3778results about "Indirect carbon-dioxide mitigation" patented technology

A combustor method and apparatus is provided. The method utilizes flameless combustion with one or more of three improvements to enhance ignition of the flameless combustor. A catalytic surface can be provided within a combustion chamber to provide flameless combustion at least in the vicinity of the catalytic surface at a temperature that is much lower than the autoignition temperature of fuel in air without the presence of the catalytic surface. Nitrous oxide or supplemental oxygen may also be used as an oxidant either instead of air or with air to reduce ignition temperatures. Further, electrical energy can be passed through the fuel conduit, raising the temperature of the conduit to a temperature above which the fuel will ignite when combined with the oxidant.

An oxy-combustor is provided to combust oxygen with gaseous low heating value fuel. A compressor upstream of the combustor compresses the fuel. The combustor produces a drive gas including steam and carbon dioxide as well as other non-condensable gases in many cases, which pass through a turbine to output power. The drive gas can be recirculated to the combustor, either through the compressor, the oxygen inlet or directly to the combustor. Recirculation can occur before or after a condenser for separation of a portion of the water from the carbon dioxide. Excess carbon dioxide and steam is collected from the system. The turbine, combustor and compressor can be derived from an existing gas turbine with fuel and air/oxidizer lines swapped.

This invention is related to so-called combined cycle co-generation installations, and it addresses present concerns of the industry. Among these, combustion stability, corrosion (due to large water content in the flue gases), large heat transfer areas, and the like. In some embodiments, an additional heat exchanger is added to heat combustion air with a portion of the exhaust gases resulting from an engine, preferably a gas turbine. As a result, the efficiency of the cycle will improve, the oxidant will be enriched by above 50% oxygen, the combustion process will be enhanced, and the dimensions of the boiler may be reduced. It is considered that the combustion air will require between 10% and 80% of the total flue gas volume, more preferably between 20% and 40%. This is the portion of the flue gases sent through the heat exchanger. A control system designed to optimize the flow of the different streams is also presented. Other inventive embodiments forego heat exchanges in lieu of precise control of two flows of exhaust gas, with preferred addition of additional oxidant to the boiler bumers.

A power plant including an air separation unit (ASU) arranged to separate nitrogen, oxygen, carbon dioxide and argon from air and produce a stream of substantially pure liquid oxygen, nitrogen, carbon dioxide and argon; a steam generator, fired or unfired, arranged to combust a fuel, e.g., natural gas, liquefied natural gas, synthesis gas, coal, petroleum coke, biomass, municipal solid waste or any other gaseous, liquid or solid fuel in the presence of air and a quantity of substantially pure oxygen gas to produce an exhaust gas comprising water, carbon dioxide, carbon monoxide, nitrogen oxides, nitrogen, sulfur oxides and other trace gases, and a steam-turbine-generator to produce electricity, a primary gas heat exchanger unit for particulate/acid gas/moisture removal and a secondary heat exchanger arranged to cool the remainder of the exhaust gases from the steam generator. Exhaust gases are liquefied in the ASU thereby recovering carbon dioxide, nitrogen oxides, nitrogen, sulfur oxides, oxygen, and all other trace gases from the steam generator exhaust gas stream. The cooled gases are liquefied in the ASU and separated for sale or re-use in the power plant. Carbon dioxide liquid is transported from the plant for use in enhanced oil recovery or for other commercial use. Carbon dioxide removal is accomplished in the ASU by cryogenic separation of the gases, after directing the stream of liquid nitrogen from the air separation unit to the exhaust gas heat exchanger units to cool all of the exhaust gases including carbon dioxide, carbon monoxide, nitrogen oxides, nitrogen, oxygen, sulfur oxides, and other trace gases.

Heating units, drug supply units and drug delivery articles capable of rapid heating are disclosed. Heating units comprising a substrate and a solid fuel capable of undergoing an exothermic metal oxidation reaction disposed within the substrate are disclosed. Drug supply units and drug delivery articles wherein a solid fuel is configured to heat a substrate to a temperature sufficient to rapidly thermally vaporize a drug disposed thereon are also disclosed.

An integrated air separation and oxygen fired power generation system includes an air separation unit and a gas turbine including an air compressor to provide compressed air for the air separation unit. The system further includes a gas turbine expander and at least one additional turbine to drive the air compressor, as well as at least one combustion unit to provide drive gas for expander and additional turbine(s). A portion of oxygen produced by the air separation unit is delivered to the combustor(s) to facilitate production of drive gas for use by the expander and additional turbine(s). Turbine inlet temperatures are controlled by recycling water or steam to the combustor(s).

The invention provides processes and apparatuses for safely, rapidly, cost-effectively and efficiently producing a superheated steam product or dry saturated steam product that can be employed to generate electrical power, or in other manufacturing and/or non-manufacturing processes, in an environmentally clean manner without causing corrosion to electrical power-generating devices. These processes and apparatuses involve the combustion of one or more fuels containing the elements hydrogen and/or carbon, which can be derived from waste materials, such as the rubber from scrap tires. Water that circulates around one or more combustion chambers and/or areas, but that does not enter into the combustion chambers or areas, becomes converted into a high purity steam product The present invention also provides processes and apparatuses for recycling or eliminating waste materials, and for transforming hazardous materials into non-hazardous materials, and fuels that can be employed in the foregoing processes and apparatuses.

The invention relates to a new and improved process and apparatus for the production of high purity hydrogen by steam reforming. The apparatus is an integrated flameless distributed combustion-membrane steam reforming (FDC-MSR) or reactor for steam reforming of a vaporizable hydrocarbon to produce H₂ and CO₂, with minimal CO, and minimal CO in the H₂ stream. The flameless distributed combustion drives the steam reforming reaction which pro-vides great improvements in heat exchange efficiency and load following capabilities. The reactor may contain multiple flameless distributed combustion chambers and multiple hydrogen-selective, hydrogen-permeable, membrane tubes. The feed and reaction gases may flow through the reactor either radially or axially. A further embodiment of the invention involves producing high purity hydrogen by dehydrogenation using an integrated FDC-membrane de-hydrogenation reactor. A still further embodiment of the invention involves a zero emission hybrid power system wherein the produced hydrogen is used to power a high-pressure internally manifolded molten carbonate fuel cell. In addition, the design of the FDC-SMR powered fuel cell makes it possible to capture good concentrations of CO₂ for sequestration or use in other processes.

A self-cooled oxidant-fuel burner consisting novel fuel and oxidant nozzles and three compartment refractory burner block design is proposed. The new oxidant-fuel burner can fire in high-temperature (2200 DEG F. to 3000 DEG F.) and high-particulate (or high process volatiles/condensates) furnaces without over-heating or causing chemical corrosion damage to it's metallic burner nozzle and refractory burner block interior. Using various embodiments of nozzle and block shape, the burner can offer a traditional cylindrical flame or flat flame depending on the heating load requirements. The new features of this burner include unique fuel nozzle design for the streamline mixing of fuel and oxidant streams, a controlled swirl input to the oxidant flow for desired flame characteristics, a controlled expansion of flame envelope in the radial and axial dimensions, and efficient sweeping of burner block interior surface using oxidant to provide convective cooling and prevent any build up of process particulates. In addition, a relatively thick wall metallic nozzle construction with heat conduction fins enable efficient heat dissipation from the nozzle tip and providing a maintenance free burner operation.

A burner assembly having improved flame length and shape control is presented, which includes in exemplary embodiments at least one fuel fluid inlet and at least one oxidant fluid inlet, means for transporting the fuel fluid from the fuel inlet to a plurality of fuel outlets-, the fuel fluid leaving the fuel outlets in fuel streams that are injected into a combustion chamber, means for transporting the oxidant fluid from the oxidant inlets to at least one oxidant outlet, the oxidant fluid leaving the oxidant outlets in oxidant fluid streams that are injected into the combustion chamber, with the fuel and oxidant outlets being physically separated, and geometrically arranged in order to impart to the fuel fluid streams and the oxidant fluid streams angles and velocities that allow combustion of the fuel fluid with the oxidant in a stable, wide, and luminous flame. Alternatively, injectors may be used alone or with the refractory block to inject oxidant and fuel gases. The burner assembly affords improved control over flame size and shape and may be adjusted for use with a particular furnace as required.

Methods and systems for low emission power generation in hydrocarbon recovery processes are provided. One system includes integrated pressure maintenance and miscible flood systems with low emission power generation. An alternative system provides for low emission power generation, carbon sequestration, enhanced oil recovery (EOR), or carbon dioxide sales using a hot gas expander and external combustor. Another alternative system provides for low emission power generation using a gas power turbine to compress air in the inlet compressor and generate power using hot carbon dioxide laden gas in the expander. Other efficiencies may be gained by incorporating heat cross-exchange, a desalination plant, co-generation, and other features.

A method of generating electrical power in which a synthesis gas stream generated in a gasifier is combusted in an oxygen transport membrane system of a boiler. The combustion generates heat to raise steam to in turn generate electricity by a generator coupled to a steam turbine. The resultant flue gas can be purified to produce a carbon dioxide product.

A combustion control system allows the dramatic reduction of NOx emission levels from industrial combustion processes without having recourse to expensive flue gas clean up methods. The system combines the technique of oscillating combustion with an adapted system for post combustion burn out of the excess of CO resulting from the low-NOx combustion zone. A process for fuel combustion includes generating an oscillating combustion zone by oscillating at least one of the fuel flow and the oxidant flow to achieve a reduced nitrogen oxide emission, selecting oscillating parameters and furnace operating parameters to maximize nitrogen oxide reduction efficiency to the detriment of carbon monoxide production, and combusting carbon monoxide downstream of the oscillating combustion zone by injecting a post combustion oxidant.

A semi-closed combined cycle power system 100 is provided which can also convert an open combined cycle gas turbine 10 into a non-polluting zero emissions power system. The prior art open combined cycle gas turbine 10 includes a compressor 20 which compresses air A' and combusts the air A' with a fuel, such as natural gas. The products of combustion and the remaining portions of the air form the exhaust E' which is expanded through the turbine 40. The turbine 40 drives the compressor 20 and outputs power. The exhaust E' exits the turbine 40 and then can optionally be routed through a heat recovery steam generator 50 to function as a combined cycle. According to this invention, the exhaust E' is not emitted into the atmosphere, but rather is routed to a divider 110. The divider 110 includes two outlets for the exhaust E' including a return duct 120 and a separation duct 130 which both receive a portion of the exhaust E'. The return duct 120 routes a portion of the exhaust E' back to the compressor 20. Before reaching the compressor 20, an oxygen duct 150 adds additional oxygen to the exhaust E' to form a gas mixture C which includes CO2 and steam from the exhaust E' and oxygen from the oxygen duct 150. This gas mixture C has characteristics which mimic those of air, so that the compressor 20 need not be modified to effectively compress the gas mixture C. The gas mixture C is compressed within the compressor 20 and routed to the combustor 30 where the fuel combusts with the oxygen of the gas mixture C' and produces exhaust E' which is substantially entirely CO2 and steam. This exhaust E' is routed through the turbine 40 and expanded to drive the compressor 20 and output power. The exhaust E' exits the turbine 40 and is routed back to the divider 110, preferably by way of a heat recovery steam generator 50 or other heat removal device, so that the semi-closed cycle operates as a combined cycle power system 100. The divider 110 directs a portion of the exhaust E' to a separation duct 130 which leads to a condenser 140. In the condenser 140 the exhaust E' is separated by condensation of the steam/water portion of the exhaust and removal of the remaining CO2 as gas from the condenser 140. The only exhaust from the semi-closed power system 100 is water and CO2 from the condenser. The CO2 exhaust is substantially pure and ready for appropriate further handling and disposal. Hence, no pollutants are emitted from the semi-closed power system 100. The return duct 120 can

The present invention relates to methods and systems for controlling a combustion reaction and the products thereof. One embodiment includes a combustion control system having an oxygenation stream substantially comprising oxygen and CO₂ and having an oxygen to CO₂ ratio, then mixing the oxygenation stream with a combustion fuel stream and combusting in a combustor to generate a combustion products stream having a temperature and a composition detected by a temperature sensor and an oxygen analyzer, respectively, the data from which are used to control the flow and composition of the oxygenation and combustion fuel streams. The system may also include a gas turbine with an expander and having a load and a load controller in a feedback arrangement.

Burner firing method and device are presented where an oxidizing oxygen-fuel burner is fired at an angle to the reducing air-fuel burner flame to reduce overall NOx emissions from high temperature furnaces. The oxidizing oxy-fuel burner stoichiometric equivalence ratio (oxygen/fuel) is maintained in the range of about 1.5 to about 12.5. The reducing air-fuel burner is fired at an equivalence ratio of 0.6 to 1.00 to reduce the availability of oxygen in the flame and reducing NOx emissions. The oxidizing flame from the oxy-fuel burner is oriented such that the oxidizing flame gas stream intersects the reducing air-fuel flame gas stream at or near the tail section of the air-fuel flame. The inventive methods improve furnace temperature control and thermal efficiency by eliminating some nitrogen and provide an effective burnout of CO and other hydrocarbons using the higher mixing ability of the oxidizing flame combustion products. The simultaneous air-fuel and oxy-fuel burner firing can reduce NOx emissions anywhere from 30% to 70% depending on the air-fuel burner stoichiometric ratio.

Apparatus includes a first and second conduits configured to form an annulus between them. An adjustable structure includes a body having an upper surface, a lower surface, and a circumferential surface abutting a portion of the internal surface of the second conduit. The structure is adjustable axially in relation to and removably attached to the first conduit via a hub. The hub defines a central passage for fuel or oxidant. The body has one or more non-central through passages configured such that flow of an oxidant or fuel therethrough causes the fuel or oxidant to intersect flow of fuel or oxidant exiting from the central passage in a region above the upper surface of the body.

A counter-flow system for use in a turbine for selecting various mixtures of fluids for use with the system. The system may be used for a combustor for a gas powered turbine which employs a heat exchanger to combust a fuel without the emission of undesired chemical species. A gas powered turbine requires expanding gases to power the turbine blades. Fuel is combusted to produce the required gases. An oxidizer is introduced into the counter-flow system in a first direction before a first portion of fuel is introduced into the oxidizer. The fuel and oxidizer mixture is then flowed through a second pathway wherein the fuel and oxidizer mixture obtains a selected amount of thermal energy. Moreover, in a second pathway an equivalence ratio of the fuel and oxidizer mixture may be altered from the original fuel and oxidizer mixture.

A combustor apparatus is provided, comprising a mixing arrangement for mixing a carbonaceous fuel with enriched oxygen and a working fluid to form a fuel mixture. A combustion chamber is at least partially defined by a transpiration member. The transpiration member is at least partially surrounded by a pressure containment member. The combustion chamber has opposed inlet and outlet portions. The inlet portion of the combustion chamber is configured to receive the fuel mixture for the fuel mixture to be combusted at a combustion temperature. The combustion chamber is further configured to direct the resulting combustion product toward the outlet portion. The transpiration member directs a transpiration substance therethrough toward the combustion chamber for buffering interaction between the combustion product and the transpiration member. Associated systems, apparatuses, and methods are also provided.

Disclosed is a regenerative heat exchanger including a brush-seal configuration to prevent mixing of fluid flows. The regenerative heat exchanger includes a regenerator, and at least two conduits, each conduit having a matrix end abutting a face of the regenerator matrix. The at least two conduits carrying at least two fluid flows, the fluid flows which pass through the regenerator matrix. The regenerative heat exchanger includes a plurality of brush-seals, each brush-seal located at a matrix end of each conduit without contacting the matrix, thereby sealing around a periphery of each conduit to prevent mixing of fluid flows. Also disclosed is a method for establishing a minimal gap between a regenerator matrix of a regenerative heat exchanger and a plurality of brush-seals.

A combustion chamber for a gas turbine is provided. The combustion chamber comprises at least one first and one second jet carrier, of which at least one is provided for injecting an operating gas in the combustion chamber such that waste gas fanned in the flame zone thereof is circulated to a mixing zone of the first jet carrier. In order to achieve a compact combustion chamber, the jet carriers are positioned in relation to each other such that waste gas from the flame zone of the first jet carrier flows directly to the mixing zone of the second jet carrier.

A multi-purpose, multi-oxy-fuel High Temperature Power Burner/Injector/Oxygen Lance, Mechanical System Apparatus Device, for steelmaking from recycled scrap and/or virgin ferrous charge, which can be employed in multi-oxy-fuel (natural gas; pulverized carbonaceous matter; heavy oil), especially by Oxygen Combusted mixture of Natural Gas/Pulverized Carbonaceous Matter in High Temperature Power Burner Mode, for efficient and rapid melting of solid ferrous charge (cold or preheated) in a special steelmaking Metallurgical Furnace or Open Hearth Furnace, Tandem Furnace, BOF, EAF, as its augmenting or only source of thermal energy; more than one Device in Oxygen-Natural Gas/Pulverized Carbonaceous Matter Power Burner Mode, can be employed as the only source of thermal energy in a modified, originally Electric Arc Furnace, as total replacement of Graphite Electrodes and Electric Arc System, the replacement being noticeably more primary energy efficient than the thermal energy provided by Graphite Electrode/Arc System; it also can be employed in an Solid Particles Injector Mode, for injecting of adequately granulated carbonaceous materials or lime into the molten steel for its carburizing or for foamy slag control; further it can be employed in a natural gas shrouded, pulsating oxygen stream, for vertically to the charge oriented soft blow supersonic Oxygen Injection Lance Mode, for decarburization of the molten metal contained in the hearth of the metallurgical furnace and foamy slag control; in one of the embodiments-generally arcuate-pivotally mounted, liquid media cooled composite body, is pivoted into and out of a furnace vessel through a small opening in the shell wall for auto-regulated constant optimal positioning of the Composite Body Tip against solid or molten charge, in each and all multi-purpose modes; furthermore, when inserted into the furnace vessel, the arcuate composite body can be rotated about its longitudinal axis for directing the oxy-fuel high temperature flame towards unmolten charge in the furnace; in an other-generally linear-embodiment, the liquid cooled composite body is attached to the mast type carrier allowing vertical movement of the composite body which enters the furnace vessel through a small opening in the furnace roof; the bimetallic, liquid cooled special tip assembly of both-arcuate and linear embodiments-of the composite body includes easy replaceable, independent, multi-opening nozzles, mounted in a protective, retracted position inside of the liquid cooled special tip assembly.

A process for combusting solid liquid or gaseous fuels in a high temperature refractory-lined reactor with the aim of generating electric power comprises mixing at least one fuel with steam. The refactory material of the reactor and the opaque gases of the reaction environment bring about high power infrared radiation which substantially instantaneously preheats the reactants on input including said reactants being intrinsically transparent to infrared radiation (N₂/O₂) but rendered opaque and thus absorbers of energy from infrared radiation thanks to dilution with steam. A high efficiency combustor is provided for carrying out the above-stated process.

An apparatus and method for using staged air combustion. The apparatus includes a burner body (10) secured to a port block (42), and a fuel passageway (12) extending through the burner body (10), terminating in a fuel nozzle (22), which injects fuel into the burner throat (40). Primary air jets (20) are configured to inject primary air into a primary combustion region (24), which is normally in the burner throat (40). A dish with a dish surface (28) is connected to the burner throat (40); the dish surface (28) extending in a divergent angle with respect to a burner centerline (35). Secondary air jets (34) are connected to the air passageway (14) and extend through the port block (42). The secondary air jets (34) inject secondary air into a secondary combustion region (38), which may be at the dish surface (28) or the hot face (30) of the burner.

A power generating system having a hybrid gasification cycle, in which CO₂ is recycled to a gasifier to be used as a gasification reactant and working fluid. The power generating system includes a source of fresh, pure oxygen, a gasifier, a particle separator arranged in flow connection with the gasifier, a syngas combustor, a gas turbine arranged in flow connection with the syngas combustor, a steam generator arranged in flow connection with the outlet of the gas turbine, and a gas compressor system which discharges a stream of compressed exhaust gas. A first portion of the stream of compressed exhaust gas is conducted to the gasifier to control the temperature in the gasifier, to provide CO₂ and steam for gasification, and to decrease the demand for fresh, pure oxygen therein.

A method of reducing pollutants exhausted into the atmosphere from the combustion of fossil fuels. The disclosed process removes nitrogen from air for combustion, separates the solid combustion products from the gases and vapors and can capture the entire vapor/gas stream for sequestration leaving near-zero emissions. The invention produces up to three captured material streams. The first stream is contaminant-laden water containing SO_x, residual NO_x particulates and particulate-bound Hg and other trace contaminants. The second stream can be a low-volume flue gas stream containing N₂ and O₂ if CO₂ purification is needed. The final product stream is a mixture comprising predominantly CO₂ with smaller amounts of H₂O, Ar, N₂, O₂, SO_X, NO_X, Hg, and other trace gases.

A reheat heat exchanger is provided particularly for use in Rankine cycle power generation systems. The reheat heat exchanger includes a high pressure path between a high pressure inlet and a high pressure outlet. The reheat heat exchanger also includes a low pressure path between a low pressure inlet and a low pressure outlet. The two paths are in heat transfer relationship. In a typical power generation system utilizing the reheat heat exchanger, the high pressure inlet is located downstream from a source of high temperature high pressure working fluid. An expander is located downstream from the high pressure outlet and upstream from the low pressure inlet. A second expander is typically provided downstream from the low pressure outlet. The reheat heat exchanger beneficially enhances the efficiency of power generation systems, particularly those which utilize expanders having inlet temperatures limited to below that produced by the source of working fluid.

A coal syngas or other syngas fired power plant is provided with no atmospheric emissions. Coal or other starter fuel is gasified within a gasifier which also receives oxygen and steam therein. The oxygen is provided from an air separator. Syngas produced within the gasifier is combusted within a gas generator along with oxygen from the air separator. Water is also introduced into the gas generator to control the temperature of combustion of the syngas with the oxygen. Products of combustion including steam and carbon dioxide are produced within the gas generator. The combustion products are expanded through a turbine for power output and then separated, such as within a condenser. Water discharged from the condenser is at least partially recirculated back to the gasifier and the gas generator. Carbon dioxide from the separator is compressed for capture without release into the atmosphere.

This invention relates to a glass melting furnace with downward firing oxygen-fuel burners placed in the breast walls of the combustion space and adjacent to the skew block. The downward firing oxygen-fuel burner may be placed at an angle so that the oxygen-fuel flame from the downward firing oxygen-fuel burner impinges on the upper surface of the glass bath. The placement and angle of the downward firing oxygen-fuel burner may maximize the amount of heat transferred to the batch cover or the molten glass, ensure the formation of high quality glass products, and protect the integrity of the downward firing oxygen-fuel burners and the glass melting furnace.

The present invention harvests and utilizes fluidized bed drying technology and waste heat streams augmented by other available heat sources to dry feedstock or fuel. This method is useful in many industries, including coal-fired power plants. Coal is dried using the present invention before it goes to coal pulverizers and on to the furnace/boiler arrangement. Coal can be intercepted on current coal feed systems ahead of the pulverizers. Drying fuel, such as coal, is done to improve boiler efficiency and reduce emissions. A two-stage bed utilized in the process first “pre-dries and separates” the feed stream into desirable and undesirable feedstock. Then, it incrementally dries and segregates fluidizable and non-fluidizable material from the product stream. This is all completed in a low-temperature, open-air system. Elevation of fan room air temperature is also accomplished using waste heat, thereby making available to the plant system higher temperature media to enhance the feedstock drying process.