6711 results about "Mixed gas" patented technology

The invention discloses a disilane mixed gas dissolving and mixing system and a control method, and relates to the technical field of gas mixing preparation, the disilane mixed gas dissolving and mixing system comprises seven modules, a storage module realizes accurate pressure control through a honeycomb gas storage tank matrix, and the tank wall adopts a nano composite structure for corrosion prevention; the premixing module forms a chaotic flow field by using a double-helix micro-channel and pulse injection; the reaction module is combined with supercritical and electromagnetic resonance to accelerate the reaction; the monitoring module fuses multispectral detection; the control system is based on deep reinforcement learning, in addition, a gradient condensation-membrane distillation separation module, a bionic safety interlocking module and other modules are further arranged, and all the modules cooperate to achieve efficient mixing and production. According to the device and the method, high-precision preparation of disilane mixed gas, precise pressure-controlled material storage, molecular-level efficient mixed reaction, multispectral precise monitoring, intelligent regulation and control, stability guarantee, high safety interlocking and intelligent maintenance are realized, faults can be reduced, the product quality and the production efficiency are improved, and the cost is reduced.

The invention discloses a preparation method and a production system of phosphorus trifluoride, and belongs to the technical field of preparation of phosphorus trifluoride. Phosphorus trichloride and first mixed gas are continuously introduced into a reactor, the first mixed gas comprises anhydrous hydrogen fluoride and inert gas, phosphorus trichloride and anhydrous hydrogen fluoride in the first mixed gas are subjected to a double decomposition reaction in the reactor, and intermediate gas containing phosphorus trifluoride is generated. Collecting intermediate gas discharged from the reactor, and rectifying and purifying the intermediate gas to obtain a phosphorus trifluoride product. The inert gas carries anhydrous hydrogen fluoride and phosphorus trichloride to generate double decomposition reaction to generate phosphorus trifluoride, and the inert gas can dilute the concentration of the raw material gas anhydrous hydrogen fluoride participating in the reaction and also can take away heat generated by the reaction, so that the temperature of the reactor is more stable, and continuous production of phosphorus trifluoride is realized.

The invention provides a blast suppression method and system for an underground cavity of a pumped storage power station. The method comprises the following steps: configuring and deploying a multispectral gas sensor array; carrying out gas explosion limit calculation and risk assessment; calculating the risk level of explosion by using the prediction model; performing graded explosion suppression operation by using a graded explosion suppression execution module; combustible gas is guided to enter an inerting area by utilizing a space flow guide optimization module; and the ignition source blocking module is used for cooperative control to block an ignition source. The technical problems of low mixed gas explosion risk prediction and monitoring precision, low explosion suppression efficiency, slow response speed and relatively high operation and maintenance cost are solved.

The invention discloses a rolling and annealing treatment process for a copper-steel composite strip, and relates to the technical field of material rolling, the process comprises the following steps: selecting a high-purity copper plate and a stainless steel plate, and depositing a nano nickel / graphene composite transition layer through a magnetron sputtering technology; the stainless steel layer is promoted to deform through front-section low-speed high-pressure rolling, and the copper layer interface bonding force is improved through rear-section high-speed low-pressure rolling; performing short-time local annealing by using a high-frequency induction coil; honeycomb-shaped micro-pits are formed in the stainless steel surface through the laser micro-texture technology, and the interface bonding force is improved in combination with the nano-nickel / graphene layer. Copper layer hardening is eliminated through low-temperature annealing, stainless steel recrystallization is promoted through medium-temperature annealing, and a nanometer precipitated phase is fixed through rapid water cooling; the heating rate is controlled, and nitrogen-hydrogen mixed gas is used for preventing oxidation; the rolling process and the annealing process are seamlessly connected, and the temperature, the stress and the atmosphere are detected in real time through an online monitoring system. The mechanical property, the corrosion resistance and the machining stability of the copper-steel composite strip are remarkably improved.

The invention relates to the technical field of pulverized coal fired boiler combustors, and particularly discloses a double-high-concentration-area oil-saving ignition pulverized coal combustor. The double-high-concentration-area oil-saving ignition pulverized coal burner comprises a flow guide device and an ignition device arranged in a combustion cylinder. The flow guide device comprises a main cylinder and a turbulent flow structure arranged on the periphery of the main cylinder, the main cylinder is connected to the inner wall of the combustion cylinder through a supporting piece, and the turbulent flow structure is of a structure protruding in the radial direction and used for disturbing the flow direction of mixed gas. Therefore, the problem that in the prior art, when the structural design of an oil-saving ignition pulverized coal burner is in a non-ignition working condition, the pulverized coal concentration distribution mode of'thick inside and thin outside 'is opposite to the design of'thick outside and thin inside' of an original burner of a boiler, and the air powder flow field characteristics of an outlet of the burner and the interior of a hearth are prone to being remarkably influenced is solved.

The present application relates to hydrogen production technology field, especially to a kind of methanol hydrogen production method, comprising the following steps: S10: methanol water is heated and vaporized to obtain methanol water vapor;S20: methanol reforming reaction obtains hydrogen mixture gas;S30: after cooling treatment to hydrogen mixture gas, through water washing tower absorption unreacted methanol water, then, adjust the relative humidity and temperature of hydrogen mixture gas;S40: hydrogen mixture gas is input into carbon dioxide absorption tower to remove carbon dioxide;S50: after removing carbon dioxide, product hydrogen is obtained and input hydrogen tank storage to supply user end.The above-mentioned methanol hydrogen production method, by methanol water vapor reforming hydrogen treatment, obtains hydrogen mixture gas.Again, hydrogen mixture gas is purified to obtain product hydrogen with very low carbon monoxide content, with raw material easy to transport, the hydrogen purity of output is high, equipment construction cost is low, and energy consumption is low and the like advantages, reach the purpose of expanding hydrogen application range.

The invention relates to a gas sensor environment anti-interference drift compensation method, system and equipment, and the method comprises the steps: collecting a mixed gas response signal in an environment, and obtaining an electromagnetic interference signal under the same timestamp; threshold truncation is carried out on spike pulses in the mixed gas response signals to obtain trend waveform signals caused by gas concentration changes, and denoising processing is carried out on the electromagnetic interference signals to obtain effective electromagnetic interference parameters; performing feature recognition on the effective electromagnetic interference parameters through a preset interference-response cooperative processing model to determine an interference mode and an interference intensity grade, synchronously analyzing the trend waveform signal to obtain a response feature curve of the target gas and the interference gas, and obtaining a drift compensation coefficient of the target gas; and carrying out collaborative optimization on the drift compensation coefficient through a preset interaction influence model to obtain a final compensation result so as to achieve the purpose of outputting a high-precision target gas concentration detection result.

The invention discloses a mixed gas-imitating gel fiber as well as a preparation method and application thereof, and belongs to the technical field of fiber materials. The mixed gas-imitating gel fiber is prepared from the following components: cellulose dispersion liquid, a silane coupling agent and viscose in a mass ratio of (1-3): (0.2-0.8): (5-10), comprising the following steps: adding sodium hydroxide into a cellulose dispersion liquid, adjusting the pH value to be alkaline, adding viscose and a silane coupling agent, and carrying out ultrasonic stirring to prepare a mixed spinning solution; the mixed spinning solution is extruded into a coagulating bath through a wet spinning device to be drafted, wet fibers are obtained, and the mixed gas-imitating gel fibers are obtained after freeze drying. The aerogel fiber disclosed by the invention has low heat conductivity coefficient, high mechanical strength and extreme temperature resistance, can solve the problem that the densification and porosity of a traditional fiber structure are difficult to balance, and effectively expands the application prospect of the aerogel fiber in the fields of cold protection, warm keeping and the like.

The invention discloses an intelligent monitoring method, device and system for tunnel construction gas, and the method comprises the steps: collecting multi-source gas data in real time through a mixed gas monitoring network disposed in a tunnel construction environment, the mixed gas monitoring network comprises a fixed gas monitoring node, a mobile gas monitoring node and a personnel wearable monitoring node; based on the multi-source gas data, constructing a three-dimensional gas concentration field dynamic model covering the whole tunnel construction area by using a data fusion and machine learning algorithm; on the basis of the three-dimensional gas concentration field dynamic model, the spatio-temporal evolution trend of the gas concentration in a future preset time period is predicted, at least one control instruction is generated and executed according to the prediction result, and the control instruction comprises an intelligent early warning instruction and / or a ventilation system adjusting instruction. According to the intelligent monitoring method, device and system, traditional post-event alarm is converted into pre-warning and active intervention, the safety of tunnel construction is remarkably improved, and the emergency response speed is remarkably increased.

The invention discloses a porous carbon material applied to a silicon-carbon negative electrode as well as a preparation method and application of the porous carbon material, and belongs to the technical field of lithium ion batteries. Uniformly mixing asphalt and mixed acid, heating and fully reacting to obtain acid modified asphalt; dispersing the acid modified asphalt in deionized water to prepare an asphalt aqueous solution, sequentially adding melamine and KOH, uniformly dispersing to obtain a mixed solution, and drying to obtain precursor powder; carbonizing the precursor powder under the protection of nitrogen, and then introducing CO2 or water vapor or mixed gas of the CO2 and the water vapor for activation; and washing and drying the activated product to obtain the porous carbon material. The obtained material has excellent conductivity, stability and high silicon loading performance, and can be applied to the field of lithium ion battery negative electrode materials, a silicon-carbon negative electrode prepared by taking the porous carbon material as a carrier is applied to a lithium ion battery, and the technical effects of high capacity density and long circulation can be achieved.

The invention discloses a spectrum aliasing decoupling and concentration inversion method under the cross influence of multi-source environmental factors, belongs to the field of industrial process control and environment monitoring, and constructs an environment-spectrum collaborative fusion decoupling model for concentration prediction. The method specifically comprises the following steps: respectively collecting absorption spectrum signals of specified mixed gas at different temperatures, pressures and known concentrations, meanwhile, collecting environmental parameter data, constructing a multi-source data set, and carrying out denoising, dimension reduction and preprocessing on the multi-source data set; constructing a self-supervised feature extraction network for adaptive modulation of environmental parameters to realize deep fusion of spectrum and environmental information; the feature expression capability and generalization performance of the self-supervised feature extraction network are improved by using a self-supervised learning mechanism; and constructing a BPBO-GRNN self-adaptive concentration inversion optimization model for realizing inversion of mixed gas concentration and self-adaptive optimization of model parameters. According to the invention, high-precision concentration inversion and stable detection of the aliasing gas can be realized.

This high-pressure tank stores, inside a tank body, a mixed gas that contains natural gas and hydrogen, and that contains more than 2% hydrogen by volume. The tank body includes: a cylindrical part extending in a first direction; and a dome part connected to both ends of the cylindrical part in the first direction. The steel material constituting the tank body has a tensile strength TS of 850 MPa or higher, has a structure in which 95% or more by area ratio is tempered martensite, and includes carbides of 100 nm or less scattered in the metal structure as precipitates. The high-pressure tank has a strength of 11250 cycles or more in crack progress analysis, suppresses the influence of hydrogen embrittlement in metal, ensures gas storage capacity, and has a reduced weight.

The invention discloses a small sample self-adaptive mixed gas sensor dynamic response modeling method, which belongs to the technical field of gas sensors, and specifically comprises the following steps: testing mixed gas through a gas sensor array, and generating a response signal; pulse signals representing gas concentration mutation characteristics are generated, the pulse signals and response signals form an initial sample set, short-time-sequence fragments are obtained through truncation separation, initial state signals are generated at a time step before a response rising point, and a short-time-sequence fragment sample set is obtained; forming an enhanced data set through non-playback extraction and carrying out normalization processing on the enhanced data set; and constructing and training to obtain gas sensor dynamic response models of different gas sensors. By simulating the complex dynamic response of the gas sensor, the data sample enhancement of the mixed gas is completed, the difficulty of training a mixed gas component identification model by using a small sample is reduced, and the model can quickly adapt to environmental change and performance difference of different sensors; and reliable and effective data enhancement support is provided for mixed gas component identification.

The invention discloses a method and a system for identifying mixed gas in transformer oil, a product and a medium, and relates to the technical field of testing or analyzing materials by means of measuring chemical or physical properties of the materials, and the method comprises the following steps: acquiring an internal structure diagram of a transformer, determining spatial position relations of parts and corresponding temperature distribution characteristics, and obtaining solubility differences of different spatial positions according to the spatial position relations and the corresponding temperature distribution characteristics. During operation, mixed gas concentration data of a plurality of detection points are collected, initial gas concentration data are recorded when an operation threshold range is deviated, and gas concentration change data are corrected according to solubility differences of different temperature zones. Calculating gas concentration space-time distribution characteristics, and determining a gas accumulation area according to the gas concentration space-time distribution characteristics and a space position relation. And separating the mixed gas components by using a gas chromatographic method, comparing preset gas types with the content of each component, and determining the corresponding gas type of each internal region. By implementing the method, the accuracy of identifying the types of the mixed gas in the transformer oil can be improved.

The invention relates to a method and device for preparing Ti-TiN core-shell powder, and the method comprises the steps that in an atomizing chamber, mixed gas is blown to a molten pool on the surface of an electrode bar, liquid drops are subjected to primary refining and primary coating nitrogen increasing treatment, the mixed gas comprises argon and nitrogen, and the volume content of the nitrogen does not exceed 10%; high-temperature pure nitrogen is blown to the flying liquid drops, so that secondary refining and secondary coating nitrogen increasing treatment are carried out, and the temperature of the high-temperature pure nitrogen is 1000-1500 DEG C; the powder which is not fully coated and the powder which is fully coated are separated through an electrostatic separation device; and the powder which is not fully coated is subjected to third-time coating nitrogen increasing treatment, so that the Ti-TiN core-shell structure powder is obtained. The prepared powder is core-shell powder with large thickness and small fineness, the yield is high, the shell layer structure is uniform, the sphericity degree of the powder is high, and the preparation efficiency is high.

The invention relates to the field of chemical engineering and steel smelting, and discloses a method for extracting vanadium by top-blowing nitrogen-oxygen mixed gas, which comprises the following steps: S1, measuring the temperature of overline-crossing molten iron, sampling, and testing and analyzing the components of the molten iron; s2, measuring the temperature of the molten iron mixed into the converter; s3, according to the temperature measurement result in the S1 and the temperature measurement result in the S2, the charging temperature is corrected; s4, according to the corrected charging temperature, the proportion of the mixed gas is adjusted in a staged mode for blowing; s5, adding a coolant and pig iron into the furnace according to an analysis result in S1; and S6, after blowing is completed, slag and steel are separated, and vanadium slag and low-residue vanadium semisteel are obtained. According to the scheme, in order to solve the problems that in an existing vanadium extraction process, the temperature of a molten pool rises too fast, the stirring effect is insufficient, and the vanadium oxidation rate is limited, the recovery rate of vanadium is increased and the content of residual vanadium in semi-steel is reduced by accurately controlling the nitrogen-oxygen mixed blowing proportion, reasonably distributing the blowing time and combining heat balance calculation and end point control; and meanwhile, molten steel quality and subsequent steelmaking process requirements are guaranteed.

The invention discloses an underground gas storage gas monitoring method and system based on optical fiber spectrum analysis. The method comprises the following steps: S1, optical fiber network deployment: arranging a corrosion-resistant optical fiber sensor network in a gas storage; s2, spectral data acquisition: transmitting light with a specific wavelength to a gas chamber at the tail end of an optical fiber through a Fourier transform infrared spectrometer, and acquiring a transmitted spectrum after interaction of gas and light; s3, spectrum decoupling and concentration calculation: based on a peak pattern fitting algorithm of the Lambert-Beer law, decoupling the infrared spectrum characteristics of the mixed gas, matching a standard spectrum database, and calculating the concentration of each gas component; s4, constructing a three-dimensional gas model: according to the position of the optical fiber sensor and the gas concentration data, establishing a gas migration model to predict a leakage position and a movement direction; according to the method, the trend, the component distribution, the concentration change and the potential leakage risk of the gas in the storage are effectively evaluated, and technical support is provided for the safety, the effectiveness and the economical efficiency of operation of the gas storage.

The invention discloses a purification method for removing quartz inclusion, which comprises the following steps: calcining a quartz sand raw material at high temperature for a certain time, then taking out and quickly putting into cold water for cold quenching; dehydrating quartz sand, feeding into a microwave reactor, heating to a set temperature, and keeping for a period of time; after the reaction is finished, cleaning the quartz sand with ultrapure water; filling the quartz sand into a high-temperature and high-pressure reactor, introducing supercritical carbon dioxide and hydrogen fluoride mixed gas, and keeping the temperature and the pressure for a period of time; and after the reaction is finished, discharging gas to obtain the high-purity quartz. Through two-stage heat treatment, a channel between gas-liquid inclusions in quartz particles and the outside can be efficiently opened, and meanwhile, the supercritical method ensures that impurities in the inclusions can be effectively dissolved out; the treatment time is short, the required temperature is low, the acid consumption is less than 10%, and the method has the advantages of high efficiency and low cost.

The invention belongs to the technical field of oil-gas field development, and particularly relates to a method for testing the content of adsorbed gas in a coal bed gas diffusion process. The problem that the desorption degree of coal bed gas cannot be clearly known at present is solved. According to the technical scheme, high-temperature and high-pressure isothermal adsorption experiments under the condition of different gas proportions are carried out, methane adsorption-desorption capacity of mixed gas of different proportions under different partial pressures is determined, gas diffusion experiments are carried out to evaluate gas migration capacity in the diffusion process and methane gas partial pressure distribution in a sample, and different experiment results are synthesized to determine the methane gas content of the sample. The desorbed gas content in the coal bed gas diffusion process can be calculated; according to the new method, the proportion of the methane desorption gas amount in the coal bed gas development process can be calculated, and the desorption degree of the adsorbed gas of the coal bed reservoir is evaluated.

The invention discloses an Mg-Ni-Nd hydrogen storage alloy with poison resistance and regeneration performance, the Mg-Ni-Nd hydrogen storage alloy comprises Nd4Mg80Ni8, Mg and Mg2Ni phases at the same time, and after hydrogen absorption and desorption activation, the Mg-Ni-Nd hydrogen storage alloy is decomposed into Mg, Mg2Ni and NdH2.61 phases in situ; the content of Mg is 85-90%, the content of Ni is 6-10%, and the content of Nd is 2-5%. The invention discloses a simulated poisoning treatment and poisoning regeneration method of an Mg-Ni-Nd hydrogen storage alloy. The poisoning atmosphere is mixed gas of CO2 and H2; the regeneration atmosphere is pure H2 atmosphere. When the alloy is used as a hydrogen storage alloy, the maximum hydrogen absorption amount reaches 5.40 wt.%. When the alloy is used as an anti-poisoning hydrogen storage alloy, the cycle index is larger than 300 times, the maximum hydrogen absorption amount is 5.10 wt%, and the CO2 concentration in the poisoning atmosphere condition and the CO2 concentration in the air are the same order of magnitude. When the alloy is used as a renewable hydrogen storage alloy, the maximum hydrogen absorption amount is 5.29 wt.%, and the hydrogen absorption amount is recovered to 97.96% of the initial hydrogen absorption amount.

The invention relates to the technical field of lithium ion batteries, in particular to a carbon source mixed gas CVD coated silicon-carbon negative electrode material, a preparation method and a lithium ion battery. The preparation method comprises the following steps: 1) preparation of a silicon-carbon material: placing porous carbon in equipment, regulating and controlling the gas speed and the dynamic rotation speed of the equipment to uniformly disperse the porous carbon, heating to 380-650 DEG C, and introducing silane mixed gas with the concentration of 5-50% to form the silicon-carbon material; and 2) coating the silicon-carbon material with mixed gas carbon: introducing mixed gas sources with different proportions into equipment, regulating and controlling the gas speed and the dynamic rotation speed of the equipment to uniformly disperse the mixed gas sources, and heating to 450-700 DEG C to realize uniform carbon coating on the surface of the silicon-carbon material. According to the invention, the problem of explosion caused by self-polymerization reaction of single acetylene is solved; and moreover, the uniform carbon coating isolates the side reaction problem caused by direct contact between the electrolyte and the nano silicon, and the stability of the silicon-carbon material is improved.

The invention discloses a process and equipment for producing special melamine by a gas phase quenching method. The production process comprises the following steps: hot process gas from an outlet of a melamine reactor is in contact with cold process gas in a crystallizer, a generated solid A is discharged from the bottom of the crystallizer, and mixed gas enters a trap for gas-solid separation to obtain a solid B; the solid A is conveyed into a high-pressure collecting device A through high-pressure conveying gas A, it is ensured that the temperature of the high-pressure conveying gas A is higher than 120 DEG C in the conveying process, after gas-solid separation is conducted in the high-pressure collecting device A, the solid A is conveyed into a packaging device A through low-pressure conveying gas A, and it is ensured that the temperature of the solid A at the conveying tail end does not exceed 85 DEG C.

The invention relates to the technical field of lithium ion batteries, in particular to a lithium-doped silicon-carbon composite material, a preparation method thereof, a negative plate and a lithium ion battery. The preparation method of the lithium-doped silicon-carbon composite material comprises the following steps: carrying out reduction reaction and activated pore-forming on a mixed material containing a carbon source, an organic pore-forming agent, a lithium supplement agent and a reducing agent to obtain lithium-doped porous carbon; performing first deposition on the lithium-doped porous carbon and mixed gas containing an inorganic lithium compound and an organic lithium compound; carrying out second deposition on the material obtained after the first deposition and silane gas to obtain a lithium compound doped silicon carbon precursor material; and mixing the lithium compound doped silicon carbon precursor material, an organic metal compound, asphalt and an organic solvent, performing spray drying, and then performing carbonization. According to the preparation method, the initial efficiency and the power performance of the silicon-carbon composite material can be improved.

The invention relates to the technical field of silicon carbide single crystal growth, in particular to a high-purity semi-insulating silicon carbide single crystal for an optical element and a growth process thereof.The growth process includes the steps that S1, silicon carbide powder, a graphite crucible and the like are assembled to form a thermal field device, the thermal field device is placed in an induction furnace, room-temperature furnace washing treatment and low-temperature furnace washing treatment are sequentially carried out, and the silicon carbide powder is obtained; carrying out thermal field impurity removal treatment; s2, assembling the silicon carbide seed crystal and the impurity-removed thermal field device, raising the temperature in the induction furnace, conveying high-purity argon or mixed gas of high-purity argon and high-purity hydrogen into the induction furnace, and performing crystal growth; s3, after crystal growth is finished, high-temperature and high-pressure annealing treatment is carried out firstly, then furnace cooling treatment is carried out, and the high-purity semi-insulating silicon carbide crystal ingot for the optical element is obtained. The silicon carbide crystal ingot with excellent light transmission performance and high resistivity is obtained by selecting specific raw materials, reasonably designing an assembly mode and combining processes of thermal field impurity removal, high-temperature and high-pressure annealing and the like.

The invention relates to the technical field of gas detection, and provides a multi-component gas detection method and system.The method comprises the steps that an MEMS-MOS gas sensor array is designed to be composed of a plurality of miniature gas sensing units; each temperature control loop is used for controlling each micro gas sensing unit to maintain the working temperature aiming at the target gas, so that each micro gas sensing unit generates differentiated and complementary dynamic resistance response signals in a mixed gas environment; collecting the resistance change of each micro gas sensing unit in the gas exposure process in real time, and generating a multi-channel digital time sequence data flow; reconstructing the multi-channel digital time sequence data stream into a two-dimensional matrix of channel number * time step; and inputting the two-dimensional matrix into a trained lightweight convolutional neural network model, and outputting gas types and corresponding concentration values contained in the mixed gas. According to the invention, rapid and accurate detection of multi-component gas can be realized in a complex environment, and the sensor has the characteristics of high sensitivity, low power consumption, suitability for portable deployment and the like.

The invention provides an online detection and compensation method for local decarburization of a high-strength spring steel band, which comprises the following steps: arranging an oxygen content sensor in a continuous annealing furnace to monitor oxygen concentration in real time, and marking a potential decarburization risk section; scanning the risk section steel strip by adopting infrared thermal imaging, and generating a carbon distribution map to position a decarburization area; pulse laser heating is conducted on the decarburization area, and methane-argon mixed gas is introduced to achieve in-situ carburization; and finally, local thermal stress is eliminated through high-frequency induction heating. According to the method, decarburization risk dynamic early warning, defect accurate positioning, local efficient carbon supplementation and stress homogenization control are achieved, and the surface quality and fatigue performance of the steel strip are remarkably improved.

The invention provides a method for rapidly preparing an SSZ-13 molecular sieve membrane based on a double-template system, and belongs to the field of preparation and application of molecular sieve membrane materials. The polymer ammonium is introduced into the sol and seed crystal suspension, so that the nucleation and crystallization process in the synthesis system is obviously accelerated, the traditional synthesis time can be shortened by 50% or above, and the rapid growth of the SSZ-13 seed crystal on the surface of the porous carrier is realized. Based on the synergistic effect of the double template agents, the preparation repeatability of the SSZ-13 molecular sieve membrane is effectively improved, and large-scale application of high-quality membrane products is facilitated. The SSZ-13 molecular sieve membrane shows excellent separation performance in CO2 / CH4 mixed gas, and has remarkable industrial application value in the field of natural gas decarburization.

The invention discloses a device and a method for promoting methanation of carbon dioxide through temperature oscillation induced by laser scanning. The device comprises a reactor, a laser and a galvanometer, a transparent cover plate is arranged at the top of the reactor, an air outlet is formed in the side surface, and an objective table is arranged in the reactor; a catalyst layer is arranged above the objective table; the catalyst layer is provided with a longitudinally-penetrating gas leading-in hole, a gas flow channel is arranged in the objective table, one end of the gas flow channel is communicated with the gas leading-in hole, and the other end of the gas flow channel is communicated with the gas inlet. Introducing mixed gas containing hydrogen and carbon dioxide into a gas inlet of the reactor, changing the irradiation position of a laser beam emitted by a laser through a galvanometer, and enabling the laser beam to periodically scan and irradiate the catalyst layer to obtain methane. The surface temperature distribution of the catalyst is dynamically regulated and controlled through laser scanning, so that the temperature of a catalytic active site is continuously switched between a high temperature and a low temperature, the thermodynamic limitation of a carbon dioxide methanation reaction can be effectively reduced, and an efficient and stable carbon dioxide methanation process is realized.

The invention relates to the technical field of semiconductor manufacturing, and discloses a tungsten oxide etching method, a semiconductor structure and a chip, and the method comprises the steps: forming a tungsten oxide thin film on a substrate; forming a mask layer with a target pattern on the tungsten oxide thin film; etching the tungsten oxide thin film with the mask layer by adopting mixed gas in ICP etching equipment; in the ICP etching equipment, the mixed gas comprises trifluoromethane and argon, the ratio range of the trifluoromethane in the mixed gas is 22.5%-74.1%, the flow rate of the mixed gas is 135-155 sccm, the ratio range of ICP power to bias power is 1.53: 1-3.3: 1, the depth-to-width ratio range of the tungsten oxide etching structure is 10: 1-23: 1, the inclination angle of the side wall of the tungsten oxide etching structure is 40-90 degrees, and the width of the tungsten oxide etching structure is 20-30 degrees. The technical problem that it is difficult to achieve a tungsten oxide etching structure with the nanoscale line width and the high aspect ratio in the prior art is solved.

The invention discloses a composite coated silicon-carbon negative electrode material as well as a preparation method and application thereof, and relates to the technical field of lithium ion batteries. The method comprises the following steps of: oxidizing and etching graphite in mixed gas of air and nitrogen at the temperature of between 400 and 500 DEG C to form graphite oxide; the preparation method comprises the following steps: dispersing water-soluble asphalt, graphene, nano silicon, melamine and monoammonium phosphate in water to form a composite liquid; and then mixing the composite liquid with graphite oxide, and then carrying out carbonization treatment. The high-performance silicon-carbon composite negative electrode material is prepared through graphite oxidation etching and a composite coating process, nano silicon is uniformly dispersed in carbon pores which are stably combined on the surface of graphite and have rich mesoporous structures, graphene and a nitrogen-doped carbon layer form a three-dimensional conductive network, and the composite negative electrode material is applied to lithium ion batteries and can be applied to lithium ion batteries. And the lithium ion battery has good low-temperature charging proportion, first efficiency and cycle performance.