The invention relates to a process method for circularly utilizing waste water produced by butadiene preparation through 
butene oxidative 
dehydrogenation and belongs to the technical field of 
chemical industry. The process method is characterized in that: firstly, most of the waste water is sent to an exhaust-heat 
recovery boiler for use after most organic matters in the waste water discharged from a water-cooling acid rinsing 
tower are deprived through a waste water 
distillation tower, and desalted water replenishing of the exhaust-heat 
recovery boiler is replaced; secondly, partial waste water returns an 
aldehyde rinsing 
tower for reusing after most aldehydes in the waste water discharged from the 
aldehyde rinsing tower are deprived through a blowdown tower, and desalted water using quantity of the 
aldehyde rinsing tower is reduced; and thirdly, low temperature condensation is carried out for 
tail gas containing acid and aldehyde, organic matters condensate liquid in the 
tail gas is recycled, and loads of a 
waste gas processing system is lightened. Compared with the prior art, a waste water classifying treatment and cyclic utilization process of the process method effectively reduces water replenishing quantity of a technical process, greatly reduces 
effluent quantity of the waste water simultaneously, reduces a 
chemical oxygen demand (COD) concentration of discharged 
sewage and an 
organic content in discharged gas, and has advantages of being economic, environment-friendly and the like.