably reduced, and oxygen is effectively removed; and the transfer of high-temperature melt is realized by casting, and the metal slag separation process is reinforced.

A refining agent for copper and copper alloy smelting is characterized in that the components of the refining agent are 5 to 15 percent by weight of calcium fluoride, 1 to 5 percent by weight of silicon dioxide, 1 to 5 percent by weight of titanium dioxide, 2 to 10 percent by weight of sodium fluosilicate, 40 to 60 percent by weight of sodium carbonate and the balance sodium tetraborate; the refining agent materials are weighed according to a formula, uniformly mixed, placed into a drying box and dried under 120 DEG C for an hour, and a metallographic inlaying machine is used for manually pressing the refining agent into the shape of a sheet. The refining agent has the advantages that the refining agent is integrated with the functions of deoxidization, degasification, impurity removal and the like, and has strong adsorbing, dissolving and combination slagging capabilities; the surface tension between the refining agent and metal melt is high, the refining agent can promote molten slag to float up, so that the molten slag can be better separated from molten metal, and thereby the effects of refining, impurity removal and melt purification are achieved; the refining agent has high chemical stability and thermal stability, does not have the corrosion effect on metal and the furnace lining, and cannot chemically react with the molten metal, the refining agent and the molten metal cannot be melted into each other as well, and thereby the original composition and properties of alloy are guaranteed; and the refining agent does not have public hazard, is safe and environment-friendly, is convenient to use, and is cheap.

The invention discloses an aluminum-containing cold forging steel smelting process, comprising the steps of blast furnace molten iron making, processing by a converter, refining and continuous casting, wherein requirements of molten iron are as follows: P is not more than 0.10%, Si is not more than 0.50% and not less than 0.30%, S is not more than 0.030%; requirements in converter refining are as follows: CaO is not less than 85%, activity degree is not less than 280 and SiO2 in fluorite is not more than 6%; low-Si pre-melted slag or refining agent replaces partial CaO and fluorite in a converter steel discharging process for rapid slag making, a refining furnace deoxidizing agent is applicable to slag deoxidization after stirring calcium carbide and aluminum particles, and Si-containing material is prohibited; during continuous casting, pure Ca lines are applicable between a medium packet impact zone and various flows, so that calcium aluminate which is low in melting point and is from reaction of Al2O3 generated from medium packet through secondary oxidation and Ca floats and is removed. The process can reduce the content of Si in steel, improve Al content and guarantee continuous pouring of molten steel.

The invention provides a cheap catalyst for catalyzing the hydrogenation deoxidization reaction of guaiacol and a preparation method thereof. The catalyst comprises the following components: a carrier ZrO2-SiO2 binary composite oxide, and two active metals of Ni and Cu, wherein the two active metals of Ni and Cu are loaded on the binary composite oxide through an immersion process. The ZrO2-SiO2 binary composite oxide which is prepared through a chemical precipitation process is used as the carrier of the catalyst, wherein the Zr/Si molar ratio is 1:1-5; and the two active metals of Ni and Cu are loaded on the carrier through the immersion process, wherein the Ni load capacity is 7-15wt%, and the Ni/Cu molar ratio is 1:0.5-1.5. The catalyst prepared in the invention has the advantages of cheap raw material, simple preparation method, high reaction activity, good carbon deposition resistance, and long service life. According to the catalytic activity evaluation of the catalyst, the conversion rate of guaiacol is near to 100%, and the top alkane yield can reach 62.7%.

The invention relates to a mechanical control and environmental-protection method for storing tobacco flakes, which is characterized by comprising the following steps: 1. constructing a tobacco leaf pile sealing space which is sealed in six surfaces and is capable of mechanically controlling a storage environment; 2. carrying out one-time thorough gas fumigation control: adopting any one or the combination of more than one of the following four methods to realize the fumigation control on insect and mildew damage to tobacco leaf piles: (1) hydrogen phosphide conventional fumigation control, (2) carbon dioxide gas fumigation control, (3) nitrogen-filled modified fumigation control and (4) iron powder deoxidant-applied deoxidization fumigation control; 3. carrying out emission or filter purification on fumigation gas after the fumigation control is finished; and 4. carrying out manual and mechanical control to discharge accumulated heat and damp in a plastic sealing tent. The method hasthe characteristics of low cost, mechanical control and environmental protection.

The invention relates to a preparation method of thin-shelled noble metal catalyst, and mainly solves the problems of the prior art of high dosage, poor selectivity and short service life of noble metal. The preparation method better solves the technical problems of the prior art by adopting the technical proposal comprising the following steps of: (a) coating the slurry of a coat porous material on the inner core of an inert carrier, drying the slurry coating and baking the slurry coating at a temperature of between 700 and 1,200 DEG C for 0.5 to 10 hours to obtain a laminar composite carrier; (b) impregnating the surface of the laminar composite carrier with a solution containing noble metal and cocatalyst components, drying the laminar composite carrier, and baking the laminar composite carrier in the air at a temperature of between 200 and 700 DEG C for 1 to 24 hours to obtain a thin-shelled catalyst precursor; and (c) reducing the thin-shelled catalyst precursor in a reducing atmosphere at a temperature between 300 and 800 DEG C for 1 to 24 hours to obtain the thin-shelled noble metal catalyst. The preparation method can be used in the industrial production of gas purification materials which are dehydrogenation-deoxidization catalysts, alkanes and aromatic hydrocarbons for selective hydrogen oxidation in a dehydrogenation process.

The invention relates to the speeding up degradation of organic pollutant in the soil, which uses strong reduction feature of metal nulvalent, synthetic metal oxidation and hydro oxidation, effectively reducing organochlorine insecticide and other contaminating pollutant, improving the biological degradation feature of organic pollutant. The above pollutant can be further degraded with the participation of organic acid. It can effectively realize the original position restoring of contaminated soil, particularly for the control and restoring of heavy polluted soil.

The invention provides an aluminum-calcium-magnesium-cerium composite alloy used for strong desulfurization, final desoxidation, and microalloying quenching and tempering of liquid steel, belonging to the technical field of ferroalloy used for steelmaking. Based on aluminum deoxidization, the aluminum-calcium-magnesium-cerium composite alloy is added with alkaline-earth metal calcium and magnesium to conduct the strong desulphurization and the final desoxidation on the liquid steel so as to reduce inclusions in steel, and adopts rare earth-cerium and alloy elements such as titanium, niobium, vanadium and the like to conduct quenching and tempering, and microalloying on the liquid steel so as to change the morphology of the inclusions, lead the steel to be solidified, crystallized and refined, and optimize the steel performance. The aluminum-calcium-magnesium-cerium composite alloy contains the following chemical compositions (mass percent): 10-60% of aluminum, 10-30% of calcium, 10-30% of magnesium, 0.5-10% of cerium, less than or equal to 1% of impurities (carbon + silicon + phosphorus + sulphur), and the balance of ferrum; and for the purpose of achieving different microalloying, the composite alloy also can contain one or more microalloying elements of titanium, niobium, molybdenum, vanadium, tungsten and boron, and the weight percentage content of the microalloying elements is 0.1-10%. In the invention, the final desoxidation, the strong desulfurization, the microalloying and the quenching and tempering of the liquid steel is completed in one step, thus improving the refining efficiency and effect, and greatly improving the steel quality.

The invention discloses an ultralow sulfur steel quick smelting method. The difficult points of slagging, deoxidizing and desulfurating in the smelting process of the ultralow sulfur steel ([S] is not more than 0.0010%) are successfully solved. The method comprises the following steps: pretreating molten steel to desulfurate and remove slag, deeply deoxidizing tapping aluminum block through a converter, modifying composite refined top slag, deoxidizing aluminum wire through a LF refining furnace, slagging through lime and feeding aluminum wire to trimming aluminum molten steel, combining the whole reasonable argon bottom blowing control in the smelting process of the LF furnace, fully playing the metallurgical thermodynamics and thermodynamics and kinetics of desulfuration, organically combining the diffusion deoxidization and sediment deoxidization, sufficiently evacuating deoxidization and desulfuration potential of the slag so that the sulfur content in the molten steel within 40min can be reduced to within 0.0010% through the LF refining furnace and the full oxygen content of casting blank is controlled within 0.0010%. The sulfur content control of the molten steel is stable, the casting blank is good in quality, the steel plate flaw detection yield can achieve above 99%, the ultralow sulfur steel production requirement is completely satisfied, and the smelting production rhythm and the continuous casting pouring furnace are guaranteed.

The invention discloses a production method of ultralow-oxygen titanium-containing ferrite stainless steel, which comprises the following steps: 1) preparing molten ferrite stainless steel under a vacuum condition in a vacuum oxygen blowing decarburization furnace, wherein the carbon mass percentage content and nitrogen mass percentage content in the molten ferrite stainless steel are both less than 0.01 percent; 2) performing deoxidization, namely adding 6 to 12 kilograms of aluminum block or grains into each ton of steel and adding 10 to 28 kilograms of active lime into each ton of steel; 3) alloying silicon and aluminum, namely adding 2 to 9 kilograms of silicoferrite which contains 70 to 80 percent of silicon into each ton of steel and adding 0 to 1 kilogram of aluminum blocks or grains into each ton of steel, wherein the aluminum content is 0.02 to 0.1 percent; 4) performing desulphurization; (5) breaking vacuum; 6) softly stirring; 7) feeding titanium wires; 8) feeding silicon and calcium wires, wherein the calcium content is 5 to 30ppm; 9) softly stirring; and 10) continuously casting. The method can be used for producing ultralow-oxygen titanium-containing ferrite stainless steel, prevent or inhibit forming magnesia alumina spinel which are harmful impurities in a production process, improve product quality, prevent the water gap of tundish from being blocked in a continuous casting process and guarantee smooth production.

The invention discloses a heat-resisting die steel material for 3D (Three-Dimensional) printing and a preparation method of the heat-resisting die steel material. The material takes a material component of a needed heat-resisting die as a basic component; C element, a deoxidization element and an anti-crack element are added, wherein the adding amounts of the three elements are of 0.1wt%-0.15wt%, 0.1wt%-0.5wt% and 0.05wt%-0.5wt% and the three elements are used for making up the loss of the C element in a 3D printing process, the oxidization in the 3D printing process is reduced and the anti-crack performance of tissues is improved; the material is of a 15-100-micron regular spherical shape. The method comprises the following steps: firstly, preparing spherical metal powder by an element compensation atomization method; carrying out a graded sieving and constant proportion mixing method to obtain the needed powder material. The prepared powder has high purity, fine powder granularity, high sphericity degree and good mobility; the density of a part is favorably improved and the powder is very suitable for laser 3D printing rapid molding; the difficulties that austenite heat-resisting steel is difficult to machine and the complicated part is difficult to manufacture are overcome, and the application of the material difficult to machine in the fields of heat energy, power, high-end heat-resisting hydraulic molds and the like is enlarged.

The invention belongs to the technical field of chemical chains, and in particular relates to an oxygen-hydrogen co-production device and method based on chemical chain reaction. According to the oxygen-hydrogen co-production device based on the chemical chain reaction, an oxygen production fluidized bed is connected with an oxygen production cyclone separator which is connected with a feed port of a hydrogen production fluidized bed, a hydrogen production fluidized bed gas outlet is formed in the upper part of the hydrogen production fluidized bed and is connected with a hydrogen production cyclone separator, and the lower part of the hydrogen production cyclone separator is connected with a fixed bed feed port in the top of a fixed bed. An oxygen carrier is subjected to deoxidization reaction in the oxygen production fluidized bed to generate oxygen, the deoxidized oxygen carrier particle enters into the hydrogen production fluidized bed to react with water vapor to produce hydrogen, the reacted oxygen carrier particle enters into the fixed bed to react with the oxygen to be regenerated, and the regenerated oxygen carrier particle is returned to the oxygen production fluidized bed to be recycled. The device provided by the invention is simple, and the method can be carried out at normal pressure; and compared with a traditional oxygen production method and a traditional hydrogen production method, energy consumption is less and production cost is reduced.

The invention relates to a process for preparing a beta layer removing gradient hard alloy. The gradient hard alloy is generally used as a matrix of coating hard alloy. The preparation process comprises the following steps of: adding merchant granular Ti(C,N) powder into titanium-containing hard alloy raw materials; meanwhile, in order to improve the activity of nitrogen in the hard alloy matrix so that the surface layer of the hard alloy matrix is easier for denitrification, adding a certain amount of carbon black so that the hard alloy matrix forms a high-carbon component; and preparing a cutter or a sample pressing blank by a standard hard alloy manufacturing process, and finally sintering, wherein a one-step sintering method is adopted in the sintering process, namely normal de-waxing and deoxidization processes are adopted for sintering, then vacuum sintering is performed after reaching the gradient sintering temperature, and the beta layer removing gradient hard alloy can be prepared by furnace cooling. The thickness of the beta-removing layer of the prepared gradient hard alloy can reach 10 to 60 microns, and the gradient hard alloy has good compactness and bending strength; and meanwhile, because the merchant medium granular Ti(C,N) powder and the one-step sintering method are adopted, the production process can be reduced, and the production cost can be lowered.

The invention discloses a coal bed gas catalytic deoxidation technique in coal field, which adopts a multistage reactor for multilevel catalytic deoxidation reaction to control the temperature of gas at the inlet of every stage of reactor and the content of O2 in the gas at the inlet, so as to ensure the temperature of gas at the outlet of every stage of reactor to be less than or equal to 660 DEG C after the catalytic deoxidation reaction. Compared with an individual reactor, the deoxidation technique of the invention can greatly reduce the quantity of the gas that is taken as return gas and used for diluting O2 in the coal bed gas of the raw materials, thus reducing the energy consumption; meanwhile, the temperature of the gas at the outlet of the deoxidation reactor can be effectively controlled to be lower than 660 DEG C, the cracking of methane can be reduced, and the loss of the methane can be obviously lowered.

A high-activity deoxidant for the deep deoxidization of N2, H2, CO, CH4, C2H4, C3H6, etc is composed of active component (the low-valence oxide of Mn and Fe) and the carrier chosen from cement, gypsum, kaolinite, alumina, diatomite, etc. Its preparing process is also disclosed.

The invention discloses a low-carbon ultra-low sulfur steel smelting method. The method comprises the following technological processes: pouring molten iron into a tank, pretreatment of molten iron, oxygen remaining operation of a converter, RH furnace vacuum decarburization, alloying and vacuum degassing in an RH furnace, deoxidization of aluminium yarn/aluminium wire in an LF refining furnace, slagging by using lime and CCM. Through combination of molten iron desulphurization and drossing, optimization of a converter steel tapping and oxygen remaining system and a slagging system, the vacuum decarburization, alloying and degassing control in the RH furnace, and the aluminium wire diffusing deoxidation slagging and aluminium wire sediment deoxidation in the LF furnace, deep decarburization and desulphurization are carried out. With an emphasis on combination of convertor steel tapping and oxygen remaining operations, RH deep decarburization and LF furnace deep desulphurization, technical optimization is carried out; due to reasonable ladle argon bottom blowing control in the smelting process, carbon content control and metallurgical thermodynamics and dynamics conditions of desulphurization are given a full play; the RH furnace decarburization is stable; LF furnace slagging and desulphurization and recarburization control effects are obvious; and low-carbon ultra-low sulfur steel smelting is achieved.

The invention relates to a cold-rolled steel strip, and especially relates to a cold-rolled steel strip for a double-layer welded tube and its manufacturing method to mainly solve technical problems comprising bad product yield and bad performance uniformity because of cover annealing generally adopted in the manufacturing of the double-layer welded tube. The chemical components of the cold-rolled steel strip for the double-layer welded tube comprise 0.015-0.054wt% of C, 0.034wt% or less of Si, 0.15-0.25wt% of Mn, 0.020wt% or less of P, 0.020wt% or less of S, 0.015-0.050wt% of Alt, and the balance Fe and inevitable impurity elements. In the invention, low carbon and low silicon are adopted, aluminum deoxidization is adopted as a crystal grain refinement element, and impurity form control, hot continuous rolling control cooling, continuous annealing temperature control and continuous flattening technologies are utilized to produce, so it is helpful for the guarantee of the yield strength, the percentage elongation after fracture and the hardness of the steel in prescribed requirement ranges. The cold-rolled steel strip makes the tube manufactured through using it have the advantages of good full-length performance uniformity, good roll bend formability, good tube barrel lap rebound controllability, good weldability, and good tube bending performance, and can guarantee the yield in the complete tube manufacturing flow.