1806 results about "Dehydrogenation" patented technology

The invention belongs to the technical field of chemical production, and particularly relates to an efficient energy-saving refining system for producing cyclohexanone through dehydrogenation, which comprises an alcohol tower, a dehydrogenation heat exchanger, a dehydrogenation reactor, an alcohol tower feeding heat exchanger, a dehydrating tower, a light tower I, a light tower II, a ketone tower and an alcohol recovery tower which are connected in sequence, a middle feeding port of the alcohol tower is communicated with a tube pass discharging port of the alcohol tower feeding heat exchanger, a top discharging port of the alcohol tower is communicated with a tube pass feeding port of the dehydrogenation heat exchanger, a bottom discharging port of the alcohol tower is communicated with a middle feeding port of the alcohol recovery tower, and an alcohol ketone drying tower is additionally arranged between the alcohol tower feeding heat exchanger and the dehydration tower. A feed port of the alcohol ketone drying tower is communicated with a shell pass discharge port of the alcohol tower feed heat exchanger, and a liquid phase discharge port of the alcohol ketone drying tower is communicated with an upper feed port of the dehydrating tower. The alcohol tower adopts a process that raw materials directly enter the tower top, tower top reflux is cancelled, steam consumption is reduced, and the purpose of saving energy is achieved.

The invention relates to the technical field of hydrogen storage and release, and discloses a cyclic hydrogen storage and release system based on aromatic cycloalkane reaction, which comprises a hydrogenation reaction unit, a dehydrogenation reaction unit, a gas-liquid separation and compression unit and an adsorption and purification unit which are sequentially connected through pipelines, the hydrogenation reaction unit, the dehydrogenation reaction unit and the gas-liquid separation and compression unit are respectively connected with the heat exchange unit; the hydrogen storage function and the hydrogen desorption function are integrally designed, the microwave heat supply dehydrogenation reactor is designed for the dehydrogenation reaction link with high energy consumption, and compared with the prior art, the microwave heat supply dehydrogenation reactor has the advantages that the heat transfer resistance is reduced, the reaction efficiency is improved, and the energy loss is reduced. The designed gas-liquid separation and adsorption purification technology is coupled, only one compressor is used in the whole process, the purification process is effectively simplified, the operation is simple and convenient, the equipment cost and the hydrogen purification cost are reduced, and the hydrogen yield and the hydrogen storage carrier cyclic utilization rate are improved. The system has the advantages of high hydrogen storage and release efficiency, small system size, high mobility and the like.

A catalyst and methods for making the catalyst are provided. An exemplary catalyst includes the formula: MoaVbTec-TadOx. In this formula, a is 1.0, b is about 0.01 to about 0.3, c is about 0.01 to about 0.09, d is about 0.01 to about 0.05, and x is the number of oxygen atoms necessary to render the catalyst electronically neutral.

The invention relates to the technical field of solar cells, in particular to copper-based paste, a TOPCon cell and a preparation method of the TOPCon cell. The copper-based slurry includes: copper powder as main powder densified in a sintering process to form a conductive phase; the hydrogen storage material is used for releasing a hydrogen element in the sintering process and locally forming a reducing atmosphere so as to prevent the copper powder from being oxidized; the hydrogen storage material comprises a liquid hydrogen storage material; and the organic carrier provides fluidity and thixotropy for the slurry. Compared with solid hydrogenated metal particles, the liquid hydrogen storage material can be more uniformly dispersed in the copper-based slurry and can coat the copper powder, so that the hydrogen element released from the copper-based slurry is more uniform, and the oxidation of the copper powder can be comprehensively inhibited. Meanwhile, the dehydrogenation amount of the liquid hydrogen storage material is far higher than that of the solid hydrogenated metal particles, the release amount of hydrogen elements can be increased by multiple times under the same mass, and then more sufficient oxidation protection is provided for the copper powder.

The invention relates to the technical field of catalyst carriers, and discloses reticular porous spherical aluminum oxide as well as a preparation method and application thereof. The preparation method comprises the following steps: (1) mixing an aluminum source, acid, a pore-forming agent, a surfactant and water to obtain pseudo sol; (2) performing ultrasonic treatment and oil ammonia column forming treatment on the pseudo sol obtained in the step (1) to obtain gamma-Al2O3 spherical gel beads; and (3) aging, washing, drying and calcining the gamma-Al2O3 spherical gel beads obtained in the step (2) to obtain the reticular porous spherical alumina. The spherical aluminum oxide prepared by the method has abundant communicated reticular pore channels, is obviously distributed in mesopore and macropore ranges, is beneficial to obviously improving dispersion and loading of a catalyst in an aluminum oxide carrier and improving the performance of petroleum reforming and propane dehydrogenation, and has industrial production utilization value and commercial value.

The invention provides a Pt-Sn bimetallic catalyst and a preparation method and application thereof.The preparation method comprises the steps that 1, a Y molecular sieve is placed in a mixed solution of KOH and methyl alcohol, centrifugation and washing are conducted till the Y molecular sieve is neutral after stirring, drying and roasting are conducted, and a non-acid KY molecular sieve is obtained; the silica-alumina ratio of the Y molecular sieve is 3-100; 2) taking the non-acidic KY molecular sieve as a carrier, and loading Sn by adopting an atomic layer deposition technology to obtain a Sn-modified non-acidic KY molecular sieve; and 3) loading Pt by using the Sn-modified non-acidic KY molecular sieve as a carrier and adopting an atomic layer deposition technology to obtain the Pt-Sn bimetallic catalyst. According to the preparation method provided by the invention, spatial distribution of Pt and Sn is accurately regulated and controlled by combining an atomic layer deposition technology, so that the electronic state of Pt species is adjusted, alkane is promoted to be dehydrogenated into an olefin intermediate, and the aromatization catalytic activity and the aromatic hydrocarbon selectivity of alkane are improved.

The invention relates to the technical field of chemical catalysis, in particular to a copper-silicon catalyzed cyclohexanol gradient dehydrogenation and hydrogen recycling method which comprises the following steps: step 1, preparing a gradient catalyst, namely carrying out surface hydroxyl regulation pretreatment on porous silica gel, and loading a copper salt solution by adopting a step-by-step impregnation method to form gradient distribution with gradually decreased copper loading capacity from outside to inside, carrying out segmented heating reduction in a reducing atmosphere containing 5vol% of H2 / N2; 2, gradient dehydrogenation reaction process control; and 3, hydrogen in-situ separation and cyclic utilization: separating hydrogen from the reaction outlet gas through a palladium alloy membrane, controlling the pressure difference of the two sides of the membrane to maintain the permeation flux, returning the separated hydrogen to the inlet of the reactor to adjust the hydrogen partial pressure, and storing the residual hydrogen. Through gradient catalyst preparation, accurate reaction process control and efficient hydrogen recovery technologies, the cyclohexanone production efficiency is improved, and long-term stability of the catalyst and efficient recycling of hydrogen are achieved.

The invention discloses a high-porosity organic salt framework confinement nano-metal hydrogen storage material and a preparation method thereof, and belongs to the field of new energy materials. The material takes a carboxylic acid organic salt framework (POS-1) as a carrier, the specific surface area of the material is 1520 m < 2 > / g, the pore size distribution is 1.8-2.5 nm, nano Mg / Ni particles (the average particle size is 3.2 + / -0.5 nm) are confined in pores through a gradient loading and in-situ reduction technology, and an atomic layer deposition (ALD) is adopted to modify a Pd nano catalyst (the loading capacity is 0.48 wt%). The reversible hydrogen storage capacity of the material at room temperature reaches 5.8 wt%, the hydrogen desorption temperature is lower than 80 DEG C, and the capacity retention ratio is larger than or equal to 92% after 100 times of circulation. The preparation method comprises the steps of organic salt framework synthesis, metal precursor gradient loading, low-temperature reduction (250 DEG C), hydrogenation activation and the like, the process is simple and controllable, and the catalyst is suitable for scenes such as a vehicle-mounted hydrogen storage system.

The invention belongs to the technical field of chemical catalysis and chemical engineering, and discloses an oxygen carrier for preparing ethylene through oxidative dehydrogenation of chemical chain ethane as well as a preparation method and application of the oxygen carrier. Comprising a main component CeO2 and loading components V and Ru, specifically, the V and the Ru are loaded on the CeO2 in a step-by-step impregnation mode, and according to the mass percent of the CeO2, the Ru accounts for 2.00%, and the V accounts for 1.00%-5.00%. The key problems that a traditional ethane dehydrogenation technology is high in dependence on precious metal, prone to sintering at high temperature, frequent in regeneration and the like are solved, and an innovative solution is provided for low-carbon efficient ethylene production.

The invention belongs to the technical field of alkane processing, and particularly relates to a process for preparing isopentene by dehydrogenation of isopentane, a catalyst and a tert-amyl alcohol preparation process. The process for preparing isopentene by dehydrogenation of isopentane comprises an isopentane dehydrogenation device and an isopentene separation device, in the isopentane dehydrogenation device, a dehydrogenation reactor is a fixed bed adiabatic reactor and is filled with a Pt-Sn-K / alumina type alkane dehydrogenation catalyst, the catalyst has hydromethanation performance under the CO2-containing dehydrogenation reaction condition, and the arrangement and operation of a dehydrogenation reactor group comprise a mode A, a mode B or a mode C; the isopentene separation device comprises a cooling separation system, a pressure swing adsorption separation system and an optional rectification system. The tert-amyl alcohol is further prepared from isoamylene under the conditions of a fixed bed hydration reactor, ethylene glycol monobutyl ether and other solvents, and the tert-amyl alcohol product is obtained through separation. The process is superior to the prior art on the whole, and has certain application prospects.

The invention relates to the field of catalytic cracking, in particular to a modified catalytic cracking catalyst and a preparation method and application thereof. The modified catalytic cracking catalyst is of a core-shell structure and comprises an inner core and an outer shell, the inner core contains catalytic cracking catalyst finished product particles and alkaline earth metal elements, and the outer shell contains the alkaline earth metal elements and rare earth metal elements. Compared with other catalysts of the same type, the modified catalytic cracking catalyst has more excellent nickel resistance on the basis of not influencing the catalytic cracking performance, and also has lower dehydrogenation activity.

The present invention provides a method for preparing an amphoteric ion-modified PVDF polymer electrolyte, belonging to the technical field of lithium metal batteries. Specifically, PVDF particles, a lithium salt, pyridinium propane sulfonate and a polar organic solvent are mixed and stirred to obtain a uniform viscous solution, which is coated on the surface of a substrate and dried under vacuum to obtain an amphoteric ion-modified PVDF polymer electrolyte. Among them, the concentrations of PVDF particles, lithium salt and pyridinium propane sulfonate in the uniform viscous solution are 80-120 g / L, 10-120 g / L and 5-60 g / L respectively. The present invention uses pyridinium propane sulfonate as an additive for the PVDF electrolyte. While promoting ion transport, it takes into account the stability of PVDF and the lithium negative electrode, inhibits the side reactions of dehydrogenation and defluorination, and improves the stability of the lithium negative electrode and the performance and cycle stability of the polymer electrolyte-based lithium metal battery.

A dehydrogenation reaction device includes a chemical hydride storage unit including a chemical hydride storage tank, a reaction unit including an acid aqueous solution storage tank, and a dehydrogenation reactor configured to generate hydrogen by reacting a chemical hydride with an acid aqueous solution, and a hydrogen storage unit including a hydrogen storage tank configured to store the hydrogen produced in the dehydrogenation reactor. The dehydrogenation reactor includes a body portion made of a metal and a reinforcement portion surrounding the outer surface of the body portion and including fiber reinforced plastic (FRP).

The invention aims to provide a solid hydrogen storage hydrogen closed cycle hydrogen source generator for an underwater vehicle, which belongs to the field of dehydrogenation devices and comprises a reactor, a pressure stabilizing common rail pipe, a hydrogen storage material delivery pump, a solid hydrogen storage material storage unit, a solid hydrogen storage material spraying device, a product collecting device and a hydrogen storage unit. The hydrogen storage material conveying pump is connected with the pressure stabilizing common rail pipe, the solid hydrogen storage material storage unit and the solid hydrogen storage material spraying device, the hydrogen storage unit is connected with the pressure stabilizing common rail pipe, and the reactor is connected with the hydrogen storage unit. The solid hydrogen storage material is used for releasing hydrogen, one part of hydrogen is conveyed to the fuel cell to react for power output of the underwater vehicle, the other part of circulating hydrogen assists the hydrogen storage material in injection, and an underwater closed circulation mode suitable for the underwater vehicle is achieved. The solid hydrogen storage material conveying module and the circulating hydrogen supply module are matched, and rapid mixing of the solid hydrogen storage material and hydrogen and large-flow injection of the solid hydrogen storage material are achieved.

The invention discloses a green synthesis ammonia and organic liquid hydrogen storage combined device. The device comprises a water electrolysis hydrogen production device, a nitrogen production device, an organic liquid hydrogen storage device, a low-pressure gas compressor, a synthesis gas compressor and an ammonia synthesis device, the water electrolysis hydrogen production device produces hydrogen and conveys the hydrogen to the organic liquid hydrogen storage device and the synthesis gas compressor; the nitrogen making device is used for making nitrogen and conveying nitrogen to the organic liquid hydrogen storage device and the synthesis gas compressor; the organic liquid hydrogen storage device reacts hydrogen-poor organic liquid with hydrogen generated by the water electrolysis hydrogen production device to generate hydrogen-rich organic liquid, nitrogen is introduced into the hydrogen-rich organic liquid for dehydrogenation reaction, and the hydrogen and the nitrogen are input into the low-pressure gas compressor; the low-pressure gas compressor and the synthesis gas compressor compress hydrogen and nitrogen and input the compressed hydrogen and nitrogen into the ammonia synthesis device; and the ammonia synthesis device generates ammonia under the action of the catalyst. The gas-liquid mass transfer efficiency and the hydrogen desorption rate are improved, the energy consumption and the operation and maintenance cost of the compressor are reduced, and accurate adjustment of the hydrogen-nitrogen ratio is achieved.

The invention discloses a chromium catalyst for propane dehydrogenation and a preparation method and application thereof, the catalyst is composed of an active component Cr2O3, an auxiliary agent, a modifier and an Al2O3-ZrO2 complex, the modifier is Y or Nd, and the auxiliary agent is at least one of Mn2O7, In2O3, CoO, OsO4 and MoO3. The catalyst is high in catalytic activity, strong in anti-coking capability, good in stability, low in cost and high in economical efficiency.

The invention discloses a preparation method of a super-hydrophilic PVDF (polyvinylidene fluoride) microfiltration membrane, belongs to the technical field of filter membrane processing, and is used for solving the technical problem that the hydrophilic performance and flux of a microfiltration membrane in the prior art need to be further improved. The preparation method comprises the following steps: putting modified PVDF, acetone, N, N-dimethylformamide and an auxiliary additive into a reaction kettle, and uniformly mixing to obtain a mixed solution; the preparation method comprises the following steps: preparing modified polyolefin from modified graphene and ethylene-co-maleic anhydride, carrying out a polymerization reaction on the modified polyolefin and PVDF subjected to a dehydrogenation fluorination reaction to obtain modified PVDF, preparing a membrane from the modified PVDF, a solvent and an auxiliary additive through a phase inversion method, and further carrying out dipping treatment to obtain the PVDF / PVDF composite membrane. The hydrophilic performance and flux of the PVDF micro-filtration membrane are improved, and the mechanical performance of the PVDF micro-filtration membrane is also improved.

The invention provides an all-silicon molecular sieve confined Pt-based bimetallic catalyst and application thereof in preparation of propylene through propane dehydrogenation. The preparation method comprises the following steps: mixing a silicon source, a template agent, a Pt precursor, an auxiliary element Cu precursor and the like by adopting an in-situ synthesis method, synthesizing under a hydrothermal condition, washing, drying, roasting and reducing to obtain the Pt-based bimetallic molecular sieve catalyst. According to the present invention, the pure silicon molecular sieve Silicalite-1 (S-1) is adopted as the carrier, such that the good carrier characteristics of high thermal stability, low acidity, rich pore structure and the like are provided, and the silicon hydroxyl group (Si-OH) in the S-1 pore channel can further provide the metal species anchoring effect so as to easily disperse and limit the active site; and the Cu auxiliary agent improves the metallicity of Pt. The synergy of the two significantly improves the performance of propylene preparation by direct dehydrogenation of propane. The synthesized PtCu-coated S-1 catalyst is low in Pt loading capacity, Pt and Cu are highly dispersed, side reactions such as deep dehydrogenation of propylene can be inhibited, and good stability is achieved.

The invention discloses a metal modified molecular sieve catalyst and a preparation method and application thereof. The catalyst is a metal-loaded molecular sieve which is modified by post-treatment after a metal component is loaded on the molecular sieve; the molecular sieve is selected from at least one of H-ZSM-5, H-Beta, H-ZSM-35, H-MOR, H-MCM-22, H-ZSM-11 and H-ZSM-22, and the molecular sieve is selected from at least one of H-ZSM-5, H-Beta, the metal is loaded on the molecular sieve through ion exchange and / or impregnation; the post-treatment modification is selected from at least one of heating treatment, water vapor treatment and silanization treatment. The metal component of the catalyst can catalyze dehydrogenation reaction and carbon dioxide activation, the molecular sieve component provides a substance diffusion channel and an acid center, and post-treatment modification can regulate the distribution of the molecular sieve acid center and improve the hydrothermal stability of the catalyst. The catalyst can efficiently promote the coupling reaction of cycloalkane and carbon dioxide, the selectivity of aromatic hydrocarbon reaches 90% or above, and the conversion rate of carbon dioxide reaches 20% or above.

The utility model discloses a heat energy utilization system of a C3 and C4 mixed dehydrogenation device, and relates to the technical field of heat energy utilization. According to the utility model, heat generated by a heat pump compressor is respectively used as a heat source of materials extracted from the side lines of a propane tower reboiler and a C3 and C4 separation tower A, heat of an aromatic solvent pipe system is used as a heat source of the reboiler of the C3 and C4 separation tower A, and heat of materials at the bottom of a C3 and C4 separation tower B is used as a heat source to exchange heat with materials at the inlet of the C3 and C4 separation tower A; surplus heat of the dehydrogenation device is fully utilized, steam consumption is reduced, and the purpose of saving energy is achieved.

The embodiment of the invention relates to a method for initiating in-situ polymerization of an electrolyte solution through electrochemical induction. A solvent of the electrolyte solution comprises cyclic ether molecules and halogen atom substituted ethylene carbonate molecules; the method comprises the following steps: carrying out constant-current charging on a battery to a set voltage, and carrying out constant-voltage charging for a specific time under the set voltage, so that halogen atoms of halogen atom substituted ethylene carbonate molecules are removed under the reduction potential of the negative electrode side of the battery to generate free radical sites, two molecular structures after halogen atoms are removed are mutually combined through the free radical sites to form a dimer, the dimer is migrated to the positive electrode side in an electrolyte solution, dehydrogenation reaction is carried out under the action of oxidation potential applied to the positive electrode side, and in-situ ring-opening polymerization reaction of cyclic ether molecules is initiated through removed hydrogen ions; therefore, in-situ polymerization solidification of the electrolyte solution is realized under the condition that a conventional initiator is not contained.

The invention discloses a catalyst for dehydrogenation of a liquid organic hydrogen energy carrier as well as a preparation method and a dehydrogenation method of the catalyst. The catalyst for dehydrogenation of the liquid organic hydrogen energy carrier comprises an active component, an auxiliary agent and a carrier, the active component is Pt, the auxiliary agent is CeO2, and the carrier is MgO-Al2O3 composite oxide; the CeO2 is dispersed on the surface of the MgO-Al2O3 composite oxide in an island form; pt is selectively dispersed on the CeO2 islands. The catalyst can inhibit agglomeration and growth of Pt particles and deposition of organic carbides on the surface of the catalyst in the dehydrogenation reaction process, and shows excellent activity and stability.

A method may include operating a dehydrogenation process whereby a hydrocarbon-containing feed is converted to light olefins, wherein the dehydrogenation process utilizes a fluidized process catalyst that circulates between a reactor and a combustor. The method may comprise withdrawing the process catalyst from the dehydrogenation process, modifying the process catalyst to form a modified catalyst, and adding the modified catalyst back to the dehydrogenation process. The process catalyst may include from 0.1 wt. % to 10 wt. % of one or more metals chosen from gallium, indium, thallium, or combinations thereof, from 1 ppmw to 1000 ppmw of one or more metals chosen from platinum, palladium, rhodium, iridium, ruthenium, osmium, or combinations thereof, and at least 85 wt. % support. Modifying the process catalyst may include adding one or more of manganese, iron, chromium, or vanadium.

The utility model relates to a precooling system for methanol synthesis gas, and belongs to the technical field of gas precooling. Comprising a compressor, a filter, a precooler, an emptying valve, a temperature sensor and a controller. One part of the nitrogen compressed by the compressor is conveyed to the filter, and the other part of the nitrogen is conveyed to the precooler, so that the amount of the nitrogen passing through the precooler is small, impurities in the precooler are few, blockage in the precooler is avoided, the amount of the conveyed nitrogen and the cooling effect on a dehydrogenation tower and a decarburization tower are ensured, and the service life of the dehydrogenation tower and the decarburization tower is prolonged. And the cleaning period of the precooler is prolonged. After the precooler runs for a certain time, the controller opens the emptying valve, the nitrogen in the dehydrogenation tower and the decarburization tower is used for back flushing the interior of the precooler, so that the nitrogen is used for purging impurities remained in the precooler, the cleaning of the precooler is completed, in the purging process, the nitrogen can still be conveyed to the dehydrogenation tower and the decarburization tower through the filter for cooling, and the cleaning efficiency of the precooler is improved. And the influence on the cooling effect of the condenser of the dehydrogenation tower and the condenser of the decarburization tower is reduced.

The invention discloses a low-concentration ether electrolyte adaptive to a high-voltage high-nickel ternary lithium ion battery, a preparation method of the low-concentration ether electrolyte and the lithium ion battery, and relates to the technical field of batteries. The ether electrolyte comprises a solvent and a solute; the solvent comprises an ether solvent, and is specifically at least one of 4-cyano tetrahydropyran, 2-(tetrahydro-2H-pyran-4-yl) acetonitrile, 2-methoxyacetonitrile, 2-ethyoxyl acetonitrile, 3-methoxypropionitrile, 3-ethyoxyl propionitrile, 3-butoxyl propionitrile, ethylene glycol bis (propionitrile) ether and 3-{2-[2-(2-cyano ethyoxyl) ethyoxyl] ethyoxyl} propionitrile. The ether solvent contains cyano groups, the strong electronegativity of the cyano groups enables the cyano groups to be coordinated with transition metal ions in the ternary material, and the cyano groups are preferentially adsorbed at the interface of the positive electrode material, so that the arrangement of solvent molecules at the interface has directivity, the proportion of ether oxygen bonds and carbon hydrogen atoms in double electric layers is reduced, and the performance of the positive electrode material is improved. And the sites which are easy to generate dehydrogenation reaction in the molecules are far away from the high-voltage positive electrode interface which is easy to generate oxidation reaction.

Provided are a natural gas helium extraction device and a natural gas helium extraction method. The natural gas helium extraction device comprises a primary concentration part, a dehydrogenation and dehydration part, a secondary concentration part, and a final purification part. The primary concentration part comprises a first compressor, a first preheater, and a first membrane separator connected in sequence. The dehydrogenation and dehydration part comprises an oxygen delivery pipe, a mixer, a plurality of dehydrogenation towers connected in parallel, a low-temperature water separator, and a water remover. The secondary membrane separator of the secondary concentration part comprises a permeate gas outlet and a non-permeate gas outlet. The non-permeate gas outlet is connected to the primary concentration part. The final purification part comprises a nitrogen circulating cooling component and a pressure swing adsorption (PSA) device. The PSA device is connected to the permeate gas outlet of the secondary membrane separator and is used to output high-purity helium. The nitrogen circulating cooling component, the PSA device, and the low-temperature water separator form a cooling loop. The natural gas helium extraction device and the natural gas helium extraction method can significantly reduce safety risks and effectively reduce equipment costs.

The utility model relates to an energy-saving production device for preparing methyl tert-butyl ether by an isobutane dehydrogenation method. A raw material gasifier is arranged between the catalytic distillation tower feeding and discharging heat exchanger and the catalytic distillation tower, a temperature sensor is arranged on a feeding pipeline from the raw material gasifier to the catalytic distillation tower, a gas phase at the top of the catalytic distillation tower is divided into two pipelines, a compressor is additionally arranged on one pipeline, and an automatic flow regulating valve is additionally arranged on the other pipeline; a cold-side material outlet of the distillation tower feeding and discharging heat exchanger is connected with a cold-side material inlet of the raw material gasifier, a cold-side material outlet of the raw material gasifier is connected with a feeding hole in the middle lower part of the catalytic distillation tower, and a tower top discharging pipeline of the catalytic distillation tower is respectively connected with an inlet of the compressor and a hot-side material inlet of the condenser; an outlet pipeline of the compressor is connected with a hot measuring material inlet of the raw material gasifier, and a hot measuring material outlet of the raw material gasifier is connected with a liquid inlet of the return tank. According to the utility model, a heat pump technology is adopted, so that the heating power of the tower kettle reboiler is reduced, and the steam consumption is reduced; and the method is more economical.

The invention discloses a preparation method of a catalyst for dehydrogenation of methylcyclohexane. The preparation method specifically comprises the following steps: step 1, preparing a catalyst carrier 2D-CrB; and 2, preparing the catalyst Pt / 2D-CrB according to the product obtained in the step 1. The invention also discloses a catalyst for dehydrogenation of methylcyclohexane. The problem that the efficiency is low when the existing catalyst is used for catalyzing the dehydrogenation reaction of methylcyclohexane is solved.

The present invention discloses a hydrophobic Cu / SiO2 catalyst and its preparation and application. The preparation method of the hydrophobic Cu / SiO2 catalyst includes: adding a Cu / SiO2 catalyst into a mixed solution of a hydrophobic treatment agent and an organic solvent, oscillating at 30-60 °C for 1-12 h, filtering after oscillation and washing with ethanol to remove the excess hydrophobic treatment agent, and then drying in an oven at 40-200 °C for 1-24 h to obtain the hydrophobic Cu / SiO2 catalyst; the hydrophobic treatment agent is one or more of methoxytrimethylsilane, trimethylchlorosilane, dimethyldiacetoxysilane, and triisopropyloxysilane. The present invention provides the application of the hydrophobic Cu / SiO2 catalyst in the dehydrogenation lactonization reaction of diglycol, improving the selectivity / yield of the target product.

The invention discloses a method and a system for improving the bonding capacity of a titanium-based material in superplastic forming / diffusion bonding, and belongs to the field of titanium alloy material heat treatment and hot working. In order to solve the problem that in the prior art, the connection quality is reduced due to hydrogen dissipation in the high-temperature SPF / DB process of titanium hydride alloy, hydrogen is mixed into an inert gas pressure source, the environmental hydrogen partial pressure is increased to inhibit hydrogen element loss, and therefore the diffusion connection capacity is improved. The method comprises the specific steps that a titanium alloy plate is subjected to hydrogen treatment, cleaned and sprayed with a separant, then the titanium alloy plate is placed in a mold to be vacuumized, argon-hydrogen mixed gas is introduced to serve as a pressure source, and forming and connecting are completed through rapid heating and pressure maintaining; and after the process is finished, carrying out vacuum annealing in a dehydrogenation temperature range to remove hydrogen elements, and introducing argon to accelerate cooling. The hydrogen element can be effectively reserved to improve the joint quality, meanwhile, the dehydrogenation step is simplified, and the method is suitable for the field of titanium-based material hot working, especially the technical field of titanium hydride alloy superplastic forming / diffusion bonding.