The invention discloses a treatment method of an organic
silicon low-boiling-point substance and particularly relates to a method of treating an organic
silicon low-boiling-point substance by utilizing reverse dropwise adding of concentrated
hydrochloric acid. The method comprises the following steps: a, adding the organic
silicon low-boiling-point substance into a reaction kettle with a filled column and stirring, and then, dropwise adding concentrated
hydrochloric acid from the middle part of the filled column while stirring to carry out reaction; 1.5-1 hour after dropwise adding the concentrated
hydrochloric acid, heating a
reaction system to 40 DEG C-50 DEG C to continuously react for 1-2 hours; b, ventilating
tail gas generated by reaction into a hydrochloric acid absorbing device, an organic absorbing device and a
tetramethylsilane condensing and recycling device in sequence; c, after the reaction in the step a is finished, standing for a certain time, and discharging the hydrochloric acid from the reaction kettle; and d, heating the reaction kettle, keeping the temperature in the kettle at 60 DEG C-70 DEG C for carrying out
distillation to obtain
tetramethylsilane. According to the treatment method disclosed by the invention, three products of the
tetramethylsilane, the hydrochloric acid and
hydrolysate can be obtained, so that a novel method is provided for treating the organic silicon low-boiling-point substance.